Publication number: 20240228864
Abstract: The present invention discloses a novel high-temperature visual acid etching test device and method; the test device includes a visual rock slab holder, an acid solution storage tank I, an acid solution storage tank II, a heating apparatus, a high-pressure water pump, a low-pressure acid pump, a back-pressure valve, an acid valve A, an acid valve B, an acid valve C, an acid valve D, an acid valve E, an acid valve F, a water valve G, a water valve H, a water valve I, a water valve J, and a water valve K; both the acid solution storage tank I and the acid solution storage tank II are provided with a piston therein, where the acid solution storage tank is divided into upper and lower independent parts by the piston. According to the present invention, the flowing process of an acid solution in a fracture can be directly observed to accurately characterize the distribution of the acid solution in the fracture, which facilitates a study on an acid etching mechanism.
Type:
Application
Filed:
January 3, 2024
Publication date:
July 11, 2024
Applicant:
Southwest Petroleum University
Inventors:
Kun WANG, Shouxin WANG, Jianchun GUO, Chi CHEN, Tao ZHANG, Xiang BAI, Xinghao GOU, Jichuan REN, Cong LU, Bo GOU, Jie LAI
Patent number: 11981616
Abstract: A method for preparing 3,3?-diaminobenzidine, the method comprising the following steps: subjecting 4,4?-biphenol and N,N-dimethylsulfamoyl chloride to an esterification reaction in a specified solvent at 40-70° C. to obtain 4,4?-biphenyl bis(N,N-dimethylaminosulfonate) as a first intermediate; subjecting the 4,4?-biphenyl bis(N,N-dimethylaminosulfonate) to a chlorination reaction with a chlorinating reagent under acidic conditions to obtain 3,3?-dichloro-4,4?-biphenyl bis(N,N-dimethylaminosulfonate) as a second intermediate; subjecting the second intermediate 3,3?-dichloro-4,4?-biphenyl bis(N,N-dimethylaminosulfonate) to an ammonolysis reaction with anammoniation reagent in the presence of a combined catalyst to obtain a crude product of 3,3?,4,4?-tetraaminobiphenyl, wherein the combined catalyst is a mixture of proline, a cuprous salt and a phase transfer catalyst; and subjecting the crude product of 3,3?,4,4?-tetraaminobiphenyl to a post-treatment to obtain a purified 3,3?,4,4?-tetraaminobiphenyl product.
Type:
Grant
Filed:
January 12, 2022
Date of Patent:
May 14, 2024
Assignees:
Hubei Huida High-Tech Co., Ltd, Borun High-Tech Co., Ltd.
Inventors:
Yun Ling, Yongfang Li, Kun Wang, Lizhu Chen, Wei Yin, Jinying Zhang