Patents by Inventor Lea Di Cioccio

Lea Di Cioccio has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11380648
    Abstract: The invention concerns a support intended for the implementation of a method of self-assembly of at least one element on a surface of the support, including at least one assembly pad on said surface, a liquid drop having a static angle of contact on the assembly pad smaller than or equal to 15°, and nanometer- or micrometer-range pillars on said surface around the pad, the liquid drop having a static angle of contact on the pillars greater than or equal to 150°.
    Type: Grant
    Filed: November 3, 2017
    Date of Patent: July 5, 2022
    Assignee: Commissariat à l'Energie Atomique et aux Energies Alternatives
    Inventors: Léa Di Cioccio, Jean Berthier, Nicolas Posseme
  • Patent number: 11305372
    Abstract: Method of assembly of a first element (I) and a second element (II) each having an assembly surface, at least one of the assembly surfaces comprising recessed metal portions (6, 106) surrounded by dielectric materials (4, 104) comprising: A) a step to bring the two assembly surfaces into contact without application of pressure such that direct bonding is obtained between the assembly surfaces, said first and second assemblies (I, II) forming a stack with a given thickness (e), B) a heat treatment step of said stack during which the back faces (10, 110) of the first (I) and the second (II) elements are held in position so that they are held at a fixed distance (E) between the given stack thickness+/?2 nm.
    Type: Grant
    Filed: October 2, 2014
    Date of Patent: April 19, 2022
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Lea Di Cioccio, Yann Beilliard
  • Patent number: 11121117
    Abstract: A method for self-assembling microelectronic components includes providing a self-aligning substrate having protrusions, each having a thickness greater than 1 ?m and an upper face and flanks, the upper face and the flanks being hydrophobic. The method also includes providing dies, each die having a first face and a second hydrophilic face, and providing a self-assembling substrate. Finally, the method includes obtaining, by capillary effect, the self-alignment of each die through the first face thereof on a protrusion of the self-aligning substrate, then obtaining the assembly of the dies through the second hydrophilic face thereof on the self-assembling substrate by direct adhesion. Such a method has application in the industrial production of 3D integrated circuits.
    Type: Grant
    Filed: March 7, 2018
    Date of Patent: September 14, 2021
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventor: Lea Di Cioccio
  • Patent number: 10910782
    Abstract: A method for bonding a first surface provided with at least one copper area surrounded by a silicon oxide area to a second surface includes an operation of treatment of the first surface by a plasma, before placing the first surface in contact with the second surface. The plasma is formed from a gas source containing a silicon oxide nitriding agent and a copper oxide reducing agent containing hydrogen. The gas source may include an N2 and NH3 and/or H2 gas mixture or a N2O and H2 gas mixture, or ammonia, which is then used both as a nitriding agent and as a reducing agent. The plasma obtained from this gas source then necessarily contains nitrogen and hydrogen, which enables, in a single operation, to provide a high-performance bonding between the first and second surfaces.
    Type: Grant
    Filed: August 31, 2011
    Date of Patent: February 2, 2021
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Laurent Vandroux, Léa Di Cioccio, Pierric Gueguen
  • Publication number: 20200020665
    Abstract: A method for self-assembling microelectronic components includes providing a self-aligning substrate having protrusions, each having a thickness greater than 1 ?m and an upper face and flanks, the upper face and the flanks being hydrophobic. The method also includes providing dies, each die having a first face and a second hydrophilic face, and providing a self-assembling substrate. Finally, the method includes obtaining, by capillary effect, the self-alignment of each die through the first face thereof on a protrusion of the self-aligning substrate, then obtaining the assembly of the dies through the second hydrophilic face thereof on the self-assembling substrate by direct adhesion. Such a method has application in the industrial production of 3D integrated circuits.
    Type: Application
    Filed: March 7, 2018
    Publication date: January 16, 2020
    Applicant: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventor: Lea DI CIOCCIO
  • Publication number: 20190259729
    Abstract: The invention concerns a support intended for the implementation of a method of self-assembly of at least one element on a surface of the support, including at least one assembly pad on said surface, a liquid drop having a static angle of contact on the assembly pad smaller than or equal to 15°, and nanometer- or micrometer-range pillars on said surface around the pad, the liquid drop having a static angle of contact on the pillars greater than or equal to 150°.
    Type: Application
    Filed: November 3, 2017
    Publication date: August 22, 2019
    Inventors: Léa DI CIOCCIO, Jean BERTHIER, Nicolas POSSEME
  • Publication number: 20180301433
    Abstract: A method of manufacturing an emissive LED display device, including the steps of forming a plurality of chips, each including at least one LED and, on a connection surface, a plurality of hydrophilic electric connection areas and a hydrophobic area; forming a transfer substrate including, for each chip, a plurality of hydrophilic electric connection areas and a hydrophobic area; arranging a drop of a liquid on each electric connection area of the transfer substrate and/or of each chip; and affixing the chips to the transfer substrate by direct bonding, using the capillary restoring force of the drops to align the electric connection areas of the chips with the electric connection areas of the transfer substrate.
    Type: Application
    Filed: April 10, 2018
    Publication date: October 18, 2018
    Applicant: Commissariat à l'Énergie Atomique et aux Énergies Alternatives
    Inventors: Ivan-Christophe Robin, Jean Berthier, Séverine Cheramy, Léa Di Cioccio
  • Patent number: 10020283
    Abstract: Method including the steps of a) Providing a first stack including a first substrate on which is deposited a first metal layer including a first metal, and a first solubilization layer distinct from the first metal layer, the first solubilization layer including a first getter material configured to solubilize the oxygen, b) Providing a second stack including a second substrate on which is deposited a second metal layer including a second metal, c) Contacting the first metal layer and the second metal layer so as to obtain a direct metal bonding between the first metal layer and the second metal layer, and d) Applying a heat treatment for annealing the bonding.
    Type: Grant
    Filed: June 2, 2014
    Date of Patent: July 10, 2018
    Assignee: COMMISSARIAT À L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Floriane Baudin, Léa Di Cioccio
  • Patent number: 9620412
    Abstract: A method for modifying crystalline structure of a copper element with a planar surface, including: a) producing a copper standard having large grains, wherein the standard includes a planar surface, b) reducing roughness of the planar surfaces to a roughness of less than 1 nm, c) cleaning the planar surfaces, d) bringing the two planar surfaces into contact, and e) annealing.
    Type: Grant
    Filed: July 1, 2010
    Date of Patent: April 11, 2017
    Assignees: Commissariat à l'énergie atomique et aux énergies alternatives, STMICROELECTRONICS (CROLLES 2) SAS
    Inventors: Lea Di Cioccio, Pierric Gueguen, Maurice Rivoire
  • Patent number: 9586207
    Abstract: A method for capillary self-assembly of a plate and a carrier, including: forming an etching mask on a region of a substrate; reactive-ion etching the substrate, the etching using a series of cycles each including isotropic etching followed by surface passivation, wherein a duration of the isotropic etching for each cycle increases from one cycle to another, a ratio between durations of the passivation and etching of each cycle is lower than a ratio for carrying out a vertical anisotropic etching to form a carrier having an upper surface defined by the region and side walls defining an acute angle with the upper surface; removing the etching mask; placing a droplet on the upper surface of the carrier; and placing the plate on the droplet.
    Type: Grant
    Filed: July 8, 2014
    Date of Patent: March 7, 2017
    Assignees: Commissariat à l'énergie atomique et aux énergies alternatives, STMicroelectronics (Crolles 2) SAS
    Inventors: Sebastien Mermoz, Lea Di Cioccio, Thomas Magis, Loic Sanchez
  • Patent number: 9522450
    Abstract: A support is provided, including a reception zone in which the external envelope matches the shape of a plate configured to be placed on a droplet deposited at least in the reception zone in order to achieve capillary self-assembly of the plate and the support, and at least one pair of tracks that extend on the support from the reception zone and that have a lyophilic-type affinity with the droplet such that an overflow of the droplet beyond the reception zone is guided in the tracks, wherein the at least one pair of tracks includes a first track and a second track that do not have the same lyophilic-type degree of affinity with the droplet.
    Type: Grant
    Filed: March 21, 2014
    Date of Patent: December 20, 2016
    Assignees: Commissariat a' l'energie atomique et aux energies alternatives, STMICROELECTRONICS (CROLLES 2) SAS
    Inventors: Jean Berthier, Lea Di Cioccio, Sebastien Mermoz
  • Patent number: 9431373
    Abstract: A three-dimensional integrated structure may include two assembled integrated circuits respectively including two metallic lines, and at least two cavities passing through one of the integrated circuits and opening onto two locations respectively in electrical contact with the two metallic lines. The cavities may be sized to place a measuring apparatus at the bottom of the cavities, and in electrical contact with the two locations.
    Type: Grant
    Filed: December 16, 2014
    Date of Patent: August 30, 2016
    Assignees: STMICROELECTRONICS SA, STMICROELECTRONICS (CROLLES 2) SAS
    Inventors: Rachid Taibi, Cédrick Chappaz, Lea Di Cioccio, Laurent-Luc Chapelon
  • Publication number: 20160144365
    Abstract: A method for capillary self-assembly of a plate and a carrier, including: forming an etching mask on a region of a substrate; reactive-ion etching the substrate, the etching using a series of cycles each including isotropic etching followed by surface passivation, wherein a duration of the isotropic etching for each cycle increases from one cycle to another, a ratio between durations of the passivation and etching of each cycle is lower than a ratio for carrying out a vertical anisotropic etching to form a carrier having an upper surface defined by the region and side walls defining an acute angle with the upper surface; removing the etching mask; placing a droplet on the upper surface of the carrier; and placing the plate on the droplet.
    Type: Application
    Filed: July 8, 2014
    Publication date: May 26, 2016
    Applicant: Commissariat A L'energie Atomique et Aux Energies Alternatives
    Inventors: Sebastien MERMOZ, Lea DI CIOCCIO, Thomas MAGIS, Loic SANCHEZ
  • Publication number: 20160133598
    Abstract: Method including the steps of a) Providing a first stack including a first substrate on which is deposited a first metal layer including a first metal, and a first solubilization layer distinct from the first metal layer, the first solubilization layer including a first getter material configured to solubilize the oxygen, b) Providing a second stack including a second substrate on which is deposited a second metal layer including a second metal, c) Contacting the first metal layer and the second metal layer so as to obtain a direct metal bonding between the first metal layer and the second metal layer, and d) Applying a heat treatment for annealing the bonding.
    Type: Application
    Filed: June 2, 2014
    Publication date: May 12, 2016
    Applicant: Commissariat A L'Energie Atomique et Aux Energies Alternatives
    Inventors: Floriane BAUDIN, Léa DI CIOCCIO
  • Patent number: 9318527
    Abstract: A method for producing at least one photosensitive infrared detector by assembling a first electronic component including plural photodiodes sensitive to infrared radiation and a second electronic component including at least one electronic circuit for reading the plurality of photodiodes, an infrared detector, and an assembly for producing such a detector, the method including: production, on each one of the first and second components, of a connection face formed at least partially by a silicon oxide (SiO2)-based layer; bonding the first component and the second component by the connection faces thereof, thus performing the direct bonding of the two components. The method can simplify hybridization of heterogeneous components for producing an infrared detector.
    Type: Grant
    Filed: May 6, 2013
    Date of Patent: April 19, 2016
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Stephanie Huet, Abdenacer Ait-Mani, Lea Di Cioccio
  • Patent number: 9240389
    Abstract: A method for producing at least one pad assembly (32, 50) on a support (19, 43) for use in a method for self-assembling at least one element (10) on the support (19, 43), comprises fanning, on the support (19, 43), a layer (28, 48) of at least one fluorinated material around the location (30, 44) of the pad assembly (32, 50), the layer (28, 48) having a thickness greater than 10 nm. The layer (28, 48) and the location (30, 44) are exposed to an ultraviolet treatment in the presence of ozone to form the pad assembly (32, 50) at said location (30, 44), wherein a drop of liquid (16) having a static contact angle on the pad assembly (32, 50) less than or equal to 15°, after the exposure to the ultraviolet treatment, has a static contact angle on the layer (28, 48) greater than or equal to 100°.
    Type: Grant
    Filed: March 20, 2013
    Date of Patent: January 19, 2016
    Assignees: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, STMICROELECTRONICS (CROLLES2) SAS
    Inventors: Léa Di Cioccio, Sébastien Mermoz, Loïc Sanchez
  • Publication number: 20150287695
    Abstract: A method for producing at least one pad assembly (32, 50) on a support (19, 43) for use in a method for self-assembling at least one element (10) on the support (19, 43), comprises fanning, on the support (19, 43), a layer (28, 48) of at least one fluorinated material around the location (30, 44) of the pad assembly (32, 50), the layer (28, 48) having a thickness greater than 10 nm. The layer (28, 48) and the location (30, 44) are exposed to an ultraviolet treatment in the presence of ozone to form the pad assembly (32, 50) at said location (30, 44), wherein a drop of liquid (16) having a static contact angle on the pad assembly (32, 50) less than or equal to 15°, after the exposure to the ultraviolet treatment, has a static contact angle on the layer (28, 48) greater than or equal to 100°.
    Type: Application
    Filed: March 20, 2013
    Publication date: October 8, 2015
    Inventors: Léa Di Cioccio, Sébastien Mermoz, Loïc Sanchez
  • Patent number: 9064783
    Abstract: A direct bonding method between at least a first layer (104) comprising silicon oxide having a thickness equal to or higher than about 10 nm and a second layer (108) of material having hydrophilicity, comprising at least the steps of: making the first layer (104) on a first substrate (102) such that the absorbance value of this first layer (104), at a vibration frequency of silanol bonds present in the first layer (104) equal to about 3660 cm?1, is equal to or higher than about 1.5×10?5 nm?1, the silanol bonds being formed in at least part of the thickness of the first layer (104) which is equal to or higher than about 10 nm; direct bonding between the first layer (104) and the second layer (108).
    Type: Grant
    Filed: October 24, 2012
    Date of Patent: June 23, 2015
    Assignee: Commissariat à l'énergie atomique et aux énergies alternatives
    Inventors: Chiara Sabbione, Lea Di Cioccio, Jean-Pierre Nieto, Laurent Vandroux
  • Patent number: 9064863
    Abstract: To avoid problems of hydrolysis of the silicon oxide formed by PECVD at the surface of at least one wafer, it is proposed to cover, in the vacuum deposition chamber used to deposit the silicon oxide, said oxide with a temporary protective layer containing nitrogen. The protective layer thus protects the silicon oxide against the outer environment and especially against humidity when the wafer provided with the silicon oxide is stored outside of the vacuum deposition chamber. Afterwards, the protective layer is removed, for example, by chemical-mechanical. polishing, just before the two wafers are placed into contact. The protective layer may be formed by a PECVD silicon nitride deposition, by plasma nitriding or nitrogen doping of a superficial portion of the silicon oxide.
    Type: Grant
    Filed: August 31, 2011
    Date of Patent: June 23, 2015
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Léa Di Cioccio, Laurent Vandroux
  • Publication number: 20150137330
    Abstract: A three-dimensional integrated structure may include two assembled integrated circuits respectively including two metallic lines, and at least two cavities passing through one of the integrated circuits and opening onto two locations respectively in electrical contact with the two metallic lines. The cavities may be sized to place a measuring apparatus at the bottom of the cavities, and in electrical contact with the two locations.
    Type: Application
    Filed: December 16, 2014
    Publication date: May 21, 2015
    Inventors: Rachid TAIBI, Cédrick CHAPPAZ, Lea DI CIOCCIO, Laurent-Luc CHAPELON