Abstract: Compounds and method of preparation of Si—X and Ge—X compounds (X=N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X=N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si-containing films.

Abstract: According to an example embodiment, a method of making a phosphoric acid fuel cell component includes situating at least one polymer film layer against a permeable component layer. The polymer film layer comprises a polymer that is chemically resistant to phosphoric acid. The polymer film layer is melted. The permeable component layer is impregnated with the melted polymer to thereby establish a region on the component layer that is impermeable to phosphoric acid. The impregnated region also provides a seal against reactant leakage from the component.

Abstract: According to an example embodiment, a method of making a fuel cell component includes permeating at least a portion of a component layer with a polymer. The portion of the component layer is adjacent an edge of the component layer. Some of the polymer is allowed to extend beyond the edge to thereby establish a flap beyond the edge of the component layer. A fuel cell component includes a component layer having a portion adjacent an edge of the layer that is impregnated with a polymer material and a flap of the polymer material extending beyond the edge.

Abstract: Halogen free amine substituted trisilylamine and tridisilylamine compounds and a method of their preparation via dehydrogenative coupling between the corresponding unsubstituted trisilylames and amines catalyzed by transition metal catalysts is described. This new approach is based on the catalytic dehydrocoupling of a Si—H and a N—H moiety to form an Si—N containing compound and hydrogen gas. The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—N containing products are halide free. Such compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si containing films.

Abstract: Methods of synthesizing Si—H containing iodosilanes, such as diiodosilane or pentaiododisilane, using a halide exchange reaction are disclosed.

Abstract: Compounds and method of preparation of Si—X and Ge—X compounds (X?N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X?N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si-containing films.

Abstract: Solid or liquid N—H free, C-free, and Si-rich perhydropolysilazane compositions comprising units having the following formula [—N(SiH3)x(SiH2-)y], wherein x=0, 1, or 2 and y=0, 1, or 2 when x+y=2; and x=0, 1 or 2 and y=1, 2, or 3 when x+y=3 are disclosed. Also disclosed are synthesis methods and applications for the same.

Abstract: Mono-substituted TSA precursor Si-containing film forming compositions are disclosed. The precursors have the formula: (SiH3)2N—SiH2—X, wherein X is selected from a halogen atom; an isocyanato group; an amino group; an N-containing C4-C10 saturated or unsaturated heterocycle; or an alkoxy group. Methods for forming the Si-containing film using the disclosed mono-substituted TSA precursor are also disclosed.

Abstract: Disclosed are Si—C free and volatile silazane precursors for high purity thin film deposition.

Abstract: Mono-substituted TSA precursor Si-containing film forming compositions are disclosed. The precursors have the formula: (SiH3)2N—SiH2—X, wherein X is selected from a halogen atom; an isocyanato group; an amino group; an N-containing C4-C10 saturated or unsaturated heterocycle; or an alkoxy group. Methods for forming the Si-containing film using the disclosed mono-substituted TSA precursor are also disclosed.

Abstract: The fuel cell (100) includes an oxidant flow plate (212), an adjacent cathode substrate layer (216) having a cathode catalyst (222), a matrix (224) for retaining a liquid electrolyte (230), wherein the matrix (224) is secured adjacent and between the cathode catalyst (222) and an anode catalyst (232). A first anode substrate (102) is secured adjacent the anode catalyst (232), and at least a second duplicate anode substrate layer (108) is secured adjacent the first anode substrate layer (102) for providing greater pore volume for storage of the liquid electrolyte (230) and to limit obstruction of the pore volume of the anode substrates (102, 108). The duplicate anode substrate layer (108) may be partially filled with the liquid electrolyte (230) at the beginning of life of the fuel cell (100).

Abstract: A quickly releasable vest capable of protecting a torso portion of a user is disclosed. The quickly releasable vest includes a self locking buckle assembly, a ferrule, an elongated strip, and a socket member. The self locking buckle assembly comprises a wedge fork with a base portion and a body portion, the base portion comprising a security means for webbing and the body portion comprising a pair of legs and a ferrule guide member. The ferrule is adapted to be slidingly disposed on the ferrule guide member. A proximal end portion of the strip is connected to a tape guide member of the ferrule. An opening on the socket member facilitates removably retaining and locking of a prong on each of the pair of legs. The wedge fork, ferrule, and elongated strip Is disposed on a torso panel and the socket member is disposed on the other torso panel.

Abstract: A quickly releasable vest capable of protecting a torso portion of a user is disclosed. The quickly releasable vest includes a self locking buckle assembly, a ferrule, an elongated strip, and a socket member. The self locking buckle assembly comprises a wedge fork with a base portion and a body portion, the base portion comprising a security means for webbing and the body portion comprising a pair of legs and a ferrule guide member. The ferrule is adapted to be slidingly disposed on the ferrule guide member. A proximal end portion of the strip is connected to a tape guide member of the ferrule. An opening on the socket member facilitates removably retaining and locking of a prong on each of the pair of legs. The wedge fork, ferrule, and elongated strip Is disposed on a torso panel and the socket member is disposed on the other torso panel.

Abstract: Compounds and method of preparation of Si—X and Ge—X compounds (X?N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X?N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si-containing films.

Abstract: A trauma resistant anti ballistic helmet (TRABH) is disclosed. The trauma resistant anti ballistic helmet includes a shell, at least one first Back Face Deformation Shield (BFDS), a ballistic fabric sheet and at least one second Back Face Deformation Shield (BFDS). The shell is composed of a plurality of helmet pre-forms. The at least one first Back Face Deformation Shield (BFDS) is disposed on at least one of an operative front portion, an operative rear portion and at least a portion of a periphery of said shell. The anti ballistic fabric sheet is disposed over the at least one first BFDS covering at least a portion the shell. The at least one second Back Face Deformation Shield (BFDS) is disposed over the ballistic resistant sheet on at least one of an operative front portion, an operative rear portion and at least a portion of the periphery of the shell.

Abstract: The fuel cell (100) includes an oxidant flow plate (212), an adjacent cathode substrate layer (216) having a cathode catalyst (222), a matrix (224) for retaining a liquid electrolyte (230), wherein the matrix (224) is secured adjacent and between the cathode catalyst (222) and an anode catalyst (232). A first anode substrate (102) is secured adjacent the anode catalyst (232), and at least a second duplicate anode substrate layer (108) is secured adjacent the first anode substrate layer (102) for providing greater pore volume for storage of the liquid electrolyte (230) and to limit obstruction of the pore volume of the anode substrates (102, 108). The duplicate anode substrate layer (108) may be partially filled with the liquid electrolyte (230) at the beginning of life of the fuel cell (100).

Abstract: According to an example embodiment, a fuel cell component manufacturing assembly includes a support member that is configured to be situated adjacent the fuel cell component to provide support for the component. The support member has a perimeter corresponding to a perimeter of the component. A platen member has a configuration corresponding to at least a portion of the support member for being received against a portion of the component. A temperature of the platen member is controllable to achieve a desired temperature of a material situated adjacent the platen member. The platen member has a surface area that is less than a surface area of the component such that only the portion of the component is subject to pressure resulting from a force urging the platen member and the support member together with the component between the support member and the platen member.

Abstract: Mono-substituted TSA precursor Si-containing film forming compositions are disclosed. The precursors have the formula: (SiH3)2N—SiH2—X, wherein X is selected from a halogen atom; an isocyanato group; an amino group; an N-containing C4-C10 saturated or unsaturated heterocycle; or an alkoxy group. Methods for forming the Si-containing film using the disclosed mono-substituted TSA precursor are also disclosed.

Abstract: According to an example embodiment, a method of making a phosphoric acid fuel cell component includes situating at least one polymer film layer against a permeable component layer. The polymer film layer comprises a polymer that is chemically resistant to phosphoric acid. The polymer film layer is melted. The permeable component layer is impregnated with the melted polymer to thereby establish a region on the component layer that is impermeable to phosphoric acid. The impregnated region also provides a seal against reactant leakage from the component.

Abstract: According to an example embodiment, a method of making a fuel cell component includes permeating at least a portion of a component layer with a polymer. The portion of the component layer is adjacent an edge of the component layer. Some of the polymer is allowed to extend beyond the edge to thereby establish a flap beyond the edge of the component layer. A fuel cell component includes a component layer having a portion adjacent an edge of the layer that is impregnated with a polymer material and a flap of the polymer material extending beyond the edge.