Patents by Inventor Mark A. Sprecker

Mark A. Sprecker has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4576741
    Abstract: Described in an isomer-directed process for producing asymmetric ketones defined according to the generic structure: ##STR1## wherein one of Z.sub.1 or Z.sub.2 is the moiety: ##STR2## and the other of Z.sub.1 or Z.sub.2 is hydrogen; wherein R.sub.11 and R.sub.21 represent hydrogen or the same or different alkyl or alkenyl with the proviso that R.sub.11 and R.sub.21 are not both hydrogen or wherein R.sub.11 and R.sub.21 taken together:(i) complete a cycloalkyl, cycloalkenyl, bicycloalkyl, mono or polyalkyl cycloalkyl or mono or polyalkyl cycloalkenyl ring, or(ii) represent alkylidene, cycloalkenyl alkylidene, aralkylidene, mono or polyalkyl cycloalkenyl alkylidene or mono or polyalkyl aralkylidene;and wherein R.sub.6, R.sub.7 and R.sub.
    Type: Grant
    Filed: November 14, 1984
    Date of Patent: March 18, 1986
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Robert P. Belko, William L. Schreiber, Michael Licciardello
  • Patent number: 4572796
    Abstract: Described is a process for producing 1,1,4,7-tetramethyl-3-indanone defined according to the structure: ##STR1## the 1,1,4,7-tetramethyl-3-indanone per se and organoleptic uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles and colognes.
    Type: Grant
    Filed: November 14, 1984
    Date of Patent: February 25, 1986
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Augustinus G. van Loveren, Mark A. Sprecker, Patrick Whelan, Marie R. Hanna
  • Patent number: 4569771
    Abstract: Described is a process for augmenting or enhancing the aroma of a drier-added fabric softener article or solid or liquid anionic, cationic, nonionic or zwitterionic detergent comprising the step of adding to the fabric softener article or detergent a composition of matter comprising a compound having the structure: ##STR1## wherein R is methyl or ethyl and intimately admixed therewith a compound selected from the group consisting of:(a) a compound having the structure: ##STR2## (b) 3-methyl-1-phenyl-pentanol-5; and (c) at least one butanoyl cyclohexane derivative defined according to the structure: ##STR3## wherein one or two of the dashed lines represent carbon-carbon double bond and the other of the dashed lines represent carbon-carbon single bonds with the proviso that when the dashed lines represent two carbon-carbon double bonds, said carbon-carbon double bonds are conjugated.
    Type: Grant
    Filed: December 21, 1984
    Date of Patent: February 11, 1986
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Wilhelmus J. Wiegers, Mark A. Sprecker
  • Patent number: 4554096
    Abstract: Described is a method for producing the compound defined according to the structure: ##STR1## as well as optical isomers thereof having the structures: ##STR2## as well as uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles such as perfumed polymers and solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions and fabric softener articles. Also described are processes and compositions for use in perfume aroma augmenting, enhancing, modifying and altering compositions and as perfume, cologne and perfumed article aroma imparting compositions of mixtures of the compound having the structure: ##STR3## taken further together with one or more butanoyl cyclohexane derivatives and/or 3-methyl-1-phenyl-pentanol-5. The processfor preparing the compound having the structure: ##STR4## involves a one-step reaction wherein the compound having the structure: ##STR5## is hydrogenated in the presence of acid.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: November 19, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Wilhelmus J. Wiegers, Mark A. Sprecker
  • Patent number: 4549983
    Abstract: Described is a method for producing the substantially pure compound defined according to the structure: ##STR1## and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles such as perfumed polymers and solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions and fabric softener articles. Also described are processes and compositions for use in perfume aroma augmenting, enhancing, modifying and altering compositions and as perfume, cologne and perfumed article aroma imparting compositions of mixtures of the compound having the structure: ##STR2## taken further together with one or more butanolyl cyclohexane derivatives and/or 3-methyl-1-phenyl-pentanol-5.The process for preparing the compound having the structure: ##STR3## involves a one-step reaction wherein the compound having the structure: ##STR4## is hydrogenated in the presence of acid.
    Type: Grant
    Filed: March 14, 1984
    Date of Patent: October 29, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Wilhelmus J. Wiegers, Mark A. Sprecker
  • Patent number: 4549982
    Abstract: Described are 1-oxoalkyl-2-isopropylnorbornane derivatives defined according to the generic structure: ##STR1## wherein X represents a moiety selected from the group consisting of: ##STR2## wherein the dashed line represents a carbon-carbon double bond or a carbon-carbon single bond and wherein R.sub.1 and R.sub.2 represent hydrogen or methyl with the proviso that R.sub.1 and R.sub.2 are not both methyl, and uses thereof in augmenting or enhancing the aroma of consumable materials selected from the group consisting of perfume compositions, colognes and perfumed articles. Also described are processes for preparing said 1-oxoalkyl-2-isopropylnorbornane derivatives by means of a low temperature catalytic Diels Alder reaction or high temperature thermal Diels Alder reaction between a bicyclopentadiene derivative and 2-methyl-3- buten-5-one according to the reaction: ##STR3## wherein R represents methyl or hydrogen.
    Type: Grant
    Filed: August 24, 1984
    Date of Patent: October 29, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: John B. Hall, Mark A. Sprecker, Robert P. Belko, Augustinus G. Van Loveren, Marie R. Hanna
  • Patent number: 4548743
    Abstract: Described is the compound having the structure ##STR1## useful in perfumery.
    Type: Grant
    Filed: April 20, 1984
    Date of Patent: October 22, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Robert P. Belko, William L. Schreiber, Michael Licciardello
  • Patent number: 4546208
    Abstract: Described is a method for producing the compound defined according to the structure: ##STR1## as well as optical isomers thereof having the structures: ##STR2## as well as uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles such as perfumed polymers and solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions and fabric softener articles. Also described are processes and compositions for use in perfume aroma augmenting, enhancing, modifying and altering compositions and as perfume, cologne and perfumed article aroma imparting compositions of mixtures of the compound having the structure: ##STR3## taken further together with one or more butanoyl cyclohexane derivatives and/or 3-methyl-1-phenyl-pentanol-5. The process for preparing the compound having the structure: ##STR4## involves a one-step reaction wherein the compound having the structure: ##STR5## is hydrogenated in the presence of acid.
    Type: Grant
    Filed: March 14, 1984
    Date of Patent: October 8, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Wilhelmus J. Wiegers, Mark A. Sprecker
  • Patent number: 4541951
    Abstract: Described is a process for preparing the compound having the structure: ##STR1## comprising the steps of reacting 1-acetyl-3,3-dimethylcyclohexane having the structure: ##STR2## with an alkyl acetate defined according to the structure: ##STR3## wherein R.sub.2 is C.sub.1 -C.sub.5 alkyl such as methylethyl, n-propyl, i-propyl, n-butyl, 2-butyl and tertiary butyl, thereby forming a diketone having the structure: ##STR4## reacting the said diketone with an allyl halide having the structure: ##STR5## (wherein X represents bromo or iodo) to form a substituted diketone having the structure: ##STR6## and then transforming the compound having the structure: ##STR7## into the compound having the structure: ##STR8## by means of a retro-Claisen reaction.
    Type: Grant
    Filed: September 14, 1984
    Date of Patent: September 17, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: John B. Hall, Mark A. Sprecker
  • Patent number: 4541949
    Abstract: Described is the composition of matter defined according to the structure: ##STR1## as well as components of such composition having the structures: ##STR2## and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles.
    Type: Grant
    Filed: September 1, 1983
    Date of Patent: September 17, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, William L. Schreiber, Futoshi Fujioka, Richard M. Boden, Manfred H. Vock, Patrick Whelan, Marie R. Hanna
  • Patent number: 4537704
    Abstract: Described are para-carboalkoxy cyclohexanones defined according to the structure: ##STR1## wherein R.sub.1 represents hydrogen or C.sub.1 -C.sub.7 alkyl and R.sub.2 represents methyl or ethyl and uses thereof in augmenting or enhancing the aroma of consumable materials including foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, perfume compositions, colognes and perfumed articles (e.g., solid or liquid anionic, cationic, nonionic or zwitterionic detergents, cosmetic compositions, fabric softener compositions, fabric softener articles, hair preparations and perfumed polymers. The compounds defined according to the structure: ##STR2## wherein R.sub.1 ' represents C.sub.4 -C.sub.7 alkyl and R.sub.2 represents methyl or ethyl are novel compounds.
    Type: Grant
    Filed: December 21, 1983
    Date of Patent: August 27, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Wilhelmus J. Wiegers, Robert P. Belko, Richard M. Boden
  • Patent number: 4534890
    Abstract: Described is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1 represents hydrogen or C.sub.2 -C.sub.4 acyl and R.sub.2 represents C.sub.1 -C.sub.3 alkyl and uses thereof in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, colognes, perfumed articles (e.g., solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations, cosmetic powders and the like), foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobacco products and smoking tobacco articles.
    Type: Grant
    Filed: January 12, 1984
    Date of Patent: August 13, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Wilhelmus J. Wiegers, Robert P. Belko, Richard M. Boden
  • Patent number: 4532357
    Abstract: Described is a process for producing 1,1-dimethyl-3-indanones defined according to the structure: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and each represents hydrogen or methyl with the proviso that at least one of R.sub.1 and R.sub.2 methyl, products produced thereby and organoleptic uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles and colognes.
    Type: Grant
    Filed: May 24, 1984
    Date of Patent: July 30, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Augustinus G. van Loveren, Mark A. Sprecker, Patrick Whelan, Marie R. Hanna
  • Patent number: 4532050
    Abstract: Described is a genus of compounds defined according to the structure: ##STR1## hereinafter termed "norbornyl esters" wherein R.sub.1, R.sub.2 and R.sub.3 represent methyl or hydrogen with the proviso that at least one of R.sub.1, R.sub.2 and R.sub.3 is hydrogen as well as uses thereof in augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfume compositions, colognes and perfumed articles (including, but not limited to, solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations and perfumed polymers). Also described is a novel process for preparing such norbornyl esters.
    Type: Grant
    Filed: August 24, 1984
    Date of Patent: July 30, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventor: Mark A. Sprecker
  • Patent number: 4524021
    Abstract: Described is a method for producing the compounds described according to the structure: ##STR1## wherein R represents ethyl or methyl as well as optical isomers thereof having the structures: ##STR2## wherein R represents methyl or ethyl, as well as uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles such as perfumed polymers and solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions and fabric softener articles. Also described are processes and compositions for use in perfume aroma augmenting, enhancing, modifying and altering compositions and as perfume, cologne and perfumed article aroma imparting compositions of mixtures of the compounds defined according to the structure: ##STR3## wherein R represents methyl or ethyl taken further together with the alcohol having the structure: ##STR4## with one or more butanoyl cyclohexane derivatives and/or 3-methyl-1-phenyl-pentanol-5.
    Type: Grant
    Filed: June 5, 1984
    Date of Patent: June 18, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Wilhelmus J. Wiegers, Mark A. Sprecker
  • Patent number: 4524020
    Abstract: Described are isopropyl substituted cyclohexenyl methyl ketones defined according to the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.11 and R.sub.21 each represents hydrogen or methyl with the provisos that:(a) at least two of R.sub.1, R.sub.21, R.sub.2 and R.sub.11 represent hydrogen;(b) either R.sub.2 is methyl and R.sub.21 is hydrogen or R.sub.21 is methyl and R.sub.2 is hydrogen; and(c) R.sub.1 is methyl only when R.sub.2 is methyl and R.sub.11 is methyl only when R.sub.21 is methyl,as well as uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations and perfumed polymers.
    Type: Grant
    Filed: August 24, 1984
    Date of Patent: June 18, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Robert P. Belko, Augustinus G. Van Loveren, Marie R. Hanna
  • Patent number: 4517213
    Abstract: Described is a genus of compounds defined according to the structure: ##STR1## hereinafter termed "norbornyl esters" wherein R.sub.1, R.sub.2 and R.sub.3 represent methyl or hydrogen with the proviso that at least one of R.sub.1, R.sub.2 and R.sub.3 is hydrogen as well as uses thereof in augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfume compositions, colognes and perfumed articles (including, but not limited to, solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations and perfumed polymers). Also described is a novel process for preparing such norbornyl esters.
    Type: Grant
    Filed: August 24, 1984
    Date of Patent: May 14, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventor: Mark A. Sprecker
  • Patent number: 4512918
    Abstract: Described are compositions for use in perfume aroma augmenting, enhancing, modifying and altering compositions and as perfume, cologne and perfumed article aroma imparting compositions of mixtures of the compound having the structure: ##STR1## taken further together with one or more butanoyl cyclohexane derivatives and/or 3-methyl-1-phenyl-pentanol-5-.
    Type: Grant
    Filed: April 7, 1983
    Date of Patent: April 23, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Wilhelmus J. Wiegers, Mark A. Sprecker
  • Patent number: 4507225
    Abstract: Described for use in augmenting or enhancing the aroma of perfume compositions, perfumed articles and colognes is the genus of compounds having the structure: ##STR1## wherein one of R.sub.1 or R.sub.2 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen or wherein both R.sub.1 and R.sub.2 are hydrogen, hereinafter referred to as 1-phenylpenten-4-one-1 and methyl homologues thereof.
    Type: Grant
    Filed: April 21, 1983
    Date of Patent: March 26, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Marie R. Hanna
  • Patent number: 4503258
    Abstract: Compounds of the following structure ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen and 2-propenyl are disclosed useful as intermediates in organic synthesis.
    Type: Grant
    Filed: November 14, 1983
    Date of Patent: March 5, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventors: John B. Hall, Mark A. Sprecker