Abstract: Resin compositions comprising flame retardant materials obtained by heating phosphonic acid salts at temperatures above 200° C., have excellent properties and exhibit manageable curing behavior. Laminates, composites, molded articles and the like, which have excellent flame retardant properties and physical characteristics, are readily prepared from the resin compositions of the invention.

Abstract: Resin compositions comprising flame retardant materials obtained by heating phosphonic acid salts at temperatures above 200° C., have excellent properties and exhibit manageable curing behavior. Laminates, composites, molded articles and the like, which have excellent flame retardant properties and physical characteristics, are readily prepared from the resin compositions of the invention.

Abstract: Resin compositions, e.g., epoxy resin compositions, comprising flame retardant materials obtained by heating phosphonic acid salts at temperatures above 200° C., have excellent properties and exhibit manageable curing behavior. Laminates, composites, molded articles and the like, which have excellent flame retardant properties and physical characteristics, are readily prepared from the resin compositions of the invention.

Abstract: Flame retardants produced by heating certain phosphonic acid salts at temperatures over 200° C. are readily compounded into high temperature polyamides that are processed at temperatures above 270° C. to provide flame retardant, high temperature polyamide compositions.

Abstract: Flame retardant polymer compositions comprising certain polymers, a flame retardant material obtained by heating certain phosphonic acid salts at temperatures over 200° C. and certain clays or metal compounds such as select metal borates, oxides, hydroxides, oxide hydroxides etc., are readily processed at elevated temperatures and under high stress conditions whereas similar compositions without the clays or metal compounds of the invention are prone to decomposition. For example, polyamide compositions comprising the flame retardant material obtained by heating certain phosphonic acid salts at temperatures over 200° C., hydrotalcite clays, and/or borates, oxides, hydroxides, oxide hydroxides of zinc or calcium, are highly stable to thermal processing under strenuous conditions such as high temperature extrusion.

Abstract: Certain phosphonic acid salts heated at temperatures over 200° C. generate thermally stable, highly efficient flame retardant materials well suited for use as flame retardant additives in polymers. Various methods for preparing flame retardant materials from more than one phosphonic acid salts are provided, wherein each method can generate different flame retardant materials from the same mixture of starting phosphonic acids. The flame retardants of the invention can be used as the sole flame retardant in a composition or in combination with other flame retardants, synergists or adjuvants.

Abstract: Flame retardant polymer compositions with excellent processing stability and flame retardant activity are obtained by incorporating into the polymer a flame retardant obtained by heating certain phosphonic acid salts at temperatures of 200° C. or higher and as flame retardant synergist melam or a melam derivative, which compositions are more readily processed under certain harsh conditions than similar compositions comprising similar synergists such as melem, melon and the like.

Abstract: Certain phosphonic acid salts heated at temperatures over 200° C. generate thermally stable, highly efficient flame retardant materials well suited for use as flame retardant additives in polymers. The flame retardants of the invention can be used as the sole flame retardant in a composition or in combination with other flame retardants, synergists or adjuvants.

Abstract: Resin compositions comprising flame retardant materials obtained by heating phosphonic acid salts at temperatures above 200° C., have excellent properties and exhibit manageable curing behavior. Laminates, composites, molded articles and the like, which have excellent flame retardant properties and physical characteristics, are readily prepared from the resin compositions of the invention.

Abstract: Resin compositions comprising flame retardant materials obtained by heating phosphonic acid salts at temperatures above 200° C., have excellent properties and exhibit manageable curing behavior. Laminates, composites, molded articles and the like, which have excellent flame retardant properties and physical characteristics, are readily prepared from the resin compositions of the invention.

Abstract: Resin compositions, e.g., epoxy resin compositions, comprising flame retardant materials obtained by heating phosphonic acid salts at temperatures above 200° C., have excellent properties and exhibit manageable curing behavior. Laminates, composites, molded articles and the like, which have excellent flame retardant properties and physical characteristics, are readily prepared from the resin compositions of the invention.

Abstract: Resin compositions, e.g., epoxy resin compositions, comprising flame retardant materials obtained by heating phosphonic acid salts at temperatures above 200° C., have excellent properties and exhibit manageable curing behavior. Laminates, composites, molded articles and the like, which have excellent flame retardant properties and physical characteristics, are readily prepared from the resin compositions of the invention.

Abstract: Resin compositions, e.g., epoxy resin compositions, comprising flame retardant materials obtained by heating phosphonic acid salts at temperatures above 200° C., have excellent properties and exhibit manageable curing behavior. Laminates, composites, molded articles and the like, which have excellent flame retardant properties and physical characteristics, are readily prepared from the resin compositions of the invention.

Abstract: Flame retardant polymer compositions with excellent processing stability and flame retardant activity are obtained by incorporating into the polymer a flame retardant obtained by heating certain phosphonic acid salts at temperatures of 200° C. or higher and as flame retardant synergist melam or a melam derivative, which compositions are more readily processed under certain harsh conditions than similar compositions comprising similar synergists such as melem, melon and the like.

Abstract: Flame retardant polymer compositions comprising certain polymers, a flame retardant material obtained by heating certain phosphonic acid salts at temperatures over 200° C. and certain clays or metal compounds such as select metal borates, oxides, hydroxides, oxide hydroxides etc., are readily processed at elevated temperatures and under high stress conditions whereas similar compositions without the clays or metal compounds of the invention are prone to decomposition. For example, polyamide compositions comprising the flame retardant material obtained by heating certain phosphonic acid salts at temperatures over 200° C., hydrotalcite clays, and/or borates, oxides, hydroxides, oxide hydroxides of zinc or calcium, are highly stable to thermal processing under strenuous conditions such as high temperature extrusion.

Abstract: A hydroxyphenyl or alkoxyphenyl phosphine oxide composition comprising (i) a first mixture of mono-(hydroxyphenyl) or (alkoxyphenyl)phosphine oxide isomers, (ii) a second mixture of bis-(hydroxyaryl) or (alkoxyphenyl)phosphine oxide isomers, (iii) a third mixture of tris-(hydroxyaryl) or (alkoxyphenyl)phosphine oxide isomers, and optionally iv) a minority amount of non-hydroxy or non-alkoxy tris-phenyl phosphine oxides is provided. Also provided are epoxy resins compositions with excellent flame retardancy and physical properties, which resins comprise the phosphine oxide composition.

Abstract: A hydroxyphenyl or alkoxyphenyl phosphine oxide composition comprising (i) a first mixture of mono-(hydroxyphenyl) or (alkoxyphenyl)phosphine oxide isomers, (ii) a second mixture of bis-(hydroxyaryl) or (alkoxyphenyl)phosphine oxide isomers, (iii) a third mixture of tris-(hydroxyaryl) or (alkoxyphenyl)phosphine oxide isomers, and optionally iv) a minority amount of non-hydroxy or non-alkoxy tris-phenyl phosphine oxides is provided. Also provided are epoxy resins compositions with excellent flame retardancy and physical properties, which resins comprise the phosphine oxide composition.

Abstract: A flame-retardant resin composition comprises a base resin (A), such as a polyamide resin, and an aromatic organophosphorus oligomer or polymer.

Abstract: Flame retardants produced by heating certain phosphonic acid salts at temperatures over 200° C. are readily compounded into high temperature polyamides that are processed at temperatures above 270° C. to provide flame retardant, high temperature polyamide compositions.

Abstract: Certain aluminum salts of organic phosphorus acids are found to have a strong effect on inhibiting the epoxy cure rate in epoxy formulations. The substances act catalytically and can be used at a low level in an epoxy formulation to adjust the reactivity of a resin formulation to give longer gel times. Compositions and methods of preparing and using the compositions are disclosed.