Abstract: An improved separator film that can be applied to a layer of composite prepreg material as well as resin based adhesive films to prevent sticking, voids and separator film contamination in formed articles, as well as providing useful handling and storage properties. The separator film of the present invention is designed to either degrade and/or volatilize away so as not to contaminate or leave voids or weak interfaces in the resulting article. The separator film also eliminates the need to inspect the formed article for remaining separator film. In general, the separator film of the present invention is made from a polymer or combination of polymers that can volatilize away or revert into monomers or simpler polymers. This volatilization or degradation into a plurality of reversion products occurs when the separator film is exposed to sufficient heat energy.

Abstract: A coating having resistance to chemical warfare agents, comprising a cured mixture of (a) a polysiloxane having unsaturated groups available for cross-linking and (b) a polysiloxane containing reactive Si--H groups. A platinum siloxane catalyst is also employed in the mixture. A representative coating composition is a mixture of vinyldimethly terminated polydimethylsiloxane polymethylhydrosiloxane; and platinum-divinyl-tetramethyldisiloxane complex catalyst. The coating composition cures at room temperature and in a relatively short period of time.

Abstract: A coating having resistance to chemical warfare agents, comprising a cured mixture of (a) a polysiloxane having unsaturated groups available for cross-linking, (b) a polysiloxane containing reactive Si-H groups and (c) an unsaturated compound such as ethyl acrylate to prevent formation of bubbles in the coating due to the liberation of hydrogen from such Si-H groups during curing, and to provide a smooth bubble-free coating. A platinum siloxane catalyst is also employed in the mixture. A representative coating composition is a mixture of compounds (a) polydimethylsiloxane, vinyl dimethylterminated; (b) polymethylhydrosiloxane, and (c) ethyl acrylate; and platinum-divinyltetramethyldisiloxane complex catalyst. The coating composition cures at room temperature and in a relatively short period of time.

Abstract: Highly fire resistant composites or laminates particularly applicable as structural components in aircraft, e.g. in the engine nacelle, as part of the acoustic panel-fire wall structure, and capable of withstanding a 2,000.degree. F. flame temperature, comprising incorporating an additive in the form of a polymeric phosphorylated amide, into a resin, e.g., a polyimide or an epoxy resin, such additive being soluble in the resin. The resulting resin containing the additive is then applied to or impregnated into a substrate such as glass fiber cloth or graphite fiber, to form a composite structure which is then cured. The resulting cured composite when subjected to high temperatures of the order of, e.g., a 2,000.degree. F. flame temperature, forms a resin char of reduced thermal conductivity which holds the fibers of the laminate together and maintains the structural stability and integrity of the laminate.

Abstract: The invention is directed to the electrodeposition of a coating of a phosphorylated amide on a metal such as aluminum and the formation of a chemical bond between the metal and the coating, such amide being in the form of (a) an organic polymer consisting of a poly (phosphinohydrazide), a poly (phosphinoguanide) or a poly (phosphinoureide), including homopolymers and copolymers thereof, and their thio analogs or (b) a 2:1 molar adduct of a nitrogen=containing compound such as hydrazine, guanidine or urea or its thio analog, and an organic phosphite or phosphonate. In the method of electrolytically depositing such coating on the metal substrate, e.g., aluminum, the substrate is employed as the anode in a non-aqueous or aqueous electrolyte containing a phosphorylated amide of the type noted above, e.g.

Abstract: Highly fire resistant composites or laminates particularly applicable as structural components in aircraft, e.g. in the engine nacelle, as part of the acoustic panel-fire wall structure, and capable of withstanding a 2,000.degree. F. flame temperature, comprising incorporating an additive in the form of a polymeric phosphorylated amide, into a resin, e.g., a polyimide or an epoxy resin, such additive being soluble in the resin. The resulting resin containing the additive is then applied to or impregnated into a substrate such as glass fiber cloth or graphite fiber, to form a composite structure which is then cured. The resulting cured composite when subjected to high temperatures of the order of, e.g., a 2,000.degree. F. flame temperature, forms a resin char of reduced thermal conductivity which holds the fibers of the laminate together and maintains the structural stability and integrity of the laminate.

Abstract: A process for enhancing adhesive bonding of a metal substrate, particularly aluminum, which comprises treating the aluminum substrate, after optional cleaning thereof in an alkaline solution, with an ammoniacal solution of a copper salt, e.g. copper sulfate, to form a cuprammonium, i.e. [Cu(NH.sub.3).sub.4 ]SO.sub.4, solution containing the complex Cu(NH.sub.3).sub.4.sup.++ ion. Such treatment provides a controlled etch of the aluminum substrate and increases the surface area thereof, resulting in enhanced reactivity of each surface with an adhesive during adhesive bonding, and providing a strong adhesive bond between the adhesive coating and the metal substrate. When such cuprammonium treatment of an aluminum surface is followed by electrodeposition of an organic coating, as described in U.S. Pat. No. 4,180,442, prior to application of an adhesive coating, a strong adhesive bond having consistently high lap shear values is obtained.

Abstract: The invention is directed to the electrodeposition of a coating of a phosphorylated amide on a metal such as aluminum, and the formation of a chemical bond between the metal and the coating, such amide being in the form of (a) an organic polymer consisting of a poly (phosphinohydrazide), a poly (phosphinoguanide) or a poly (phosphinoureide), including homopolymers and copolymers thereof, and their thio analogs or (b) a 2:1 molar adduct of a nitrogen-containing compound such as hydrazine, guanidine or urea or its thio analog, and an organic phosphite or phosphonate. In the method of electrolytically depositing such coating on the metal substrate, e.g., aluminum, the substrate is employed as the anode in a non-aqueous or aqueous electrolyte containing a phosphorylated amide of the type noted above, e.g.

Abstract: Highly fire resistant composites or laminates particularly applicable as structural components in aircraft, e.g. in the engine nacelle, as part of the acoustic panel-fire wall structure, and capable of withstanding a 2,000.degree. F. flame temperature, comprising incorporating an additive in the form of a polymeric phosphorylated amide, into a resin, e.g., a polyimide or an epoxy resin, such additive being soluble in the resin. The resulting resin containing the additive is then applied to or impregnated into a substrate such as glass fiber cloth or graphite fiber, to form a composite structure which is then cured. The resulting cured composite when subjected to high temperatures of the order of, e.g., a 2,000.degree. F. flame temperature, forms a resin char of reduced thermal conductivity which holds the fibers of the laminate together and maintains the structural stability and integrity of the laminate.

Abstract: Highly fire resistant composites or laminates particularly applicable as structural components in aircraft, e.g. in the engine nacelle, as part of the acoustic panel-fire wall structure, and capable of withstanding a 2,000.degree. F. flame temperature, comprising incorporating an additive in the form of a phosphorylated amide, into a resin, e.g., a polyimide or an epoxy resin, such additive being soluble in the resin. The resulting resin containing the additive, e.g., phenyl phosphonic acid diamide, is then applied to or impregnated into a substrate such as glass fiber cloth or graphite fiber, to form a composite structure which is then cured. The resulting cured composite when subjected to high temperatures of the order of, e.g., a 2,000.degree. F. flame temperature, forms a resin char of reduced thermal conductivity which holds the fibers of the laminate together and maintains the structural stability and integrity of the laminate.

Abstract: Highly fire resistant composites or laminates particularly applicable as structural components in aircraft, e.g. in the engine nacelle, as part of the acoustic panel-fire wall structure, and capable of withstanding a 2,000.degree. F. flame temperature, comprising incorporating an additive in the form of an ammonium salt, or an amine salt, of a phosphonic acid or a phosphinic acid, into a resin, e.g., a polyimide or an epoxy resin, such additive being soluble in the resin. The resulting resin containing the additive, e.g., the ammonium, or amine, salt of phenyl phosphonic or phenyl phosphinic acid, is then applied to or impregnated into a substrate such as glass fiber cloth or graphite fiber, to form a composite structure which is then cured. The resulting cured composite when subjected to high temperatures of the order of, e.g., a 2,000.degree. F.

Abstract: Production of a device or filter for removal of ozone from air, e.g. in aircraft cabins, by depositing an oxide film containing manganese dioxide on a substrate, particularly a light weight thermally stable substrate, e.g. polybenzimidazole, by treatment with a permanganate solution containing a soluble ceric salt such as ceric ammonium nitrate, and preferably also a dichromate such as sodium dichromate, to form a dense strongly adherent film or coating of MnO.sub.2, ceric oxide and preferably also chromic oxide, on the substrate. A solution containing an oxidizable organic component such as abietic acid can be first applied to the substrate, followed by treatment with the above permanganate solution.

Abstract: Fire barrier composition particularly applicable as an acoustic panel-fire wall structure in aircraft, capable of withstanding a 2,000.degree. F. flame temperature, comprising incorporating a silica-containing material such as silicic acid or the reaction product of silicic acid and maleic anhydride, into a resin, particularly a polyimide resin. The resulting silica-containing resin, e.g. silicic acid-filled polyimide, is then applied to a substrate such as graphite fiber or glass cloth, to form a composite structure, which is then cured. The resulting cured composite when subjected to high temperature, e.g. a 2,000.degree. F. flame temperature, forms silicon carbide and/or silicon nitride, in situ, which stabilizes any char that forms.

Abstract: Filter for removal of ozone from air, e.g. in aircraft cabins, comprising a porous and preferably light weight and thermally stable substrate, particularly an organic polymer such as polybenzimidazole, containing a film or coating of manganese dioxide. The article can be formed by treating the substrate with a permanganate solution under conditions to reduce the permanganate to MnO.sub.2.

Abstract: Production of a device or filter for removal of ozone from air, e.g. in aircraft cabins, by depositing an oxide film containing manganese dioxide on a substrate, particularly a light weight thermally stable substrate, e.g. polybenzimidazole, by treatment with a permanganate solution containing a soluble ceric salt such as ceric ammonium nitrate, and preferably also a dichromate such as sodium dichromate, to form a dense strongly adherent film or coating of MnO.sub.2, ceric oxide and preferably also chromic oxide, on the substrate. A solution containing an oxidizable organic component such as abietic acid can be first applied to the substrate, followed by treatment with the above permanganate solution.

Abstract: The invention is directed to the electrodeposition of a coating of an organic compound or polymer on a metal such as aluminum, and the formation of a chemical bond between the metal and the coating. In the method for electrolytically depositing such coating on the metal substrate, e.g. aluminum, the substrate is employed as the anode in a non-aqueous electrolyte containing a coating compound, preferably a carboxyl-substituted aminosilane such as .gamma.-aminopropyltriethoxysilane, which has been reacted with any of various anhydrides such as phthalic, maleic, or succinic anhydride, and electrodepositing a coating on the metal substrate, the organic coating formed being chemically bonded to the substrate, thereby enhancing adhesive bonding to the metal substrate or enhancing spot weldability of such substrate, such coating being strongly bonded to the substrate and being corrosion resistant.