Abstract: A method is provided for producing a carbide compound, such as silicon carbide. A reactor is provided which has a chamber defined therein which is divided into a combustion zone and a reaction zone. A combustible mixture comprising carbon monoxide and an oxidant is injected into the combustion zone and accordingly combusted to form hot combustion products. At least one reactant is injected at the boundary between the zones so as to be carried into the reaction zone by the combustion products and react to produce a precursor product powder comprising an oxide, such as silicon dioxide, and carbon. This precursor product powder is heated in an inert atmosphere to yield the desired carbide compound.

Abstract: In the production of carbon black, low BTU content gases are combusted in a compact combustion zone with near stoichiometric amounts of oxidant gases, tempered to the desired temperature and volume with a diluent gas stream which can be selected from air and filter off-gases, and introduced into a reactor for the pyrolysis of a carbonceous feedstock to form carbon black.

Abstract: The moving of adjacent axial stream at sufficiently different speeds to create turbulence and rapid mixing of feedstock and hot gases in a carbon black reactor is utilized to provide a high surface area carbon black.

Abstract: Pitch is converted to mesophase pitch in the presence of catalytically effective amounts of oxides, diketones, carboxylates and carbonyls of metals selected from vanadium, chromium, molybdenum, iron, nickel and cobalt. The crystalloidal or mesophase pitch obtained can be used for the production of carbon fibers and other carbon and graphite products and articles of manufacture of unusually high quality.

Abstract: A method for producing carbon black employing a carbon black reactor which comprisesa cylindrical precombustion zone;a combustion gas introduction means adapted to tangentially introduce combustion gas into the cylindrical precombustion zone; anda cylindrical reaction zone in open communication with the cylindrical precombustion zone, wherein the axis of rotation of the cylindrical reaction zone and the axis of rotation of the cylindrical precombustion zone are substantially collinear, where the method comprises tangentially introducing a combustion gas into the cylindrical precombustion zone of the carbon black to create a spiralling flow and subjecting a portion of the spiralling flow to a counter-rotational force within the cylindrical precombustion zone; wherein the counter-rotational force is created by a helix-shaped fin positioned at least partially within the cylindrical precombustion zone; and wherein the helix-shaped fin is rotated about its axis by a motorized means thereby facilitating the creatio

Abstract: Pitch is converted to mesophase pitch in the presence of catalytically effective amounts of oxides, diketones, carboxylates and carbonyls of metals selected from vanadium, chromium, molybdenum, iron, nickel and cobalt. The crystalloidal or mesophase pitch obtained can be used for the production of carbon fibers and other carbon and graphite products and articles of manufacture of unusually high quality.

Abstract: Aerosols such as a carbon black containing smoke are subjected to an auto-preseparation by passing the aerosol or smoke through loose particles collected and accumulated and only thereafter passing the aerosol or smoke through a separator such as a filter bag. This changes the characteristic of the aerosol in either reducing the total content of solids or increasing the average particle size of the solids in the aerosol or achieving both of these features. Thereby the load on the downstream separator and the capacity of the separator, e.g. a carbon black filter house, is substantially reduced.

Abstract: The tint residual of carbon black being produced in an oil furnace charging oxygen-enriched air falls as oxygen enrichment increases. An apparatus for conducting the process utilizing a low BTU fuel with external tangential combustors is also disclosed.

Abstract: Feed oils are injected axially into a carbon black reactor in a manner which slows buildup of deposits in the reactor. This is accomplished utilizing a nozzle configuration for injecting the feed oil into the carbon black reactor so that deposit-forming contaminants are directed away from the walls of the reactor. In one aspect, the feed oil is separated into two streams, one stream is contaminant-rich and the other is substantially contaminant-free. The contaminant-rich stream is fed into the reactor surrounded by the substantially contaminant-free stream. In another embodiment, a feed nozzle for a carbon black reactor is formed by a first feed tube surrounded coaxially by a second feed tube. The first feed tube can be utilized to inject contaminant-rich feed oil into the reactor. The second feed tube can be utilized to inject contaminant-free oil into the reactor in a manner such that it surrounds the contaminant-rich stream.

Abstract: A novel heat exchanger for recuperating heat from a combustion gas stream is disclosed. The heat is recuperated in a steam generator formed from a shell and tube heat exchanger. To reduce deposits on the combustion gas side of the heat exchanger the tube walls are porous so that the pressure across the tube walls during steam generation will continuously drive a small amount of water or steam from the liquid side to the smoke side to remove deposits on the tubes.

Abstract: The tint residual of produced carbon black appears to go through a maximum value at a toluene photelometer of between about 65 and about 75. A process is disclosed for maximizing the tint residual of carbon black product at constant reactor volume and combustion gas flow by measuring the photelometer of the produced carbon black and changing the feedstock rate so that the photelometer of the carbon black being produced falls within the range of 65 to about 75.

Abstract: A counter-rotational flow of combustion gas within a carbon black reactor is created by a baffle, such as an axially aligned helix-shaped fin, to promote the mixing of combustion gas and feedstock.

Abstract: In the production of carbon black, low BTU content gases are combusted in a compact combustion zone with near stoichiometric amounts of oxidant gases, tempered to the desired temperature and volume with a diluent gas stream which can be selected from air and filter off-gases, and introduced into a reactor for the pyrolysis of a carbonceous feedstock to form carbon black.

Abstract: A venturi tube fluid flow meter comprising an inlet section with a first pressure probe upstream of the throat section that is an inner-end closed tube traversing the diameter of the inlet section and pressure probe that is a capped tube extending into the flow path of the throat section at the minimum diameter thereof with this tube containing two perforations 180.degree. apart and orthogonal to the center line of the throat section.

Abstract: High tint residual carbon black is produced in a vortex flow, venturi oil furnace carbon black reactor by charging the liquid feed or make hydrocarbon axially as a solid jet into a swirling mass of hot combustion gases upstream from the venturi and passing the hydrocarbon feed and hot combustion gases under carbon black forming conditions through the venturi section of the carbon black reactor.

Abstract: Carbon black reactors have dual fluid injectors whereby liquid hydrocarbonaceous feedstock atomized by discharging the feedstock through a dual fluid injector with an atomizing fluid. A method for cleaning coke deposits from such dual fluid injectors comprises interrupting the supply of atomizing fluid thereto a cleaning interval effective to remove the coke deposits.

Abstract: Carbon black reactor effluent is quenched and is then passed to a carbon black preagglomeration zone prior to being passed through the tubes of a shell-tube in direct heat exchange zone. The preagglomeration zone produces larger particles of carbon black, thereby minimizing deposits of carbon on the inner peripheries of the tubes of the heat exchange zone so as to maintain the desired high heat transfer efficiency.

Abstract: Aerosols such as a carbon black containing smoke are subjected to an auto-preseparation by passing the aerosol or smoke through loose particles collected and accumulated and only thereafter passing the aerosol or smoke through a separator such as a filter bag. This changes the characteristic of the aerosol in either reducing the total content of solids or increasing the average particle size of the solids in the aerosol or achieving both of these features. Thereby the load on the downstream separator and the capacity of the separator, e.g. a carbon black filter house, is substantially reduced.

Abstract: A method and apparatus for producing carbon black in which combustion gas is introduced into a precombustion or combustion zone of a carbon black reactor in a manner to produce a vortex of combustion gases traveling axially through said reactor and a flow of fluid which contains feedstock is introduced into the reactor in a manner to produce another axially moving vortex internal to the combustion gas vortex with both of these vortices passed through a combustion zone to produce carbon black. In embodiments of the invention, method and apparatus for producing a vortex of feedstock, a vortex of cooling air interfaced with axially flowing feedstock, or combined vortices of feedstock and cooling air.

Abstract: Two carbon black reactors in sequence, one being a high-structure carbon black reactor, the other being a low structure carbon black reactor, one feeding into the other, yield low tint residual carbon black.