Abstract: A system for treating exhaust gases from a combustion engine and a method for using the same results in improved NOx conversion during engine startup. The system includes a compact SCR flow-through monolith installed upstream of a close-coupled SCR wall-flow filter, wherein the compact SCR flow-through monolith may be extruded or made of a thin-walled substrate, such that the SCR flow-through monolith has a smaller volume with lower heat capacity and higher catalyst loading relative to the SCR wall-flow filter.

Abstract: A catalyst article comprises an SCR catalyst and a NOx adsorber catalyst, where each of these catalysts comprise a metal molecular sieve, each with a different metal. The catalyst article can be close coupled with other components to give a NOX performance advantage from cold start to a combined DOC and SCRF system. Higher NOX conversion is also shown in under-floor location due to NOx storage before SCR light off and selective NH3 slip control, allowing higher NH3 fill levels. Systems comprising the catalyst article and methods of using the catalyst article to give improved hydrocarbon and carbon monoxide control, as well as ammonia slip control, are described. The systems can include flow-through or wall-flow monoliths.

Abstract: A substrate monolith 6 having a length L and comprising a first zone 11 of substantially uniform length defined at one end by a first end of the substrate monolith, which first zone comprising a selective catalytic reduction (SCR) catalyst for reducing oxides of nitrogen with a nitrogenous reductant in exhaust gas emitted from an internal combustion engine and a second zone 8 of substantially uniform length less than L defined at one end by a second end of the substrate monolith, which second zone comprising (a) at least one particulate metal oxide or a mixture of any two or more thereof for trapping gas phase platinum group metal (PGM), which at least one particulate metal oxide does not act as a support for any other catalytic component; or (b) a component capable of trapping and/or alloying with gas phase PGM.

Abstract: Provided is an improved catalyst for treating exhaust gas, particularly for selectively reducing NOx, and methods for using the same, wherein the catalyst includes a blend of a transition metal promoted zeolite and an un-promoted zeolite, wherein both zeolites have the same framework type.

Abstract: A vehicle comprises a compression ignition engine provided with engine management means and having a catalyst for exhaust gas aftertreatment, wherein the engine management means is configured, when in use, to detect idle conditions and upon determining that idle conditions exist, stops the engine entirely, wherein the catalyst comprises a honeycomb substrate monolith coated with a catalytic washcoat comprising one or more precious metal, which catalytic washcoat being arranged between a first, upstream washcoat zone and a second, downstream washcoat zone, wherein a thermal mass in the first washcoat zone is different from a thermal mass in the second washcoat zone and wherein a washcoat layer in the first, upstream washcoat zone is substantially contiguous with a washcoat layer in the second, downstream washcoat zone.

Abstract: An exhaust system for treating an exhaust gas from an internal combustion engine is disclosed. The system comprises a modified lean NO trap (LNT), a urea injection system, and an ammonia-selective catalytic reduction catalyst. The modified LNT comprises a first layer and a second layer. The first layer comprises a NO adsorbent component and one or more platinum group metals. The second layer comprises a diesel oxidation catalyst zone and an NO oxidation zone. The diesel oxidation catalyst zone comprises a platinum group metal, a zeolite, and optionally an alkaline earth metal. The NO oxidation zone comprises a platinum group metal and a carrier. The modified LNT stores NO at temperatures below about 200° C. and releases at temperatures above about 200° C. The modified LNT and a method of using the modified LNT are also disclosed.

Abstract: An exhaust system 20 for an internal combustion engine comprises a) a first catalysed substrate monolith 12 comprising a first washcoat coating disposed in a first washcoat zone 16 of the substrate monolith and a second washcoat coating disposed in a second washcoat zone 18 of the substrate monolith, wherein the first washcoat coating comprises a catalyst composition comprising at least one platinum group metal (PGM) and at least one support material, wherein at least one PGM in the first washcoat coating is liable to volatilise when the first washcoat coating is exposed to relatively extreme conditions including relatively high temperatures, wherein the second washcoat coating comprises at least one material supporting copper for trapping volatilised PGM and wherein the second washcoat coating is oriented to contact exhaust gas that has contacted the first washcoat; and b) a second catalysed substrate monolith 14 comprising a catalyst for selectively catalysing the reduction of oxides of nitrogen to dinitrog

Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.

Abstract: Provided is an SCRF article having different SCR catalysts compositions disposed on a wall-flow filter substrate in zones that are arranged in series with respect to the inlet and outlet faces of the substrate. Also provided is method of reducing backpressure and ammonia slip that involves the use of such SCRF articles.

Abstract: A catalyst composition comprises a mixed metal catalyst which comprises unalloyed palladium and palladium-gold alloy disposed on a support, wherein the palladium-gold alloy is enriched in gold and at least one promoter in which said promoter comprises at least one reducible metal oxide.

Abstract: An apparatus is disclosed. The apparatus comprises a lean-burn internal combustion engine, engine management means and an exhaust system for treating exhaust gas of the engine. The exhaust system comprises a first oxidation catalyst disposed on a first honeycomb monolith substrate. The first oxidation catalyst comprises platinum supported on a first metal oxide support comprising at least one reducible oxide, and is substantially free of alkali metals and alkaline earth metals. The engine management means is arranged, when in use, intermittently to modulate the lambda composition of the exhaust gas entering the first oxidation catalyst to a rich lambda composition.

Abstract: A synthetic aluminosilicate zeolite catalyst containing at least one catalytically active transition metal selected from the group consisting of Cu, Fe, Hf, La, Au, In, V, lanthanides and Group VIII transition metals, which aluminosilicate zeolite is a small pore aluminosilicate zeolite having a maximum ring size of eight tetrahedral atoms, wherein the mean crystallite size of the aluminosilicate zeolite determined by scanning electron microscope is >0.50 micrometer.

Abstract: An oxidation catalyst for treating an exhaust gas from a compression ignition engine, which oxidation catalyst comprises: a first washcoat region comprising platinum (Pt) and a first support material, wherein the first washcoat region is substantially free of a hydrocarbon adsorbent; a second washcoat region comprising platinum (Pt), palladium (Pd) and a second support material, wherein the second washcoat region has a ratio by mass of platinum (Pt) to palladium (Pd) of 4:1 to 1:1; a hydrocarbon adsorbent; and a substrate; wherein the first washcoat region is arranged to contact inlet exhaust gas before the hydrocarbon adsorbent, and the first washcoat region is arranged to contact inlet exhaust gas before the second washcoat region.

Abstract: A diesel engine includes an exhaust system having a particulate filter made from a porous material having a mean pore diameter of from 5 ?m to 40 ?m, a porosity of at least 40% and a bulk volumetric heat capacity of at least 0.50 J cm?3 K?1 at 500° C. The filter includes a diesel oxidation catalyst (DOC) located in a first catalyst zone on the front end of the filter and at least one catalyst zone located downstream thereof, for oxidizing carbon monoxide, hydrocarbons and nitrogen monoxide. The engine includes engine management means, in use, to provide continuously or intermittently an exhaust gas having sufficient nitrogen oxides or hydrocarbon and/or an exhaust gas of sufficiently high temperature to combust particulate matter. The platinum group metal (PGM) loading in the first catalyst zone is greater than the total PGM loading in the at least one downstream catalyst zone.

Abstract: A catalysed soot filter comprising an oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from a compression ignition engine disposed on a filtering substrate, wherein the oxidation catalyst comprises: a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; an alkaline earth metal component; a support material comprising a modified alumina incorporating a heteroatom component.

Abstract: An oxidation catalyst for treating an exhaust gas from a diesel engine and an exhaust system comprising the oxidation catalyst are described. The oxidation catalyst comprises: a first washcoat region for adsorbing NOx, wherein the first washcoat region comprises a zeolite catalyst, wherein the zeolite catalyst comprises a noble metal and a zeolite; a second washcoat region for oxidising nitric oxide (NO), wherein the second washcoat region comprises platinum (Pt) and a support material; and a substrate having an inlet end and an outlet end.

Abstract: An apparatus is disclosed. The apparatus comprises a lean-burn internal combustion engine, engine management means and an exhaust system for treating exhaust gas of the engine. The exhaust system comprises a first oxidation catalyst disposed on a first honeycomb monolith substrate. The first oxidation catalyst comprises platinum supported on a first metal oxide support comprising at least one reducible oxide, and is substantially free of alkali metals and alkaline earth metals. The engine management means is arranged, when in use, intermittently to modulate the lambda composition of the exhaust gas entering the first oxidation catalyst to a rich lambda composition.

Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.

Abstract: An oxidation catalyst for treating an exhaust gas produced by a combustion engine, wherein the oxidation catalyst comprises a substrate and a catalyst layer, wherein the catalyst layer comprises: a first support material; a first noble metal; and a second noble metal; wherein the catalyst layer is disposed on a surface of the substrate, and the catalyst layer has a non-uniform distribution of the first noble metal in a direction perpendicular to the surface of the substrate. The oxidation catalyst can be used to oxidize carbon monoxide (CO), hydrocarbons (HCs) and also oxides of nitrogen (NOx) in such an exhaust gas.

Abstract: A zoned catalysed substrate monolith comprises a first zone and a second zone that are arranged axially in series. The first zone comprises a platinum group metal loaded on a support and a first base metal oxide or a first base metal loaded on an inorganic oxide. The first base metal oxide is iron oxide, manganese oxide, copper oxide, zinc oxide, nickel oxide, or mixtures thereof. The first base metal is iron, manganese, copper, zinc, nickel, or mixtures thereof. The second zone comprises copper or iron loaded on a zeolite and a second base metal oxide or a second base metal loaded on an inorganic oxide. The second base metal oxide is iron oxide, manganese oxide, copper oxide, zinc oxide, nickel oxide, or mixtures thereof. The second base metal is iron, manganese, copper, zinc, nickel, or mixtures thereof. The second base metal is different from the first base metal.