Patents by Inventor Pierre Martin

Pierre Martin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4822919
    Abstract: There is described a process for producing fungicidally active 4-phenylpyrrole derivatives of the formula I ##STR1## wherein R is halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -haloalkyl, andn is 0, 1 or 2, which process comprises reacting a 3-trifluoromethyl-4-phenylpyrrole of the formula II ##STR2## wherein R.sub.n is as defined under the formula I, and R.sub.1 is hydrogen or an acyl group, at elevated temperature and elevated pressure, with ammonia. Important intermediates and the production thereof are also described.
    Type: Grant
    Filed: August 26, 1987
    Date of Patent: April 18, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Pierre Martin, Robert W. Lang
  • Patent number: 4812580
    Abstract: The invention relates to a process for the preparation of 4-phenylpyrrole derivatives of the formula I ##STR1## wherein R.sub.n, R.sub.1 and R.sub.2 are as defined in claim 1, which comprises reacting a phenacylamine of formula II ##STR2## with a compound of formula IIIT--CH.dbd.CH--R.sub.1 (III)to give an intermediate of formula IV ##STR3## and cyclizing said intermediate, in the presence of a base, to give the compound I. Important intermediates and novel final products are also described.
    Type: Grant
    Filed: September 4, 1987
    Date of Patent: March 14, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Pierre Martin
  • Patent number: 4800753
    Abstract: A geomechanical probe for a drilling well comprises a logging box located between two inflatable preventers and including a plurality of tracers movable radially and urged outwards by springs for engaging the well wall. The tracers are mounted on pistons which are received in cylinders and urged radially inwards by springs for retracting the tracers, the pistons being driven outwardly to displace the tracers into working positions abutting the well wall by supply of actuating fluid to the cylinders. The position of the tracers is determined by differential transformers having cores fixed for radial movement with respective tracers. The preventers are inflated with pressurized fluid which is supplied thereto along passages in the probe which also supply pressurized fluid to the well space between the preventers to act upon the well wall.
    Type: Grant
    Filed: August 15, 1986
    Date of Patent: January 31, 1989
    Assignee: Compagnie Francaise Des Petroles
    Inventors: Damien M. Despax, Jean-Pierre A. Martin, Francois C. Gueuret
  • Patent number: 4778901
    Abstract: Intermediates for the production of microbicidal pyrrolines of the formula ##STR1## in which R is halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 14 C.sub.6 -haloalkyl, and n is 0, 1 or 2, and a method of converting the pyrrolines to phytofungicidal pyrroles by oxidation with bromine or oxygen. Catalysts are provided for the oxidation with oxygen.
    Type: Grant
    Filed: June 3, 1987
    Date of Patent: October 18, 1988
    Assignee: Ciba-Geigy Corporation
    Inventor: Pierre Martin
  • Patent number: 4709053
    Abstract: The invention relates to a process for the preparation of 4-phenylpyrrole derivatives of the formula I ##STR1## wherein R.sub.n, R.sub.1 and R.sub.2 are as defined in claim 1, which comprises reacting a phenacylamine of formula II ##STR2## with a compound of formula IIIT--CH.dbd.CH--R.sub.1 (III)to give an intermediate of formula IV ##STR3## and cyclizing said intermediate, in the presence of a base, to give the compound I.Important intermediates and novel final products are also described.
    Type: Grant
    Filed: September 9, 1985
    Date of Patent: November 24, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Pierre Martin
  • Patent number: 4705801
    Abstract: There is described a process for producing fungicidally active 4-phenylpyrrole derivatives of the formula I ##STR1## wherein R is halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -haloalkyl, and n is 0, 1 or 2, which process comprises reacting a 3-trifluoromethyl-4-phenylpyrrole of the formula II ##STR2## wherein R.sub.n is as defined under the formula I, and R.sub.1 is hydrogen or an acyl group, at elevated temperature and elevated pressure, with ammonia. Important intermediates and the production thereof are also described.
    Type: Grant
    Filed: October 7, 1985
    Date of Patent: November 10, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Pierre Martin, Robert W. Lang
  • Patent number: 4687861
    Abstract: There are described novel microbicides and the production thereof, which correspond to the formula I ##STR1## in which R is halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -haloalkyl, and n is 0, 1 or 2. The novel compounds are valuable active substances, particularly for controlling phytopathogenic fungi and bacteria. The compounds are suitable for protecting cultivated plants and seed, and can be advantageously used for the protection of stored stocks and provisions.
    Type: Grant
    Filed: November 22, 1985
    Date of Patent: August 18, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Pierre Martin
  • Patent number: 4665186
    Abstract: 2,2,4,4-Tetrasubstituted-4-formylbutyronitriles are intermediates for the preparation of the known 2-chloro-3,5-dimethylpyridine and 2,5-dichloro-3-methylpyridine which in turn are suitable for the production of different compounds, in particular insecticides and herbicides.
    Type: Grant
    Filed: March 31, 1986
    Date of Patent: May 12, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Eginhard Steiner, Pierre Martin
  • Patent number: 4598156
    Abstract: Indoles of the formula I which are unsubstituted in the 2- and 3-positions: ##STR1## wherein Z is hydrogen or a group --COR, and X and Y have the meanings defined in claim 1, can be produced by a novel, simple and economical process which comprises reacting a compound of the formula II ##STR2## at a temperature of between 0.degree. and 120.degree. C., in the presence of a mercury or palladium catalyst, with benzoic acid vinyl ester, or with the vinyl ester of an aliphatic C.sub.1 -C.sub.4 -monocarboxylic acid; and optionally saponifying compounds of the formula I in which Z is --COR. The compounds of the formula I can be used for example for producing indigo dyes, or they can be used as pharmaceutical or agricultural active substances.
    Type: Grant
    Filed: February 7, 1983
    Date of Patent: July 1, 1986
    Assignee: Ciba Geigy Corporation
    Inventor: Pierre Martin
  • Patent number: 4595755
    Abstract: There is described a novel process for producing 1,2,5,6-tetrahydro-4H-pyrrolo[3,2,1-ij]-quinolin-4-one (4-lilolidone), usable as fungicide and corresponding to the formula ##STR1## as well as novel 5-halo-1,2,3-(1,2-dihydropyrrolo)-4-quinolones of the formula ##STR2## in which "Hal" is chlorine or bromine, which are formed as intermediates during the process.
    Type: Grant
    Filed: July 29, 1985
    Date of Patent: June 17, 1986
    Assignee: Ciba-Geigy Corporation
    Inventor: Pierre Martin
  • Patent number: 4577028
    Abstract: Novel 5-haloalkyl-pyridines suitable for producing pesticidal compositions, particularly insecticides, and corresponding to the formula ##STR1## wherein R is a C.sub.2 -C.sub.10 -alkyl group which is uniformly or nonuniformly substituted by 1 to 21 halogen atoms, and X is halogen;processes for producing them, as well as to the novel starting products and intermediates used or intermediately produced or formed in the production processes.
    Type: Grant
    Filed: October 14, 1982
    Date of Patent: March 18, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Pierre Martin, Eginhard Steiner
  • Patent number: 4556717
    Abstract: 1-[2-(2,4-Dichlorophenyl)-pentyl]-1H-1,2,4-triazole can be produced, in a novel, simple, economical and isomer-free form, by reacting 2-(2,4-dichlorophenyl)-valeronitrile, in the presence of hydrogen, an acid and a hydrogenation catalyst, with a compound H.sub.2 N--NH--R to a compound of the formula ##STR1## hydrogenating the compound (III) catalytically to a compound ##STR2## hydrolysing compounds (IV) wherein R is not hydrogen, and converting the compounds (IV) wherein R=H, or salts thereof, with formamide and/or [3-(dimethylamino)-2-azaprop-2-en-1-ylidene]-dimethylammonium chloride, into 1-[2-(2,4-dichlorophenyl)-pentyl]-1H-1,2,4-triazole, or converting compounds (IV) wherein R=--COR', with aqueous formic acid, into the corresponding N,N'-bisformyl derivatives, and reacting these with formamide, optionally in the presence of NH.sub.3, to 1-[2-(2,4-dichlorophenyl)-pentyl]-1H-1,2,4-triazole. R in the formulae is hydrogen, --CHO, --COR', --COOR' or --CONH.sub.2, and R' is C.sub.1 -C.sub.
    Type: Grant
    Filed: June 16, 1983
    Date of Patent: December 3, 1985
    Assignee: Ciba Geigy Corporation
    Inventors: Hansjurg Wetter, Peter Baumeister, Paul Radimerski, Pierre Martin
  • Patent number: 4550165
    Abstract: There is described a novel process for producing 1,2,5,6-tetrahydro-4H-pyrrolo[3,2,1-ij]-quinolin-4-one (4-lilolidone), usable as fungicide and corresponding to the formula ##STR1##
    Type: Grant
    Filed: March 22, 1983
    Date of Patent: October 29, 1985
    Assignee: Ciba Geigy Corporation
    Inventor: Pierre Martin
  • Patent number: 4523720
    Abstract: An assembly for use with a food processor and adapted to permit processing of large food items, the assembly including a tubular member mountable on the open end of the processor bowl and provided with an inwardly directed wall terminating in a boss.
    Type: Grant
    Filed: May 21, 1984
    Date of Patent: June 18, 1985
    Assignee: Robot-Coupe, S.A.
    Inventors: John Behringer, Pierre Martin
  • Patent number: 4511571
    Abstract: Novel substituted N-(2-pyridyloxyphenyl)-N'-benzoylureas of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are each hydrogen, methyl or halogen,R.sub.5 is the radical --CHF.sub.2, or a C.sub.2 -C.sub.10 -alkyl group which is uniformly or nonuniformly substituted by 1 to 21 halogen atoms, andR.sub.6 is halogen,processes and starting products for producing these compounds, as well as compositions containing these, for use in combating pests, particularly for combating insects which infest plants and animals. The novel compounds have a specially high ovolarvicidal and ovicidal action against insects that damage plants.
    Type: Grant
    Filed: October 12, 1982
    Date of Patent: April 16, 1985
    Assignee: Ciba Geigy Corporation
    Inventors: Manfred Boger, Josef Ehrenfreund, Pierre Martin, Eginhard Steiner
  • Patent number: 4469896
    Abstract: Chloropyridines of the formula ##STR1## wherein either R is chlorine and R' is methyl or trifluoromethyl, or R is methyl, trichloromethyl or trifluoromethyl and R' is chlorine, or R and R' are methyl, can be obtained by a novel, simple process by the addition of trichloroacetaldehyde to methacrylonitrile or .alpha.-trifluoromethacrylonitrile, 2,2-dichloropropionaldehyde, pentachloropropionaldehyde or 2,2-dichloro-3,3,3-trifluoropropionaldehyde to acrylonitrile, or 2,2-dichloropropionaldehyde to methacrylonitrile, in the presence of a catalyst, in particular copper powder or copper(I) chloride, and cyclizing the open-chain intermediate obtained.The chloropyridines of the formula (I) are known per se and are suitable for the production of different compounds, in particular of insecticides and herbicides.
    Type: Grant
    Filed: July 8, 1983
    Date of Patent: September 4, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Eginhard Steiner, Pierre Martin
  • Patent number: 4360676
    Abstract: 3,3,5-Trichloroglutaric acid imide can be produced either by reacting a trichloroacetic acid alkyl ester, in the presence of a catalyst, with acrylonitrile to the corresponding 2,2,4-trichloro-4-cyanobutyric acid alkyl ester, converting this into the amide, and cyclizing the 2,2,4-trichloro-4-cyano-butanecarboxylic acid amide, in an aqueous acid medium, to the 3,3,5-trichloroglutaric acid imide; or by reacting trichloroacetonitrile, in the presence of a catalyst, to 2,2,4-trichloro-4-cyanobutyronitrile, and cyclizing this, in an aqueous acid medium, to 3,3,5-trichloroglutaric acid imide. The catalyst used for the addition reactions can be for example copper(I) chloride or copper(II) oxide. 3,3,5-Trichloroglutaric acid imide can be converted, by treatment with a dehydrating chlorinating agent, such as POCl.sub.3, into the known 2,3,5,6-tetrachloropyridine, which for its part is used for producing various active substances, particularly insecticides, herbicides and fungicides.
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: November 23, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Pierre Martin, Daniel Bellus
  • Patent number: 4354262
    Abstract: A control logic system comprising at least one sub-system including a master processor, two slave processors and an interchange memory which exchanges information between the master processor and the slave processors. The slave processors access a common memory via an interprocessor interface.
    Type: Grant
    Filed: May 5, 1980
    Date of Patent: October 12, 1982
    Assignee: Compagnie Industrielle des Telecommunications Cit-Alcatel
    Inventors: Jean Guezou, Bernard LeDieu, Jean-Pierre Martin
  • Patent number: 4351961
    Abstract: Compounds of the formula I ##STR1## wherein X is chlorine or fluorine, are suitable for producing 2,2-dimethyl-3-(2'-chloro-3',3',3'-trifluoroprop-1'-en-1'-yl)- and 2,2-dimethyl-3-(2',3'-dichloro-3',3'-difluoroprop-1'-en-1'-yl)-cyclopropan ecarboxylic acids and insecticidally effective esters thereof (pyrethroids). The cyclobutanones (I) can be produced by the addition reaction of 2,4,4,5-tetrachloro-5,5-difluoro- or 2,4,4-trichloro-5,5,5-trifluoropentane-1-carboxylic acid chloride with isobutylene, and rearrangement of the resulting 2-chloro-2-(2',2',3'-trichloro-3',3'-difluoropropyl)- or 2-chloro-2-(2',2'-dichloro-3',3',3'-trifluoropropyl)-3,3-dimethylcyclobuta n-1-one in the presence of catalysts.
    Type: Grant
    Filed: November 28, 1980
    Date of Patent: September 28, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Pierre Martin, Eginhard Steiner, Daniel Bellus
  • Patent number: 4339815
    Abstract: A multiplex connection unit for use in a time-division exchange comprising identical connection modules and a control interface connected to the control units of the exchange. A module comprises transcoders, synchronizing units (one per transcoder), a traffic distributor connected to the switching network, a signalling receiver and a signalling sender connected to the traffic distributor and to the control interface.
    Type: Grant
    Filed: May 5, 1980
    Date of Patent: July 13, 1982
    Assignee: Compagnie Industrielle des Telecommunications Cit-Alcatel
    Inventors: Jean-Rene Herledan, Bernard Le Dieu, Jean-Pierre Martin, Daniel Quemere