Abstract: The present application discloses a method for etching a Mo-based metal gate stack with an aluminum nitride barrier, comprising the steps of forming a SiO2 interface layer, a high K dielectric layer, a Mo-based metal gate layer, an AlN barrier layer, a silicon gate layer and a hard mask in sequence on a semiconductor substrate; performing lithography on the semiconductor substrate with the SiO2 interface layer, the high K dielectric layer, the Mo-based metal gate layer, the AlN barrier layer, the silicon gate layer and the hard mask using a photoresist, and etching the hard mask; removing the photoresist, and performing an anisotropic etching for silicon gate with high selectivity to the underlying AlN barrier layer and metal gate by dry etching using the hard mask; performing an anisotropic etching for the AlN barrier layer, the Mo-based metal gate layer, and the high K dielectric layer by a dry etching.

Abstract: The present invention provides a method for integrating the dual metal gates and the dual gate dielectrics into a CMOS device, comprising: growing an ultra-thin interfacial oxide layer or oxynitride layer by rapid thermal oxidation; forming a high-k gate dielectric layer on the ultra-thin interfacial oxide layer by physical vapor deposition; performing a rapid thermal annealing after the deposition of the high-k; depositing a metal nitride gate by physical vapor deposition; doping the metal nitride gate by ion implantation with P-type dopants for a PMOS device, and with N-type dopants for an NMOS device, with a photoresist layer as a mask; depositing a polysilicon layer and a hard mask by a low pressure CVD process, and then performing photolithography process and etching the hard mask; removing the photoresist, and then etching the polysilicon layer/the metal gate/the high-k dielectric layer sequentially to provide a metal gate stack; forming a first spacer, and performing ion implantation with a low energy

Abstract: A method for manufacturing a metal gate stack structure in gate-first process comprises the following steps after making conventional LOCOS and STI isolations: growing an untra-thin interface layer of oxide or oxynitride on a semiconductor substrate by rapid thermal oxidation or chemical process; depositing a high dielectric constant (K) gate dielectric on the untra-thin interface oxide layer and then performing rapid thermal annealing; depositing a TiN metal gate; depositing a barrier layer of AlN or TaN; depositing a poly-silicon film and a hard mask, and performing photo-lithography and the etching of the hard mask; after photo-resist removing, etching the poly-silicon film/metal gate/high-K gate dielectric sequentially to form the metal gate stack structure. The manufacturing method of the present invention is suitable for integration of high-K dielectric/metal gate in nano-scale CMOS devices, and removes obstacles of implementing high-K/metal gate integration.

Abstract: The present invention provides a method of adjusting a metal gate work function of an NMOS device, comprising: depositing a layer of metal nitride film or metal film on a high K dielectric as a metal gate electrode by a physical vapor deposition process; implanting elements such as Tb, Er, Yb or Sr into the metal gate electrode by an ion implantation process; performing a high temperature annealing so that the doped metal ions are driven to and accumulate on the interface between the metal gate electrode and the high K gate dielectric, or form dipoles by an interface reaction on the interface between the high K gate dielectric and SiO2, which achieves the object of adjusting an effective work function of the metal gate. This method can be widely used with simple steps included and convenient implementation. Also, the method has a strong capability of adjusting the metal gate work function, and is well-compatible with CMOS process.

Abstract: The present application discloses a method for etching a Mo-based metal gate stack with an aluminum nitride barrier, comprising the steps of forming a SiO2 interface layer, a high K dielectric layer, a Mo-based metal gate layer, an AlN barrier layer, a silicon gate layer and a hard mask in sequence on a semiconductor substrate; performing lithography on the semiconductor substrate with the SiO2 interface layer, the high K dielectric layer, the Mo-based metal gate layer, the AlN barrier layer, the silicon gate layer and the hard mask using a photoresist, and etching the hard mask; removing the photoresist, and performing an anisotropic etching for silicon gate with high selectivity to the underlying AlN barrier layer and metal gate by dry etching using the hard mask; performing an anisotropic etching for the AlN barrier layer, the Mo-based metal gate layer, and the high K dielectric layer by a dry etching.

Abstract: A method of manufacturing a metal gate/high K dielectric gate stack includes the steps of: forming an interfacial layer of SiON or SiO2 on a silicon substrate; depositing a high K dielectric film on the interfacial layer; performing a rapid thermal anneal of the high K dielectric film; depositing a TaN metal gate electrode film on the high K dielectric film; depositing a polysilicon gate layer on the TaN metal gate electrode film, and then depositing a hard mask layer; patterning a photoresist mask, and performing an anisotropic etching of the hard mask layer; removing the photoresist mask, and etching the polysilicon by reactive ion etching with the hard mask as masking layer using a mixed gas of Cl2/HBr; and etching the TaN metal gate electrode/high K dielectric gate stack by reactive ion etching with the hard mask as masking layer using BCl3-based etchant gas.

Abstract: The present application discloses a method for tuning the work function of a metal gate of the PMOS device, comprising the steps of depositing a layer of metal nitride or a metal on a layer of high-k gate dielectric by physical vapor deposition (PVD), as a metal gate; doping the metal gate with dopants such as Al, Pt, Ru, Ga, Ir by ion implantation; and driving the doped metal ions to the interface between the high-k gate dielectric and interfacial SiO2 by high-temperature annealing so that the doped metal ions accumulate at the interface or generate dipoles by interfacial reaction, which in turn tunes the work function of the metal gate. The inventive method can be widely used and its process is simple and convenient, has a better ability of tuning the work function of the metal gate, and is compatible with the conventional CMOS process.

Abstract: The present application discloses a method for manufacturing a full silicidation metal gate, comprises the steps of forming locally oxidized isolation or shallow trench isolation, performing prior-implantation oxidation and then doping 14N+; removing the prior-implantation oxidation layer formed before ion implantation, performing gate oxidation, and depositing a polysilicon layer; performing lithography and etching to form a gate electrode of polysilicon; implanting and activating dopants; depositing metal such as Ni; performing a first annealing so that Ni reacts with a portion of polysilicon; selectively removing unreacted Ni; performing a second annealing so that the whole gate electrode is converted into nickel silicide to form a full silicidation metal gate electrode. The present invention provides a full silicidation metal gate electrode which overcomes the disadvantages of polysilicon gate electrode.

Abstract: A method of patterning a dielectric layer with a Zep 520 positive EB photoresist as a mask, comprising the steps of depositing an ?-Si film on the dielectric layer; providing a layer of Zep 520 positive EB photoresist having high-resolution patterns therein by electron beam direct writing; etching the ?-Si film by chlorine-based plasma with the layer of Zep 520 positive EB photoresist as a mask, so as to transfer the high-resolution patterns of the Zep 520 positive EB photoresist to the underlying ?-Si film; removing the Zep 520 positive EB photoresist; etching the dielectric layer by fluorine-based plasma with the ?-Si film having high-fidelity patterns as a hard mask, so as to provide patterns of recesses; and removing the ?-Si film by wet etching or dry etching. The inventive method is completely compatible with and easily incorporated into the conventional CMOS processes, with high reliability and resolution for providing nanoscale fine patterns of recesses.

Abstract: A method for manufacturing a bulk Si nanometer surrounding-gate MOSFET based on a quasi-planar process, including: local oxidation isolation or shallow trench isolation; depositing buffer SiO2 oxide layer/SiN dielectric layer on the bulk Si; electron beam exposure; etching two adjacent slots; depositing SiN sidewalls; isotropically etching Si; dry oxidation; removing SiN by wet etching; forming the nanowire by stress self-constraint oxidation; depositing and anisotropically etching oxide dielectric layer and planarizing surface; releasing the nanowire by wet etching while keeping sufficiently thick SiO2 at bottom as isolation; growing gate dielectric and depositing gate material; etching back the gate and isotropically etching the gate material by using the gate dielectric as a block layer; shallow implantation in the source/drain region; depositing and etching sidewalls; deep implantation in the source/drain region to form contact.

Abstract: A method for manufacturing a bulk Si nanometer surrounding-gate MOSFET based on a quasi-planar process, including: local oxidation isolation or shallow trench isolation; depositing buffer SiO2 oxide layer/SiN dielectric layer on the bulk Si; electron beam exposure; etching two adjacent slots; depositing SiN sidewalls; isotropically etching Si; dry oxidation; removing SiN by wet etching; forming the nanowire by stress self-constraint oxidation; depositing and anisotropically etching oxide dielectric layer and planarizing surface; releasing the nanowire by wet etching while keeping sufficiently thick SiO2 at bottom as isolation; growing gate dielectric and depositing gate material; etching back the gate and isotropically etching the gate material by using the gate dielectric as a block layer; shallow implantation in the source/drain region; depositing and etching sidewalls; deep implantation in the source/drain region to form contact.