Patents by Inventor Richard B. Greenwald

Richard B. Greenwald has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4107176
    Abstract: This application is directed to cycloalkanes containing the moiety --SO.sub.2 --CH.sub.2 --X-- wherein X represents ##STR1## wherein R is hydrogen or alkyl and R' is alkyl and to the preparation of these compounds which find utility as silver halide complexing agents. This application is also concerned with cycloalkanes containing the moiety ##STR2## useful as intermediates in the preparation of the aforementioned compounds. Also included within the confines of this disclosure are the 2-thioether-substituted derivatives of certain of the above-identified cycloalkanes and with the synthesis of all of these compounds.
    Type: Grant
    Filed: February 2, 1977
    Date of Patent: August 15, 1978
    Assignee: Polaroid Corporation
    Inventors: David H. Evans, Richard B. Greenwald
  • Patent number: 4102684
    Abstract: Certain 4-hydroxypyrazoles are employed as silver halide developing agents which find particular utility in diffusion transfer photographic processes.
    Type: Grant
    Filed: August 1, 1977
    Date of Patent: July 25, 1978
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4089866
    Abstract: Novel substantially colorless dye precursors represented by the formula ##STR1## WHEREIN R.sup.1 is hydrogen or alkyl; R.sup.2, R.sup.3 and R.sup.5 is alkyl; R.sup.4 is alkyl or phenyl; Z, taken with N, represents the atoms necessary to make a benzthiazole radical; X is an acid anion; and n is 1 when R.sup.5 carries a negative charge and 2 when R.sup.5 is electrically neutral.
    Type: Grant
    Filed: November 12, 1976
    Date of Patent: May 16, 1978
    Assignee: Polaroid Corporation
    Inventors: Stanley M. Bloom, Alan L. Borror, Richard B. Greenwald
  • Patent number: 4056539
    Abstract: This invention relates to indole (na) phthalide indicator dyes substituted with a particular class of hydrogen bonding groups, such as, perhaloalkyl carbinols. These dyes are useful as optical filter agents in photographic processes to protect a selectivity exposed photosensitive material from further exposure during processing in the presence of incident light.
    Type: Grant
    Filed: March 22, 1976
    Date of Patent: November 1, 1977
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4049450
    Abstract: Certain 4-hydroxypyrazoles are employed as silver halide developing agents which find particular utility in diffusion transfer photographic processes.
    Type: Grant
    Filed: March 30, 1976
    Date of Patent: September 20, 1977
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4047954
    Abstract: Alkanes containing an intralinear sulfonyl group and an intralinear sulfinyl group separated by a single carbon substituted with at least one hydrogen atom are employed as silver halide solvents in photographic processes and compositions.
    Type: Grant
    Filed: July 19, 1976
    Date of Patent: September 13, 1977
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4047955
    Abstract: Alkanes containing an intralinear sulfonyl group and a (dialkylamino)oxosulfonium group separated by -CH- are employed as silver halide solvents in photographic processes and compositions.
    Type: Grant
    Filed: August 30, 1976
    Date of Patent: September 13, 1977
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4046568
    Abstract: Alkanes containing an intralinear sulfonyl group and an intralinear 1-piperazinylsulfonamido group separated by a single carbon substituted with at least one hydrogen atom are employed as silver halide solvents in photographic processes and compositions.
    Type: Grant
    Filed: July 19, 1976
    Date of Patent: September 6, 1977
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4032538
    Abstract: 1,3-Disulfonylcycloalkanes substituted in the 2-position with at least one hydrogen atom are employed as silver halide complexing agents in both conventional and diffusion transfer photography. Preferred compounds are those possessing an S-containing moiety substituted in the 2-position and particularly those containing 6, 7 or 8 members in the cyclic ring and substituted in the 2-position with R.sup.2 -S--CH.sub.2m wherein R.sup.2 is a hydrocarbon radical and m is a whole number 0 to 5. The latter thioether-substituted 1,3-disulfonylcycloalkanes comprise the novel compounds of the present invention.
    Type: Grant
    Filed: February 2, 1976
    Date of Patent: June 28, 1977
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4020176
    Abstract: This invention relates to highly fluorinated diazides of the formula N.sub.3 CH.sub.2 (CF.sub.2).sub.x CH.sub.2 N.sub.3 wherein x is a positive integer from 2 to 12; to the preparation of these diazides by the reaction of excess sodium azide with a ditosylate of the formula C.sub.7 H.sub.7 SO.sub.3 CH.sub.2 (CF.sub.2).sub.x CH.sub.2 O.sub.3 SC.sub.7 H.sub.7 wherein x has the same meaning given above; and to the synthesis of highly fluorinated primary diamines of the formula H.sub.2 NCH.sub.2 (CF.sub.2).sub.x CH.sub.2 NH.sub.2 wherein x has the same meaning given above by catalytic hydrogenation of said diazides.
    Type: Grant
    Filed: July 14, 1975
    Date of Patent: April 26, 1977
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4010168
    Abstract: This invention relates to 1-naphthol (na)phthalide indicator dyes substituted with a particular class of hydrogen bonding groups, such as, perhaloalkyl carbinols. These dyes are useful as optical filter agents in photographic processes to protect a selectively exposed photosensitive material from further exposure during processing in the presence of incident light.
    Type: Grant
    Filed: November 4, 1974
    Date of Patent: March 1, 1977
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4009167
    Abstract: This application is directed to compounds of the formula ##STR1## wherein R.sup.1 is lower alkyl; R.sup.2 is hydrogen, lower alkyl or --CH.sub.2 ).sub.m S--CH.sub.2).sub.n Y wherein m is a whole number 2 to 5, n is a whole number 1 to 4 and Y is hydrogen, --OH or --COOR wherein R is hydrogen or lower alkyl; and X is ##STR2## wherein A is a halide or sulfonate, R.sup.3 is hydrogen or --CH.sub.2).sub.n Y wherein n and Y have the same meaning given above, R.sup.4 is --CH.sub.2).sub.n Y wherein n and Y have the same meaning given above and R.sup.5 is lower alkyl. These compounds are useful as silver halide solvents in photography.
    Type: Grant
    Filed: April 29, 1976
    Date of Patent: February 22, 1977
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4006150
    Abstract: This invention is concerned with pyridine N-oxides substituted in the ortho and/or para position with an alkylsulfonylmethyl group which find utility in photography for effecting an increase in photographic speed.
    Type: Grant
    Filed: March 31, 1976
    Date of Patent: February 1, 1977
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 4006151
    Abstract: Novel substantially colorless dye precursors represented by the formula ##STR1## WHEREIN R.sup.1 is hydrogen or alkyl; R.sup.2, R.sup.3 and R.sup.5 is alkyl; R.sup.4 is alkyl or phenyl; Z, taken with N, represents the atoms necessary to make up a pyridine, quinoline, benzoxazole, benzthiazole or benzselenazole radical; X is an acid anion; and n is 1 when R.sup.5 carries a negative charge and 2 when R.sup.5 is electrically neutral.
    Type: Grant
    Filed: June 25, 1975
    Date of Patent: February 1, 1977
    Assignee: Polaroid Corporation
    Inventors: Stanley M. Bloom, Alan L. Borror, Richard B. Greenwald
  • Patent number: 3976647
    Abstract: This application is directed to compounds of the formula ##EQU1## wherein R.sup.1 is lower alkyl; R.sup.2 is hydrogen, lower alkyl or ##EQU2## wherein m is a whole number 2 to 5, n is a whole number 1 to 4 and Y is hydrogen, --OH or --COOR wherein R is hydrogen or lower alkyl; and X is ##EQU3## wherein R.sup.3 is hydrogen or ##EQU4## wherein n and Y have the same meaning given above, R.sup.4 is ##EQU5## wherein n and Y have the same meaning given above and R.sup.5 is lower alkyl. These compounds are useful as silver halide solvents in photography.
    Type: Grant
    Filed: April 1, 1975
    Date of Patent: August 24, 1976
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 3975423
    Abstract: This application is directed to compounds of the formula ##EQU1## wherein R.sup.1 and R.sup.2 each represent lower alkyl and m is a whole number 2 to 5, preferably 2 or 3. These compounds are useful as silver halide solvents in photography.
    Type: Grant
    Filed: May 8, 1975
    Date of Patent: August 17, 1976
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Richard B. Greenwald
  • Patent number: 3958992
    Abstract: 1,3-disulfonylcycloalkanes substituted in the 2-position with at least one hydrogen atom are employed as silver halide complexing agents in both conventional and diffusion transfer photography. Preferred compounds are those possessing an S-containing moiety substituted in the 2-position and particularly those containing 6, 7 or 8 members in the cyclic ring and substituted in the 2-position with R.sup.2 -S-CH.sub.2).sub.m wherein R.sup.2 is a hydrocarbon radical and m is a whole number 0 to 5. The latter thioether-substituted 1,3-disulfonylcycloalkanes comprise the novel compounds of the present invention.
    Type: Grant
    Filed: December 23, 1974
    Date of Patent: May 25, 1976
    Assignee: Polaroid Corporation
    Inventor: Richard B. Greenwald
  • Patent number: 3956363
    Abstract: New substituted indenyl acetic acids and nontoxic pharmaceutically acceptable amides, esters and salts derived therefrom. The substituted indenyl acetic acids disclosed herein have anit-inflammatory, anti-pyretic and analgesic activity.
    Type: Grant
    Filed: August 23, 1974
    Date of Patent: May 11, 1976
    Assignee: Merck & Co., Inc.
    Inventors: Tsung-Ying Shen, Richard B. Greenwald, Howard Jones, Bruce O. Linn, Bruce E. Witzel