Abstract: A process for depositing a thin film of a transition metal nitride, e.g., titanium nitride, on a substrate is provided. The vapors of a transition metal organometallic coompound or a transition metal amido compound are mixed with ammonia gas and allowed to react near a substrate heated to a temperature in the range of 100.degree. C. to 400.degree. C., resulting in deposition of a film on the substrate.

Abstract: A method is disclosed for the volatilization and transport of an alkaline earth metal precursor. The presence of an amine or ammonia significantly increases transport of the voltalized alkaline earth metal precursor as compared to transport under the same conditions but without the amine or ammonia.

Abstract: Transparent glass windows comprising thereon titanium silicide (TiSi.sub.2) as the principal solar screening layer for reducing transmission of near infrared and visible radiation. In some embodiments, a protective layer of silicon or metal oxide, about 300 angstroms thick, is placed thereover. The protective layer serves to protect the silicide from oxidation during high-temperature processing procedures and increases the abrasion-resistance of the window product. The particular importance of titanium silicide film is that it allows production of a window that is neutral in color when viewed in transmission as well as in reflection. Thus, one is able to provide a durable, pyrolytic, high-performance, color-neutral, solar-shielding window product.

Abstract: Transparent, electrically conductive and infrared-reflective films of zinc oxyfluoride are produced by chemical vapor deposition from vapor mixtures of zinc, oxygen and fluorine-containing compounds. The substitution of fluorine for some of the oxygen in zinc oxide results in dramatic increases in the electrical conductivity. For example, diethyl zinc, ethyl alcohol and hexafluoropropene vapors are reacted over a glass surface at 400.degree. C. to form a visibly transparent, electrically conductive, infrared reflective and ultraviolet absorptive film of zinc oxyfluoride. Such films are useful in liquid crystal display devices, solar cells, electrochromic absorbers and reflectors, energy-conserving heat mirrors, and antistatic coatings.

Abstract: The flow of a gas containing entrained particulate matter may be accurately, reliably and continuously measured, utilizing an apparatus comprising a self-cleaning orifice, including counter-rotating continuously scraped cylinders, and thermophoretic pressure taps.

Abstract: Boron nitride, in its soft or "graphitic" form is utilized as a high-temperature lubricant in an oxidizing atmosphere. A particular application for the lubricant is on or in flexible, ceramic-fiber side seals on a continuous glass coating apparatus and the moving edges of glass itself, thereby minimizing any flow to or from the reactor of gaseous reactants.

Abstract: Transparent glass sheets comprising thereon titanium-nitride as the principal solar screening layer for reducing transmission of near infrared and, thereover, a layer of tin oxide of about 300 to 800 angstroms thick. The tin oxide layer serves to protect the titanium nitride from oxidation during high-temperature processing procedures, increases the abrasion-resistance, and at roughly the midpoint of the 300 to 800 angstrom range, is useful in reducing the color and visible reflectivity properties of some titanium nitride films. In practice, some of the tin oxide, that is not required for physical protection of the TiN or visual effect, can be positioned between the nitride and the glass substrate.

Abstract: This disclosure describes a novel method of coating a substrate, e.g., a transparent glass substrate, with a very thin inorganic coating of predetermined varying composition, e.g. an electrically-conductive tin oxide coating. The coating is carried out in such a way that quality control problems associated with leakage of the coating reactants from the reaction zone are virtually eliminated. The resulting coating can exhibit excellent non-iridescent properties even at thicknesses well below on micrometer.

Abstract: This disclosure describes a novel method of coating a substrate, e.g., including a transparent glass substrate, with a very thin inorganic coating of predetermined varying composition, e.g. an electrically-conductive tin oxide coating. The coating is carried out in such a way that quality control problems associated with leakage of the coating reactants from the reaction zone are virtually eliminated. The resulting coating can exhibit excellent non-iridescent properties even at thicknesses well below one micrometer.

Abstract: A process for coating a wide moving web with the product of chemical reactants first brought into contact at a point proximate the glass surface. The process comprises a primary distribution of reactants (across the width of the substrate) through a row of small apertures, then a segregation through a secondary passage to a reaction zone at the surface of the substrate. Reactant distribution pipes are advantageously positioned and shaped to form only a gradual increase in width of the reactant flow path as they enter the reaction zone.

Abstract: A novel process for placing a thin film of a metal nitride, e.g. titanium nitride, on a glass substrate by mixing a metal halide with a reducing gas like ammonia, preferably within a range of from about 250.degree. C. to 320.degree. C., and then reacting the gases at the surface of a glass substrate heated to, e.g., about 400.degree. C. to about 700.degree. C. to form the film on the glass.

Abstract: Apparatus for continuous of mixing two reactants in proximity to an object upon which a reaction product is to be coated continuously and uniformly means is provided for maintaining reactants from premature contact. The reactant-feed holes are placed at a distance above the surface to be coated to optimize the combination of manufacturing practicality and the precision with which the holes can be economically formed.

Abstract: In a photovoltaic cell structure containing a visibly transparent, electrically conductive first layer of metal oxide, and a light-absorbing semiconductive photovoltaic second layer, the improvement comprising a thin layer of transition metal nitride, carbide or boride interposed between said first and second layers.

Abstract: This disclosure describes transparent glass window structures of the type bearing a first coating of infra-red reflective material which is advantageously less than about 0.85 microns in thickness and wherein the observance of iridescence resulting from such a first coating is markedly reduced by provision of a layer of continuously varying refractive index between the glass and the coating, such that the refractive index increases continuously from the glass to the first coating, thereby preventing the observation of iridescence. The invention also encompasses simple processes for providing such windows. A particular advantage of the invention is its efficacy with clear and lightly tinted glasses wherein the problem of iridescent color has had its greatest commercial impact.

Abstract: This disclosure describes transparent glass window structures of the type bearing a coating of infra-red reflective material which is advantageously less than about 0.85 microns in thickness and wherein the observance of iridescence resulting from such a reflective coating is markedly reduced by provision of a very thin coating system beneath said infra-red reflective coating. The thin coating system forms means to reflect and refract light to interfere with the observation of iridescence. A particular advantage of the invention is the ability of the thin coating system to be coated in a fraction of time presently required to coat anti-iridescent interlayers of the prior art.

Abstract: An improved process for chemical vapor deposition of coatings of the type bearing silicon oxide or silicon oxide/tin oxide mixtures. The process involves the use of mono- or di-alkoxy terminated permethylpolysilanes, preferably monomethoxypentamethyldisilane, as a silicon-donating reactant. Also disclosed are novel transparent silicon-bearing coating compositions which can be formed by the improved process to have any desired refractive index value from about 1.44 to about 2.0.

Abstract: This disclosure describes transparent glass window structures of the type bearing a coating of infra-red reflective material which is advantageously less than about 0.85 microns in thickness and wherein the observance of iridescence resulting from such a reflective coating is markedly reduced by provision of a very thin coating system beneath said infra-red reflective coating. The thin coating system forms means to reflect and refract light to interfere with the observation of iridescence. A particular advantage of the invention is the ability of the thin coating system to be coated in a fraction of time presently required to coat anti-iridescent interlayers of the prior art.

Abstract: An improved structure for solar cells is disclosed. It incorporates a layer of titanium dioxide between previously used layers of tin oxide and silicon. The new cells shows increased efficiency and improved thermal stability.

Abstract: This disclosure describes transparent glass window structures of the type bearing a first coating of infra-red reflective material which is advantageously less than about 0.85 microns in thickness and wherein the observance of iridescence resulting from such a first coating is markedly reduced by provision of a second coating arranged in register with said first coating, the second coating providing at least two interfaces which, with the mass of the second coating, form means to reflect and refract light therefrom to interfere with the observation of iridescence. The invention also encompasses processes for providing such windows. A particular advantage of the invention is its efficacy with clear and lightly tinted glasses wherein the problem of iridescent color has had its greatest commercial impact.

Abstract: Electrically-conductive films of tin oxide are prepared by a novel process utilizing gaseous chemical compounds which react to form a tin-fluorine bond at a temperature which is (1) high enough so that the newly-created tin-fluorine bond-bearing molecule remains in the vapor-phase; and (2) low enough so that oxidation of the molecule occurs only after the indicated re-arrangement. Films prepared by the process of the invention are characterized by surface resistances as low as 1 ohm per square when the film thickness is as thin as about a micron. These films are also characterized by extremely good reflectance of infrared radiation.