Abstract: A composition for forming an electrode. The composition includes a hybrid active material compound doped with a dopant. The hybrid active material comprises the reaction product of a metal fluoride compound and a metal complex. A method of making the composition is included.

Abstract: The disclosure is directed to an apparatus comprising a substrate and a composition disposed on the substrate. The catalyst comprises a polypropylene carbonate (PPC) and a catalyst selected from the group consisting of an acid with a pKa less than or equal to 1 in water, a phase transfer catalyst, and a metal salt. The substrate and composition can be used in insulators between batteries, for example in a battery pack.

Abstract: Energy storage devices, battery cells, and batteries of the present technology may include a first current collector and a second current collector. The batteries may include an anode material coupled with the first current collector. The batteries may include a cathode material coupled with the second current collector. The batteries may also include a polymeric material coupled between the cathode material and the anode material. The polymeric material may be characterized by a cationic backbone. The polymeric material may be configured to selectively provide anionic transport across the polymeric material while limiting cationic transport across the polymeric material.

Abstract: Energy storage devices, battery cells, and batteries of the present technology may include a first current collector and a second current collector. The batteries may include an anode material coupled with the first current collector. The batteries may include a cathode material coupled with the second current collector. The batteries may also include a separator positioned between the cathode material and the anode material. The batteries may include a hydrogen-scavenger material incorporated within the anode active material or the cathode active material. The hydrogen scavenger material may absorb or react with hydrogen at a temperature above or about 20° C.

Abstract: Insulators and polymer-coated insulators are provided. The insulators can include thermally-insulating nanoparticles and a binder configured to volatilize at a volatilization temperature. Insulators can also include an inorganic thermally-insulating material forming a porous structure. The porous structure can be configured to reduce the mean free path of gases in the insulator as compared to gases outside the porous structure. Polymer-coated insulators including an inorganic thermally-insulating material and a polymer coating disposed on the surface of the inorganic thermally-insulating material are also provided. Insulators can also include thermally-insulating nanoparticles and an opacifier. The opacifier can include a carbonaceous material coated with a refractory material that inhibits oxidation of the carbonaceous material at a carbon oxidation temperature. The insulators or polymer-coated insulators can be disposed between battery cells or battery cell blocks in an apparatus.

Abstract: Batteries are described that include a cathode, an anode, and a separator that electrically insulates the cathode from the anode. The separator includes a cation exchange membrane positioned between a first anion exchange membrane and a second anion exchange membrane, and has a hydroxide ion conductivity of at least about 10 mS/cm, and a diffusion ratio of hydroxide ions to at least one type of metal ion of at least about 100:1. Also described are methods of making a battery that include forming a separator between a cathode electrode and an anode electrode. The separator includes a cation exchange membrane positioned between a first anion exchange membrane and a second anion exchange membrane. The methods also include contacting the cathode electrode with a cathode current collector and the anode electrode with an anode current collector, where the cathode and anode currently collectors are electrically insulated from each other by a spacer material.

Abstract: Batteries are described that include a cathode material, and anode material, and a polymeric material that separates the cathode material from the anode material. The polymeric material has hydroxide ion conductivity of at least about 50 mS/cm, and a diffusion ration of hydroxide ions to at least one type of metal ion of at least about 10:1. Also described are methods of making a battery that include forming a layer of polymeric material between a first electrode and second electrode of the battery. In additional methods, the polymeric material is coated on at least one of the electrodes of the battery. In further methods, the polymeric material is admixed with at least one of the electrode materials to make a composite electrode material that is incorporated into the electrode.

Abstract: Insulators and polymer-coated insulators are provided. The insulators can include thermally-insulating nanoparticles and a binder configured to volatilize at a volatilization temperature. Insulators can also include an inorganic thermally-insulating material forming a porous structure. The porous structure can be configured to reduce the mean free path of gases in the insulator as compared to gases outside the porous structure. Polymer-coated insulators including an inorganic thermally-insulating material and a polymer coating disposed on the surface of the inorganic thermally-insulating material are also provided. Insulators can also include thermally-insulating nanoparticles and an opacifier. The opacifier can include a carbonaceous material coated with a refractory material that inhibits oxidation of the carbonaceous material at a carbon oxidation temperature. The insulators or polymer-coated insulators can be disposed between battery cells or battery cell blocks in an apparatus.

Abstract: Insulators and polymer-coated insulators are provided. The insulators can include thermally-insulating nanoparticles and a binder configured to volatilize at a volatilization temperature. Insulators can also include an inorganic thermally-insulating material forming a porous structure. The porous structure can be configured to reduce the mean free path of gases in the insulator as compared to gases outside the porous structure. Polymer-coated insulators including an inorganic thermally-insulating material and a polymer coating disposed on the surface of the inorganic thermally-insulating material are also provided. Insulators can also include thermally-insulating nanoparticles and an opacifier. The opacifier can include a carbonaceous material coated with a refractory material that inhibits oxidation of the carbonaceous material at a carbon oxidation temperature. The insulators or polymer-coated insulators can be disposed between battery cells or battery cell blocks in an apparatus.

Abstract: A composition for forming an electrode. The composition includes a metal fluoride compound doped with a dopant. The addition of the dopant: (i) improves the bulk conductivity of the composition as compared to the undoped metal fluoride compound; (ii) changes the bandgap of the composition as compared to the undoped metal fluoride compound; or (iii) induces the formation of a conductive metallic network. A method of making the composition is included.

Abstract: A bipolar battery including a first electrochemical cell and a second electrochemical cell is provided.

Abstract: A composition for forming an electrode. The composition includes a metal fluoride, such as copper fluoride, and a matrix material. The matrix material adds capacity to the electrode. The copper fluoride compound is characterized by a first voltage range in which the copper fluoride compound is electrochemically active and the matrix material characterized by a second voltage range in which the matrix material is electrochemically active and substantially stable. A method for forming the composition is included.

Abstract: A cobalt-containing phosphate material can comprise lithium (Li) (or, alternatively or additionally other alkali metal(s)), cobalt (Co), phosphate (PO4), and at least two additional metals other than Li and Co (e.g., as dopants and/or metal oxides), and can have a molar ratio of Co to a total amount of Co and the additional metals (e.g., as dopants and/or metal oxides) of at least 0.2, at least 0.3, at least 0.5, at least 0.7, or at least about 0.75. The cobalt-containing phosphate material can have a molar ratio of Co to a total amount of Co and the additional metals (e.g., as dopants and/or metal oxides) ranging from 0.2 to 0.98, from 0.3 to 0.98, from 0.3 to 0.94, from 0.5 to 0.98, from 0.5 to 0.94, or alternatively from 0.5 to 0.9, from 0.7 to 0.9, or from 0.75 to 0.85.

Abstract: An electrolyte solution comprising an additive wherein the additive is not substantially consumed during charge and discharge cycles of the electrochemical cell. Additives include Lewis acids, electron-rich transition metal complexes, and electron deficient pi-conjugated systems.

Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures, high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.

Abstract: An electrolyte solution comprising an additive wherein the additive is not substantially consumed during charge and discharge cycles of the electrochemical cell. Additives include Lewis acids, electron-rich transition metal complexes, and electron deficient pi-conjugated systems.

Abstract: A composition for forming an electrode. The composition includes a hybrid active material compound doped with a dopant. The hybrid active material comprises the reaction product of a metal fluoride compound and a metal complex. A method of making the composition is included.

Abstract: An electrode for an electrochemical cell including a metal fluoride containing active electrode material and an intrinsically conductive coating wherein the coating is applied to the active electrode material by heating the mixture for a time and at a temperature that limits degradation of the cathode active material. The active material can be a hybrid material formed from the reaction of a metal fluoride and a metal complex.

Abstract: Combinations of additives for use in electrolyte formulations that provide a number of desirable characteristics when implemented within batteries, such as reduction, suppression, and/or inhibition of undesirable gas generation over several cycles of charging and discharging, in some cases during operation at high temperature and in some cases during high temperature storage.