Abstract: Urea (multi)-(meth)acrylate (multi)-silane precursor compounds, synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds, either neat or in a solvent, and optionally with a catalyst, such as a tin compound, to accelerate the reaction. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-(meth)acrylate (multi)-silane precursor compound synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof.

Abstract: The present application is directed to a curable composition and a method for isolating a working area in a patient's mouth. The curable composition can include a borate-crosslinked polysiloxane, at least one ethylenically unsaturated monomer comprising at least two polymerizable groups, and an initiator.

Abstract: Presently described are components of a spray application system. At least one component comprises a liquid repellent surface layer. The liquid repellent surface (e.g. layer) may comprise a porous layer and a lubricant impregnated into pores of the porous layer; a fluoropolymer; a fluorochemical material and an organic polymeric binder; or a fluorochemical material melt additive and a thermoplastic polymeric material component. The component is typically a liquid reservoir, a liquid reservoir liner, a lid for a liquid reservoir or liner, or a combination thereof. In some embodiments, the component comprises a thermoplastic polymeric material. In some favored embodiments, the component is a removable liquid reservoir or liner. In some favored embodiments, the component is a collapsible liquid reservoir or liner. The spray application system typically further comprises a gravity-fed spray gun.

Abstract: A barrier film that includes a substrate, a first polymer layer on a major surface of the substrate, an oxide layer on the first polymer layer, and a second polymer layer on the oxide layer. At least one of the first or second polymer layers includes a siloxane reaction product of a secondary or tertiary amino-functional silane having at least two silane groups. A method of making the barrier film and articles and a barrier assembly including the barrier film are also disclosed.

Abstract: Compositions of matter described as urea (multi)-urethane (meth)acrylate-silanes having the general formula RA—NH—C(O)—N(R4)—R11—[O—C(O)NH—RS]n, or RS—NH—C(O)—N(R4)—R11—[O—C(O)NH—RA]n. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-urethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making such urea (multi)-urethane (meth)acrylate-silane precursor compounds, and their use in composite films and electronic devices are also described.

Abstract: Compositions of matter described as urea (multi)-urethane (meth)acrylate-silanes having the general formula RA—NH—C(O)—N(R4)—R11—[O—C(O)NH—Rs]n, or RS—NH—C(O)—N(R4)—R11—[O—C(O)NH—RA]n. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-urethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making such urea (multi)-urethane (meth)acrylate-silane precursor compounds, and their use in composite films and electronic devices are also described.

Abstract: Described are compounds of the formula: wherein RAryl is an aryl group; R1 is a linear or branched C2-C40 hydrocarbyl group; R2 is a C1-C4 alkyl; Rf is a perfluorinated group of having an average of 3 to 5 carbon atoms; and subscript x is 1 to 3.

Abstract: A hardcoat composition is described comprising urethane (meth)acrylate oligomer having a first functional groups; an acrylic polymer having second functional groups; wherein the first and second functional groups form a hydrogen bond; and silica nanoparticles. The hardcoat composition may be cured by actinic radiation, upon which the acrylic polymer may be removed by solvent extraction. Also described are articles comprising the cured hardcoat described herein disposed on a surface of a substrate and methods of making an article.

Abstract: The disclosure relates to compositions, methods of applying such compositions, and methods for curing such compositions to a depth of cure of up to about 30 mm within about 0.5 second to about two minutes per light exposure area.

Abstract: The present invention is an optically clear, curable adhesive including a polyvinylbutyral, a polyurethane (meth)acrylate, a (meth)acrylate monomer, and a photoinitiator. The polyvinylbutyral has a dynamic viscosity of between about 9 and about 13 mPA·s and a polyvinyl alcohol weight percent of less than about 18%. The polyurethane (meth)acrylate includes the reaction product of a diol, at least one diisocyanate, and a hydroxyfunctional (meth)acrylate or an isocyanatofunctional (meth)acrylate. When the optically clear, curable adhesive is placed between two transparent substrates and made into a laminate, the laminate has a haze of less than about 6%, a transmission of greater than about 88%, and an optical clarity of greater than about 98% when cured. The optically clear, curable adhesive also has a peel adhesion of at least about 100 g/cm based on ASTM 3330 when cured.

Abstract: Compositions of matter described as urea (multi)-urethane (meth)acrylate-silanes having the general formula RA—NH—C(O)—N(R4)—R11—[O—C(O)NH—RS]n, or RS—NH—C(O)—N(R4)—R11—[O—C(O)NH—RA]n. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-urethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making such urea (multi)-urethane (meth)acrylate-silane precursor compounds, and their use in composite films and electronic devices are also described.

Abstract: The present invention is an optically clear, curable adhesive including a polyvinylbutyral, a polyurethane (meth)acrylate, and a photoinitiator. The polyvinylbutyral has a dynamic viscosity of between about 9 and about 13 mPA·s and a polyvinyl alcohol weight percent of less than about 18%. The polyurethane (meth)acrylate includes the reaction product of a diol, at least one diisocyanate, and a hydroxyfunctional (meth)acrylate or an isocyanatofunctional (meth)acrylate. When the optically clear, curable adhesive is placed between two transparent substrates and made into a laminate, the laminate has a haze of less than about 6%, a transmission of greater than about 88% and an optical clarity of greater than about 98% when cured. The optically clear, curable adhesive also has a peel adhesion of at least about 100 g/cm based on ASTM 3330 when cured.

Abstract: There is provided an article comprising at least a first surface having a fluorine-containing polymeric binder resin layer and a plurality of microspheres partially embedded in a first major surface of the binder resin layer and adhered thereto; wherein the fluorine-containing polymer is derived in part from at least one partially fluorinated, or non-fluorinated, monomer; and wherein the article exhibits a stain resistance to yellow mustard at elevated temperature and humidity as measured by the change in b* of less than 50. There are also provided such articles wherein the fluorine-containing polymer is derived in part from at least one partially fluorinated, or non-fluorinated, monomer; and wherein the fluorine content along the polymeric backbone of the fluorine-containing polymer is from about 27% to 72% by weight. There are also provided such articles wherein the article is a thermoformable article exhibiting chemical resistance according to ASTM D5402-06.

Abstract: A photochromic article is provided, containing a structural component, a fluid in contact with the structural component, and a photochromic organic dye in contact with the fluid; and a barrier layer disposed on the structural component to provide a barrier for the fluid and photochromic organic dye. The structural component includes a polymeric material that is porous, includes a plurality of cavities, or a combination thereof. A method of changing a light transmission of a photochromic article is provided. A method of forming a photochromic article is also provided.

Abstract: Compounds having hindered amine and oxyalkyl amine light stabilizers can mitigate the adverse effects of actinic radiation, such as visible and ultraviolet light, in particular on substrates such as glass or ceramic substrates. Polymers derived from such compounds. Nanoparticles, substrates, such as glass or ceramic substrates, or both nanoparticles and substrates, having such compounds affixed thereto. Articles containing at least one of such polymers, nanoparticles, substrates, or compounds.

Abstract: Presently described are components of a spray application system. At least one component comprises a liquid repellent surface layer. The liquid repellent surface (e.g. layer) may comprise a porous layer and a lubricant impregnated into pores of the porous layer; a fluoropolymer; a fluorochemical material and an organic polymeric binder; or a fluorochemical material melt additive and a thermoplastic polymeric material component. The component is typically a liquid reservoir, a liquid reservoir liner, a lid for a liquid reservoir or liner, or a combination thereof. In some embodiments, the component comprises a thermoplastic polymeric material. In some favored embodiments, the component is a removable liquid reservoir or liner. In some favored embodiments, the component is a collapsible liquid reservoir or liner. The spray application system typically further comprises a gravity-fed spray gun.

Abstract: A method of making an infrared-reflecting optically transparent assembly comprises: coating a curable composition onto a major surface of an optically transparent thermoplastic polymer film; at least partially curing the curable composition, which may be optionally at least partially dried, to provide a thermoformable composite film; and laminating the thermoformable composite film to an infrared-reflecting multilayer optical film to provide the infrared-reflecting optically transparent assembly. The curable composition comprises urethane (meth)acrylate compound, (meth)acrylate monomer, and silicone (meth)acrylate. The infrared-reflecting optically transparent assembly and methods of including it in an infrared-reflecting lens assembly are also disclosed.

Abstract: Presently described are components of a spray application system. At least one component comprises a liquid repellent surface layer. The liquid repellent surface (e.g. layer) may comprise a porous layer and a lubricant impregnated into pores of the porous layer; a fluoropolymer; a fluorochemical material and an organic polymeric binder; or a fluorochemical material melt additive and a thermoplastic polymeric material component. The component is typically a liquid reservoir, a liquid reservoir liner, a lid for a liquid reservoir or liner, or a combination thereof. In some embodiments, the component comprises a thermoplastic polymeric material. In some favored embodiments, the component is a removable liquid reservoir or liner. In some favored embodiments, the component is a collapsible liquid reservoir or liner. The spray application system typically further comprises a gravity-fed spray gun.

Abstract: Described are compounds of the formula: wherein RAryl is an aryl group; R1 is a linear or branched C2-C40 hydrocarbyl group; R2 is a C1-C4 alkyl; Rf is a perfluorinated group of having an average of 3 to 5 carbon atoms; and subscript x is 1 to 3.

Abstract: A barrier film including a substrate; a base polymer layer adjacent to the substrate; an oxide layer adjacent to the base polymer layer; a adhesion-modifying layer adjacent to the oxide layer; and a top coat polymer layer adjacent to the adhesion-modifying layer. An optional inorganic layer can be applied over the top coat polymer layer. The inclusion of a adhesion-modifying layer provides for enhanced resistance to moisture and improved peel strength adhesion of the top coat polymer layer to the underlying barrier stack layers.