Abstract: Trace hydrogen may be removed from a dry gas by passing the dry gas at a temperature from about 0° C. to about 60° C. through at least one layer of a first hopcalite catalyst to produce product gas that is at least substantially free of hydrogen, wherein the first hopcalite catalyst has a molar ratio of copper to manganese of more than 0.55. Advantages include increase hydrogen capacity, lower feed and regeneration temperatures and lower sensitivity to carbon dioxide than equivalent processes using standard hopcalite catalyst having a Cu/Mn molar ratio from 0.45 to 0.55.

Abstract: Disclosed herein are rapid cycle pressure swing adsorption (PSA) process for separating O2 from N2 and/or Ar. The processes use a carbon molecular sieve (CMS) adsorbent having an O2/N2 and/or O2/Ar kinetic selectivity of at least 5 and an O2 adsorption rate (1/s) of at least 0.2000 as determined by linear driving force model at 1 atma and 86° F.

Abstract: An adsorbent for removing CO2 from a gas mixture, the adsorbent comprising alumina and a carbonate compound where the carbonate to alumina IR absorbance intensity ratio is reduced by washing the adsorbent with water. The disclosure also describes a method of making adsorbent particles, process for removing CO2 from a gas mixture using the adsorbent, and an adsorption unit using the adsorbent.

Abstract: A rapid cycle pressure swing adsorption (RCPSA) air purification process, apparatus, and device for the removal of at least one of water, carbon dioxide, nitrous oxide, and one or more hydrocarbons from a feed air stream prior to cryogenic air separation.

Abstract: Disclosed herein are multi-bed rapid cycle pressure swing adsorption (RCPSA) processes for separating O2 from N2 and/or Ar, wherein the process utilizes at least five adsorption beds each comprising a kinetically selective adsorbent for O2 having an O2 adsorption rate (1/s) of at least 0.20 as determined by linear driving force model at 1 atma and 86° F.

Abstract: Disclosed herein are novel RHO zeolites useful as kinetically selective adsorbents for oxygen and/or nitrogen. The adsorbents can be used in pressure swing adsorption processes for selectively adsorbing oxygen and/or nitrogen from feed streams such as an air stream or crude argon stream. Also disclosed are novel methods of preparing RHO zeolites, including in particular mixed-cation RHO zeolites.

Abstract: Disclosed herein are rapid cycle pressure swing adsorption (PSA) process for separating O2 from N2 and/or Ar. The processes use a carbon molecular sieve (CMS) adsorbent having an O2/N2 and/or O2/Ar kinetic selectivity of at least 5 and an O2 adsorption rate (1/s) of at least 0.2000 as determined by linear driving force model at 1 atma and 86° F.

Abstract: Disclosed herein are multi-bed rapid cycle pressure swing adsorption (RCPSA) processes for separating O2 from N2 and/or Ar, wherein the process utilizes at least five adsorption beds each comprising a kinetically selective adsorbent for O2 having an O2 adsorption rate (1/s) of at least 0.20 as determined by linear driving force model at 1 atma and 86° F.

Abstract: An adsorbent for removing CO2 from a gas mixture, the adsorbent comprising alumina and a carbonate compound where the carbonate to alumina IR absorbance intensity ratio is reduced by washing the adsorbent with water. The disclosure also describes a method of making adsorbent particles, process for removing CO2 from a gas mixture using the adsorbent, and an adsorption unit using the adsorbent.

Abstract: Disclosed herein are new processes for adsorbing oxygen using adsorbent compositions comprising RHO zeolites kinetically selective for oxygen. The RHO zeolites can be used in pressure swing adsorption processes for separating oxygen from oxygen containing streams, such as for, but not limited to, purifying a crude argon feed stream or separating oxygen from an air feed stream.

Abstract: An adsorbent for removing CO2 from a gas mixture, the adsorbent comprising alumina and a carbonate compound where the carbonate to alumina IR absorbance intensity ratio is reduced by washing the adsorbent with water. The disclosure also describes a method of making adsorbent particles, process for removing CO2 from a gas mixture using the adsorbent, and an adsorption unit using the adsorbent.

Abstract: Disclosed herein are new processes for adsorbing oxygen using adsorbent compositions comprising RHO zeolites kinetically selective for oxygen. The RHO zeolites can be used in pressure swing adsorption processes for separating oxygen from oxygen containing streams, such as for, but not limited to, purifying a crude argon feed stream or separating oxygen from an air feed stream.

Abstract: Disclosed herein are novel RHO zeolites useful as kinetically selective adsorbents for oxygen and/or nitrogen. The adsorbents can be used in pressure swing adsorption processes for selectively adsorbing oxygen and/or nitrogen from feed streams such as an air stream or crude argon stream. Also disclosed are novel methods of preparing RHO zeolites, including in particular mixed-cation RHO zeolites.

Abstract: A rapid cycle pressure swing adsorption (RCPSA) air purification process, apparatus, and device for the removal of at least one of water, carbon dioxide, nitrous oxide, and one or more hydrocarbons from a feed air stream prior to cryogenic air separation.

Abstract: An adsorbent for removing CO2 from a gas mixture, the adsorbent comprising alumina and a carbonate compound where the carbonate to alumina IR absorbance intensity ratio is reduced by washing the adsorbent with water. The disclosure also describes a method of making adsorbent particles, process for removing CO2 from a gas mixture using the adsorbent, and an adsorption unit using the adsorbent.

Abstract: An adsorbent for removing CO2 from a gas mixture, the adsorbent comprising alumina and a carbonate compound where the carbonate to alumina IR absorbance intensity ratio is reduced by washing the adsorbent with water. The disclosure also describes a method of making adsorbent particles, process for removing CO2 from a gas mixture using the adsorbent, and an adsorption unit using the adsorbent.

Abstract: The invention provides systems and methods for separating ethane and heavier hydrocarbons from a natural gas stream. In aspects of the invention, an adsorption unit is integrated with a cryogenic gas processing plant in order to overcome methane recovery limitations by sending the tail gas from the adsorption unit to the cryogenic gas processing plant to recover methane that would otherwise be lost.

Abstract: Embodiments of the present invention provide systems and methods for efficiently producing both a low-pressure ozone stream and high-pressure oxygen stream using a single air separation unit. The low-pressure ozone stream and high-pressure oxygen stream can be produced with significant energy savings and can be used in variety of applications, including the extraction of precious metals from ore with aqueous oxidation reactors and high-pressure oxidation reactors.

Abstract: Process of reducing water, CO2 and N2O in feed air, which: a first adsorbent such as alumina (25-40% volume) and a second adsorbent such as X zeolite (60-75% volume) are used; the online time of the adsorbent is determined by determining the concentration measured by an analyzer for CO2 concentration at a position within the length of the second adsorbent when a maximum level of N2O is simultaneously obtained at the downstream end of the second adsorbent in the feed direction, wherein the online time is the time taken from commencing passing the feed air to the first and second adsorbents to the measurement by the analyzer of the determined concentration of CO2; at least the second adsorbent is regenerated by heated regeneration gas at a temperature of 140° C.-220° C.; and the molar ratio of the regenerating gas to feed air supplied during one iteration of the cycle is 0.08-0.5.

Abstract: Embodiments of the present invention provide systems and methods for efficiently producing both a low-pressure ozone stream and high-pressure oxygen stream using a single air separation unit. The low-pressure ozone stream and high-pressure oxygen stream can be produced with significant energy savings and can be used in variety of applications, including the extraction of precious metals from ore with aqueous oxidation reactors and high-pressure oxidation reactors.