Patents by Inventor Tsuyoshi Sugimoto

Tsuyoshi Sugimoto has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20160349644
    Abstract: A toner includes a base particle including a polyester resin and a colorant. A sea-island structure is observed by a transmission electron microscope (TEM) in a cross-sectional image of the toner. The island structure includes the colorant and has an average diameter of from 0.2 ?m to 1.0 ?m, and the number of the island structure is from 5 to 30.
    Type: Application
    Filed: May 12, 2016
    Publication date: December 1, 2016
    Inventors: Shin HASEGAWA, Tsuyoshi SUGIMOTO, Hideyuki SANTO, Koh OHNUMA, Kohsuke NAGATA, Suzuka KARATO
  • Patent number: 9488925
    Abstract: A magenta toner for electrophotography, including: a polyester resin; and a colorant containing a naphthol-based pigment, wherein the magenta toner for electrophotography satisfies requirements <1> and <2> below: <1> [G?(100)(THF insoluble matter)] is 1.0×105 Pa to 1.0×107 Pa, and a ratio of [G?(40)(THF insoluble matter)] to the [G?(100)(THF insoluble matter)] is 3.5×10 or less, where the [G?(100)(THF insoluble matter)] is a storage modulus at 100° C. of THF insoluble matter of the toner and the [G?(40)(THF insoluble matter)] is a storage modulus at 40° C. of the THF insoluble matter of the toner; and <2> an X-ray diffraction pattern of the naphthol-based pigment in a crystalline state has a plurality of peaks in a range of 0°?2??35°, and a sum of half value widths of the peaks is 5° to 10°.
    Type: Grant
    Filed: February 25, 2015
    Date of Patent: November 8, 2016
    Assignee: Ricoh Company, Ltd.
    Inventors: Ryuta Chiba, Shinya Nakayama, Tsuyoshi Sugimoto, Hiroshi Yamada, Susumu Chiba, Shinsuke Nagai, Hiroshi Yamashita, Masana Shiba
  • Publication number: 20160259257
    Abstract: A toner includes a polyester resin including a polyester resin component A (A) insoluble in tetrahydrofuran; and a polyester resin component B (B) soluble in tetrahydrofuran. The toner has a first glass transition temperature (Tg1st) of from 20° C. to 50° C., measured at a first temperature rising in differential scanning calorimetry (DSC), and satisfies the following formulae (1) and (2): T=1/{a/(TgA+273)+b/(TgB+273)}?273??(1) T?TgAB>30×a??(2) wherein a and b represent weight ratios of (A) and (B) to a total weight of (A) and (B), and satisfy the equation a+b=1; and TgA, TgB and TgAB represent second glass transition temperatures (Tg2nd), measured at a second temperature rising in differential scanning calorimetry, of (A), (B), and a mixture of (A) and (B), respectively.
    Type: Application
    Filed: February 23, 2016
    Publication date: September 8, 2016
    Inventors: Tsuyoshi SUGIMOTO, Shinya NAKAYAMA, Hiroshi YAMADA, Hideyuki SANTO, Shin HASEGAWA, Suzuka KARATO, Kohsuke NAGATA, Koh OHNUMA
  • Publication number: 20160231661
    Abstract: A toner, wherein the toner has glass transition temperature [Tg1st (toner)] of 20° C. to 50° C., where the glass transition temperature [Tg1st (toner)] is measured in a first heating in differential scanning calorimetry (DSC) of the toner, wherein tetrahydrofuran (THF) insoluble matter of the toner has glass transition temperature [Tg2nd (THF insoluble matter)] of ?40° C. to 30° C., where the glass transition temperature [Tg2nd (THF insoluble matter)] is measured in a second heating in differential scanning calorimetry (DSC) of the tetrahydrofuran (THF) insoluble matter, wherein the THF insoluble matter has a storage modulus at 100° C. [G?(100) (THF insoluble matter)] of 1.0×105 Pa to 1.0×107 Pa, and wherein a ratio of a storage modulus of the THF insoluble matter at 40° C. [G?(40) (THF insoluble matter)] to the storage modulus of the THF insoluble matter at 100° C. [G?(100) (THF insoluble matter)] is 3.5×10 or less.
    Type: Application
    Filed: August 29, 2014
    Publication date: August 11, 2016
    Inventors: Shinsuke NAGAI, Shinya NAKAYAMA, Tsuyoshi SUGIMOTO, Susumu CHIBA, Kohsuke NAGATA, Daisuke ASAHINA
  • Publication number: 20160223926
    Abstract: Provided is a resin for a toner, which is a copolymer including a crystalline segment, and having a maximum elastic stress value at 100° C. (ES-100) of 1,000 Pa or less, and a maximum elastic stress value at 70° C. (ES70) of 1,000 Pa or greater when the temperature is lowered from 100° C. to 70° C., where the maximum elastic stress values are measured according to a large amplitude oscillatory shear procedure.
    Type: Application
    Filed: August 13, 2014
    Publication date: August 4, 2016
    Inventors: Azumi MIYAAKE, Daisuke ASAHINA, Toyoshi SAWADA, Hiroshi YAMASHITA, Tsuyoshi SUGIMOTO, Shinya NAKAYAMA, Susumu CHIBA, Satoyuki SEKIGUCHI
  • Publication number: 20160209766
    Abstract: A toner, including: a polyester resin, wherein the polyester resin includes a diol component and a crosslink component as constituent components thereof, wherein the diol component contains an aliphatic diol having 3 to 10 carbon atoms in an amount of 50 mol % or more, wherein the crosslink component contains a trihydric or higher aliphatic alcohol, and wherein the toner has a glass transition temperature (Tg1st) of 20° C. to 50° C., where the glass transition temperature (Tg1st) is measured in first heating in differential scanning calorimetry (DSC) of the toner.
    Type: Application
    Filed: August 13, 2014
    Publication date: July 21, 2016
    Inventors: Susumu CHIBA, Tsuyoshi SUGIMOTO, Shinya NAKAYAMA, Kohsuke NAGATA, Shinsuke NAGAI, Daisuke ASAHINA
  • Publication number: 20160209767
    Abstract: A toner, including: a colorant; a binder resin; and a releasing agent, wherein the binder resin includes a polyester resin, and the toner satisfies requirements (1) and (2) below: (1): G?(50)?3.0×107 Pa and 1.0×105 Pa?G?(60)?1.0×107 Pa, where G?(50) is a storage modulus at 50° C. of the toner and G?(60) is a storage modulus at 60° C. of the toner; and (2): a spin-spin relaxation time of the toner at 50° C. measured by solid echo method of pulse NMR is 1.0 ms or shorter.
    Type: Application
    Filed: August 13, 2014
    Publication date: July 21, 2016
    Inventors: Kohsuke NAGATA, Shinya NAKAYAMA, Tsuyoshi SUGIMOTO, Daisuke ASAHINA, Susumu CHIBA
  • Publication number: 20160187795
    Abstract: Provided is a toner including at least a polyester resin, wherein the polyester resin has a urethane bond and a urea bond, wherein a ratio (B)/(A) between a nitrogen content (A) in a compound that is contained in a pyrolysate of the toner produced when the toner is pyrolyzed from 50° C. to 700° C. and has two isocyanate groups and a nitrogen content (B) in a compound that is contained in the pyrolysate and has one isocyanate group and one amino group satisfies 0.6?(B)/(A)?1.3, and wherein a nitrogen content in the surface of the toner is from 0 atom % to 0.9 atom %.
    Type: Application
    Filed: December 27, 2015
    Publication date: June 30, 2016
    Inventors: Akinori SAITOH, Tsuyoshi SUGIMOTO, Shinsuke NAGAI, Hiroyuki TAKEDA, Takahiro KADOTA, Akihiro TAKEYAMA
  • Publication number: 20160091812
    Abstract: A toner includes a binder resin including a copolymer resin containing structural units derived from crystalline and non-crystalline resins, respectively. Spin-spin relaxation time (t50) of the toner at 50° C. measured by pulse NMR is ?0.05 msec., spin-spin relaxation time (t130) at 130° C. when warmed from 50° C. to 130° C. is >15 msec., and spin-spin relaxation time (t?70) at 70° C. when cooled from 130° C. to 70° C. is ?1.00 msec. A binarized image obtained by binarizing a phase image of the toner observed by a tapping mode AFM based on intermediate value between maximum and minimum phase difference values in the phase image includes first phase difference images constituted by large phase-difference portions and a second phase difference image constituted by a small phase-difference portion. The first phase difference images are dispersed in the second phase difference image. The dispersion diameter of the first phase difference images is 150 nm or less.
    Type: Application
    Filed: November 27, 2013
    Publication date: March 31, 2016
    Inventors: Keiji MAKABE, Tsuyoshi SUGIMOTO, Akinori SAITO, Suzuka AMEMORI, Toyoshi SAWADA, Hiroshi YAMASHITA, Shinya NAKAYAMA, Atsushi YAMAMOTO, Daisuke ASAHINA, Satoyuki SEKIGUCHI
  • Patent number: 9239530
    Abstract: To provide a toner, which contains a colorant, a binder resin, and a releasing agent, wherein the toner satisfies the following (a) to (c): (a) the toner contains at least a polyester resin as the binder resin; (b) the toner has Tg1st of 25° C. to 50° C.; and (c) the toner has a TMA compressive deformation rate (TMA %) of 10% or lower at 50° C. under a condition having relative humidity of 70%, wherein the Tg1st is glass transition temperature of the toner for first heating, as the toner is measured by a DSC system (a differential scanning calorimeter).
    Type: Grant
    Filed: September 12, 2013
    Date of Patent: January 19, 2016
    Assignee: Ricoh Company, Ltd.
    Inventors: Daisuke Asahina, Hiroshi Yamashita, Masana Shiba, Tsuyoshi Sugimoto, Yukari Fukuda, Rintaro Takahashi
  • Publication number: 20160004179
    Abstract: A toner, including: a copolymerization resin, wherein the copolymerization resin includes: a unit derived from a polyester resin including a polycarboxylic acid having a valence of 2 or more and a polyol having a valence of 2 or more; and a unit derived from a resin having a polyhydroxycarboxylic acid skeleton, where the unit derived from the resin having a polyhydroxycarboxylic acid skeleton is bonded to the unit derived from the polyester resin via at least one of a urethane group and a urea group, and wherein the toner has a relative degree of crystallization of 10% or more and less than 50%.
    Type: Application
    Filed: January 20, 2014
    Publication date: January 7, 2016
    Applicant: Ricoh Company, Ltd.
    Inventors: Tsuyoshi SUGIMOTO, Hiroshi YAMASHITA, Daisuke ASAHINA, Susumu CHIBA, Satoyuki SEKIGUCHI
  • Patent number: 9207553
    Abstract: To provide a toner including a binder resin and a colorant, wherein the toner has a glass transition temperature by differential scanning calorimetry (DSC) of 20° C. or greater and less than 50° C., an endothermic peak temperature by DSC of 50° C. or greater and less than 80° C. and an amount of compressive deformation at 50° C. by a thermomechanical analysis of 5% or less.
    Type: Grant
    Filed: June 12, 2013
    Date of Patent: December 8, 2015
    Assignee: Ricoh Company, Ltd.
    Inventors: Tsuyoshi Sugimoto, Hiroshi Yamashita, Susumu Chiba, Satoyuki Sekiguchi
  • Patent number: 9201325
    Abstract: A toner including a binder resin which contains a crystalline polyester resin and a non-crystalline polyester resin, wherein the crystalline polyester resin has at least two diffraction peaks in a range of 20°<2?<25° as detected by X-ray diffraction measurement, and has a melting point which is 60° C. or higher but lower than 80° C., and wherein the diffraction peaks each have a half width which is less than 1.0°.
    Type: Grant
    Filed: April 14, 2011
    Date of Patent: December 1, 2015
    Assignee: Ricoh Company, Ltd.
    Inventors: Tsuyoshi Sugimoto, Osamu Uchinokura, Satoshi Ogawa, Junichi Awamura, Satoshi Kojima, Daisuke Ito, Teruki Kusahara, Daisuke Inoue, Mamoru Hozumi, Shoko Sato
  • Patent number: 9152067
    Abstract: Toner contains a binder resin and a colorant, wherein the binder resin contains a resin having a polyhydroxy carboxylic acid skeleton, wherein the toner has a half effusion temperature of from 80° C. to 120° C. as measured by a temperature rising method using a flow tester.
    Type: Grant
    Filed: July 1, 2013
    Date of Patent: October 6, 2015
    Assignee: Ricoh Company, Ltd.
    Inventors: Susumu Chiba, Hiroshi Yamashita, Daisuke Asahina, Tsuyoshi Sugimoto, Taichi Nemoto, Satoyuki Sekiguchi
  • Publication number: 20150253687
    Abstract: A magenta toner for electrophotography, including: a polyester resin; and a colorant containing a naphthol-based pigment, wherein the magenta toner for electrophotography satisfies requirements <1> and <2> below: <1> [G?(100)(THF insoluble matter)] is 1.0×105 Pa to 1.0×107 Pa, and a ratio of [G?(40)(THF insoluble matter)] to the [G?(100)(THF insoluble matter)] is 3.5×10 or less, where the [G?(100)(THF insoluble matter)] is a storage modulus at 100° C. of THF insoluble matter of the toner and the [G?(40)(THF insoluble matter)] is a storage modulus at 40° C. of the THF insoluble matter of the toner; and <2> an X-ray diffraction pattern of the naphthol-based pigment in a crystalline state has a plurality of peaks in a range of 0°?2??35°, and a sum of half value widths of the peaks is 5° to 10°.
    Type: Application
    Filed: February 25, 2015
    Publication date: September 10, 2015
    Inventors: Ryuta Chiba, Shinya Nakayama, Tsuyoshi Sugimoto, Hiroshi Yamada, Susumu Chiba, Shinsuke Nagai, Hiroshi Yamashita, Masana Shiba
  • Publication number: 20150248070
    Abstract: A toner, including: base particles containing a polyester resin, a colorant, and a release agent, wherein the toner has a glass transition temperature (Tg1st) of 20° C. to 50° C. where the glass transition temperature (Tg1st) is measured in first heating of differential scanning calorimetry (DSC) of the toner, wherein tetrahydrofuran (THF) insoluble matter of the toner has a glass transition temperature [Tg2nd (THF insoluble matter)] of 30° C. or lower where the glass transition temperature [Tg2nd (THF insoluble to matter)] is measured in second heating of differential scanning calorimetry (DSC) of the THF insoluble matter, and wherein 50% or less of the colorant is present within a region of 1,000 nm from a surface of each of the base particles toward a center thereof.
    Type: Application
    Filed: February 24, 2015
    Publication date: September 3, 2015
    Inventors: Ryuta CHIBA, Shinya Nakayama, Hiroshi Yamada, Minoru Masuda, Akinori Saitoh, Hideyuki Santo, Shinsuke Nagai, Akihiro Takeyama, Hiroyuki Takeda, Tsuyoshi Sugimoto, Suzuka Amemori, Kohsuke Nagata
  • Publication number: 20150240346
    Abstract: An in-line coating device includes: a coating section configured to perform coating on a workpiece; and a transport section configured to transport a plurality of the workpieces in the coating section. The coating section is provided with a plurality of coating materials which are aligned. The transport section transports the workpieces such that the workpieces face the plurality of coating materials. The in-line coating device includes a voltage applying section configured to, when the workpiece is transported and faces each coating material, apply to the workpiece, a bias voltage to attract particles emitted from the coating material toward the workpiece. The bias voltages applied to the workpiece by the voltage applying section when the workpiece faces one of the coating materials can be different from that applied when the workpiece faces another one of the coating material.
    Type: Application
    Filed: September 30, 2013
    Publication date: August 27, 2015
    Inventors: Keisuke Yamamoto, Satoru Moriya, Toshihide Asano, Tsuyoshi Sugimoto, Motoki Yaginuma, Yasuhiro Numao
  • Publication number: 20150153671
    Abstract: A resin composition for a toner including a polyester resin and a colorant, wherein the polyester resin has A(10)-A(180) of 70 or greater, where A(10) (%) is a transmittance of light having a wavelength of 500 nm through a mixture of 20 parts by mass of the polyester resin added to 80 parts by mass of ethyl acetate and stirred at 25° C. for 10 minutes, and A(180) (%) is the transmittance after the mixture is left to stand for 3 hours.
    Type: Application
    Filed: June 13, 2013
    Publication date: June 4, 2015
    Inventors: Yoshitaka Yamauchi, Kazumi Suzuki, Tatsuya Morita, Hiroshi Yamashita, Tsuyoshi Sugimoto, Daisuke Asahina
  • Patent number: 9034548
    Abstract: A toner containing colorant, releasing agent, and binder resin containing crystalline polyester resin, and non-crystalline polyester resin containing urethane bond, urea bond, or both, the non-crystalline polyester resin containing first and second non-crystalline polyester resins, both containing urethane bond, or urea bond, or both, wherein monomers constituting the first non-crystalline polyester resin contains isocyanate monomer for forming the urethane bond, the urea bond, or the both, in an amount of 0.5 mol % or greater to total amount of the monomers, monomers constituting the second non-crystalline polyester resin contain isocyanate monomer for forming the urethane bond, the urea bond, or the both, in an amount of 0.5 mol % or greater to total amount of the monomers, the first non-crystalline polyester resin has Tg of ?60° C. or higher but lower than 10° C., and the second non-crystalline polyester resin has Tg of 30° C. or higher but lower than 70° C.
    Type: Grant
    Filed: December 10, 2012
    Date of Patent: May 19, 2015
    Assignee: Ricoh Company, Ltd.
    Inventors: Tatsuru Moritani, Hiroshi Yamashita, Tsuyoshi Sugimoto, Daisuke Asahina, Rintaro Takahashi, Susumu Chiba
  • Publication number: 20150132690
    Abstract: A toner includes a binder resin including a copolymer resin (A) having a structural unit derived from a crystalline polyester resin (A1) and another structural unit derived from an amorphous polyester resin (A2), and an amorphous resin (B) in an amount of from 30 to 70% by weight based on total weight of the binder resin. The binarized image of the AFM phase image of the binder resin consists of first phase-contrast images serving as large-phase-difference portions and second phase-contrast images serving as small-phase-difference portions with the first phase-contrast images dispersed in the second phase-contrast images forming a dot-like or streaky structure. The average value of dispersion diameters, corresponding to maximum Feret diameters, of the first phase-contrast images in the dot-like structure, or widths, corresponding to minimum Feret diameters, of the first phase-contrast images in the streaky structure, is less than 100 nm.
    Type: Application
    Filed: November 6, 2014
    Publication date: May 14, 2015
    Inventors: Daisuke ASAHINA, Azumi MIYAAKE, Tsuyoshi SUGIMOTO, Susumu CHIBA, Shinya NAKAYAMA, Hiroshi YAMASHITA, Satoyuki SEKIGUCHI