Abstract: An ultraviolet light-resistant article that includes: a substrate having a glass or glass-ceramic composition and first and second primary surfaces; an ultraviolet light-absorbing element having a an absorptivity greater than 50% at wavelengths from about 100 nm to about 380 nm and a thickness between about 10 nm and about 100 nm; and a dielectric stack formed with a plasma-enhanced process. Further, the light-absorbing element is between the substrate and the dielectric stack. Alternatively, the light-absorbing element can include one or more ultraviolet light-resistant layers disposed within the dielectric stack over the first primary surface.

Abstract: Methods of characterizing ion-exchanged chemically strengthened glass containing lithium are disclosed. The methods allow for performing quality control of the stress profile in chemically strengthened Li-containing glasses having a surface stress spike produced in a potassium-containing salt, especially in a salt having both potassium and sodium. The method allows the measurement of the surface compression and the depth of the spike, and its contribution to the center tension, as well as the compression at the bottom of the spike, and the total center tension and calculation of the stress at the knee where the spike and the deep region of the stress profile intersect. The measurements are for a commercially important profile that is near-parabolic in shape in most of the interior of the substrate apart from the spike.

Abstract: Chemically strengthened glass articles having at least one deep compressive layer extending from a surface of the article to a depth of layer DOL of about 130 ?m up to about 175 ?m or, alternatively, to a depth of compression (DOC) in a range from about 90 ?m to about 120 ?m within the article. The compressive layer has a stress profile that includes a first substantially linear portion extending from a relatively shallow depth to the DOL or DOC and a second portion extending from the surface to the shallow depth. The second portion is substantially linear at a depth from 0 ?m to 5 ?m and has a steeper slope than that of the first portion of the profile. Methods of achieving such stress profiles are also described.

Abstract: Silicon-silica hybrid materials made by metallothermal reduction from silica and methods of producing such compositions are provided. The compositions have novel properties and provide significant improvements in Coulombic efficiency, dilithiation capacity, and cycle life when used as anode materials in lithium battery cells.

Abstract: Prism-coupling systems and methods for characterizing large depth-of-layer waveguides formed in glass substrates are disclosed. One method includes making a first measurement after a first ion-exchange process that forms a deep region and then performing a second measurement after a second ion-exchange process that forms a shallow region. Light-blocking features are arranged relative to the prism to produce a mode spectrum where the contrast of the mode lines for the strongly coupled low-order modes is improved at the expense of loss of resolution for measuring characteristics of the shallow region. Standard techniques for determining the compressive stress, the depth of layer or the tensile strength of the shallow region are then employed. A second measurement can be made using a near-IR wavelength to measure characteristics of the deeper, first ion-exchange process. Systems and methods of measuring ion-exchanged samples using shape control are also disclosed.

Abstract: Methods of characterizing ion-exchanged chemically strengthened Li-containing glasses include: a) measuring a mode spectrum of the glass sample; b) using the mode spectrum, estimating a first contribution to the center tension associated with a spike region and estimating a second contribution to the center tension due to a deep region only, wherein the deep region is assumed to follow a power-law stress profile; and c) determining a total center tension by adding of the first and second contributions to the center tension. The methods can be used for quality control during manufacturing of glass samples by comparing the total center tension to a center tension specification that provides optimum strength and durability.

Abstract: Prism-coupling systems and methods for characterizing large depth-of-layer waveguides formed in glass substrates are disclosed. One method includes making a first measurement after a first ion-exchange process that forms a deep region and then performing a second measurement after a second ion-exchange process that forms a shallow region. Light-blocking features are arranged relative to the prism to produce a mode spectrum where the contrast of the mode lines for the strongly coupled low-order modes is improved at the expense of loss of resolution for measuring characteristics of the shallow region. Standard techniques for determining the compressive stress, the depth of layer or the tensile strength of the shallow region are then employed. A second measurement can be made using a near-IR wavelength to measure characteristics of the deeper, first ion-exchange process. Systems and methods of measuring ion-exchanged samples using shape control are also disclosed.

Abstract: A non-frangible glass article strengthened by a dual or two-step ion exchange (IOX) process, where the first IOX step leads to a depth of compressive layer FSM_DOL>0.1·t or, in some embodiments, FSM_DOL>0.15·t, where t is the thickness of the glass, is provided. The glass article has a compressive stress CS1 after the first IOX step at the surface of from 100 MPa to 400 MPa or, in some embodiments, from 150 MPa to 300 MPa. The first IOX step is followed by a second IOX step, leading to a “spike” compressive stress CS2 after the second IOX step at the surface of greater than 500 MPa or, in some embodiments, 700 MPa. The width of the spike generated by the second IOX is between 1 ?m and 30 ?m, or between 8 ?m and 15 ?m, using the criteria where the magnitude (absolute value) of the slope of the spike is higher than 20 MPa/?m.

Abstract: A crystallized layer can be formed on a substrate from a precursor layer deposited on a surface of the substrate. The precursor layer can be an oxide, a nitride, a carbide, or an oxynitride. The process for forming the crystallized layer includes melting the precursor layer formed on the surface of the substrate by localized topical heating of the precursor layer and then cooling the melted precursor layer so that it crystallized to form a scratch resistant crystallized layer. The scratch resistant crystallized layer can have a hardness of 15 GPa or greater.

Abstract: A glass exhibiting non-frangible behavior in a region where substantially higher central tension is possible without reaching frangibility is provided. This region allows greater extension of the depth of compression in which fracture-causing flaws are arrested, without rendering the glass frangible despite the presence of high central tension region in the sample.

Abstract: Methods of forming metal coatings by metallothermal reduction from metal oxide-containing glasses and glass ceramics are provided. The resulting products have metal surfaces which can be porous and further, have high reflectivities.

Abstract: Systems and methods for measuring the stress profile of ion-exchanged glass are disclosed, based on the TM and TE guided mode spectra of the optical waveguide formed in the ion-exchanged glass. The method includes digitally defining from the TM and TE guided mode spectra positions of intensity extrema, and calculating respective TM and TE effective refractive indices from these positions. The method also includes calculating TM and TE refractive index profiles nTM(z) and nTE(z) using either an inverse WKB calculation or a fitting process that employs assumed functions for nTM(z) and nTE(z). The method also includes calculating the stress profile S(z)=[nTM(z)?nTE(z)]/SOC, where SOC is a stress optic coefficient for the glass substrate. Systems for performing the method are also disclosed.

Abstract: Chemically strengthened glass articles having at least one deep compressive layer extending from a surface of the article to a depth of layer DOL of about 130 ?m up to about 175 ?m or, alternatively, to a depth of compression (DOC) in a range from about 90 ?m to about 120 ?m within the article. The compressive layer has a stress profile that includes a first substantially linear portion extending from a relatively shallow depth to the DOL or DOC and a second portion extending from the surface to the shallow depth. The second portion is substantially linear at a depth from 0 ?m to 5 ?m and has a steeper slope than that of the first portion of the profile. Methods of achieving such stress profiles are also described.

Abstract: Glass bodies and methods of making glass bodies and more particularly glass bodies, for example, microlenses and arrays of microlenses and methods of making the same are described. Cordierite powder is vitrified to form a glass body or glass bodies for instance a microlens or microlenses.

Abstract: One embodiment of the disclosure relates to an optical connector. The optical connector may include a ferrule, a waveguide, and an inorganic adhesive composition. The ferrule may include a fiber-receiving passage defining an inner surface. The inorganic adhesive composition may be disposed within the ferrule and in contact with the inner surface of the ferrule and the waveguide. The inorganic adhesive composition may include at least about 50% by weight of metal oxide.

Abstract: A sol-gel method for forming durable, scratch-resistant coatings on glass substrates. Zirconia coatings, for example, are formed from a solution of zirconium oxychloride octahydrate in an organic, polar, aprotic solvent such as dimethylformamide. Annealed coatings, which optionally include an additive such as graphene, have a low coefficient of friction and can exhibit high hardness and hydrophobicity.

Abstract: Apparatus and methods for measuring mode spectra for ion-exchanged glass substrates having a steep index region are disclosed. An interfacing fluid is provided between the coupling prism and the glass substrate. The interfacing fluid thickness is selected so that the variation in modal birefringence with fluid thickness is reduced to an acceptable level. The coupling prism can include a prism coating on the coupling surface so that the substrate-prism interface includes the prism coating. The coupling prism can also include stand-off members that serve to define the thickness of the interfacing fluid.

Abstract: One embodiment of the disclosure relates to an optical connector. The optical connector may include a ferrule, a waveguide, and an inorganic adhesive composition. The ferrule may include a fiber-receiving passage defining an inner surface. The inorganic adhesive composition may be disposed within the ferrule and in contact with the inner surface of the ferrule and the waveguide. The inorganic adhesive composition may include at least about 50% by weight of metal oxide.

Abstract: A planar ion-exchanged glass sheet for out-of-plane light beam coupling includes a first surface, a ion-exchanged first glass region adjacent and parallel to the first surface, a core glass region adjacent and parallel to the first glass region, a ion-exchanged second glass region adjacent and parallel to the core glass region, and a second surface adjacent and parallel to the second glass region. One edge of the glass sheet has an angled end face that is inclined to the plane extends across a thickness of at least one of the glass regions. Methods of making the planar ion-exchanged glass sheet, coupling an out-of-plane light beam into a plane using the planar ion-exchanged glass sheet, and scattering the coupled light to illuminate at least select regions of an exposed surface of the glass sheet are also disclosed.

Abstract: Systems and methods of for measuring birefringence and stress in a sample made of ion-exchanged glass or a ceramic are disclosed, wherein the method includes digitally capturing TE and TM angular spectra of intensity versus pixel number for the sample. The TE and TM angular spectra are processed to minimize differences between respective regions of the TE and TM angular spectra. The amount of shift in pixels that best overlaps the processed TE and TM spectra is determined. The birefringence B is calculated by multiplying the pixel shift by the index resolution. The stress is calculated by multiplying the birefringence by the stress-optic coefficient.