Publication number: 20200119341
Abstract: A spinel-structured lithium manganese-based positive electrode active material includes a lithium manganese oxide represented by Formula 1, and a coating layer which is disposed on a surface of the lithium manganese oxide and includes at least one coating element selected from the group consisting of aluminum, titanium, tungsten, boron, fluorine, phosphorus, magnesium, nickel, cobalt, iron, chromium, vanadium, copper, calcium, zinc, zirconium, niobium, molybdenum, strontium, antimony, bismuth, silicon, and sulfur, and a positive electrode and a lithium secondary battery which include the positive electrode active material, Li1+aMn2?bM1bO4?cAc ??[Formula 1] wherein, in Formula 1, M1 is at least one metallic element including lithium (Li), A is at least one element selected from the group consisting of fluorine, chlorine, bromine, iodine, astatine, and sulfur, 0?a?0.2, 0<b?0.5, and 0?c?0.1.
Type:
Application
Filed:
November 6, 2018
Publication date:
April 16, 2020
Applicant:
LG Chem, Ltd.
Inventors:
So Ra Baek, Wang Mo Jung, Min Suk Kang, Sang Wook Lee, Eun Sol Lho, Wen Xiu Wang
Publication number: 20200020942
Abstract: A positive electrode active material contains a lithium-rich lithium manganese-based oxide, wherein the lithium manganese-based oxide has a composition of the following chemical formula (1), and wherein a lithium ion conductive glass-ceramic solid electrolyte layer containing at least one selected from the group consisting of thio-LISICON(thio-lithium super ionic conductor), LISICON(lithium super ionic conductor), Li2S—SiS2—Li4SiO4, and Li2S—SiS2—P2S5—Lil is formed on the surface of the lithium manganese-based oxide particle: Li1?xMyMn1?x?yO2?zQz ??(1) wherein, 0<x?0.2, 0<y?0.2, and 0?z?0.5; M is at least one element selected from the group consisting of Al, Mg, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Ga, In, Ru, Zn, Zr, Nb, Sn, Mo, Sr, Sb, W, Ti and Bi; and Q is at least one element selected from the group consisting of P, N, F, S and Cl.
Type:
Application
Filed:
September 7, 2018
Publication date:
January 16, 2020
Applicant:
LG Chem, Ltd.
Inventors:
Gi Beom Han, Jintae Hwang, Wang Mo Jung, Min Kyu You, Chi Ho Jo, Sungbin Park, Inseong Ju, Hyuck Hur, Younguk Park, Tae Gu Yoo