Abstract: Disclosed is a method of preparing inorganic particles using a hydrothermal synthesis device, including introducing a precursor liquid or slurry stream including a reaction precursor for preparation of an inorganic material into a hydrothermal synthesis reactor, introducing a supercritical liquid stream including water into the hydrothermal synthesis reactor, preparing an inorganic slurry by hydrothermal reaction in the hydrothermal synthesis reactor and discharging the inorganic slurry therefrom, and filtering the discharged inorganic slurry, wherein the precursor liquid or slurry stream includes an NH3 source at a high temperature of the supercritical liquid stream and thus clogging of the stream in the hydrothermal synthesis reactor is inhibited by pH changes in the hydrothermal reaction.

Abstract: The present disclosure provides a method for testing a cycle life of a positive electrode active material for a secondary battery capable of predicting and assessing a cycle life of a positive electrode active material with high accuracy and excellent reliability in a short period of time using a simple method.

Abstract: The present disclosure suppresses, by uniformly coating lithium transition metal composite oxide particles with LiwNbxOy (1?w?8, 1?x?13, 1?y?20), a direct contact between a positive electrode active material and a liquid electrolyte and thereby suppresses a side reaction between the positive electrode active material and the liquid electrolyte, and improves stability at high temperatures and high voltages, and in particular, is effective in enhancing battery performance by forming Li2O—Nb2O5 through reacting the coating layer with Li present on the surfaces of the lithium transition metal composite oxide particles.

Abstract: A positive electrode active material for a secondary battery is provided. The positive electrode active material is a secondary particle including primary particles of a lithium composite metal oxide that contains nickel, cobalt, and manganese, wherein the manganese content in the lithium composite metal oxide exceeds 50 at % with respect to the sum content of nickel, cobalt, and manganese, and the primary particle is doped with one or two or more dopant elements selected from the group consisting of Nb, Sn, Mo, and Ta, the dopant element content being higher in a surface region of the primary particle than in the interior of the primary particle, and the dopant element concentration being 500 to 5,000 ppm with respect to the total weight of the positive electrode active material. In addition, a lithium secondary battery which includes the positive electrode active material is provided.

Abstract: A positive electrode active material for a secondary battery and a secondary battery including the same are provided. The positive electrode active material for a secondary battery includes on the surface of a core, a surface treatment layer composed of a B and Si-containing amorphous oxide, and thus may exhibit reduced moisture reactivity, improved thermal and chemical stability, and high-voltage stability.

Abstract: Disclosed is a precursor for preparing a lithium composite transition metal oxide. More particularly, a transition metal precursor, including a composite transition metal compound represented by Formula 1 below, used to prepare a lithium transition metal oxide: NiaMbMn1?(a+b)(O1?x)2??(1) wherein M is at least one selected form the group consisting of Ti, Co, Al, Cu, Fe, Mg, B, Cr, Zr, Zn and Period II transition metals; and 0.2?a?0.25, 0?b?0.1, and 0<x<0.5.

Abstract: The present disclosure relates to a positive electrode active material which reduces lithium by-products and improves structural stability and includes a lithium-nickel based transition metal composite oxide in which an alkaline earth metal having oxidation number of +2 is doped and a phosphate coated layer formed on the outer surface of the composite oxide. Accordingly, a second battery including the positive electrode active material has excellent capacity characteristics, and also improves structural stability during charging/discharging and prevents swelling, thereby being capable of exhibiting excellent life characteristics. Therefore, the present invention may be easily applied to industry in need thereof, and particularly to electric vehicles industry requiring high capacity and long-term life characteristics.

Abstract: Disclosed are a cathode active material for lithium secondary batteries including lithium-containing metal oxide particles; a first surface treatment layer formed on the surfaces of the lithium-containing metal oxide particles and including at least one compound selected from the group consisting of fluorine-doped metal oxides and fluorine-doped metal hydroxides; and a second surface treatment layer formed on a surface of the first surface treatment layer and including a fluorine copolymer, and a method of manufacturing the same.

Abstract: Disclosed are a cathode active material and a lithium secondary battery including the same, and a method of manufacturing the cathode active material, the method including: (a) manufacturing a lithium metal oxide according to formula 1 below: Li1+zNiaMnbCo1?(a+b)O2 ??(1) wherein 0?z?0.1, 0.1?a?0.8, 0.1?b?0.8 and a+b<1; (b) dry mixing the lithium metal oxide, and a precursor including zirconium and fluorine; and (c) changing the precursor including zirconium and fluorine into ZrO2 and substituting some of oxygen (O) anions with F by heat-treatment after dry mixing of step (b), wherein the cathode active material is coated with ZrO2 and F.

Abstract: Disclosed is a lithium-cobalt based complex oxide represented by Formula 1 below including lithium, cobalt and manganese wherein the lithium-cobalt based complex oxide maintains a crystal structure of a single O3 phase at a state of charge (SOC) of 50% or more based on a theoretical amount: LixCo1-y-zMnyAzO2??(1) wherein 0.95?x?1.15, 0?y?0.3 and 0?z?0.2; and A is at least one element selected the group consisting of Al, Mg, Ti, Zr, Sr, W, Nb, Mo, Ga, and Ni.

Abstract: Disclosed is a lithium manganese (Mn)-based oxide including Mn as an essential transition metal and having a layered crystal structure, in which the amount of Mn is greater than that of other transition metal(s), the lithium manganese-based oxide exhibits flat level section characteristics in which release of oxygen occurs together with lithium deintercalation during first charging in a high voltage range of 4.4 V or higher, and at least one of a transition metal layer including Mn and an oxygen layer is substituted or doped with a pillar element.

Abstract: The present invention provides a method for preparing a core-shell structured particle, the method using a continuous Couette-Taylor crystallizer in which a core reactant inlet, a shell reactant inlet, and a product outlet are sequentially formed on an outer cylinder along a flow direction of a fluid flowing in a Couette-Taylor fluid passage between the outer cylinder and an inner cylinder, wherein a core particle is primarily formed in the fluid passage by a core reactant supplied through the core reactant inlet; a shell layer is formed on a surface of the core particle to cover the core particle by a shell reactant supplied through the shell reactant inlet; and a core-shell structured particle in which the shell layer is formed on the circumference of the core particle, is discharged to the outside through the product outlet.

Abstract: Provided are a method of preparing a cathode active material including coating a surface of a lithium transition metal oxide with a lithium boron oxide by dry mixing the lithium transition metal oxide and a boron-containing compound and performing a heat treatment, and a cathode active material prepared thereby. A method of preparing a cathode active material according to an embodiment of the present invention may easily transform lithium impurities present in a lithium transition metal oxide into a structurally stable lithium boron oxide by performing a heat treatment near the melting point of a boron-containing compound. Also, a coating layer may be formed in which the lithium boron oxide is uniformly coated in an amount proportional to the used amount of the boron-containing compound even at a low heat treatment temperature.

Abstract: Disclosed are a transition metal precursor for preparation of a lithium transition metal oxide, in which a ratio of tap density of the precursor to average particle diameter D50 of the precursor satisfies the condition represented by Equation 1 below, and a lithium transition metal oxide prepared using the same.

Abstract: Disclosed is a method of preparing inorganic particles using a hydrothermal synthesis device, including introducing a precursor liquid or slurry stream including a reaction precursor for preparation of an inorganic material into a hydrothermal synthesis reactor, introducing a supercritical liquid stream including water into the hydrothermal synthesis reactor, preparing an inorganic slurry by hydrothermal reaction in the hydrothermal synthesis reactor and discharging the inorganic slurry therefrom, and filtering the discharged inorganic slurry, wherein the precursor liquid or slurry stream includes an NH3 source at a high temperature of the supercritical liquid stream and thus clogging of the stream in the hydrothermal synthesis reactor is inhibited by pH changes in the hydrothermal reaction.

Abstract: A device for preparing a lithium composite transition metal oxide includes first and second mixers continuously arranged in a direction in which a fluid proceeds, wherein the first mixer has a closed structure including a hollow fixed cylinder, a rotating cylinder having the same axis as that of the hollow fixed cylinder and having an outer diameter that is smaller than an inner diameter of the fixed cylinder, an electric motor to generate power for rotation of the rotating cylinder, a rotation reaction space, as a separation space between the hollow fixed cylinder and the rotating cylinder, in which ring-shaped vortex pairs periodically arranged along a rotating shaft and rotating in opposite directions are formed, first inlets through which raw materials are introduced into the rotation reaction space, and a first outlet to discharge a reaction fluid formed from the rotation reaction space.

Abstract: The present disclosure relates to a cathode active material for a lithium secondary battery with improved rate characteristics in which a spinel surface structure is formed by fluorine coating on a surface of layered lithium nickel-manganese-cobalt cathode active material and a method for manufacturing the same, and according to the present disclosure, there is provided a lithium secondary battery with improved rate characteristics that may be charged to a capacity close to a full charge in a short time when compared to a related art and thus is suitable for high capacity of a secondary battery.

Abstract: Disclosed is a hydrothermal synthesis device for continuously preparing an inorganic slurry using a hydrothermal method. The hydrothermal synthesis device includes a mixer to mix at least one precursor solution for preparing an inorganic material, injected via at least one supply tube, to prepare an intermediate slurry, a connection tube provided at a side of the mixer, continuously discharging the prepared intermediate slurry to a reactor, and having a hydrophobic coating on an inner surface of a portion thereof adjacent to the reactor, and the reactor performing hydrothermal reaction of the intermediate slurry supplied from the connection tube by receiving a liquid stream heated to supercritical or subcritical conditions using a heat exchanger and connected to the connection tube into which the intermediate slurry prepared from the mixer is introduced and to at least one injection tube into which the heated liquid stream is injected.

Abstract: Disclosed are a precursor of an electrode active material for a lithium secondary battery, in which a metal material ionizable through electrolytic decomposition is uniformly coated on a surface of a primary precursor formed of a transition metal hydrate, and a method of preparing the same.

Abstract: Disclosed is a hydrothermal synthesis device for continuously preparing an inorganic slurry using a hydrothermal method. The hydrothermal synthesis device includes a mixer to mix at least one precursor solution for preparing an inorganic material, injected via at least one supply tube, to prepare an intermediate slurry, a connection tube provided at a side of the mixer, continuously discharging the prepared intermediate slurry to a reactor, and having an inner surface contacting a precursor solution mixture on which abrasive polishing has been performed, and the reactor performing hydrothermal reaction of the intermediate slurry supplied from the connection tube by receiving a liquid stream heated to supercritical or subcritical conditions using a heat exchanger and connected to the connection tube into which the intermediate slurry prepared from the mixer is introduced and to at least one injection tube into which the heated liquid stream is injected.