Patents by Inventor Willi Volksen

Willi Volksen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5446074
    Abstract: New photosensitive polyamic acid precursors are disclosed which have the formula: ##STR1## where Z is a tetravalent organic radical which contains at least one aromatic ring, Z' is a divalent organic radical which contains at least one aromatic ring, and R* is a photosensitive group. Particularly preferred compounds include BPDA-PDA and BPDA-ODA polyamic acid precursors. The precursor compositions within the practice of this invention are i-line, g-line, and i-/g-line active and show good photoresolution. The films formed exhibit excellent self-adhesion and adhesion to glass ceramic and silicon wafer substrates have low internal stress, a very low degree of solvent swelling, high thermal stability, and excellent mechanical properties such as high modulus/tensile strength and high elongation at break.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: August 29, 1995
    Assignee: International Business Machines Corporation
    Inventors: George Czornyj, Moonhor Ree, Willi Volksen, Dominic C. Yang
  • Patent number: 5310625
    Abstract: The present invention relates to an improved process for forming negative tone images of photosensitive polyimides on a substrate having improved wall angles.
    Type: Grant
    Filed: August 3, 1993
    Date of Patent: May 10, 1994
    Assignee: International Business Machines Corporation
    Inventors: Marie Angelopoulos, Daniel G. Berger, Jeffrey W. Labadie, Eric D. Perfecto, Martha I. Sanchez, Sally A. Swanson, Willi Volksen
  • Patent number: 5302851
    Abstract: The present invention relates to a circuit assembly comprising the polyimide poly(3,4'-oxydiphenylene pyromellitimide).
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: April 12, 1994
    Assignee: International Business Machines Corporation
    Inventors: Moonhor Ree, Willi Volksen, Do Y. Yoon
  • Patent number: 5206117
    Abstract: The present invention relates to photosensitive negative and positive tone compositions for imagewise deposition of polyimide on a substrate.
    Type: Grant
    Filed: March 13, 1992
    Date of Patent: April 27, 1993
    Inventors: Jeffrey W. Labadie, Dennis R. McKean, Willi Volksen, Gregory M. Wallraff
  • Patent number: 5045608
    Abstract: Block copolymers of polyimide and poly (phenylquinoxaline) have been synthesized. They are useful, particularly as dielectric layers in thin film multilayer structures. The most preferred embodiments are formed from polyimides which are those from pyromellitic dianhydride and oxydianiline. The most preferred poly (phenylquinoxaline) is a monofunctional oligomer, which yields the best microstructure.
    Type: Grant
    Filed: September 27, 1989
    Date of Patent: September 3, 1991
    Assignee: IBM Corporation
    Inventors: James L. Hedrick, Jr., Donald C. Hofer, Jeffrey W. Labadie, Sally A. Swanson, Willi Volksen
  • Patent number: 4954578
    Abstract: Thin films of polyimide having electrical insulation, low thermal expansion, high glass transition temperature, and good adhesion are made by dispersing fine domains of relatively flexible polyimide which is fluorinated in a matrix of relatively rigid polyimide.
    Type: Grant
    Filed: October 25, 1988
    Date of Patent: September 4, 1990
    Assignee: International Business Machines Corporation
    Inventors: Moonhor Ree, Sally A. Swanson, Willi Volksen, Do Y. Yoon
  • Patent number: 4849501
    Abstract: A composition for the application of a planar polyimide coating having a glass transition temperature above 300.degree. C. comprises a solution in an anhydrous, aprotic solvent of an aromatic diamine and a dialkyldihydrogen pyromellitate which is more than 90% meta isomer.
    Type: Grant
    Filed: April 19, 1988
    Date of Patent: July 18, 1989
    Assignee: International Business Machines Corporation
    Inventors: Richard D. Diller, deceased, Anthony F. Arnold, Ying Ying Cheng, Patricia M. Cotts, Donald C. Hofer, Mahmoud Khojasteh, Elwood H. Macy, Prabodh R. Shah, Willi Volksen
  • Patent number: 4818812
    Abstract: Integrated circuit module wherein the cap is sealed to the substrate with a liquid crystalline polyester melt containing about 25 to about 100 mole percent of recurring Units I and O to about 75 mole percent of recurring Units II wherein ##STR1## wherein each R and R.sub.2 is arylene or cycloalkylene or alkylene or alkylidene.
    Type: Grant
    Filed: August 22, 1983
    Date of Patent: April 4, 1989
    Assignee: International Business Machines Corporation
    Inventors: James Economy, John R. Susko, Willi Volksen, Robin A. Wheater
  • Patent number: 4612210
    Abstract: A surface coating of high glass temperature and superior mechanical properties along with excellent planarization and gap filling is used to coat substrates. The coating comprises a polyamide alkyl ester from a pyromellitic alkyl diester and a para-linked aromatic diamine dissolved in a solvent containing at least 10% of a co-solvent boiling above 220.degree. C.
    Type: Grant
    Filed: July 25, 1985
    Date of Patent: September 16, 1986
    Assignee: International Business Machines Corporation
    Inventors: Donald C. Hofer, Debra B. LaVergne, Robert J. Twieg, Willi Volksen
  • Patent number: 4467000
    Abstract: A process for coating a substrate to provide good planarization and good mechanical and thermal stability, the process comprising applying to the substrate an amino-terminated oligomer and an ester, with the oligomer being formed from an aromatic diamine and from an aromatic dianhydride, and the ester being formed from an aromatic tetracarboxylic acid and an alcohol, and by reacting said oligomer and said ester in situ, with the process being characterized in that the ester reacts with an amine group of the oligomer to form a high molecular weight polyamide at a temperature between 40.degree. C. and 140.degree. C., and continues to react to form a cyclic imide.
    Type: Grant
    Filed: March 29, 1983
    Date of Patent: August 21, 1984
    Assignee: International Business Machines Corporation
    Inventors: James Economy, Willi Volksen, Do Y. Yoon
  • Patent number: 4259223
    Abstract: Microspheres are produced by cobalt gamma radiation initiated polymerization of a dilute aqueous vinyl pyridine solution. Addition of cross-linking agent provides higher surface area beads. Addition of monomers such as hydroxyethylmethacrylate acrylamide or methacrylamide increases hydrophilic properties and surface area of the beads. High surface area catalytic supports are formed in the presence of controlled pore glass substrate.
    Type: Grant
    Filed: October 2, 1978
    Date of Patent: March 31, 1981
    Assignee: California Institute of Technology
    Inventors: Alan Rembaum, Amitava Gupta, Willi Volksen
  • Patent number: 4224359
    Abstract: Microspheres are produced by cobalt gamma radiation initiated polymerization of a dilute aqueous vinyl pyridine solution. Addition of cross-linking agent provides higher surface area beads. Addition of monomers such as hydroxyethylmethacrylate acrylamide or methacrylamide increases hydrophilic properties and surface area of the beads. High surface area catalytic supports are formed in the presence of controlled pore glass substrate.
    Type: Grant
    Filed: October 2, 1978
    Date of Patent: September 23, 1980
    Assignee: California Institute of Technology
    Inventors: Alan Rembaum, Amitava Gupta, Willi Volksen
  • Patent number: 4197220
    Abstract: Amine containing polymeric microspheres such as polyvinyl pyridine are complexed with metal salts or acids containing metals such as gold, platinum or iron. After reduction with sodium borohydride, the salt is reduced to finely divided free metal or metal oxides, useful as catalysts. Microspheres containing covalent bonding sites can be used for labeling or separating proteins.
    Type: Grant
    Filed: May 26, 1978
    Date of Patent: April 8, 1980
    Assignee: California Institute of Technology
    Inventors: Alan Rembaum, Willi Volksen
  • Patent number: 4170685
    Abstract: Microspheres are produced by cobalt gamma radiation initiated polymerization of a dilute aqueous vinyl pyridine solution. Addition of cross-linking agent provides higher surface area beads. Addition of monomers such as hydroxyethylmethacrylate acrylamide or methacrylamide increases hydrophilic properties and surface area of the beads. High surface area catalytic supports are formed in the presence of controlled pore glass substrate.
    Type: Grant
    Filed: March 22, 1977
    Date of Patent: October 9, 1979
    Assignee: California Institute of Technology
    Inventors: Alan Rembaum, Amitava Gupta, Willi Volksen
  • Patent number: 4123396
    Abstract: Amine containing polymeric microspheres such as polyvinyl pyridine are complexed with metal salts or acids containing metals such as gold, platinum or iron. After reduction with sodium borohydride, the salt is reduced to finely divided free metal or metal oxides, useful as catalysts. Microspheres containing covalent bonding sites can be used for labeling or separating proteins.
    Type: Grant
    Filed: August 27, 1976
    Date of Patent: October 31, 1978
    Assignee: California Institute of Technology
    Inventors: Alan Rembaum, Willi Volksen
  • Patent number: RE34524
    Abstract: A composition for the application of a planar polymide coating having a glass transition temperature above 300.degree. C. comprises a solution in an anhydrous, aprotic solvent of .Iadd.the reaction product .Iaddend.of an aromatic diamine and a .[.dialkyldihydrogen.]. .Iadd.dialkyl .Iaddend.pyromellitate .Iadd.diacyl chloride .Iaddend.which .[.is more than.]. .Iadd.comprises about .Iaddend.90% .Iadd.or more .Iaddend.meta isomer.
    Type: Grant
    Filed: July 18, 1991
    Date of Patent: January 25, 1994
    Assignee: International Business Machines Corporation
    Inventors: Richard D. Diller, deceased, Anthony F. Arnold, Ying Y. Cheng, Patricia M. Cotts, Donald C. Hofer, Mahmoud M. Khojasteh, Elwood H. Macy, Prabodh R. Shah, Willi Volksen