Patents by Inventor Yasushi Tohi

Yasushi Tohi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10435494
    Abstract: A novel ethylene/?-olefin/non-conjugated polyene copolymer comprising structural units derived from ethylene (A), an ?-olefin (B) of 3 to 20 carbon atoms, and a non-conjugated polyene (C) containing intramolecularly two or more partial structures in total selected from the group consisting of structures of Formulae (I) and (II), and having a small number of long-chain branches, The novel ethylene/?-olefin/non-conjugated polyene copolymer contains a non-conjugated polyene such as VNB as a copolymerization component and a small long-chain branch content and is excellent in curing properties in the case of crosslinking using peroxide; and a process for producing the ethylene/?-olefin/non-conjugated polyene copolymer, and a use thereof are provided.
    Type: Grant
    Filed: July 9, 2018
    Date of Patent: October 8, 2019
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Kotaro Ichino, Yoshiharu Kikuchi, Yasushi Tohi, Tomoaki Matsugi, Yasushi Yanagimoto, Mitsunao Arino, Keisuke Shishido, Mikio Hosoya
  • Patent number: 10131726
    Abstract: A novel ethylene/?-olefin/non-conjugated polyene copolymer comprising structural units derived from ethylene (A), an ?-olefin (B) of 3 to 20 carbon atoms, and a non-conjugated polyene (C) containing intramolecularly two or more partial structures in total selected from the group consisting of structures of Formulae (I) and (II), and having a small number of long-chain branches, The novel ethylene/?-olefin/non-conjugated polyene copolymer contains a non-conjugated polyene such as VNB as a copolymerization component and a small long-chain branch content and is excellent in curing properties in the case of crosslinking using peroxide; and a process for producing the ethylene/?-olefin/non-conjugated polyene copolymer, and a use thereof are provided.
    Type: Grant
    Filed: February 13, 2015
    Date of Patent: November 20, 2018
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Kotaro Ichino, Yoshiharu Kikuchi, Yasushi Tohi, Tomoaki Matsugi, Yasushi Yanagimoto, Mitsunao Arino, Keisuke Shishido, Mikio Hosoya
  • Publication number: 20180319917
    Abstract: A novel ethylene/?-olefin/non-conjugated polyene copolymer comprising structural units derived from ethylene (A), an ?-olefin (B) of 3 to 20 carbon atoms, and a non-conjugated polyene (C) containing intramolecularly two or more partial structures in total selected from the group consisting of structures of Formulae (I) and (II), and having a small number of long-chain branches, The novel ethylene/?-olefin/non-conjugated polyene copolymer contains a non-conjugated polyene such as VNB as a copolymerization component and a small long-chain branch content and is excellent in curing properties in the case of crosslinking using peroxide; and a process for producing the ethylene/?-olefin/non-conjugated polyene copolymer, and a use thereof are provided.
    Type: Application
    Filed: July 9, 2018
    Publication date: November 8, 2018
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Kotaro ICHINO, Yoshiharu KIKUCHI, Yasushi TOHI, Tomoaki MATSUGI, Yasushi YANAGIMOTO, Mitsunao ARINO, Keisuke SHISHIDO, Mikio HOSOYA
  • Publication number: 20160355622
    Abstract: A novel ethylene/?-olefin/non-conjugated polyene copolymer comprising structural units derived from ethylene (A), an ?-olefin (B) of 3 to 20 carbon atoms, and a non-conjugated polyene (C) containing intramolecularly two or more partial structures in total selected from the group consisting of structures of Formulae (I) and (II), and having a small number of long-chain branches, The novel ethylene/?-olefin/non-conjugated polyene copolymer contains a non-conjugated polyene such as VNB as a copolymerization component and a small long-chain branch content and is excellent in curing properties in the case of crosslinking using peroxide; and a process for producing the ethylene/?-olefin/non-conjugated polyene copolymer, and a use thereof are provided.
    Type: Application
    Filed: February 13, 2015
    Publication date: December 8, 2016
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Kotaro ICHINO, Yoshiharu KIKUCHI, Yasushi TOHI, Tomoaki MATSUGI, Yasushi YANAGIMOTO, Mitsunao ARINO, Keisuke SHISHIDO, Mikio HOSOYA
  • Publication number: 20160280819
    Abstract: A catalyst for olefin polymerization, comprising: (A-1) a bridged metallocene compound represented by the following Formula [1-1], and (b) at least one compound selected from: (b-1) an organoaluminum oxy compound, (b-2) a compound which forms an ion pair, and (b-3) an organoaluminum compound: wherein in Formula [1-1], R1, R2, R3, R4, R5, R8, R9, and R12 are each selected from a hydrogen, a hydrocarbon group and a silicon-containing group; the four groups of R6, R7, R10, and R11 are not hydrogen atoms, and are each selected from a hydrocarbon group or a silicon-containing group; R13 and R14 are each a hydrocarbon group or the like, excluding a hydrogen atom and a methyl group; M is Ti, Zr or the like; Y is carbon or the like; Q is a halogen or the like; and j is an integer from 1 to 4.
    Type: Application
    Filed: June 6, 2016
    Publication date: September 29, 2016
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Yasushi TOHI, Masahiko OKAMOTO, Ryoji MORI, Takashi NAKAGAWA, Shigenobu IKENAGA, Hiromasa MARUBAYASHI, Kouji NAGAHASHI, Shiro OTSUZUKI
  • Patent number: 9382356
    Abstract: A catalyst for olefin polymerization, comprising: (A-1) a bridged metallocene compound represented by the following Formula [1-1], and (b) at least one compound selected from: (b-1) an organoaluminum oxy compound, (b-2) a compound which forms an ion pair, and (b-3) an organoaluminum compound: wherein in Formula [1-1], R1, R2, R3, R4, R5, R8, R9, and R12 are each selected from a hydrogen, a hydrocarbon group and a silicon-containing group; the four groups of R6, R7, R10, and R11 are not hydrogen atoms, and are each selected from a hydrocarbon group or a silicon-containing group; R13 and R14 are each a hydrocarbon group or the like, excluding a hydrogen atom and a methyl group; M is Ti, Zr or the like; Y is carbon or the like; Q is a halogen or the like; and j is an integer from 1 to 4.
    Type: Grant
    Filed: November 16, 2007
    Date of Patent: July 5, 2016
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Yasushi Tohi, Masahiko Okamoto, Ryoji Mori, Tatsuya Nakamura, Takashi Yukita, Takashi Nakagawa, Miyuki Konno, Yuichi Yamamura, Shiegenobu Ikenaga, Mayumi Hiwara, Naritoshi Hirota, Hiromasa Marubayashi, Kouji Nagahashi, Shiro Otsuzuki, Tomohiro Yamaguchi, Masashi Higuchi, Yasuo Ichiki, Takayuki Kajihara
  • Patent number: 9340628
    Abstract: To provide a process for producing an olefin polymer, which makes it possible to use, as a solvent for use in the catalyst preparation and the like, an aliphatic hydrocarbon solvent instead of an aromatic hydrocarbon solvent causing large environmental burden, and which has good olefin polymerization activity. A process for producing an olefin polymer, characterized by having a step comprising feeding an olefin polymerization catalyst solution, which is obtained by mixing a metallocene compound, a compound that reacts with the metallocene compound to form an ion pair and at least one compound selected from an organoaluminum compound and an organoaluminum oxy compound with a saturated hydrocarbon solvent, to a polymerization reactor and solution-polymerizing an olefin in the polymerization reactor.
    Type: Grant
    Filed: April 23, 2013
    Date of Patent: May 17, 2016
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Yasushi Tohi, Yasuhiro Hasada, Hiroshi Noguchi
  • Publication number: 20150094434
    Abstract: To provide a process for producing an olefin polymer, which makes it possible to use, as a solvent for use in the catalyst preparation and the like, an aliphatic hydrocarbon solvent instead of an aromatic hydrocarbon solvent causing large environmental burden, and which has good olefin polymerization activity. A process for producing an olefin polymer, characterized by having a step comprising feeding an olefin polymerization catalyst solution, which is obtained by mixing a metallocene compound, a compound that reacts with the metallocene compound to form an ion pair and at least one compound selected from an organoaluminum compound and an organoaluminum oxy compound with a saturated hydrocarbon solvent, to a polymerization reactor and solution-polymerizing an olefin in the polymerization reactor.
    Type: Application
    Filed: April 23, 2013
    Publication date: April 2, 2015
    Inventors: Yasushi Tohi, Yasuhiro Hasada, Hiroshi Noguchi
  • Patent number: 8802779
    Abstract: The propylene-based polymer composition of the present invention includes 41 to 95 parts by weight of a propylene-based polymer (A) having a Tm measured by DSC of not less than 120° C. and not more than 170° C., and 59 to 5 parts by weight (provided that the total of (A) and (B) is 100 parts by weight) of a propylene/ethylene/?-olefin copolymer (B) that contains 84.0 to 60.0 mol % of constitutional units derived from propylene, 15.0 to 30.0 mol % of constitutional units derived from ethylene, and 1.0 to 10.0 mol % of constitutional units derived from an ?-olefin having 4 to 20 carbon atoms and has a B-value of not less than 0.9 and not more than 1.5. This polymer composition is excellent in transparency, low-temperature impact resistance, and mechanical properties (flexibility or rigidity, etc.) and also excellent in heat resistance.
    Type: Grant
    Filed: December 22, 2006
    Date of Patent: August 12, 2014
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiko Okamoto, Ryoji Mori, Takashi Nakagawa, Hiromasa Marubayashi, Shigenobu Ikenaga, Yasushi Tohi, Kouji Nagahashi
  • Patent number: 8785574
    Abstract: According to the invention, a single or plural kinds of bridged metallocene compounds having differing cyclopentadienyl-derived groups afford macromonomers that are a source of long-chain branches and simultaneously catalyze the repolymerization of the macromonomers into olefin polymers having a large number of long-chain branches, small neck-in in the T-die extrusion, small take-up surge and superior mechanical strength. The olefin polymerization catalysts and the polymerization processes can efficiently produce the olefin polymers.
    Type: Grant
    Filed: December 20, 2013
    Date of Patent: July 22, 2014
    Assignees: Mitsui Chemicals, Inc., Prime Polymer Co., Ltd.
    Inventors: Hideki Bando, Yasuo Satoh, Takashi Yukita, Yasuyuki Harada, Yoshiho Sonobe, Yasushi Tohi, Yusuke Sekioka, Masao Suzuki, Daisuke Tanifuji
  • Publication number: 20140114031
    Abstract: Metallocene compounds of the invention are useful as olefin polymerization catalysts or catalyst components. Olefin polymerization processes of the invention involve an olefin polymerization catalyst containing the metallocene compound. In detail, the olefin polymerization catalysts can catalyze with high polymerization activity the production of olefin polymers having high melt tension, excellent mechanical strength and good particle properties, and the olefin polymerization processes involve the catalysts. Ethylene polymers according to the invention are obtained by the polymerization processes and have higher processability and easy-opening properties and particularly excellent mechanical strength compared to conventional ethylene polymers. Thermoplastic resin compositions of the invention contain the ethylene polymers.
    Type: Application
    Filed: December 20, 2013
    Publication date: April 24, 2014
    Applicant: Prime Polymer Co., Ltd.
    Inventors: Hideki BANDO, Yasuo SATOH, Takashi YUKITA, Yasuyuki HARADA, Yoshiho SONOBE, Yasushi TOHI, Yusuke SEKIOKA, Masao SUZUKI, Daisuke TANIFUJI
  • Patent number: 8604140
    Abstract: The invention provides a method for preventing fouling in chemical equipment, comprising adding an antifouling agent which comprises a polyoxyalkylene polymer having Mn of 30,000 or less to a component in the chemical equipment.
    Type: Grant
    Filed: March 31, 2010
    Date of Patent: December 10, 2013
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Naoshi Nagai, Shiro Nakatsuka, Kazuoki Nakai, Kenji Sugimura, Yasushi Tohi, Ken Yoshitsugu, Hideki Bando, Yasuyuki Harada
  • Patent number: 8445609
    Abstract: An object of the present invention is to provide a method for producing an olefin polymer, with which an olefin polymer having good particle properties can be produced in high activity, fouling inside the polymerization vessel, such as a vessel wall or an impeller, can be effectively prevented, and a long-term stable operation is achieved. A method for producing an olefin polymer according to the present invention is characterized by including (co)polymerizing at least one olefin selected from the group consisting of ethylene and ?-olefins having 3 to 20 carbon atoms in a polymerization vessel in the presence of (A) a solid catalyst component for olefin polymerization, (B) an aliphatic amide, and (C) an organoaluminum compound.
    Type: Grant
    Filed: April 21, 2010
    Date of Patent: May 21, 2013
    Assignees: Mitsui Chemicals, Inc., Prime Polymer Co., Ltd.
    Inventors: Yasushi Tohi, Ken Yoshitsugu, Naoya Akiyama, Toshio Fujita, Masatoshi Chinaka
  • Publication number: 20120135903
    Abstract: A lubricating oil composition comprising: boron atoms from about 5-75 ppm; and 100% by mass being (i) 90 to 10% of a (co)polymer of specified kinematic viscosity and acid values, primarily derived from 1-decene, (ii) 5 to 85% of a (co)polymer having specified kinematic viscosity and molecular weight distribution, mostly derived from 1-octene, and (iii) 5 to 15% of a fatty acid ester.
    Type: Application
    Filed: May 5, 2011
    Publication date: May 31, 2012
    Inventors: Shota ABE, Ryousuke Kaneshige, Yuriko Ilmura, Yasushi Tohi, Michio Toriumi, Junichi Yoshizono
  • Publication number: 20120095167
    Abstract: The invention provides a method for preventing fouling in chemical equipment, comprising adding an antifouling agent which comprises a polyoxyalkylene polymer having Mn of 30,000 or less to a component in the chemical equipment.
    Type: Application
    Filed: March 31, 2010
    Publication date: April 19, 2012
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Naoshi Nagai, Shiro Nakatsuka, Kazuoki Nakai, Kenji Sugimura, Yasushi Tohi, Ken Yoshitsugu, Hideki Bando, Yasuyuki Harada
  • Patent number: 8129489
    Abstract: The present invention provides an ethylene polymer that has excellent fluidity and moldability as well as gives a molded product having excellent mechanical strength. The ethylene polymer of the present invention contains 0.02 to 1.50 mol % of a constitutional unit derived from ?-olefin having 6 to 10 carbon atoms, and has the density of 945 to 975 kg/m3, which satisfies both of the following requirements [1] and [2] simultaneously: [1] in CFC, all the components having a molecular weight of 100,000 or more are eluted at a temperature of 85° C. or higher; and [2] the components eluted at a temperature of 80° C. or lower account for up to 5% of all the components eluted in CFC.
    Type: Grant
    Filed: August 12, 2005
    Date of Patent: March 6, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiko Okamoto, Tetsuji Kasai, Yasushi Tohi, Koji Endo, Shiro Otsuzuki, Takahiro Akashi, Kenji Iwamasa, Yoshiyuki Hirase, Keiko Fukushi, Shinichi Nagano
  • Publication number: 20120041162
    Abstract: [Object] An object of the present invention is to provide a method for producing an olefin polymer, with which an olefin polymer having good particle properties can be produced in high activity, contamination inside the polymerization vessel, such as a vessel wall or an impeller, can be effectively prevented, and a long-term stable operation is achieved. [Means for Achieving the Object] A method for producing an olefin polymer according to the present invention is characterized by including (co)polymerizing at least one olefin selected from the group consisting of ethylene and ?-olefins having 3 to 20 carbon atoms in a polymerization vessel in the presence of (A) a solid catalyst component for olefin polymerization, (B) an aliphatic amide, and (C) an organoaluminum compound.
    Type: Application
    Filed: April 21, 2010
    Publication date: February 16, 2012
    Inventors: Yasushi Tohi, Ken Yoshitsugu, Naoya Akiyama, Toshio Fujita, Masatoshi Chinaka
  • Patent number: 8017705
    Abstract: Disclosed is a method for producing a syndiotactic propylene polymer having a syndiotactic pentad fraction (rrrr fraction) of not less than 85%, a melting point (Tm) within the range of 145-170° C. and a limiting viscosity [?] within the range of 0.1-10 dl/g by a solution polymerization method using a group 4 crosslinked metallocene compound, which is not accompanied by precipitation of a polymer (excluding white turbidity). Also disclosed is a production method which enables to continuously perform such a production.
    Type: Grant
    Filed: November 16, 2007
    Date of Patent: September 13, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tomohiro Yamaguchi, Junpei Tanaka, Shiro Otsuzuki, Yasushi Tohi, Kouji Nagahashi, Nobukazu Yamahira, Shigenobu Ikenaga, Sunil Krzysztof Moorthi, Kazunori Kamio
  • Patent number: 7879960
    Abstract: A high molecular weight propylene polymer exhibiting high stereoregularity (isotactic) and high position selectivity can be effectively produced by polymerizing at least one monomer selected from propylene, ?-olefins and polyenes in the presence of a catalyst for olefin polymerization comprising: (A) a bridged metallocene compound represented by the General Formula [I] given in claims (diphenylmethylene(3-tert-butyl-5-ethyl-cyclopentadienyl)(fluorenyl)zirconium dichloride, etc.); and (B) one or more compound(s) selected from (b-1) an organoaluminumoxy compound (b-2) a compound which reacts with the bridged metallocene compound (A) to form an ion pair, and (b-3) an organoaluminum compound.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: February 1, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Munehito Funaya, Naritoshi Hirota, Mayumi Hiwara, Yasushi Tohi, Koji Kawai, Ryoji Mori, Masahiko Okamoto, Shigenobu Ikenaga, Hiromasa Marubayashi
  • Patent number: RE42957
    Abstract: A process for producing an olefin polymer is provided, in which ethylene and at least one kind or more of monomers selected from ?-olefins are polymerized by a high temperature solution polymerization in a temperature range between 120 and 300° C., in the presence of an olefin polymerization catalyst composed of a bridged metallocene compound represented by general formula [I] described below and at least one kind or more compounds (B) selected from (b-1) an organoaluminum oxy-compound, (b-2) a compound capable of forming an ion pair in a reaction with the bridged metallocene compound mentioned above, and (b-3) an organoaluminum compound.
    Type: Grant
    Filed: March 30, 2005
    Date of Patent: November 22, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yasushi Tohi, Kenji Sugimura, Toshiyuki Tsutsui