Patents by Inventor Yasushi Tohi

Yasushi Tohi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20060199925
    Abstract: An ethylene-based polymer which is a copolymer obtained from ethylene and a C3 to C10?-olefin and satisfies the following requirements (i), (ii), (iii) and (iv) simultaneously provides a blow-molded product and an extrusion-molded product excellent in moldability, mechanical strength and outward appearance. (i) melt flow rate [MFR2 (g/10 min)] under a loading of 2.16 kg at 190° C. is in the range of 0.01 to 10, (ii) melt tension [MT (g)] and the above melt flow rate [MFR2 (g/10 min)] satisfy the following relationship: MT?3.2×MFR2?0.55, (iii) an activation energy [Ea] of fluidization is less than 30 (KJ/mol), and (iv) swell ratio is 1.36 or more.
    Type: Application
    Filed: May 19, 2004
    Publication date: September 7, 2006
    Inventors: Sadahiko Matsuura, Naoto Matsukawa, Makoto Mitani, Junji Saito, Terunori Fujita, Yasushi Tohi, Koji Endo, Kenji Iwamasa, Keiko Takahashi
  • Publication number: 20060194914
    Abstract: An automobile part comprising a polypropylene resin composition, the polypropylene resin composition comprising a propylene homopolymer (A1), an elastomer (B) and an inorganic filler (C) in specified proportions. The polypropylene homopolymer (A1) exhibits an MFR (230° C.) of 20 to 300 g/10 min, a ratio of position irregular units derived from 2,1-insertion or 1,3-insertion of propylene monomer relative to all propylene structural units, determined from a 13C-NMR spectrum, each of 0.05% or less, and an Mw/Mn, determined by GPC, of 1 to 3.
    Type: Application
    Filed: April 26, 2006
    Publication date: August 31, 2006
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Koji Kawai, Masahiro Yamashita, Yasushi Tohi, Keita Itakura, Ikunori Sakai, Mikio Hashimoto, Takeshi Minoda, Masamichi Naito, Toru Takaoka, Nobuo Kawahara, Hiromu Kaneyoshi
  • Publication number: 20060189775
    Abstract: An ethylene polymer containing 0.01 to 1.20 mol % of a constitutional unit derived from ?-olefin having 6 to 10 carbon atoms, wherein with respect to cross fractionation chromatography (CFC), either (1) the weight average molecular weight (Mw) of the components eluted at 73 to 76° C. does not exceed 4,000, or (2) the ethylene polymer satisfies the following relationship (Eq-1), provides a molded product having excellent moldability and therefore excellent mechanical strength and appearance: Sx/Stotal?0.1??(Eq-1) wherein Sx is the sum of the total peak areas related to the components eluted at 70 to 85° C., and Stotal is the sum of the total peak areas related to the components eluted at 0 to 145° C.
    Type: Application
    Filed: February 17, 2004
    Publication date: August 24, 2006
    Inventors: Mamoru Takahashi, Masahiko Okamoto, Tetsuji Kasai, Yasushi Tohi, Shiro Otsuzuki, Shinichi Nagano, Yasuo Funabara, Takahiro Akashi
  • Patent number: 7081493
    Abstract: An automobile part comprising a polypropylene resin composition, the polypropylene resin composition comprising a propylene homopolymer (A1), an elastomer (B) and an inorganic filler (C), or comprising a propylene block copolymer (A2) and an inorganic filler (C) optionally together with an elastomer (B), in specified proportions. The propylene homopolymer (A1), or the propylene homopolymer segment of the propylene block copolymer (A2) exhibits an MFR (230-C) of 20 to 300 g/10 min, a ratio of position irregular units derived from 2,1-insertion or 1,3-insertion of propylene monomer relative to all propylene structural units, determined from a 13C-NMR spectrum, each of 0.2% or less, and an Mw/Mn, determined by GPC, of 1 to 3.
    Type: Grant
    Filed: March 8, 2002
    Date of Patent: July 25, 2006
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Koji Kawai, Masahiro Yamashita, Yasushi Tohi, Keita Itakura, Ikunori Sakai, Mikio Hashimoto, Takeshi Minoda, Masamichi Naito, Toru Takaoka, Nobuo Kawahara, Hiromu Kaneyoshi
  • Publication number: 20060161013
    Abstract: The bridged metallocene compound or the olefin polymerization catalyst which comprises the compound, enables high polymerization activity in polymerizing one or more monomers selected from ethylene and ?-olefins. The bridged metallocene compound contains specific substituted cyclopentadienyl and fluorenyl groups which are linked via carbon or silicon atoms. In the method for the preparation of polyolefins, one or more monomers, preferably ethylene as an essential monomer, selected from ethylene and ?-olefins are copolymerized in the presence of the olefin polymerization catalyst comprising the bridged metallocene compound, so that an ethylene based polymer with an ethylene content of more than 50 mol % is obtained.
    Type: Application
    Filed: February 17, 2003
    Publication date: July 20, 2006
    Inventors: Yasushi Tohi, Koji Endo, Hiromu Kaneyoshi, Naomi Urakawa, Yuichi Yamamura, Koji Kawai
  • Publication number: 20060116303
    Abstract: A synthetic lubricating oil comprising an ?-olefin (co)polymer defined by the following features (i) to (v): (i) the (co)polymer contains constituent units derived from (a) at least one monomer selected from ?-olefins of 8 to 20 carbon atoms in amounts of 90 to 100% by mol and contains constituent units derived from (b) ethylene in amounts of 0 to 10% by mol, (ii) the dynamic viscosity at 100° C. is in the range of 8 to 500 mm2/s, (iii) the number-average molecular weight (Mn), as measured by gel permeation chromatography, is in the range of 500 to 15,000, (iv) the (co)polymer satisfies the following formulas (I) and (II): A?24.0×Exp (?0.0239×K) ??(I) B?0.0775×K ??(II) wherein A is a content (%) of a (co)polymer having a molecular weight, as measured by gel permeation chromatography, of not more than 1,000, B is a content (%) of a (co)polymer having a molecular weight of not less than 20,000, and K is a dynamic viscosity (mm2/s) at 100° C.
    Type: Application
    Filed: November 25, 2005
    Publication date: June 1, 2006
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Yuriko Iimura, Hideki Hirano, Yasushi Tohi, Naomi Urakawa
  • Publication number: 20050228155
    Abstract: The metallocene compound according to the invention and the olefin polymerization catalyst containing the compound are intended to produce a catalyst capable of preparing an isotactic polymer with a high polymerization activity. The metallocene compound contains a substituted cyclopentadienyl group and a (substituted) fluorenyl group and has a structure wherein these groups are bridged by a hydrocarbon group or the like. The process for preparing a metallocene compound according to the invention is intended to selectively prepare a specific metallocene compound so as not to produce an isomer, and in this process an intermediate product is synthesized by a specific method.
    Type: Application
    Filed: February 10, 2005
    Publication date: October 13, 2005
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Koji Kawai, Masahiro Yamashita, Yasushi Tohi, Nobuo Kawahara, Kenji Michiue, Hiromu Kaneyoshi, Ryoji Mori
  • Patent number: 6939928
    Abstract: The metallocene compound according to the invention and the olefin polymerization catalyst containing the compound are intended to produce a catalyst capable of preparing an isotactic polymer with a high polymerization activity. The metallocene compound contains a substituted cyclopentadienyl group and a (substituted) fluorenyl group and has a structure wherein these groups are bridged by a hydrocarbon group or the like. The process for preparing a metallocene compound according to the invention is intended to selectively prepare a specific metallocene compound so as not to produce an isomer, and in this process an intermediate product is synthesized by a specific method.
    Type: Grant
    Filed: October 5, 2000
    Date of Patent: September 6, 2005
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Koji Kawai, Masahiro Yamashita, Yasushi Tohi, Nobuo Kawahara, Kenji Michiue, Hiromu Kaneyoshi, Ryoji Mori
  • Publication number: 20050131171
    Abstract: The present invention provides a process for preparing a low molecular weight olefin (co)polymer having a narrow molecular weight distribution with high productivity, by polymerizing or copolymerizing an olefin in the presence of an olefin polymerization catalyst comprising (A) a specific Group 4 transition metal compound, and (B) at least one compound selected from the group consisting of (B-1) an organometallic compound, (B-2) an organoaluminum compound, (B-3) an organoaluminum oxy-compound, and (B-4) a compound which reacts with the Group 4 transition metal compound (A) to form an ion pair; and compounds useful in that process.
    Type: Application
    Filed: October 30, 2003
    Publication date: June 16, 2005
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Yasushi Tohi, Naomi Urakawa, Koji Endo, Koji Kawai, Kazunori Okawa, Toshiyuki Tsutsui, Chiemi Okawa
  • Publication number: 20050124771
    Abstract: The invention provides a process using olefin polymerization catalysts exhibiting excellent polymerization activities. The olefin polymerization catalysts of the invention contain a transition metal compound of and at least one of an organometallic compound, an organoaluminum oxy-compound or a compound which reacts with said transition metal compound to form an ion pair. The process using the inventive catalysts is useful in producing ?-olefin/conjugated diene copolymers having specific properties.
    Type: Application
    Filed: January 5, 2005
    Publication date: June 9, 2005
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Terunori Fujita, Yasushi Tohi, Makoto Mitani, Shigekazu Matsui, Junji Saito, Masatoshi Nitabaru, Kiyoaki Sugi, Haruyuki Makio, Toshiyuki Tsutsui
  • Patent number: 6875718
    Abstract: The invention provides olefin polymerization catalysts exhibiting excellent polymerization activities, a process for olefin polymerization using the catalysts, a novel transition metal compound useful for the catalysts, and ?-olefin/conjugated diene copolymers having specific properties. The olefin polymerization catalysts of the invention contain (A) a transition metal compound of formula (I), and (B) an organometallic compound, an organoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compounds of the invention are compounds of formula (I) wherein M is a transition metal atom of Group 3 or 4 of the periodic table; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: April 5, 2005
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Terunori Fujita, Yasushi Tohi, Makoto Mitani, Shigekazu Matsui, Junji Saito, Masatoshi Nitabaru, Kiyoaki Sugi, Haruyuki Makio, Toshiyuki Tsutsui
  • Patent number: 6770723
    Abstract: The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an &agr;-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: August 3, 2004
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Terunori Fujita, Yasushi Tohi, Makoto Mitani, Shigekazu Matsui, Junji Saito, Masatoshi Nitabaru, Kiyoaki Sugi, Haruyuki Makio, Toshiyuki Tsutsui
  • Publication number: 20030187121
    Abstract: An automobile part comprising a polypropylene resin composition, the polypropylene resin composition comprising a propylene homopolymer (A1), an elastomer (B) and an inorganic filler (C), or comprising a propylene block copolymer (A2) and an inorganic filler (C) optionally together with an elastomer (B), in specified proportions. The propylene homopolymer (A1), or the propylene homopolymer segment of the propylene block copolymer (A2) exhibits an MFR (230° C.) of 20 to 300 g/10 min, a ratio of position irregular units derived from 2,1-insertion or 1,3-insertion of propylene monomer relative to all propylene structural units, determined from a 13C-NMR spectrum, each of 0.2% or less, and an Mw/Mn, determined by GPC, of 1 to 3.
    Type: Application
    Filed: November 12, 2002
    Publication date: October 2, 2003
    Inventors: Koji Kawai, Masahiro Yamashita, Yasushi Tohi, Keita Itakura, Ikunori Sakai, Mikio Hashimoto, Takeshi Minoda, Masamichi Naito, Toru Takaoka, Nobuo Kawahara, Hiromu Kayenoshi
  • Patent number: 6444603
    Abstract: The invention relates to a catalyst component which can provide, in combination with a transition metal compound, a catalyst for ethylenically unsaturated monomer polymerization, a catalyst comprising the catalyst component and a transition metal compound, and a process for ethylenically unsaturated monomer polymerization using the catalyst. The catalyst component comprises a compound obtained by the reaction of, in any order, (i) a compound comprising a metal of Group 13 of the periodic table; (ii) a compound capable of reacting with the compound (i) to be bonded to two or more of the Group 13 metal; (iii) a compound capable of reacting the compound (i); and optionally (iv) a hydrocarbon compound or the like.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: September 3, 2002
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yasushi Tohi, Haruyuki Makio, Terunori Fujita, Toshiyuki Tsutsui
  • Publication number: 20020115557
    Abstract: The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an &agr;-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc.
    Type: Application
    Filed: August 31, 2001
    Publication date: August 22, 2002
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Terunori Fujita, Yasushi Tohi, Makoto Mitani, Shigekazu Matsui, Junji Saito, Masatoshi Nitabaru, Kiyoaki Sugi, Haruyuki Makio, Toshiyuki Tsutsui
  • Publication number: 20020055600
    Abstract: The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an &agr;-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc.
    Type: Application
    Filed: August 31, 2001
    Publication date: May 9, 2002
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Terunori Fujita, Yasushi Tohi, Makoto Mitani, Shigekazu Matsui, Jungi Saito, Masatoshi Nitabaru, Kiyoaki Sugi, Haruyuki Makio, Toshiyuki Tsutsui
  • Patent number: 6369177
    Abstract: The present invention is intended to provide an olefin polymerization catalyst exhibiting excellent olefin polymerization activity and capable of producing polyolefins of excellent properties and to provide a process for olefin polymerization using this catalyst.
    Type: Grant
    Filed: February 15, 2000
    Date of Patent: April 9, 2002
    Assignee: Mitsui Chemicals Inc
    Inventors: Yasushi Tohi, Shigekazu Matsui, Terunori Fujita
  • Patent number: 6313243
    Abstract: The present invention is intended to provide an olefin polymerization catalyst exhibiting excellent olefin polymerization activity and capable of producing polyolefins of excellent properties and to provide a process for olefin polymerization using this catalyst.
    Type: Grant
    Filed: February 15, 2000
    Date of Patent: November 6, 2001
    Assignee: Mitsui Chemicals INC
    Inventors: Yasushi Tohi, Shigekazu Matsui, Terunori Fujita
  • Patent number: 6309997
    Abstract: The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an &agr;-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: October 30, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Terunori Fujita, Yasushi Tohi, Makoto Mitani, Shigekazu Matsui, Junji Saito, Masatoshi Nitabaru, Kiyoaki Sugi, Haruyuki Makio, Toshiyuki Tsutsui
  • Patent number: 6297333
    Abstract: The olefin polymerization catalyst of the invention is formed from a Group IVB transition metal compound represented by the following formula (I) and an organoaluminum oxy-compound or a compound which reacts with the transition metal compound to form an ion pair.
    Type: Grant
    Filed: May 20, 1999
    Date of Patent: October 2, 2001
    Assignee: Mitsui Chemicals Inc
    Inventors: Junichi Imuta, Masayasu Yoshida, Yasushi Tohi