A method and apparatus for removing fouling materials from the surface of a plurality of porous membranes (9) arranged in a membrane module (4) by providing, from within the module, by means (10) other than gas passing through the pores of said membranes, gas bubbles in a uniform distribution relative to the porous membrane array such that the bubbles move past the surfaces of the membranes (9) to dislodge fouling materials therefrom. The membranes (9) are arranged in close proximity to one another and mounted to prevent excessive movement therebetween. The bubbles also produce vibration and rubbing together of the membranes to further assist removal of fouling materials.
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This application is a continuation of application Ser. No. 10/369,813, filed Feb. 18, 2003, which is a continuation of application Ser. No. 09/336,059, filed Jun. 18, 1999, which is a continuation, under 35 U.S.C. § 120, of International Patent Application No. PCT/AU97/00855, filed on Dec. 18, 1997 under the Patent Cooperation Treaty (PCT), which was published by the International Bureau in English on Jul. 2, 1998, which designates the U.S. and claims the benefit of Australian Provisional Patent Application No. PO 4312, filed Dec. 20, 1996 and Australian Provisional Patent Application No. PO 8918, filed Sep. 1, 1997.FIELD OF THE INVENTION
The present invention relates to the use of a gas bubble system to remove fouling materials from the surface of membranes used in filtration systems and the like.BACKGROUND OF THE INVENTION
A variety of membrane filtration systems are known and many of these use pressurised systems operating at high transmembrane pressures (TMP) to produce effective filtering and high filtrate flux. These systems are highly effective but are also expensive to produce, operate and maintain. Simpler systems using membrane arrays freely mounted vertically in a tank and using suction applied to the fibre lumens to produce TNP have also been developed, however, these systems have been found in the past to be less effective than the pressurised systems.
Examples of such known systems are illustrated in U.S. Pat. No. 5,192,456 to Ishida et al, U.S. Pat. No. 5,248,424 to Cote et al and WO 97/06880 to Zenon Environmental Inc.
The Ishida et al patent describes an activated sludge treating apparatus where air flow is used to clean the outer surface of the filter membrane. In this arrangement the air blower used for biological treatment of the waste water is also used as a secondary agitation source to clean the surface of the membranes. The membrane modules are of the plate type. The membranes also have a low packing density and thus do not have the problems associated with cleaning tightly packed fibre bundles. Air is bubbled from beneath the modules and is supplied externally from the membrane array.
The Cote et al patent again describes a system of cleaning arrays of fibres. In this case the fibres are mounted in a skein to form an inverted U-shaped or parabolic array and the air is introduced below the array to produce bubbles which contact the fibres with such force they keep the surfaces relatively free of attached microorganisms and deposits of inanimate particles. The fibres are freely swayable as they are only attached at either end and this assists removal of deposits on their outer surface. The bubbles of gas/air flow are provided from a source external of the fibre bundle and move generally transverse to the lengths of fibre. This limits the depth of fibre bundle which can be effectively cleaned.
The invention disclosed in the Zenon Environmental, Inc. PCT Application No. WO 97/06880 is closely related to the Cote et al patent. In this document the fibres are unconfined, vertically arranged and dimensioned to be slightly longer than the distance between the opposed faces of the headers into which the fibre ends are mounted to allow for swaying and independent movement of the individual fibres. The skein is aerated with a gas distribution means which produces a mass of bubbles which serve to scrub the outer surface of the vertically arranged fibres as they rise upwardly through the skein.
Our own International Patent Application WO96/07470 describes an earlier method of cleaning membranes using a gas backwash to dislodge material from the membrane walls by applying a gas pressure to the filtrate side of the membranes and then rapidly decompressing the shell surrounding the feed side of the membranes. Feed is supplied to the shell while this gas backwash is taking place to cause turbulence and frothing around the membrane walls resulting in further dislodgment of accumulated solids.SUMMARY OF THE INVENTION
The present invention relates particularly to a plurality of porous membranes arranged to form a membrane module arranged in a relatively tightly packed bundle. These porous membranes may be in the form of fibres or plate type membranes as described in the above prior art.
The present invention seeks to overcome or at least ameliorate the problems of the prior art by providing a simple effective system and method for removing fouling materials from the surface of the porous membranes by use of gas bubbles.
According to one aspect, the present invention provides a method of removing fouling materials from the surface of a plurality of porous membranes arranged in a membrane module, the porous membranes forming an array, the module having a header used to mount the membranes, the header connected to a source of pressurized gas, the method comprising providing, through the header, gas bubbles in a uniform distribution relative to the porous membrane array such that said bubbles move past the surfaces of said membranes to dislodge fouling materials therefrom, said membranes being arranged in close proximity to one another and mounted to prevent excessive movement therebetween. The porous membranes may comprise hollow fibre membranes. Preferably, the fibre membranes are arranged in bundles surrounded by a perforated cage which serves to prevent said excessive movement therebetween.
According to a second aspect, the present invention provides a membrane module comprising a plurality of porous membranes, said membranes being arranged in close proximity to one another and mounted to prevent excessive movement therebetween, the membranes forming an array, the module having a header used to mount the membranes, the header connected to a source of pressurized gas so as to permit formation of gas bubbles such that, in use, said gas moves through said header, and said bubbles move past the surfaces of said membranes to dislodge fouling materials therefrom.
The gas bubbles may be provided from within the module by a variety of methods including gas distribution holes or openings in the header, a porous tube located within the module or a tube or tubes positioned to output gas within the module, the tubes may be in the form of a comb of tubes containing holes which sit within the module. Another method of providing gas bubbles includes creating gas in-situ by means of spark type ozone generators or the like. Further types of gas provision are detailed below and in the preferred embodiments of the invention.
According to one preferred form, the present invention provides a method of removing fouling materials from the surface of a plurality of porous hollow fibre membranes mounted and extending longitudinally in an array to form a membrane module, said membranes being arranged in close proximity to one another and mounted to prevent excessive movement therebetween, the method comprising the steps of providing, from within said array, via the header connected to a source of pressurized gas, uniformly distributed gas bubbles, said distribution being such that said bubbles pass substantially uniformly between each membrane in said array to scour the surface of said membranes and remove accumulated solids from within the membrane module.
For preference, said membranes are mounted vertically to form said array and said bubbles pass generally parallel to the longitudinal extent of said fibres. Preferably, said uniformly distributed gas bubbles are provided at the lower end of the array. Optionally, a backwash may be used in conjunction with the removal process to assist solids removal from the membrane pores and outer surface of the membranes.
For preference, the membranes comprise porous hollow fibres, the fibres being fixed at each end in a header, the lower header having a plurality of holes formed therein through which gas is introduced to provide the gas bubbles. The fibres are normally sealed at the lower end and open at their upper end to allow removal of filtrate. Some of the fibres may also be used to provide bubbles of scouring gas to the array by feeding gas through selected ones of the fibres in the array. The fibres are preferably arranged in cylindrical arrays or bundles.
Filtrate is normally withdrawn from the fibres by application of suction applied thereto, however, it will be appreciated that any suitable means of providing TMP may be used. A porous sheet may be used in conjunction with the holes or separately to provide a more uniform distribution of gas bubbles. The porous sheet also provides the added advantage of preventing solids ingressing into the air supply plenum chamber.
According to a further preferred aspect, the present invention provides a membrane module comprising a plurality of porous hollow membrane fibres extending longitudinally between and mounted at each end to a respective potting head, said membrane fibres being arranged in close proximity to one another and mounted to prevent excessive movement therebetween, one of said potting heads having a uniform distributed array of aeration holes formed therein and said fibres being substantially uniformly mounted in said one potting head relative to said aeration holes.
According to a preferred further aspect, the present invention provides a filtration system including a membrane module according to said second aspect wherein said filter module is positioned vertically in a tank containing feed liquid to be filtered, means to apply a transmembrane pressure to said fibres in said array to cause filtrate to pass through pores in said fibres and means to supply continually or intermittently a supply of pressurized gas to said aeration holes so as to produce gas bubbles which move upwardly and uniformly between said fibres to scour the outer surfaces thereof.
Optionally, when the module is contained in a separate vessel, periodic draindown of the vessel is carried out after the scouring step to remove solids accumulated during the scouring process. Apart from draindown, other methods can be used for accumulated solids removal. These include continual bleed off of concentrated feed during the filtration cycle or overflow at the top of the tank by pumping feed into the base of the tank at regular intervals at a rate sufficient to cause overflow and removal of accumulated solids. This would be typically done at the end of a backwash cycle.
It should be understood that the term “gas” used herein includes any gas, including air and mixtures of gases as well as ozone and the like.
It will be appreciated that the above described invention may be readily applied to our own modular microporous filter cartridges as used in our continuous microfiltration systems and described in our earlier U.S. Pat. No. 5,405,528. These cartridges may be modified by providing gas distribution holes in the lower plug and providing a manifold for supplying gas to said holes such that, in use, the gas passes through the holes and forms scouring bubbles which pass upward through the filter medium. In a preferred arrangement, the filter medium would be sealed at the lower end and filtrate withdrawn under a vacuum from the upper end while the cartridge or cartridges were positioned in a tank containing the feed.
The embodiments of the invention will be described in relation to microporous fibre membranes, however, it will be appreciated that the invention is equally applicable to any form of membrane module.BRIEF DESCRIPTION OF THE DRAWINGS
Preferred embodiments of the present invention will now be described, by way of example only, with reference to the accompanying drawings in which:
The holes are formed as part of the potting process as described below. The arrangement of the holes relative to one another as well as the arrangement of fibres relative to the holes and each other has been found to effect the scouring efficiency of the gas bubbles.
The maldistribution of gas within the fibre bundle can be overcome by appropriate distribution and sizing of holes to ensure that bubble flow around the fibres is uniform across the bundle. In a cylindrical bundle of closely packed fibres it has been found that the distance traveled through the bundle by bubbles introduced towards the centre of the bundle is larger than those introduced towards the outer extremity of the bundle, resulting in a higher resistance to bubble flow at the centre of the bundle than at its border or periphery.
As outlined above, one method of addressing the maldistribution of gas bubbles is to provide a porous sheet (not shown) across the holes to provide an even pore distribution and thus a uniform gas flow. Another method is to provide a distribution of hole size relative to the distribution of resistance. Since the gas flowrate (Q) per unit area (A) is inversely proportional to the resistance (R),
the relationship between the hole diameter (d) and the resistance becomes
using the above relationship it is possible to design a hole size and position configuration which compensates for resistance differences within the bundle. For example, if the resistance at the centre of the bundle is 50% higher than that at its periphery, the hole size at the centre (dc) and on the periphery (dp) would be the following for a uniform distribution of gas:
Known methods of forming holes require the drilling of holes or other forms of post-potting formation. Such methods have the disadvantage of requiring avoidance of the fibres/membranes when drilling or the like to avoid damage. This imposes limitations on the fibre packing density and hole size as, where fibres are tightly packed, it very difficult to drill holes without interfering with or damaging the fibres. Further, it is difficult to accurately locate holes relative to the fibres/membranes.
The process used in one aspect of the present invention seeks to overcome or at least the ameliorate the problems and disadvantages outlined above.
According to this aspect, the present invention provides a method of forming openings in a membrane pot for use in gas distribution comprising the steps of: providing a mould for potting membrane ends, said mould having provided therein formations for forming said openings during the potting process; positioning said membrane ends in said mould which is filled with a curable potting material; allowing said potting material to at least partially cure and, demoulding said membranes.
Preferably, said membranes ends are uniformly distributed in relation to said formations. In another aspect, the invention includes a membrane assembly including at least one membrane pot formed according to the above method.
In use, the guide 25 is placed about the mould 20 and the mould 20 filled to the required level with potting material. The platform 21 is then raised to lower the fibre ends into the mould 20. The fibre ends are normally fanned before insertion to ensure even distribution and also trimmed to ensure a uniform length.
Once the potting material has partially cured, the pot is ejected from the mould by raising the central ejector portion 23 of the mould. The mould 20 is normally heated to assist curing. If desired, the mould 20 may be centrifuged during the potting process to assist the penetration of the potting material into the fibre walls.
This process normally results in the ends of the fibres in this pot being sealed, however, it will be appreciated that, by appropriate transverse cutting of the pot, the fibre ends may be opened for withdrawal of filtrate from the lumens.
A trial module 4 of this type was packed with 11,000 fibres (o.d./i.d. 650/380 μm). The fibre lumens at the lower end were blocked with polyurethane and 60 holes of 4.5 mm in diameter distributed within the fibre bundle. The lower end was connected to an air line sealed from the feed.
In the preferred embodiment shown in
In the manufacture of membrane modules 4, it is desirable to pot the fibres 9 in a uniform distribution relative to the holes 10. Moreover, smaller and more holes will help distribution of gas/air, but holes that are too small will reduce bubble size and thus the shear force applied to the outer surface of the fibres. It is preferable that size of holes should be within the range of 0.01 to 5 mm, however, it will be appreciated that the size and position of holes 10 will vary with module size, fibre packing density, fibre diameter, fibre pore size and other factors.
Another way to reduce maldistribution of gas/air is to use a layer of porous sheet (not shown) which has much smaller pore size than the holes 10. In this case, the major pressure drop of air will be across the porous sheet. If the porous sheet has uniformly distributed pores, the air distribution across the air end of the module will tend to be evenly spread.
To further improve distribution of air bubbles, a porous tube 16 can be inserted in the centre of the cylindrical module 4. When air passes through porous tube 16, it produces uniform bubbles which pass out through the array of fibres scouring solids on the fibre membrane walls. It will be appreciated that more than one porous tube could be used and such tubes could be distributed throughout the bundle. Fibres of large pore size or made of non-woven material could also be used as porous tubes within the bundle.
Zones 1 and 2 compare the effect of using a porous sheet at the air end on the suction performance for the module with a screen surrounding the fibre bundle. Initially the suction pressure decreased (i.e. TMP increased) quickly because of the module was new. Then both suction pressure and resistance tended to be stable. By comparison, the increase in suction resistance was faster after removing the porous sheet as illustrated in Zone 2. These results illustrate that the air end combined with a porous sheet helps to distribute air between fibres.
The use of the screen 8 has a dual effect on filtration. The restriction of fibre movement by screen facilitates solid accumulation during suction. On the other hand, limited free space between fibres reduces coalescence of air bubbles, producing better scouring effect. It has also been found that the restriction of fibre movement in conjunction with the movement of gas bubbles produces high frequency vibrations in the fibres and rubbing between the closely packed fibre surfaces which further improves the removal of accumulated solids. Zones 3 and 4 in
During the operation in Zone 3 some by-pass of air bubbles was observed. This was due to different resistance around the aeration holes, especially on the border where comparatively less fibres were distributed around those holes. We therefore used a porous. annulus sheet covering holes at the outer border of the lower potting head. Results in Zone 4 show the improvement compared to Zone 3.
Solid concentration is an important issue to filtration and fouling rate. When a tank drain was carried out every 10 cycles, solids were built up quickly, which influenced filtration performance. When the tank was drained down every 3 cycles, the increase in suction resistance was significantly reduced as reflected in Zone 5.
The frequency of air scrubbing and backwash on the filtration performance was also investigated.
Longer term trials were conducted to compare the effect of porous sheet on suction performance.
The embodiments relate to membrane filtration systems and typically to a system using suction to produce transmembrane pressure, however, it will be appreciated that the scouring system is equally applicable to any form of fibre membrane filtration process, including pressurised filtration systems.
The scouring process and method may be used in conjunction with any standard backwashing regimes including liquid backwashing, pressurised gas backwashing, combinations of both, as well as with chemical cleaning and dosing arrangements.
The scouring process would normally be used in conjunction with the backwash stage, however, it may also be used continually during the filtration and backwash stages. Cleaning chemicals such as chlorine may be added to the gas providing the bubbles to further assist the scouring process. Solids removed in the scouring process may be intermittently or continually removed. With continual removal of solid a clarifier or the like can be used. The clarifier can be used in front of the module, in parallel with module or the module can be in the clarifier itself. Chemical dosing can be used in conjunction with the clarifier when required.
The filter system using such a scouring process may be used for sewage/biological waste treatment or combined with a bioreactor, activated sludge or similar system.
It will be appreciated that further embodiments and exemplifications of the invention are possible without departing from the spirit or scope of the invention described.
1. A method for filtering a feed liquid, the method comprising:
- providing a vessel;
- providing a membrane module, the membrane module comprising a plurality of porous hollow fiber membranes, the membranes comprising a plurality of pores and an outer surface, wherein the membranes are mounted in a header in close proximity to one another so as to prevent excessive movement therebetween, wherein the membranes form an array, wherein gas bubbles may be introduced into the membrane module, and wherein the membrane module is contained within the vessel;
- providing a feed liquid to the vessel, the feed liquid comprising a fouling material, wherein the feed liquid is provided to the vessel at a rate sufficient to cause an overflow;
- applying a transmembrane pressure to the membranes in the module, whereby a filtrate passes through pores in the membranes, thereby producing a concentrated feed comprising the fouling material in the vessel; and
- removing the fouling material from the vessel, wherein the fouling material is carried out of the vessel in the overflow therefrom.
2. The method according to claim 1, further comprising:
- connecting the header to a source of a pressurized gas; and
- providing, through the header but not through the pores of the membranes, gas bubbles in a uniform distribution relative to the porous membrane array such that the gas bubbles move past the outer surfaces of the membranes and vibrate the membranes to dislodge the fouling material therefrom.
3. The method according to claim 1, further comprising:
- mounting the membranes relative to one another so as to produce a rubbing effect between the membranes when vibrated.
4. The method according to claim 3, wherein the hollow fiber membranes are arranged in at least one bundle.
5. The method according to claim 4, wherein the bundle is surrounded by a perforated cage, whereby excessive movement between the hollow fiber membranes is prevented.
6. The method according to claim 4, comprising the additional step of:
- providing gas bubbles from within the module through gas distribution holes or openings in the header.
7. The method according to claim 1, further comprising:
- providing gas bubbles from within the module through at least one tube situated within the module.
8. The method according to claim 7, wherein the tube comprises a plurality of holes.
9. The method according to claim 7, wherein the tube comprises a comb of tubes.
10. The method according to claim 1, further comprising:
- draining down a liquid within the vessel to remove accumulated solids dislodged from the membranes.
11. The method according to claim 10, wherein the draining down comprises periodically draining down.
12. The method according to claim 10, wherein the draining down comprises continuously draining down.
13. The method according to claim 1, further comprising:
- scouring the membranes.
14. The method according to claim 13, wherein the step of scouring comprises liquid backwashing.
15. The method according to claim 13, wherein the step of scouring comprises pressurized gas backwashing.
16. The method according to claim 13, wherein the step of scouring comprises chemically cleaning.
17. The method according to claim 13, wherein the step of scouring comprises chemically dosing.
18. The method according to claim 13, wherein the scouring is continuous.
19. The method according to claim 13, wherein the scouring is intermittent.
20. A filtration system comprising:
- a membrane module comprising a plurality of porous hollow membrane fibers, each of the fibers having an upper end and a lower end, the fibers extending longitudinally between and mounted at the upper end to an upper potting head and at the lower end to a lower potting head, wherein the fibers are sealed at the lower end and open at the upper end to allow removal of a filtrate, the fibers being arranged in close proximity to one another and mounted in a bundle in a substantially taut manner between the upper potting head and the lower potting head to prevent excessive movement therebetween, wherein the fibers are surrounded by a perforated cage to further prevent excessive movement of the fibers, the fibers being substantially uniformly mounted in the lower potting head relative to a distributed array of aeration holes in the lower potting head, wherein the aeration holes are sized and located such that bubbles, formed by a pressurized gas passing therethrough when the module is immersed in a liquid, pass substantially uniformly between the fibers, wherein the lower potting head is connected to a source of the pressurized gas, and wherein the fibers are arranged to be vibrated by the gas bubbles, the fibers being mounted relative to one another so as to produce a rubbing effect between the fibers when vibrated by the gas bubbles; and
- a vessel, wherein the membrane module is situated in the vessel, the vessel comprising a feed inlet whereby a feed liquid is provided to the vessel at a rate sufficient to cause an overflow, such that at least one fouling material is carried out of the vessel in the overflow.
21. The filtration system according to claim 20, further comprising a porous sheet through which a pressurized gas is supplied, whereby gas bubbles are provided from within the module.
22. The filtration system according to claim 20, further comprising at least one porous tube through which a pressurized gas is supplied, whereby gas bubbles are provided from within the module.
23. The filtration system according to claim 22, wherein the porous tube comprises a comb of porous tubes.
24. A method of removing accumulated solids from an outer surface of a plurality of porous hollow fiber membranes, the method comprising:
- providing a plurality of porous hollow fiber membranes, the porous hollow fiber membranes extending longitudinally in an array to form a membrane module, wherein the membranes are arranged in close proximity to one another and mounted to prevent excessive movement therebetween, wherein the module is contained within a vessel;
- providing, from within the array, by means other than gas passing through the pores of the membranes, uniformly distributed gas bubbles, the distribution being such that the bubbles pass substantially uniformly between each membrane in the array to scour the surface of the membranes, vibrate the membranes, and remove accumulated solids from within the membrane module; and
- removing accumulated solids from the vessel, wherein the accumulated solids are carried out of the vessel in an overflow of a concentrated feed therefrom.
25. The method according to claim 24, wherein the membranes are mounted vertically to form the array and the bubbles pass generally parallel to a longitudinal extent of the fibers.
26. The method according to claim 25, wherein the uniformly distributed gas bubbles are provided at a lower end of the array.
Filed: Jul 12, 2005
Publication Date: Jan 5, 2006
Applicant: U.S. Filter Wastewater Group, Inc. (Warrendale, PA)
Inventors: Fufang Zha (Hurlstone Part), Clinton Kopp (Bismarck, ND), Robert McMahon (Concord), Warren Johnson (Bligh Park), Thomas Beck (North Richmond)
Application Number: 11/179,391
International Classification: B01D 65/02 (20060101);