THREAD
A thread that includes a first fiber having at least one groove extending in a length direction thereof; and at least one second fiber constructed to generate a potential by external energy. The second fiber is disposed in a region corresponding to the groove of the first fiber such that a space is between the groove of the first fiber and the second fiber.
The present application is a continuation of International application No. PCT/JP2020/043598, filed Nov. 24, 2020, which claims priority to Japanese Patent Application No. 2019-212975, filed Nov. 26, 2019, the entire contents of each of which are incorporated herein by reference.
FIELD OF THE INVENTIONThe present invention relates to a thread formed by twisting different fibers.
BACKGROUND OF THE INVENTIONIn recent years, in order to realize a comfortable and healthy life style, various daily life products with improved comfort, health, or hygiene have been devised. In particular, clothing made of fibers having antifungal properties have been devised. The fibers having antifungal properties are, for example, charge generating fibers that exhibit antifungal properties by charge generated by a piezoelectric effect. The piezoelectric thread disclosed in Patent Document 1 is an example of charge generating fiber. When tension is applied to the piezoelectric thread, charge is generated on the surface of the piezoelectric thread, and an electric field is generated in a space formed between fibers by the charge. The piezoelectric thread exerts an effect such as an antifungal effect by the generated electric field.
- Patent Document 1: International Publication No. 2017/212836
There is room for improvement in a conventional charge generating fiber in terms of constraining a fungus in the vicinity of the space where an electric field is generated.
Therefore, an object of the invention is to provide a thread having a better antifungal effect than a conventional charge generating thread having antifungal properties.
A thread of the invention includes a first fiber having at least one groove extending in a length direction thereof; and at least one second fiber constructed to generate a potential by external energy. The second fiber is disposed in a region corresponding to the groove of the first fiber such that a space is between the first fiber and the second fiber.
In the thread of the invention, the second fiber is disposed in the region corresponding to the groove of the first fiber, and a space is formed between the first fiber and the second fiber, so that an electric field can be generated in the space. In addition, since the groove is formed in the first fiber, the surface area of the first fiber increases, and a fungus easily adhere to the first fiber. Thus, the thread including the first fiber and the second fiber exhibits a good antifungal effect.
According to the present invention, a thread that gives a space in which a good electric field is generated can be realized.
The thread 1 is composed of a first fiber 10 and second fibers 20. The first fiber 10 has at least one a groove 12 extending in a length direction, and is surrounded by a plurality of second fibers 20. When energy is applied to the second fibers 20, charge is generated. In the thread 1 of the present embodiment, the second fibers 20 are disposed to fit within the groove 12 of the first fiber 10, and are twisted together with the first fiber 10. In
Conventionally, it has been known that proliferation and metastasis of a bacterium, a fungus, and the like can be suppressed by an electric field (See, for example, Tetsuaki Tsuchido, Hiroki Kourai, Hideaki Matsuoka, Junichi Koizumi, Kodansha: Microbial Control—Science and Engineering. In addition, see, for example, Koichi Takaki, Application of High Voltage and Plasma Technology to Agricultural and Food Field, J. HTSJ, Vol. 51, No. 216). In addition, a potential generating the electric field may cause a current to flow through a current path formed by moisture or a circuit formed by a micro discharge phenomenon. It is considered that this current weakens a fungus and suppresses proliferation and metastasis of the fungus.
When the thread 1 of the embodiment receives external energy (for example, when a tension is applied in an axial direction of the thread 1), charge is generated, and an electric field is generated. Alternatively, when the thread 1 receiving external energy is brought close to a thing having a predetermined potential (including a ground potential) such as a human body, an electric field is also generated between the thread 1 and the thing. When the thread 1 receives external energy and is close to a thing having a predetermined potential (including a ground potential) such as a human body, a current flows between the thread 1 of the present invention and the thing through a liquid such as sweat.
Disruption of a cell of a fungus and degeneration of the cytoplasm occur by an electric field or an electric current. Therefore, the cell of the fungus and the electron transmission system for maintaining the life of the fungus are disturbed, and the fungus is killed or the fungus itself is weakened. In addition, oxygen contained in a liquid such as sweat or water may be changed into an active oxygen species by an electric field or a current. Active oxygen species includes an oxygen radical, and these effects kill or weaken a fungus. Thus, the thread 1 has a remarkable antifungal effect. In the present description, the “antifungal effect” is a concept including both an effect of killing a fungus and an effect of weakening a fungus.
In the embodiment, the first fiber 10 is a modified cross-section fiber (modified filament) made of a fiber material such as a polyester, a nylon, or an acrylic.
Furthermore, in the embodiment, the second fiber 20 is made of, for example, a piezoelectric polymer. Examples of the piezoelectric polymer include a polyvinylidene fluoride (PVDF) and a polylactic acid (PLA), and any of them can be used as a raw material of the second fiber 20. Among them, the polylactic acid (PLA) is a piezoelectric polymer having no pyroelectricity. The polylactic acid is uniaxially stretched to generate piezoelectricity. The polylactic acid includes PLLA having a right-handed helical structure obtained by polymerizing an L-form monomer and PDLA having a left-handed helical structure obtained by polymerizing a D-form monomer and having a polarity of a piezoelectric constant opposite to that of PLLA.
The polylactic acid (PLA) is a chiral polymer, and its main chain has a helical structure. When the polylactic acid is uniaxially stretched and molecules are oriented, piezoelectricity appears. When heat treatment is further performed to increase the crystallinity, the piezoelectric constant increases. The second fiber 20 made of a uniaxially stretched polylactic acid has a tensor component of d14 and d25 as the piezoelectric strain constant when a thickness direction is defined as a first axis, a stretching direction 900 is defined as a third axis, and a direction orthogonal to both the first axis and the third axis is defined as a second axis. Therefore, when the second fiber 20 made of a uniaxially stretched polylactic acid is distorted in a direction of 45 degrees with respect to the uniaxially stretched direction, charge is generated.
As shown in
The polylactic acid has piezoelectricity due to orientation of molecules by stretching, and thus does not need poling unlike other piezoelectric polymers such as PVDF or piezoelectric ceramics. The piezoelectric constant of the uniaxially stretched polylactic acid is about 5 to 30 pC/N, and has a very high piezoelectric constant among polymers. Furthermore, the piezoelectric constant of the polylactic acid does not vary with time and is extremely stable.
As illustrated in
Ideally, the angle (twist angle of the second fibers 20) between stretching direction 900 of the second fibers 20 and the stretching direction of the thread 1 is preferably 45 degrees. When such a thread 1 is stretched under tension, the second fibers 20 are stretched along the axial direction of the thread 1, and are shrunk along the width direction of the thread 1. Therefore, the axial direction of the thread 1 corresponds to the second diagonal line 910B illustrated in
Of course, the inclination of the second fiber 20 with respect to the axial direction of the thread 1 is not limited to 45 degrees to the left. When a shearing stress is applied to the second fiber 20, charge is generated. Therefore, the stretching direction 900 of the second fiber 20 may cross at least the axial direction of the thread 1. Considering this, the twist angle of the second fiber 20 may be larger than 0 degrees and smaller than 90 degrees to the left. In general, as the twist angle of the second fiber 20 approaches 45 degrees to the left, the charge generation efficiency is improved. However, usually, the thread is used for knitted fabrics, textile fabrics, and sewing, and the direction in which the thread extends may not be constant. That is, since an external force is not necessarily applied in the long axis direction of the thread, the twist angle of the second fiber 20 is not limited to the above.
In the embodiment, since the first fiber 10 has the groove 12, the surface area of the first fiber 10 is larger than that of a fiber having no groove, and the possibility that fungus adheres to the first fiber 10 is relatively high. As shown in
Further, as shown in
The cross section of the space SP is smaller than the cross section of the thread 1. The space SP may be smaller than the cross section of the first fiber 10 or smaller than the cross section of the second fiber 20.
As in the thread 1, in the thread 2, the angle between the stretching direction 900 of the second fiber 20 and the stretching direction of the thread 2 is ideally preferably 45 degrees. When such a thread 2 is stretched under tension, the second fibers 20 are stretched along the axial direction of the thread 2, and are shrunk along the width direction of the thread 2. Therefore, the stretching direction of the thread 2 corresponds to the first diagonal line 910A illustrated in
Since charge generates when the shearing stress is applied in the second fiber 20, the inclination with respect to the stretching direction of the thread 2 is not limited to 45 degrees to the right, and may at least intersect with the stretching direction of the thread 2. However, as the twist angle of the second fiber 20 approaches 45 degrees to the right, the charge generation efficiency is improved. In the embodiment, the groove 12 of the first fiber 10 is a V-shaped groove, and a surface of the second fiber 20 is arcuate. That is, the shape of the groove 12 of the first fiber 10 is a shape that is not along the surface of the second fiber 20. However, in other embodiments, the shape of the groove 12 of the first fiber 10 may be a shape along the surface of the second fiber 20. For example, the groove 12 of the first fiber 10 is a semicircular groove, and the surface of the second fiber 20 is arcuate. Furthermore, usually, the thread is used for knitted fabrics, textile fabrics, and sewing, and the direction in which the thread extends may not be constant. That is, since an external force is not necessarily applied in the long axis direction of the thread, the twist angle of the second fiber 20 is not limited to the above.
As shown in
An electric field directed mainly from the inside to the outside of the thread 1 is formed in the cross section of the thread 1, and an electric field directed mainly from the outside to the inside the thread 2 is formed in the cross section of the thread 2. When the thread 1 and the thread 2 are brought close to each other, these electric fields leak out into the air and are synthesized, and an electric field is formed by a potential difference between the thread 1 and the thread 2 as illustrated in
Alternatively, a current may flow through a current path formed by moisture between the thread 1 and the thread 2, or a circuit formed by a micro discharge phenomenon. Even when the thread 1 or the thread 2 and a thing having a predetermined potential close to each other are brought close to each other, a current may flow through a current path formed by moisture, or a circuit formed by a micro discharge phenomenon.
Furthermore, the thread 1 and the thread 2 do not need to have potentials of opposite polarity. Even if the thread 1 and the thread 2 have potentials of the same polarity, an electric field or a current is generated if there is a potential difference between them. That is, the thread 1 and the thread 2 may have different potentials when charges are generated.
As the fiber that generates a negative charge on the surface, a Z thread using PDLA is also conceivable in addition to an S thread using PLLA. Furthermore, as the fiber that generates a positive charge on the surface, the S thread using PDLA is also conceivable in addition to the Z thread using PLLA.
In the embodiment, only the second fiber 20 contains the polylactic acid. However, in other embodiments, the first fiber 10 may also contain the polylactic acid. Then, when the first fiber 10 is twisted, charge is generated.
In the embodiment, the number of the first fibers 10 in the thread 1 or the thread 2 is 1, but in other embodiments, the number of the first fibers 10 may be plural.
In the embodiment, the first fiber 10 and the second fiber 20 are long fibers (filaments), and the thread 1 and the thread 2 are twisted threads made of long fibers. However, the thread 1 and thread 2 are not limited to the twisted threads made of long fibers. In another embodiment, the first fiber 10 and the second fiber 20 may be short fibers (spans), and the thread 1 and the thread 2 may be spun threads made of short fibers. In other embodiments, the first fiber 10 and the second fiber 20 may be long fibers and short fibers (or short fibers and long fibers), respectively, and the thread 1 and the thread 2 may be twisted threads made of two types of fibers.
In the embodiment, the first fibers 10 are heteromorphic modified cross-section fibers (modified filaments) and the second fibers 20 are circular cross-section fibers (circular filaments). However, the second fibers 20 are not limited to the circular cross-section fibers. In another embodiment, the second fibers 20 are a modified cross-section fibers like the first fibers 10.
In other embodiments, both the first fiber 10 and the second fiber 20 may be charge generating fibers that generate charge. Furthermore, when both the first fiber 10 and the second fiber 20 are charge generating fibers, either one may have a lower elastic modulus than the other, and when only one of the first fiber 10 and the second fiber 20 is charge generating fiber, the other may have a lower elastic modulus than the one. In this case, since the fiber has a low elastic modulus, the thread tends to stretch, and the shearing stress tends to be applied to the charge generating fiber. Furthermore, when both of the first fiber 10 and the second fiber 20 are charge generating fibers, either one may have a lower coefficient of static friction than the other, and when only one of the first fiber 10 and the second fiber 20 is charge generating fiber, the other may have a higher coefficient of static friction. In this case, the shearing stress tends to be applied to the charge generating fiber.
As illustrated in
The thread 3 is S-twisted or Z-twisted depending on the direction of twisting. In the embodiment, by using the groove 12 of the first fiber 10 and the protrusion 24 of the second fiber 20, the twist angle of the second fiber 20 can be made close to a desired angle (45 degrees to the left or 45 degrees to the right), and the thread 3 can be made into a medium twisted thread or a hard twisted thread. Since the shape and size of the internal space of the groove 12 do not exactly fit the shape and size of the protrusion 24, the space SP exists between the first fiber 10 and the second fiber 20. Therefore, a leakage electric field is easily formed. Such a thread 3 has the same good antifungal effect as the thread 1 and the thread 2.
In the embodiment, the groove 12 of the first fiber 10 is parallel to the length direction of the first fiber 10 as shown in
The above-mentioned threads (thread 1, thread 2, thread 3, etc.) can be applied to daily life products such as medical parts and clothing. For example, the thread (thread 1, thread 2, thread 3, etc.) can be applied to a mask, underwear (in particular, socks), a towel, insoles such as shoes and boots, sportswear in general, a hat, bedding (bedclothes, a mattress, a sheet, a pillow, a pillow cover, and the like), a toothbrush, a froth, a water purifier, a filter for an air conditioner or an air cleaner, a stuffed toy, a pet-related product (a mat for a pet, clothing for a pet, and an innerwear for a pet), various mat products (a foot, a hand, and a toilet seat), s curtain, s kitchen utensil (s sponge or s cloth), seats (a seats for a car, a train, an airplane, etc.), a cushioning material for a motorbike helmet and an exterior material thereof, a sofa, a bandage, a gauze, a suture, clothes for a doctor and a patient, a supporter, a sanitary product, a sporting good (an inner of a wear and a glove, an arm guard used in a martial art, or the like), a filter for an air conditioner or an air cleaner, a packaging material, and a screen door.
Of the clothing, in particular, socks (or supporters) always expand and contract along a joint by movement such as walking, and thus the thread (thread 1, thread 2, thread 3, etc.) generates charge with high frequency. In addition, socks absorb moisture such as sweat and become a hotbed for proliferation of a fungus, but the threads (thread 1, thread 2, thread 3, etc.) can suppress proliferation of a fungus, and thus exert a remarkable effect as a fungus-countermeasure application for odor prevention.
Finally, description of this embodiment should be considered to be exemplary in all respects and not restrictive. The scope of the present invention is defined not by the embodiments but by the claims. Furthermore, the scope of the invention is intended to include all modifications within the meaning and scope equivalent to the claims.
DESCRIPTION OF REFERENCE SYMBOLS
-
- 1, 2, 3: Thread
- 10: First fiber
- 20: Second fiber
- 12: Groove
- 14, 24: Protrusion
- SP: Space
- 900: Stretching direction
- 910A: First diagonal line
- 910B: Second diagonal line
Claims
1. A thread comprising:
- a first fiber having at least one groove extending in a length direction thereof; and
- at least one second fiber constructed to generate a potential by external energy,
- the second fiber disposed in a region corresponding to the groove of the first fiber such that a space is between the groove of the first fiber and the second fiber.
2. The thread according to claim 1, wherein a cross section of the space between the first fiber and the second fiber is smaller than a cross section of the thread.
3. The thread according to claim 1, wherein a shape of the groove of the first fiber corresponds to a shape along a surface of the second fiber.
4. The thread according to claim 1, wherein a shape of the groove of the first fiber does not correspond to a shape along a surface of the second fiber.
5. The thread according to claim 1, wherein the first fiber and the second fiber are modified cross-section fibers, the second fiber has at least one protrusion extending in the length direction thereof, and the second fiber is disposed such that the protrusion engages with the groove of the first fiber.
6. The thread according to claim 1, wherein the first fiber has a lower elastic modulus than the second fiber.
7. The thread according to claim 1, wherein the first fiber has a higher coefficient of static friction than the second fiber.
8. The thread according to claim 1, wherein an opening width of the groove substantially matches a diameter of the second fiber.
9. The thread according to claim 1, wherein an opening width of the groove is larger than a diameter of the second fiber.
10. The thread according to claim 1, wherein the second fiber contains a polylactic acid.
11. The thread according to claim 1, wherein the first fiber is longer than the second fiber.
12. The thread according to claim 1, wherein the first fiber is shorter than the second fiber.
13. The thread according to claim 1, wherein the first fiber and the second fiber are twisted together.
14. The thread according to claim 1, wherein the first fiber has a plurality of grooves extending in the length direction thereof; and a plurality of second fibers, a respective second fiber of the plurality of second fibers being disposed in a region corresponding to a respective groove of the plurality of grooves of the first fiber.
15. The thread according to claim 1, wherein a sectional shape of the first fiber is a cross shape, a star polygon, or a concave polygon.
16. The thread according to claim 1, wherein a cross section of the at least one groove is V-shaped, and a cross section of the at least one second fiber is circular.
17. The thread according to claim 1, wherein the thread comprises a plurality of the first fibers and a plurality of the second fibers arranged to surround the plurality of first fibers.
18. The thread according to claim 1, wherein both the first fiber and the second fiber are constructed to generate a potential by external energy.
19. The thread according to claim 1, wherein the first fiber and the second fiber have the same sectional shape.
20. The thread according to claim 1, wherein the at least one groove is parallel to the length direction of the first fiber.
Type: Application
Filed: Apr 12, 2022
Publication Date: Jul 28, 2022
Inventors: Takafumi INOUE (Nagaokakyo-shi), Nobuhito TSUBAKI (Nagaokakyo-shi), Masayuki TSUJI (Nagaokakyo-shi), Eiji TAGUCHI (Nagaokakyo-shi), Hirokazu HAYASHI (Osaka)
Application Number: 17/719,024