Preparation of aliphatic alpha, omega-aminonitriles

Abstract

Aliphatic alpha,omega-aminonitriles are prepared by partial hydrogenation of aliphatic alpha,omega-dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst by a process in which the catalyst(a) contains a compound based on a metal selected from the group consisting of nickel, cobalt, iron, ruthenium and rhodium and(b) contains from 0.01 to 25% by weight, based on (a), of a promoter based on a metal selected from the group consisting of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminum, tin, phosphorus, arsenic, antimony, bismuth and rare earth metals and(c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or on an alkaline earth metal,with the proviso that the component (a) is not based on iron or iron and one of the metals selected from the group consisting of cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group consisting of titanium, manganese, chromium and molybdenum, and with the further proviso that, when a compound based on only ruthenium or ruthenium and rhodium or nickel and rhodium is selected as component (a), the promoter (b) may be dispensed with.

Claims

1. In a process for the preparation of aliphatic alpha,omega-aminonitriles by partial hydrogenation of aliphatic alpha,omega-dinitriles at elevated temperature and superatmospheric pressure in the presence of a solvent and of a catalyst, the improvement which comprises hydrogenating an aliphatic alpha,omega dinitrile in the presence of a catalyst which

(a) has a compound containing a metal selected from the group consisting of iron, nickel, ruthenium and rhodium and

(b) has from 0.01 to 25% by weight, based on (a), of a promoter containing a metal selected from the group consisting of palladium, platinum, iridium, osmium, iron, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, bismuth and rare earth metals, and

(c) from 0 to 5% by weight, based on (a), of a trace component containing a metal selected from the group consisting of an alkali metal and an alkaline earth metal,

iron or

iron and one of the metals selected from the group consisting of cobalt, ruthenium and rhodium when (b) is a promoter having a metal selected from the group consisting of titanium, manganese, chromium and molybdenum,

when a compound based on only

ruthenium or

ruthenium and rhodium or

rhodium and nickel

(I) precipitating precursors of the components (a) to (c) from aqueous solutions in the presence or absence of carriers yielding a precipitate, then

(II) optionally processing the resulting precipitate to give extrudates or pellets, then

(III) drying the precipitate or pellets or extrudates at a temperature of from 80.degree. to 150.degree. C. yielding a dried product, and

(IV) then calcinating the dried product at a temperature from 150.degree. to 1000.degree. C. in a gas stream comprising air or nitrogen yielding a calcined product then

(V) optionally, passivating the surface of the calcined product at from 20.degree. to 80.degree. C. by means of an oxygen/nitrogen mixture yielding a passivated product, then

(VI) activating the calcined or passivated product by exposing it to a reducing atmosphere for from 2 to 24 hours at from 200.degree. to 500.degree. C.