Method for quasi-instantaneous polymerization of filament wound composite materials
A method of winding fibers on a mandrel, the wound fibers being in tension, includes providing a source of fibers, imposing a torque on the source that resists dispensing the fibers from the source to exert a tension on the fibers, adding ultra-violet sensitive material that is polymerized by exposure to ultra-violet light to a resin matrix, impregnating dispensed fibers with the additive containing resin matrix, rotating a mandrel to wind the impregnated fibers on the mandrel, the rotation of the mandrel acting to overcome the torque on the source and putting the fibers in tension, and in situ, quasi instantaneously polymerizing the additive containing resin matrix on the mandrel by means of exposing the additive containing resin matrix to ultra-violet light for a selected period of time, such polymerization acting to lock in the tension in the fibers at the time of polymerization. A rail gun fabricated by means of the above method is further included.
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The present invention claims the benefit of U.S. Provisional Application No. 61/041,816, filed Apr. 2, 2008 and incorporated herein in its entirety by reference.
FIELD OF THE INVENTIONThe present invention relates generally to filament winding methods used to produce components using composite materials. More particularly, the present application relates to an improved method of filament winding that involves continuously quasi-instantaneously polymerizing a resin matrix, using ultra violet light, as winding is taking place. This results in whatever tension is being applied to the filamentary material being maintained, thereby creating radial prestress that can be very advantageous in a number of applications.
BACKGROUND OF THE INVENTIONFilament winding is a well-known process that has been used in various industries to manufacture products having high structural efficiency in terms of strength and stiffness. Filament winding generally involves winding a fiber bundle that is impregnated with a thermosetting or, less generally, a thermoplastic resin matrix onto a suitably shaped mandrel or mold. Frequently, in this process, the mandrel is a body of revolution, but this does not have to be the case. The fiber bundle typically referred to as “tow” in the case of carbon or graphite or “roving” in the case of glass, is applied to the mandrel under tension. During filament winding, tension is applied to both maintain fiber collimation and to create radial stress (“prestress”) in the component being wound. Once the mandrel is covered to the desired thickness, the mandrel is often heated in an oven autoclave to cure or set the resin. Following curing, the mandrel may be removed from the wound fiber and a hollow, high-efficiency structure remains. Alternatively, the prestressed fiber is left in place to provide a prestressed layer on the mandrel. Such is the case when the mandrel forms a rail gun or a gun barrel.
Prestressing has been used for centuries dating back to times of the Napoleonic Wars when wire was wrapped under tension onto cast cannon barrels to improve barrel life. This process generally was referred to as “autofrettaging” for metallic structures. Prestressing materials this way is known as an important process for manufacturing parts requiring substantial fatigue strength and structural integrity. Today, prestressing is used in a variety of industrial and military applications.
Wet filament winding is one type of filament winding. In wet filament winding, a thermoset resin is impregnated into dry fibers during the filament winding operation. However, during this process, radial stress created by fiber tension causes the resin to flow or migrate. When the resin migrates this way, tension begins to be lost. This problem is exacerbated during curing (polymerization) under heat, which typically causes a reduction in the viscosity of the resin.
In some instances, to prevent loss of tension, the curing is carried-out in stages in which layers were successively cured. However, staged winding generally requires time intensive manufacture.
Alternatively, in some instances, the use of a thermoplastic matrix in filament winding has been utilized to achieve the ‘locking-in’ of the applied fiber tension. This is typically done by instantaneously cooling-down the pre-heated resin ‘in situ’, as the fibers are being laid down. However, using such materials is generally unsuited for many applications, involving relatively high material costs and complex processing equipment.
The use of a thermosetting resin and ‘in situ’ curing using a combination of fast reacting resin matrix accelerators and the application of heat has also been proposed for continuously curing during the filament winding process. While high prestress components can be produced in this manner, the process is relatively difficult to carry out, requires cumbersome equipment and machines, does not provide much flexibility in operation, and utilizes a cure that is not truly “instant” and therefore permits some undesirable resin migration and lost tension.
It would be advantageous to improve upon present processes to enhance the functionality, reliability and safety associated with use of filament wound devices that require radial prestress to be present. Therefore, what is needed is a filament winding process which allows for an easily implemented and cost effective means for maintaining significant radial prestress by suppressing resin flow and the consequent loss of tension and radial pressure.
SUMMARY OF THE INVENTIONThe present invention comprises a filament winding method for producing thick structures made of composite materials. This method generally includes the steps of providing a plurality of fibers that are placed in tension, impregnating a resin with additives that are caused to polymerize when exposed to ultra-violet radiation, wetting the plurality of fibers with the resin containing the additives, generating a tension in the fibers, winding fibers on a mandrel such that the plurality of fibers create radial pressure due to tension applied to the fibers, and continuously curing the plurality of fibers quasi-instantaneously by polymerizing the prestressed plurality of fibers as the fibers are about to contact the mandrel using ultra-violet (UV) light while the fibers are still under tension. Radial and tangential prestresses are accordingly continuously locked in during the process of forming a relatively thick, polymerized structure.
Generally in these embodiments, the fibers are impregnated with resin using a wet-out tank to infiltrate fiber filaments with resin containing the UV sensitive additives. In some embodiments, an infra-red heater is used to augment the cure initiated by the ultra-violet radiation of the resin as well.
In other embodiments, steps for manufacturing a rail gun barrel include providing a plurality of fibers that are placed in tension, impregnating a resin containing ultra-violet sensitive additives onto the plurality of fibers, winding the plurality of fibers onto the conductors and insulators that comprise the rail gun barrel while maintaining the tension in the fibers, and polymerizing the fibers quasi-instantaneously using ultra-violet light. The general outside configuration of such a product may typically be oval in cross section and of considerable length. In these embodiments, the tension used during the winding process may be as high as can be effectively achieved without damage to the fibers. Moreover, the radial prestress aids in preventing separation of the insulators from the conductors under the influence of the repelling magnetic forces that occur during operation of a rail gun. Further, helical windings can be applied to the mandrel or rail gun barrel. In such a case, a strip UV light source is caused to move along the rail gun barrel in a lagging disposition to the point of tangential application of the fibers to the rail gun barrel.
The present invention is a method of winding fibers on a mandrel, the wound fibers being in tension. The method includes providing a source of fibers, imposing a torque on the source that resists dispensing the fibers from the source to exert a tension on the fibers, adding ultra-violet sensitive material that is polymerized by exposure to ultra-violet light to a resin matrix, impregnating dispensed fibers with the additive containing resin matrix, rotating a mandrel to wind the impregnated fibers on the mandrel, the rotation of the mandrel acting to overcome the torque on the source and putting the fibers in tension, and in situ, quasi instantaneously polymerizing the additive containing resin matrix on the mandrel by means of exposing the additive containing resin matrix to ultra-violet light for a selected period of time, such polymerization acting to lock in the tension in the fibers at the time of polymerization. The present invention is further a rail gun fabricated by means of the above method.
The above summary of the invention is not intended to describe each illustrated embodiment or every implementation of the present invention. The figures and the detailed description that follow more particularly exemplify these embodiments.
The invention may be more completely understood in consideration of the following detailed description of various embodiments of the invention in connection with the accompanying drawings, in which:
While the invention is amenable to various modifications and alternative forms, specifics thereof have been shown by way of example in the drawings and will be described in detail. It should be understood, however, that the intention is not to limit the invention to the particular embodiments described. On the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.
DETAILED DESCRIPTION OF THE DRAWINGSThroughout the several figures, and initially to
After being pulled from the fiber spool 14, the fibers 13 are subjected to a resin impregnator 18, such as wet-out tank 20. During this step, fibers 13 are infiltrated with resin 21. While a typical wet-out tank 20 is described, a variety of other well-known approaches can be employed to infiltrate fiber filaments 13 with resin 21. In a drum type wet-out tank 20, such as the one seen in
Guide components 26, such as bars, rollers or combs may be used to ensure sufficient contact with the surface 23 of the drum 22 is experienced by the fibers 13. Generally, such guides 26 cause adequate angular contact with the surface 23 of the drum 22 to be effected. Further, an adjustable doctor blade 28 is shown mounted above the resin bath 24 for skimming off excessive resin 21 to achieve the desired resin-to-fiber ratio.
Importantly, in the present embodiment, the resin 21 impregnated upon the fibers 13 contains a ultra-violet responsive additive 30 that is useful in the subsequent quasi-instantaneous curing process. This additive 30 allows curing (polymerization) by an ultra-violet light 32 to quasi-instantly take place, thereby locking in the fiber tension thereby creating the desired prestresses. Such additives 30 include, but are not limited to: the epoxy based resin formulation 51180J-P made by UV Chemistry Inc. of Torrance, Calif., USA and epoxy based resin formulation EMI 612, made by Electrochemical Materials Inc. See
Once the fibers 13 have been sufficiently impregnated with resin 21 (containing the ultra-violet responsive additive 30) by a wet-out tank 20 or similar resin impregnator 18, the fibers 13 are wound in tension around the outer surface of a mandrel 16. These fibers 13 are wound in a controlled pattern around the outside surface of the mandrel 16 to form a hollow fiber structure 30. Cylindrical, tapered, or spherical shapes and tubes of various cross-section, length, and diameter can be formed.
As the fibers 13 are first wound around mandrel 16, an ultra-violet light source 32 is placed generally at the point of tangency of the fibers 13 with the mandrel 16 to effect the quasi-instantaneous curing proximate such point 36. Such curing is virtually totally effective at such point 36 for translucent fibers 13. For opaque fibers 13, a heat source 34 may used to further cure the resin coated fiber bundle 12.
Specifically, ultra-violet light source 32 is directed to the outside of the wound fibers 13 at the location 36 where the fiber bundle 12 comes into tangential contact with the mandrel 16. At this point 36, tangential and radial (normal) stresses are being experienced by the fiber bundle 12. The ultra-violet radiation given off by the light source 32 acts to polymerize (solidify) the resin matrix 21 impregnating the fiber bundle 12 in a quasi-instantaneous fashion. Polymerization and curing of the fibers 13 locks in the desirable tangential and radial stresses being experienced continually as the fibers 13 are wound around the mandrel 16. If not for such rapid curing, resin 21 would flow and migrate thereby causing tension to be lost. This curing is done at a rate even much faster than that done by instant prior art polymerization using heat, and therefore provides a diminished opportunity for resin migration and lost tension.
As noted above, a second, optional light source 34 is shown in the figures as well. This light source 34 is preferably directed at the inside (underside) surface of the fiber 13 being wound, at or just prior to the location 36 where the fibers 13 are first in tangential contact 36 with the mandrel 16. The second light source 34 may be either a secondary ultra-violet light source or an infrared heat source. For most fibers 13, especially the translucent fibers 13, ultra-violet light curing will be sufficient. However, for opaque fibers 13, such as carbon or graphite, the polymerization process may need to be augmented by use of infra-red radiative heating to ensure that the initial polymerization is maintained once exposure to ultra-violet light ceases. In some circumstances, a second ultra-violet light 34 may be used to simply augment the ultra-violet cure as the second light source 34 as well. Further, additional post curing of the resulting structure at an elevated temperature may be used to ensure that the resin is fully cured or polymerized.
Performing the filament winding process can therefore be carried out using the steps of the disclosed method in which a user is able to produce a thick prestressed structure by filament winding composite materials that maintain fiber collimation and tension in the solidified structure. The first step includes, providing a plurality of filamentary fibers 13 in a fiber bundle 12 such as from a continuous source, such as spool 14. As indicated, this material may be carbon, graphite, glass, or other suitable material. This spool 14 of material is acted on by a resisting torque to place the filamentary material 13 in tension as winding progresses. Next, a user must impregnate a resin 21 (containing additives that are be caused to polymerize when exposed to ultra-violet light) onto a plurality of fibers 13 of the fiber bundle 12. This may be done by means of a drum-type wet out tank 20 or other impregnation means. The fibers 13 are then wound on a mandrel 16, the rotation of the mandrel 16 acting to overcome the resisting torque and to thereby place the fibers 13 in tension. The winding is such that the fibers 13 create radial and axial pressure due to the tension applied to the fibers 13.
The resin coated fibers 13 are then polymerized using ultra-violet light to cure the fibers quasi-instantaneously as the fibers 13 first come into contact with the mandrel 16 at a point of tangency 36 to create a polymerized structure 30. Radial and tangential stresses are accordingly continuously locked in the resulting mandrel-wound fiber element as the ultra-violet light quasi-instantly cures the resin coated fibers 13. When the fiber element is of desired thickness, it may be removed from the mandrel for further curing or use apart from the mandrel. In the case of the mandrel 16 being a gun barrel or rail gun, the polymerized fiber element is left in place to afford greater strength to the gun barrel or rail gun.
In some embodiments, impregnating the fibers 13 with resin 21 specifically involves using a wet-out tank 20 to infiltrate fiber filaments 13 with resin 21, although this impregnation of resin 21 may occur in several well-known manners. Further, in some embodiments an infra-red heater 34 is used to augment the cure of the resin, in addition to the ultra-violet curing light 32.
A number of applications are therefore made possible by the filament wound parts produced. One important application is that related to the fabrication of gun barrels and rail guns. In such applications, the solidified, prestressed fiber bundle 12 is left in place on the mandrel 16 (the gun barrel or rail gun). Particularly, rail guns are enhanced by high levels of radial prestress in order to react the magnetic forces which occur in the device. Specifically, it is desired that repulsive (outward directed) magnetic forces be opposed by prestress so that no separation of components that are acted upon by the repulsive magnetic forces occurs. Failing to have this prestress may result in the separation of the conductor and insulator components (noted in the embodiments described below) thereby generating gas plasmas and arcing. Therefore, a filament wound prestressed, solidified fiber bundle 12 helps to ensure that the noted components comprising the rail are held in intimate contact during the application of very high repelling magnetic forces characteristic of such devices when the rail gun is operated.
Applicant carried out a series of experiments in which the filament winding and ultra-violet curing technique noted above was evaluated for constructing a rail gun. Among other things, it was demonstrated during the investigation that it is possible to produce in-situ curing of both glass and carbon filaments 13 impregnated with resin matrices 21 and UV additives 30 that can be quasi-instantaneously polymerized using ultra-violet radiation. It was also shown that use of such in-situ curing permits the tension that is induced in the fiber filaments 13 to be maintained since resin migration and the resulting loss of tension that occurs with resin matrices that are not cured quasi instantaneously does not occur. A race track specimen 50 of the mandrel 16 was wound as indicated above. See
Some problems were experienced when attempting to wind a typical “racetrack” configuration 50 for a barrel (mandrel 16) due to a lack of lateral pressure occurring on the straight sides 58. Therefore, using a rail gun (mandrel 16) design having some level of curvature of the sides is contemplated to alleviate this problem. Such a design can, at all locations on the exterior margin, be described by a radius 62 (see
A first such design that is circular in cross section is disclosed in
As illustrated in
Steps for manufacturing a rail gun barrel include providing a plurality of fibers 13 that are placed in tension, impregnating a resin 21 containing ultra-violet sensitive additives 30 onto the plurality of fibers 13, winding the plurality of fibers 13 onto a mandrel 16 that comprises in part the product including a rail gun, and polymerizing fibers 13 quasi-instantaneously using ultra-violet light 32. The general outside configuration of such a product may preferably be circular or oval in cross section and of considerable length. In these embodiments, the tension used during the winding process may be maximized without damage to the fibers 13. Radial prestress helps to prevent separation of the insulators 64 from the conductors 66 under the influence of the repelling magnetic forces that occur during operation of a rail gun.
Other possible applications include conventional metal gun barrels, energy storing flywheels rims or pressure vessels. Conventional gun barrels will provide improved fatigue life and durability using this filament winding method to provide a prestressed structure exterior to the metal gun barrel. Also, because flywheel rims are highly stressed components having thick predominately hoop-wound composite rings that can be spun at very high speeds, they are accordingly very effective rotational energy storage components. Such devices can be used for emergency power supplies for military and commercial computers, rapid opening of missile silos, power conservation with cranes, regenerative braking in vehicles, etc. Use of prestressed materials is very important to each of these potential applications. These parts can therefore be produced using an “in situ” curing process which is cheaper and more flexible in application than those used for thermosetting resins such as in-situ mixing of resin and reactive curing agents. This is likewise applicable to the prestressing of thermoplastic resins used as matrices in filament winding which typically involves maintenance of tension in the fibers while the previously heated matrix is cooled to lock-in the fiber tension.
Although specific examples have been illustrated and described herein, it will be appreciated by those of ordinary skill in the art that any arrangement calculated to achieve the same purpose could be substituted for the specific example shown. This application is intended to cover adaptations or variations of the present subject matter. Therefore, it is intended that the invention be defined by the attached claims and their legal equivalents
Claims
1. A method of winding fibers on a mandrel, the wound fibers being in tension, comprising:
- providing a source of fibers, imposing a torque on the source that resists dispensing the fibers from the source to exert a tension on the fibers;
- adding ultra-violet sensitive material that is polymerized by exposure to ultra-violet light to a resin matrix;
- impregnating dispensed fibers with the additive containing resin matrix,
- rotating a mandrel to wind the impregnated fibers on the mandrel, the rotation of the mandrel acting to overcome the torque on the source and putting the fibers in tension; and
- in situ, quasi instantaneously polymerizing the additive containing resin matrix on the mandrel by exposing the additive containing resin matrix to ultra-violet light for a selected period of time, such polymerization acting to lock in the tension in the fibers at the time of polymerization.
2. The method of claim 1, including forming at least a portion of the fibers of an opaque material; providing an infra-red radiative heater proximate the mandrel and heating the resin matrix with the radiative heater after at least partial polymerization, thereby ensuring that polymerization is maintained after exposure to the ultra-violet light ceases.
3. The method of claim 1, including forming the mandrel with an outer margin which at all points has a radius, winding the fibers commencing at a point of tangency to the mandrel, and exposing the additive containing resin matrix to ultra-violet light proximate the point of tangency.
4. The method of claim 1, including winding the fibers helically on the mandrel and causing a strip ultra-violet light to lag behind a point at which the fiber is first applied to the mandrel.
5. The method of claim 1 wherein the ultra-violet sensitive material is one or of the materials selected from the list consisting of: the epoxy based resin formulation 51180J-P and the epoxy based resin formulation EMI 612.
6. The method of claim 1, including forming a gun barrel of the mandrel.
7. The method of claim 1, including forming a rail gun of the mandrel.
8. The method of claim 1, including forming a flywheel of the mandrel.
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Type: Grant
Filed: Mar 31, 2009
Date of Patent: Nov 22, 2011
Patent Publication Number: 20100043764
Assignee: BAE Systems Land & Armaments, L.P. (Santa Clara, CA)
Inventor: Brian H. Jones (Brea, CA)
Primary Examiner: Troy Chambers
Attorney: Patterson Thuente Christensen Pedersen, P.A.
Application Number: 12/415,462
International Classification: B65H 81/08 (20060101);