Thermoelectric power generator for variable thermal power source
Traditional power generation systems using thermoelectric power generators are designed to operate most efficiently for a single operating condition. The present invention provides a power generation system in which the characteristics of the thermoelectrics, the flow of the thermal power, and the operational characteristics of the power generator are monitored and controlled such that higher operation efficiencies and/or higher output powers can be maintained with variably thermal power input. Such a system is particularly beneficial in variable thermal power source systems, such as recovering power from the waste heat generated in the exhaust of combustion engines.
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This application relates to and claims the benefit of priority of U.S. Provisional Patent Application No. 60/694,746 entitled Freedom Car & Vehicle Technologies Program, filed Jun. 28, 2005.
STATEMENT REGARDING FEDERALLY SPONSORED R&DThe U.S. Government may claim to have certain rights in this invention or parts of this invention under the terms of Contract No. DE-FC26-04NT42279 awarded by the U.S. Department of Energy.
BACKGROUND OF THE INVENTION1. Field of the Invention
The present application relates to the field of thermoelectric power generation, and more particularly to systems for improving the generation of power from thermoelectrics where the heat source varies in temperature and heat flux.
2. Description of the Related Art
Thermoelectrics are solid state devices that operate to become cold on one side and hot on the other side when electrical current passes through. They can also generate power by maintaining a temperature differential across the thermoelectric. Under many operating conditions, however, thermoelectric power generators are exposed to a combination of changing heat fluxes, hot side heat source temperatures, cold side heat rejection temperatures, and other variable conditions. In addition, the device properties, such as TE thermal conductance, Figure of Merit Z, heat exchanger performance all have a range of manufacturing tolerances that combine to, in general, reduce device performance. As a result, performance varies and operation at a predetermined set point can lead to performance degradation compared to design values.
Any process that consumes energy that is not 100% efficient generates waste energy, usually in the form of heat. For example, internal combustion engines generate a substantial amount of waste heat. In order to improve the efficiency of the internal combustion engine; such as in automobiles, various ways to capture some of this waste heat and convert it to a useful form have been considered. Placing thermoelectrics on the exhaust system of an automobile has been contemplated (See U.S. Pat. No. 6,986,247 entitled Thermoelectric Catalytic Power Generator with Preheat). However, because the exhaust system varies greatly in heat and heat flux, providing a system that is effective has been illusive. By way of example, compared to optimal performance, degradation in automobile waste heat recovery system performance can be very significant, amounting to at least 30%.
SUMMARY OF THE INVENTIONThis invention is directed to improvement to thermoelectric generation systems, particularly where the thermal power source is one of variable thermal output. Improvements may be obtained by controlling the operation of the system so as to maintain meaningful proximity to optimal operating efficiencies. The system is designed to reduce losses from both the variations from changing operating conditions and the differences associated with design and fabrication differences.
In one embodiment, a thermoelectric power generation system has a source of thermal power, a thermoelectric generator having at least two thermoelectric modules, a thermal power delivery system controllable to deliver thermal power from the thermal power source to one of the at least two thermoelectric modules and to deliver thermal power from the thermal power source to both of the at least two thermoelectric modules. A controller is preferably in communication with the thermal power delivery system to provide control for the delivery of thermal power.
Advantageously, the thermoelectric power generation system is controllable to deliver thermal power from the thermal power source to one of the at least two thermoelectric modules and to deliver thermal power from the thermal power source to the other of the at least two thermoelectric modules and to deliver thermal power to both of the at least two thermoelectric modules. Of-course, the system isn't limited to two thermoelectric modules, but could be any number of modules. Preferably, the controller can deliver power to a variety of combinations of differing capacity thermoelectrics so as to enhance efficient power production. In one embodiment, the thermal power delivery system uses a hot-side working fluid, with the flow rate of the hot-side working fluid is controllable via the controller. An output is preferably adapted to move waste heat from the thermoelectric generator. The controller is in communication with the output to control the cooling conditions provided by the output. In one embodiment, the thermoelectric generator further has a cold-side working fluid in thermal communication with the output, wherein the controller is adapted to control the cold-side working fluid flow rate to control the operating properties of the thermoelectric modules.
Another aspect of the present invention involves a thermoelectric power generation system for use with an engine, the system has a thermoelectric generator having an input adapted to receive thermal power from a thermal power source, and further has an output adapted to move waste heat from the thermoelectric generator. An output delivery system is adapted to direct the waste heat to at least two locations, and a controller is in communication with the output delivery system. The controller is adapted to select at least one of the at least two locations for delivery of the waste heat.
Preferably, one of the at least two locations is a radiator of the engine. In one embodiment, the engine is in a vehicle adapted to carry occupants, and one of the at least two locations is the occupant compartment. Preferably, the controller is adapted to control the removal of waste heat from the cold side, and the controller causes the thermoelectric generator to operate substantially efficiently as the thermal power varies. In one embodiment, the thermoelectric generator has at least two thermoelectric modules, and the controller directs thermal power to at least one of the two thermoelectric modules during certain conditions and directs thermal power to both of the at least two thermoelectric modules during other conditions of varying thermal power. Preferably, the at least two thermoelectric modules are of differing capacity. In one embodiment, the thermoelectric generator has at least three thermoelectric modules, and the controller directs thermal power to any one of the thermoelectric modules. Of-course, any number of thermoelectric modules could be used as appropriate to match the available thermal power.
Another aspect of the invention involves a method of generating power from a variable thermal power source. The method involves directing thermal power to a hot-side input to a thermoelectric generator; removing waste heat from a cold-side output of the thermoelectric generator, and controlling the directing of thermal power in a manner to cause the thermoelectric generator to operate substantially efficiently as the thermal power varies.
In one embodiment, the method further involves the step of controlling the removing of waste heat from the cold-side output to cause the thermoelectric generator to operate substantially efficiently as the thermal power varies. Advantageously, the thermoelectric generator has at least two thermoelectric modules, and the step of controlling involves directing thermal power to at least one of the two thermoelectric modules during certain conditions and directing thermal power to both of the at least two thermoelectric modules during other conditions of varying thermal power. Of-course, the any number of a thermoelectric modules could be used, with the controller advantageously adapted to direct thermal power to combinations of the thermoelectric modules to adjust the capacity of the thermoelectric generator to the thermal power in.
In one embodiment, the thermoelectric generator has at least three thermoelectric modules, and the step of controlling involves directing thermal power to any one of the thermoelectric modules. Preferably, the properties of the thermoelectric modules differ, and the step of controlling further involves directing thermal power to any combination of the thermoelectric modules to achieve substantially optimal operating efficiency. Alternatively, the step of controlling involves directing thermal power to any combination of the thermoelectric modules to achieve substantially maximum operating power. In yet another embodiment, the step of controlling involves directing thermal power to any combination of the thermoelectric modules to achieve a desired level of operation for operating efficiency and power production.
The present invention relates to a thermoelectric power generation system which is capable of generating power more efficiently than a standard system, particularly suited for a thermal power source with variable thermal output. The present invention is useful for many waste heat recovery, waste heat harvesting and power generation applications. However, in order to illustrate the invention, a specific embodiment is described. The particular embodiment that is presented is the use of a thermoelectric generator to generate electrical power from thermal power contained in the exhaust of a vehicle. This particular example illustrates the advantage of designing the power generation system to monitor and control the conditions that affect power production, even under varying operating conditions. Substantial improvements can be derived by controlling TE couple properties, for example as describe in U.S. Pat. No. 6,672,076, entitled Efficiency Thermoelectrics Utilizing Convective Heat Flow, working fluid mass flow, operating current (or voltage), TE element form factor and system capacity. This patent is incorporated by reference herein. Improvements can also be obtained by designing the thermoelectric system to have thermal isolation in the direction of flow as described in U.S. Pat. No. 6,539,725 entitled Efficiency Thermoelectric Utilizing Thermal Isolation which is also incorporated by reference herein. Thus, in one embodiment, it is desirable to control the number of thermoelectric couples activated to produce power, to control the cooling conditions, to control cooling fluid flow rate, and/or to control temperatures and TE material properties.
Automotive waste heat recovery is used as an example of the present invention. However, the invention is applicable to improve the performance of power generation, waste heat recovery, cogeneration, power production augmentation, and other uses. As further examples, the present invention can be used to utilize waste heat in the engine coolant, transmission oil, brakes, catalytic converters, and other sources in cars, trucks, busses, trains, aircraft and other vehicles. Similarly, waste heat from chemical processes, glass manufacture, cement manufacture, and other industrial processes can be utilized. Other sources of waste heat such as from biowaste, trash incineration, burn off from refuse dumps, oil well burn off, can be used. Power can be produced from solar, nuclear, geothermal and other heat sources. Application to portable, primary, standby, emergency, remote, personal and other power production devices are also part of this invention. In addition, the present invention can be coupled to other devices in cogeneration systems, such as photovoltaic, fuel cell, fuel cell reformers, nuclear, internal, external and catalytic combustors, and other advantageous cogeneration systems. It should also be understood that the number of TE modules described in any embodiment herein is not of any import, but is merely selected to illustrate the invention.
The present invention is introduced using examples and particular embodiments for descriptive and illustrative purposes. Although examples are presented to show how various configurations can be employed to achieve the desired improvements, the particular embodiments are only illustrative and not intended in any way to restrict the inventions presented. It should also be noted that the term thermoelectric or thermoelectric element as used herein can mean individual thermoelectric elements as well as a collection of elements or arrays of elements. Further, the term thermoelectric is not restrictive, but used to include thermoionic and all other solid-state cooling and heating devices. In addition, the terms hot and cool or cold are relative to each other and do not indicate any particular temperature relative to room temperature or the like. Finally, the term working fluid is not limited to a single fluid, but can refer to one or more working fluids.
The particular illustrations herein depict just a few possible embodiment of a TE generator in accordance with the present invention. Other variations are possible and are part of the present invention. The system could consist of at least 2, but any number of TE modules that can operate at least partially independent of each other. Advantageously each such TE module has a different capacity, as depicted by being different sizes in as described in more detail in connection with
Automotive exhaust provides waste heat from the engine. This waste heat can be used as a source of thermal power for generation of electrical power using thermoelectric generators. This particular application is chosen for description of the invention because it provides a good example of highly variable operating conditions, in which thermal power output of the exhaust varies continually. The actual temperature and heat flux of the exhaust, which is used as the input thermal power source for the thermoelectric power generation system, varies substantially. Exhaust temperatures at the outlet of a catalytic converter typically vary from 450 to 650° C. and exhaust heat flux varies often more than a factor of 10 between idle and rapid acceleration conditions. Thus, this particular application provides a good example for an understanding of the present invention.
Such a thermoelectric power generator 100 is typically designed for a steady state operation, in order to maintain the thermoelectric operation at or substantially close to peak efficiency. When conditions vary from these design criteria, the thermoelectric efficiency drops, or can even become negative, as further explained with reference to
Some brief background on thermoelectric efficiency with reference to
For illustrative purposes, the cold-side temperature is assumed to be the same for all three hot side temperatures. As seen in
The relationship between efficiency and hot side temperature for operation at peak efficiency and peak power is illustrated in
An illustration of the change in Qh with current, I, is provided in
The performance noted above does have the characteristic that close to the peak value of power output the performance reduction is small for moderate changes in current, I and Qh, so performance is not degraded appreciably for modest changes in Qh. However, several other factors which interact with the thermal power control system contribute substantially to reductions in system efficiency. These factors are discussed below and the mechanisms and designs that reduce their impact on efficiency are described and are part of the present invention.
If, for example, the couples are identical, the power output curves could be as shown in
Ideally, each couple would operate at the current that produces peak power output. To achieve this, several conditions can be controlled to obtain more optimal performance from the thermoelectric generator, more consistent with the graph depicted in
In operation, hot side fluid 701 enters hot side duct 716 and transfers heat to heat exchanger 703. The hot side fluid, cooled by giving up some of its heat content to the first heat exchanger 703, then transfers an additional amount of it heat to heat exchanger 704, and then some additional heat to heat exchanger 705. The hot side fluid 701 then exits to the right at an output port 702. Heat is transferred from hot side heat exchangers 703, 704 and 705 to hot side shunts 706, 707, 708, the through TEs 709, and then through cold side shunts 710. In the process, electrical power is produced by the TEs 709 and can be extracted through electrical connections 714 and 715. Any remaining waste heat is removed by transfer through cold side shunts 710, which are in good thermal communication with the cold side duct 711, which in turn is in good thermal communication with the cold side cold side fluid 712 as it passes through the cold side duct 712 before the cold side fluid exits to the left at the cold side duct output port 713.
The TE power generator 700 depicted in
An advantageous configuration of a TE power generator system 900, for example for power generation from waste heat from an engine, is depicted in schematic form in
In operation, the hot exhaust 903 passing through the hot side duct 901 heats a hot side working fluid 906, which passes through the hot side working fluid conduit 902. This hot-side working fluid 906 provides heat for the hot side of the TE generator 919. The TE generator 919 is operated generally as described in the description of
For this embodiment, as well as for all embodiments of he invention, the hot side fluid (906 in this case) can be steam, NaK, HeXe mixture, pressurized air, high boiling point oil, or any other advantageous fluid. Further, the hot side fluid 906 can be a multi-phase system, as an example, nanoparticles dispersed in ethylene glycol/water mixture, a phase change multi-phase system, or any other advantageous material system. Further, by utilizing direct thermal connection, and by eliminating unneeded components, solid material systems, including heat pipes, could replace the fluid-based systems described above.
For this embodiment, and all embodiments of the invention, the cold-side loop may also employ any heat elimination mechanism, such as a finned aluminum tubular cores, evaporative cooling towers, impingement liquid coolers, heat pipes, vehicle engine coolants, water, air, or any other advantageous moving or stationary heat sinking apparatus.
The controller 916 controls the TE generator 919, hot and cold side heat exchangers, based on sensors and other inputs. The controller 916 monitors and controls the functions to, at least in part, produce, control, and adjust or modify electrical power production. Examples of a TE generator 919 are provided in more detail in the discussions of
The TE controller 916 is in communication with, and/or monitors operating conditions in any or all of the following components: mechanisms for devices measuring, monitoring, producing, or controlling the hot exhaust; components within the TE generator 919; devices within the cold side loop such as valves, pumps, pressure sensors, flow, temperature sensors; and/or any other input or output device advantageous to power generation. An advantageous function of the controller is to vary the operation of the hot side and/or cold size fluid flows so as to advantageously change the electrical output of the TE generator. For example, the controller could control, change and monitor pump speed, operate valves, govern the amount of thermal energy storage or usage and vary TE generator output voltage or current, as well as perform other functions such as adjust hot exhaust production and/or any other advantageous changes to operation. As an example of control characteristics, if the system is utilized for waste heat recovery in a vehicle, and the cold side fluid is engine coolant, a 2-way valve can be controlled by the controller or any other control mechanism to advantageously direct the flow.
Gasoline engines perform more efficiently once they warm up. Cold-side loop flow warmed by removing waste heat from the TE generator 919 can speed up the heating of the engine, if properly directed. Alternatively, the heated cold-side coolant 910 could pass through a heat exchanger to heat passenger air and then return to the TE generator inlet or be directed to the engine, to help heat it. If the engine is hot, the cold-side coolant could be directed to a radiator or any other advantageous heat sink, bypassing the engine, and then returning to the TE generator inlet.
In operation, flow of the hot side fluid 1001 provides thermal power to the TE generators TEG1 1011, TEG2 1012, and TEG3 1013, can be operated by suitably functioning valves V1-V6 1005, 1006. By way of example, at a low thermal power input, valves V1 and V4, 1005, 1006 would open to heat the hot side and cool the cold side of one TE generator TEG1 1011. The other valves V2-V6 would remain in a state to prevent heating of the second TE generator TEG2 1012, and the third TE generator TEG3 1013. The pump 909 (shown in
Alternatively, the first TE generator TEG, 1011 could be shut off by shutting off valves V1 and V4 1005, 1006 (or just Valve V1) if performance were further improved by doing so. Similarly, at higher thermal powers, TEG3, 1013, could be engaged either alone or in combination with TEG1, 1011, and/or TEG2, 1012. The control, sensors, valves, and pump described in
Operation of TE system 919B follows the principles described for
As mentioned above, although three TE generators are shown, at least two or more in any number could be used. Each TE generator could be multiple modules operating between different hot sides and/or cold side temperatures.
Further, as part of this invention, exhaust flow could be directed through any or all of the hot side pathways to vary performance not associated with electrical production, for example, to adjust exhaust back pressure, improve combustion efficiency, adjust emissions, or any other reason. In addition, the construction of the TE modules to be devised so that in the case of waste heat recovery from a fluid stream the configuration could adjust noise or combustion characteristics to incorporate all or part of the features of mufflers, catalytic converters, particulate capture or treatment, or any other desirable integration with a device that is useful in overall system operation.
Claims
1. A thermoelectric power generation system comprising:
- a thermoelectric generator having an input adapted to receive a varying thermal power from a thermal power source, and further having an output adapted to move waste heat from the thermoelectric generator;
- a thermal power delivery system adapted to selectively deliver thermal power to at least two locations; and
- a controller in communication with the delivery system, the controller programmed to utilize information regarding at least one parameter selected from the group consisting of fuel mass flow rate, air mass flow rate, pressure, exhaust temperature, and engine revolutions per minute (RPM) to select at least one of the at least two locations for delivery of the thermal power by the delivery system such that the thermoelectric generator operates substantially efficiently as the thermal power received by the thermoelectric generator varies.
2. The thermoelectric power generation system of claim 1, wherein the thermal power source comprises an engine, the thermal power selectively directed by the delivery system comprises the waste heat from the thermoelectric generator, and wherein one of the at least two locations is a radiator of the engine.
3. The thermoelectric power generation system of claim 1, wherein the thermal power source comprises a combustion engine, the thermal power selectively directed by the delivery system comprises the waste heat from the thermoelectric generator, and the combustion engine is in a vehicle adapted to carry occupants, and wherein one of the at least two locations is the occupant compartment.
4. The thermoelectric power generation system of claim 1, wherein the controller is adapted to control the removal of waste heat from a cold side of the thermoelectric generator.
5. The thermoelectric power generation system of claim 1, wherein the thermoelectric generator has at least two thermoelectrics, and wherein the controller selectively directs thermal power from the thermal power source to only one of the two thermoelectrics during certain conditions and selectively directs thermal power from the thermal power source to both of the at least two thermoelectrics during other conditions of varying thermal power.
6. The thermoelectric power generation system of claim 1, wherein the thermoelectric generator has at least three thermoelectrics, and wherein the controller selectively directs thermal power from the thermal power source to any one of the thermoelectrics.
7. The thermoelectric power generation system of claim 1, wherein the thermoelectric generator comprises at least two thermoelectrics at the at least two locations.
8. The thermoelectric power generation system of claim 7, wherein the delivery system is controllable to selectively deliver thermal power from the thermal power source either to a first number of thermoelectrics of the at least two thermoelectrics or to a second number of thermoelectrics of the at least two thermoelectrics, the first number less than the second number.
9. The thermoelectric power generation system of claim 7, wherein the delivery system is controllable to selectively deliver thermal power from the thermal power source either to one thermoelectric of the at least two thermoelectrics or to two thermoelectrics of the at least two thermoelectrics.
10. The thermoelectric power generation system of claim 7, wherein the delivery system is controllable to selectively deliver thermal power from the thermal power source either to a first thermoelectric of the at least two thermoelectrics, a second thermoelectric of the at least two thermoelectrics, or to both the first thermoelectric and the second thermoelectric.
11. The thermoelectric power generation system of claim 7, wherein the controller is in communication with the delivery system to control the cooling conditions provided by the delivery system.
12. The thermoelectric power generation system of claim 11, further comprising a cold-side working fluid in thermal communication with the delivery system, wherein the controller is in communication with the delivery system to control the cold-side working fluid flow rate to control the operating properties of the at least two thermoelectrics.
13. The thermoelectric power generation system of claim 1, wherein the delivery system uses a hot-side working fluid, and wherein the flow rate of the hot-side working fluid is controllable via the controller.
14. The thermoelectric power generation system of claim 1, wherein the at least one parameter comprises fuel mass flow rate.
15. The thermoelectric power generation system of claim 1, wherein the at least one parameter comprises air mass flow rate.
16. The thermoelectric power generation system of claim 1, wherein the at least one parameter comprises pressure.
17. The thermoelectric power generation system of claim 1, wherein the at least one parameter comprises exhaust temperature.
18. The thermoelectric power generation system of claim 1, wherein the at least one parameter comprises engine RPM.
1120781 | December 1914 | Altenkirch et al. |
2362259 | November 1944 | Findley |
2363168 | November 1944 | Findley |
2519241 | August 1950 | Findley |
2944404 | July 1960 | Fritts |
2949014 | August 1960 | Belton, Jr. et al. |
2984077 | May 1961 | Gaskill |
3004393 | October 1961 | Alsing |
3006979 | October 1961 | Rich |
3019609 | February 1962 | Pietsch |
3071495 | January 1963 | Hanlein |
3085405 | April 1963 | Frantti |
3125860 | March 1964 | Reich |
3129116 | April 1964 | Corry |
3137142 | June 1964 | Venema |
3178895 | April 1965 | Mole et al. |
3197342 | July 1965 | Neild, Jr. |
3212275 | October 1965 | Tillman, Jr. |
3213630 | October 1965 | Mole |
3252504 | May 1966 | Newton |
3505728 | September 1967 | Hare et al. |
3391727 | July 1968 | Topouszian |
3527621 | September 1970 | Newton |
3599437 | August 1971 | Panas |
3607444 | September 1971 | Debucs |
3626704 | December 1971 | Coe, Jr. |
3635037 | January 1972 | Hubert |
3663307 | May 1972 | Mole |
3681929 | August 1972 | Schering |
3779814 | December 1973 | Miles et al. |
3817043 | June 1974 | Zoleta |
3859143 | January 1975 | Krebs |
4038831 | August 2, 1977 | Gaudel et al. |
4047093 | September 6, 1977 | Levoy |
4055053 | October 25, 1977 | Elfving |
4065936 | January 3, 1978 | Fenton et al. |
4125122 | November 14, 1978 | Stachurski |
4281516 | August 4, 1981 | Berthet et al. |
4297841 | November 3, 1981 | Cheng |
4297849 | November 3, 1981 | Buffet |
4420940 | December 20, 1983 | Buffet |
4448028 | May 15, 1984 | Chao et al. |
4494380 | January 22, 1985 | Cross |
4499329 | February 12, 1985 | Benicourt et al. |
4665707 | May 19, 1987 | Hamilton |
4730459 | March 15, 1988 | Schlicklin et al. |
4731338 | March 15, 1988 | Ralston et al. |
4753682 | June 28, 1988 | Cantoni |
4823554 | April 25, 1989 | Trachtenberg et al. |
4858069 | August 15, 1989 | Hughes |
4905475 | March 6, 1990 | Tuomi |
4988847 | January 29, 1991 | Argos et al. |
4989626 | February 5, 1991 | Takagi et al. |
5006178 | April 9, 1991 | Bijvoets |
5029446 | July 9, 1991 | Suzuki |
5038569 | August 13, 1991 | Shirota et al. |
5092129 | March 3, 1992 | Bayes et al. |
5097829 | March 24, 1992 | Quisenberry |
5111664 | May 12, 1992 | Yang |
5193347 | March 16, 1993 | Apisdorf |
5228923 | July 20, 1993 | Hed |
5232516 | August 3, 1993 | Hed |
5254178 | October 19, 1993 | Yamada et al. |
5300197 | April 5, 1994 | Mitani et al. |
5385020 | January 31, 1995 | Gwilliam et al. |
5419780 | May 30, 1995 | Suski |
5419980 | May 30, 1995 | Okamoto et al. |
5429680 | July 4, 1995 | Fuschetti |
5448891 | September 12, 1995 | Nakagiri et al. |
5499504 | March 19, 1996 | Mill et al. |
5544487 | August 13, 1996 | Attey et al. |
5561981 | October 8, 1996 | Quisenberry et al. |
5563368 | October 8, 1996 | Yamaguchi |
5566774 | October 22, 1996 | Yoshida |
5584183 | December 17, 1996 | Wright et al. |
5592363 | January 7, 1997 | Atarashi et al. |
5594609 | January 14, 1997 | Lin |
5605047 | February 25, 1997 | Park et al. |
5682748 | November 4, 1997 | DeVilbiss et al. |
5713426 | February 3, 1998 | Okamura |
5724818 | March 10, 1998 | Iwata et al. |
5802856 | September 8, 1998 | Schaper et al. |
5822993 | October 20, 1998 | Attey |
5860472 | January 19, 1999 | Batchelder |
5867990 | February 9, 1999 | Ghoshal |
5900071 | May 4, 1999 | Harman |
RE36242 | June 29, 1999 | Apisdorf |
5921088 | July 13, 1999 | Imaizumi et al. |
5955772 | September 21, 1999 | Shakouri et al. |
5959341 | September 28, 1999 | Tsuno et al. |
5966941 | October 19, 1999 | Ghoshal |
5975856 | November 2, 1999 | Welle |
5987890 | November 23, 1999 | Chiu et al. |
6000225 | December 14, 1999 | Ghoshal |
6050326 | April 18, 2000 | Evans |
6082445 | July 4, 2000 | Dugan |
6084172 | July 4, 2000 | Kishi et al. |
6096966 | August 1, 2000 | Nishimoto et al. |
6119463 | September 19, 2000 | Bell |
6127766 | October 3, 2000 | Roidt |
6213198 | April 10, 2001 | Shikata et al. |
6223539 | May 1, 2001 | Bell |
6274802 | August 14, 2001 | Fukuda et al. |
6282907 | September 4, 2001 | Ghoshal |
6319744 | November 20, 2001 | Hoon et al. |
6334311 | January 1, 2002 | Kim et al. |
6346668 | February 12, 2002 | McGrew |
6347521 | February 19, 2002 | Kadotani et al. |
6359725 | March 19, 2002 | Islam |
6366832 | April 2, 2002 | Lomonaco et al. |
6367261 | April 9, 2002 | Marshall et al. |
6393842 | May 28, 2002 | Kim |
6401462 | June 11, 2002 | Bielinski |
6412287 | July 2, 2002 | Hughes et al. |
6446442 | September 10, 2002 | Batchelor et al. |
6477844 | November 12, 2002 | Ohkubo et al. |
6481213 | November 19, 2002 | Carr et al. |
6510696 | January 28, 2003 | Guttman et al. |
6530231 | March 11, 2003 | Nagy et al. |
6530842 | March 11, 2003 | Wells et al. |
6530920 | March 11, 2003 | Whitcroft et al. |
6539725 | April 1, 2003 | Bell |
6539729 | April 1, 2003 | Tupis et al. |
6560968 | May 13, 2003 | Ko |
6563039 | May 13, 2003 | Caillat et al. |
RE38128 | June 3, 2003 | Gallup et al. |
6580025 | June 17, 2003 | Guy |
6598403 | July 29, 2003 | Ghoshal |
6598405 | July 29, 2003 | Bell |
6605773 | August 12, 2003 | Kok et al. |
6606866 | August 19, 2003 | Bell |
6625990 | September 30, 2003 | Bell |
6637210 | October 28, 2003 | Bell |
6650968 | November 18, 2003 | Hallum et al. |
6653002 | November 25, 2003 | Parise |
6672076 | January 6, 2004 | Bell |
6807811 | October 26, 2004 | Lee |
6812395 | November 2, 2004 | Bell |
6886356 | May 3, 2005 | Kubo et al. |
6907739 | June 21, 2005 | Bell |
6948321 | September 27, 2005 | Bell |
6959555 | November 1, 2005 | Bell |
6975060 | December 13, 2005 | Styblo et al. |
6986247 | January 17, 2006 | Parise |
7100369 | September 5, 2006 | Yamaguchi et al. |
7111465 | September 26, 2006 | Bell |
7231772 | June 19, 2007 | Bell |
7246496 | July 24, 2007 | Goenka et al. |
7273981 | September 25, 2007 | Bell |
7421845 | September 9, 2008 | Bell |
7426835 | September 23, 2008 | Bell |
7587902 | September 15, 2009 | Bell |
7608777 | October 27, 2009 | Bell et al. |
20010005990 | July 5, 2001 | Kim |
20010029974 | October 18, 2001 | Cohen et al. |
20020014261 | February 7, 2002 | Caillat et al. |
20030029175 | February 13, 2003 | Lee |
20030094265 | May 22, 2003 | Chu et al. |
20040045594 | March 11, 2004 | Hightower |
20040055312 | March 25, 2004 | Bell |
20040076214 | April 22, 2004 | Bell |
20040177876 | September 16, 2004 | Hightower |
20040261829 | December 30, 2004 | Bell |
20040261831 | December 30, 2004 | Tsuneoka et al. |
20040267408 | December 30, 2004 | Kramer |
20050074646 | April 7, 2005 | Rajashekara et al. |
20050194034 | September 8, 2005 | Yamaguchi et al. |
20050247336 | November 10, 2005 | Inaoka |
20050263176 | December 1, 2005 | Yamaguchi et al. |
20050263177 | December 1, 2005 | Bell |
20060005548 | January 12, 2006 | Ruckstuhl |
20060075758 | April 13, 2006 | Rice et al. |
20060130888 | June 22, 2006 | Yamaguchi et al. |
20060150657 | July 13, 2006 | Spurgeon et al. |
20060157102 | July 20, 2006 | Nakajima |
20060174633 | August 10, 2006 | Beckley |
20060188418 | August 24, 2006 | Yoon et al. |
20070000255 | January 4, 2007 | Elliot et al. |
20070033951 | February 15, 2007 | Goenka et al. |
20070220902 | September 27, 2007 | Matsuoka et al. |
20070272290 | November 29, 2007 | Sims et al. |
20080035195 | February 14, 2008 | Bell |
20080173342 | July 24, 2008 | Bell |
20080245398 | October 9, 2008 | Bell |
20080250794 | October 16, 2008 | Bell |
20080289677 | November 27, 2008 | Bell |
20080307796 | December 18, 2008 | Bell et al. |
20090000310 | January 1, 2009 | Bell et al. |
20090007572 | January 8, 2009 | Bell et al. |
20090007952 | January 8, 2009 | Kondoh et al. |
20090139556 | June 4, 2009 | Bell et al. |
20090293499 | December 3, 2009 | Bell et al. |
20090301103 | December 10, 2009 | Bell et al. |
20100024859 | February 4, 2010 | Bell et al. |
20100031987 | February 11, 2010 | Bell |
20100031988 | February 11, 2010 | Bell |
20100052374 | March 4, 2010 | Bell |
20100095996 | April 22, 2010 | Bell |
20100101238 | April 29, 2010 | LaGrandeur |
20100101239 | April 29, 2010 | LaGrandeur |
20100236595 | September 23, 2010 | Bell |
20100326092 | December 30, 2010 | Goenka |
20110067742 | March 24, 2011 | Bell et al. |
1195090 | October 1998 | CN |
1236429 | November 1999 | CN |
1249067 | March 2000 | CN |
1343294 | April 2002 | CN |
13 01 454 | August 1969 | DE |
43 29 816 | March 1994 | DE |
0 389 407 | September 1990 | EP |
0 545 021 | June 1993 | EP |
0834421 | April 1998 | EP |
0 878 851 | November 1998 | EP |
1 324 400 | July 2003 | EP |
1475532 | November 2004 | EP |
1 515 376 | March 2005 | EP |
1 641 067 | March 2006 | EP |
1679480 | July 2006 | EP |
1 280 711 | January 1962 | FR |
2 261 638 | September 1975 | FR |
2 419 479 | October 1979 | FR |
2 543 275 | September 1984 | FR |
2 550 324 | February 1985 | FR |
2 879 728 | June 2006 | FR |
231 192 | May 1926 | GB |
817 077 | July 1959 | GB |
952 678 | March 1964 | GB |
1 040 485 | August 1966 | GB |
2 027 534 | February 1980 | GB |
2 267 338 | December 1993 | GB |
2 333 352 | July 1999 | GB |
56-18231 | February 1981 | JP |
60-80044 | July 1985 | JP |
63-262076 | October 1988 | JP |
01 131830 | May 1989 | JP |
01 200122 | August 1989 | JP |
01-281344 | November 1989 | JP |
03-102219 | April 1991 | JP |
04 103925 | April 1992 | JP |
4-165234 | June 1992 | JP |
5-219765 | August 1993 | JP |
6-342940 | December 1994 | JP |
7-007187 | January 1995 | JP |
7-198284 | January 1995 | JP |
07-074397 | March 1995 | JP |
07-54189 | June 1995 | JP |
7 156645 | June 1995 | JP |
A-7-202275 | August 1995 | JP |
07-253224 | October 1995 | JP |
07253264 | February 1996 | JP |
08-098569 | April 1996 | JP |
08-222771 | August 1996 | JP |
A-8-293627 | November 1996 | JP |
09042801 | February 1997 | JP |
09-092761 | April 1997 | JP |
09-254630 | September 1997 | JP |
09-276076 | October 1997 | JP |
10-163538 | June 1998 | JP |
10-275943 | October 1998 | JP |
10290590 | October 1998 | JP |
11-317481 | November 1998 | JP |
H10-325561 | December 1998 | JP |
11-046021 | February 1999 | JP |
11-182907 | July 1999 | JP |
11-201475 | July 1999 | JP |
11-274574 | October 1999 | JP |
11 274575 | October 1999 | JP |
11-041959 | December 1999 | JP |
2000 018095 | January 2000 | JP |
H2000-58930 | February 2000 | JP |
2000-185542 | July 2000 | JP |
H2000-214934 | August 2000 | JP |
2000-274788 | October 2000 | JP |
2000-274871 | October 2000 | JP |
2000-274874 | October 2000 | JP |
2000 286469 | October 2000 | JP |
2000-286469 | October 2000 | JP |
2000-323759 | November 2000 | JP |
2001-24240 | January 2001 | JP |
2001-210879 | August 2001 | JP |
2001-267642 | September 2001 | JP |
2001-336853 | January 2002 | JP |
2002-13758 | January 2002 | JP |
2002-199761 | July 2002 | JP |
2002 232028 | August 2002 | JP |
2003-86223 | March 2003 | JP |
2003175720 | June 2003 | JP |
2004 079883 | March 2004 | JP |
2004-360522 | December 2004 | JP |
2005-212564 | August 2005 | JP |
07 111334 | October 2005 | JP |
2005 317648 | November 2005 | JP |
2006 214350 | August 2006 | JP |
2008 042994 | February 2008 | JP |
2008 274790 | November 2008 | JP |
2008 300465 | December 2008 | JP |
2009 033806 | February 2009 | JP |
66619 | February 1973 | LU |
2 099 642 | December 1997 | RU |
2 142 178 | November 1999 | RU |
2 154 875 | August 2000 | RU |
2174475 | October 2001 | RU |
329 870 | October 1970 | SE |
337 227 | August 1971 | SE |
184886 | July 1966 | SU |
1142711 | February 1985 | SU |
1170234 | July 1985 | SU |
1196627 | December 1985 | SU |
WO 95/01500 | January 1995 | WO |
WO 97/47930 | December 1997 | WO |
WO 99/58907 | November 1999 | WO |
WO 01/52332 | July 2001 | WO |
WO 02/00458 | January 2002 | WO |
WO 03/074951 | September 2003 | WO |
WO 03/090286 | October 2003 | WO |
WO 2004/092662 | October 2004 | WO |
WO 2005/023571 | March 2005 | WO |
WO 2005/098225 | October 2005 | WO |
WO 2006/037178 | April 2006 | WO |
WO 2006/043514 | April 2006 | WO |
WO 2006/064432 | June 2006 | WO |
WO 2007/001289 | January 2007 | WO |
WO 2008/042077 | April 2008 | WO |
WO 2010/014958 | February 2010 | WO |
WO 2010/048575 | April 2010 | WO |
- International Search Report PCT/US2006/025330, dated Jul. 11, 2007.
- Bell, L.E., “Alternate Thermoelectric Thermodynamic Cycles with Improved Power Generation Efficiencies” Thermoelectrics, 2003 Twenty-Second International Conference on—ICT La Grande Motte, France Aug. 17-21, 2003, Piscataway, NJ, USA, IEEE, Aug. 17, 2003, pp. 558-562, XP010697375, ISBN: 0-7803-8301-X.
- Bell, L.E., “Use of Thermal Isolation to Improve Thermoelectric system Operating Efficiency,” Thermoelectrics, 2002. Proceedings ICT '02. Twenty-First International Conference on Aug. 25, 2002, Piscataway, NJ, USA, IEEE, Aug. 25, 2002, pp. 477-487, XPO10637528, ISBN: 0-7803-7683-8.
- Buist, R.J. et al. “A New Concept for Improving Thermoelectric Heat Pump Efficiency”, Borg-Warner Thermoelectrics Wolf and Algonquin Road, pp. 60-63, 1976.
- Buist, R., et al. “Theoretical Analysis of Thermoelectric Cooling Performance Enhancement Via Thermal and Electrical Pulsing”, Journal of Thermoelectricity, No. 4, 1996.
- Crane, D. T., et al.: “Progress Towards Maximizing the Performance of a Themoelectric Power Generator”, Thermoelectrics, 2006. ICT '06. 25th International Conference on, IEEE, PI, Aug. 1, 2006, pp. 11-16, XP031062639, ISBN: 978-1-4244-0810-8 the whole document.
- CRC Handbook of Thermoelectrics, ed. D.M. Rowe, Chapter 54, Medium-Scale Cooling: Thermoelectrice Technology and Chap. 55, Modeling of Thermoelectric Cooling Systems, (ISBN: 0-8493-0146-7), Jul. 1995, pp. 667-683.
- Database WPI Week 198227 Thomson Scientific, London, GB; AN 1982-J1035E, XP002485188 & SU 861 869 B (Bochin G V) Sep. 7, 1981 & SU 861 869 A1 (Bochin German V [SU]; Butyrskij Velentin; Kochkarev Vladimir; Kubalov) Sep. 7, 1981.
- Diller, R. W., et al.: “Experimental results confirming improved performance of systems using thermal isolation” Thermoelectrics, 2002. Proceedings ICT '02. Twenty-First International Conference on Aug. 25-29, 2002, Piscataway, NJ USA, IEEE, Aug. 25, 2002, pp. 548-550, XP010637541 ISBN: 0-7803-7683-8.
- Diller, R.W., et al., “Experimental Results Confirming Improved Efficiency of Thermoelectric Power Generation Systems with Alternate Thermodynamic Cycles,” 22nd International Conference on Thermoelectrics, 2003, pp. 571-573.
- Fleurial, J-P, et al.: “Development of Segmented Thermoelectric Multicouple Converter Technology” Aerospace Conference, 2006 IEEE Big Sky, MT, USA Mar. 4-11, 2006, Piscataway, NJ, USA, IEEE, Mar. 4, 2006, pp. 1-10, XP010928672 ISBN: 978-07803-9545-9.
- Goldsmid, H.J., “Electronic Refrigeration”, Pion Ltd, 207 Brondesbury Park, London (1986).
- Kwon, H., et al., Hyundai Motor Co., corresponding to KR 9706106 A, published Jun. 24, 1997 (2 pages), Derwent-Acc-No. 1998-283540.
- Miner, A., et al. “Thermo-Electro-Mechanical Refrigeration Based on Transient Thermoelectric Effects”, Applied Physics letters, vol. 75, pp. 1176-1178 (1999).
- Tada, S., et al., “A New Concept of Porous Thermoelectric Module Using a Reciprocating Flow for Cooling/Heating Systems (Numerical Analysis for Heating Systems)” 16th International Conference on Thermoelectrics (1977).
- International Preliminary Report on Patentability for International Application No. PCT/US2006/025330, dated Mar. 5, 2008 in 7 pages.
- Angrist, Direct Energy Conversion, Third Edition, Ed. Ally & Bacon, Chap. 4 (1976).
- Bass, J.C. et al., Performance of the 1 kW Thermoelectric Generator for Diesel Engines, American Institute of Physics, 1995, p. 295-298.
- Bell Lon E., High Power Density Thermoelectric Systems, BSST LLC, Irwindale, California, Proc. of 23rd Int'l Conf. on Thermoelectrics, Jul. 2004.
- Bell, Lon E., Increased Thermoelectric System Thermodynamic Efficiency by Use of Convective Heat Transport, BSST LLC, Irwindale, California, Proc. 21st Int'l Conf. on Thermoelectrics, Aug. 2002.
- Birkholz, Ulrich et al., Conversion of Waste Exhaust Heat in Automobiles Using FeSi2-Thermoelements, 7th International Conference on TE Energy Conversion, p. 124-128, 1988.
- BSST LLC, Freedom Car & Vehicle Technologies Program, BSST LLC Project Phase 1 Report : High Efficiency Thermoelectric Waste Energy Recovery System for Passenger Vehicle Application, U.S. Department of Energy, Jun. 1, 2005, p. 1-95.
- Cobble, Milan H., Calculations of Generator Performance, CRC Press, Inc. 1995, p. 489.
- Crane, D.T., Modeling High-Power Density Thermoelectric Assemblies Which Use Thermal Isolation, BSST LLC, Irwindale, California, Proc. of 23rd Int'l Conf. on Thermoelectrics, Jul. 2004.
- Crane, Douglas T., Optimizing Thermoelectric Waste Heat Recovery From an Automobile Cooling System, Dissertation submitted to the Faculty of Graduate School of the University of Maryland, 2003.
- Hendricks, Terry et al., Advanced Thermoelectric Power System Investigations for Light-Duty and Heavy Duty Applications, National Renewable Energy Laboratory, Center for Transportation Technology & Systems, Colorado, Proc. 21st Int'l Conf. on Thermoelectrics, Aug. 2002, pp. 381-386.
- Hsu, Kuei Fang et al., Cubic AgPbmSbTe2+m: Bulk Thermoelectric Materials with High Figure of Merit, Science, Feb. 6, 2004, p. 818-821, vol. 303.
- Ikoma et al., Thermoelectric Module and Generator for Gasoline Engine Vehicles, 17th International Conference on Thermoelectrics, 1998, p. 464-467.
- Lofy, John et al., Thermoelectrics for Environmental Control in Automobiles, 21st International Conference on Thermoelectronics, 2002, p. 471-476.
- Menchen, William R. et al., Thermoelectric Conversion to Recover Heavy Duty Diesel Exhaust Energy, Teledyne Energy Systems, Timonium, MD, 1990, SAE Proc. of the Annual Automotive Tech. Dev. Contractor's Meeting, pp. 445-449.
- Snyder, G. Jeffrey et al., Thermoelectric Efficiency and Compatibility, The American Physical Society, Oct. 2, 2003, vol. 91, No. 14.
- Snyder, G. Jeffrey, Application of the Compatibility Factor to the Design of Segmented and Cascaded Thermoelectric Generators, Applied Physics Letters, Mar. 2004.
- Ursell, T.S. et al., Compatibility of Segmented Thermoelectric Generators, 21st International Conference on Thermoelectronics, 2002, p. 412-417.
Type: Grant
Filed: Jun 28, 2006
Date of Patent: Jul 17, 2012
Patent Publication Number: 20100236595
Assignee: BSST, LLC (Irwindale, CA)
Inventors: Lon E. Bell (Altadena, CA), Douglas Todd Crane (Pasadena, CA)
Primary Examiner: Jennifer Michener
Assistant Examiner: Matthew Martin
Attorney: Knobbe Martens Olson & Bear, LLP
Application Number: 11/476,325
International Classification: H01L 35/30 (20060101);