Patents Issued in May 27, 2014
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Patent number: 8735483Abstract: A polymerizable composition includes: a polymerization initiator; a polymerizable compound; a tungsten compound; and an alkali-soluble binder.Type: GrantFiled: November 19, 2012Date of Patent: May 27, 2014Assignee: FUJIFILM CorporationInventors: Naotsugu Muro, Kimi Ikeda, Kazuto Shimada, Daisuke Arioka
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Patent number: 8735484Abstract: Disclosed is an amorphous copolyester polymerized of a diacid and diols. The diacid is selected from a group consisting of terephthalic acid, 5-tert-butylisophthalic acid, and dimethyl 2,6-naphthalenedicarboxylate. The diols are selected at least two from a group consisting of ethylene glycol, 2,2-dimethyl-1,3-propanediol, and tricyclodecanedimethanol. The molar ratio of the tricyclodecanedimethanol is 30% to 95% of the diols.Type: GrantFiled: December 27, 2012Date of Patent: May 27, 2014Assignee: Industrial Technology Research InstituteInventors: Cheng-Hsing Fan, Kuo-Chen Shih, Ming-Tsong Leu, Li-Cheng Jheng
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Patent number: 8735485Abstract: The invention relates to a rubber mixture, in particular for pneumatic vehicle tires, more particularly for the inner liner of a pneumatic vehicle tire, seat belts, belts and hoses. The rubber mixture is characterized by the following composition: 30 to 100 phr of at least one halobutyl rubber, 0 to 70 phr of at least one other diene rubber, 5 to 100 phr of at least one dry mixture compound containing at least 25% of at least one delaminated aluminohydrosilicate modification, the delaminated aluminohydrosilicate modification having a two-layer grid, 10 to 100 phr of at least one carbon black with an STSA surface as defined according to ASTM-D 6556 of from 10 to 60 m2/g and a DBP number defined according to ASTM-D 2414 of from 50 to 160 mL/100g, 3 to 20 phr of at least one mineral-oil softener, and other additives.Type: GrantFiled: March 29, 2011Date of Patent: May 27, 2014Assignee: Continential Reifen Deutschland GmbHInventors: Thomas Müller-Wilke, Mario R. Conde, Steffi Meissner
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Patent number: 8735486Abstract: An exterior body of an electric appliance is produced by kneading one or more resin components and one or more flame retardancy-imparting components to give a composition, and molding the composition by an injection molding method or a compression molding method. At least one of the flame retardancy-imparting components is a catalytic cracking catalyst and the catalytic cracking catalyst is a silica-magnesia catalyst which is double oxide of silicon oxide and magnesium oxide or which is formed by binding silicon oxide and magnesium oxide. The at least one flame retardancy-imparting component is contained in an amount of 0.5 wt % to 40 wt % of the resin composition. No metal hydroxide and no polyvinyl chloride are contained in the composition.Type: GrantFiled: January 12, 2011Date of Patent: May 27, 2014Assignee: Panasonic CorporationInventors: Takehiko Yamashita, Kunihiko Takeda
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Patent number: 8735487Abstract: A tire comprising at least one cured rubber component having boron nitride dispersed within a cured rubber matrix.Type: GrantFiled: June 30, 2009Date of Patent: May 27, 2014Assignee: Bridgestone CorporationInventors: Mary M. Matthiesen, Amy Randall, Mindaugas Rackaitis
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Patent number: 8735488Abstract: The invention relates to black having a CTAB surface area of 100 to 160 m?/g, a quartile ratio of more than 1.60, and an FP index of >0. Said black is produced in a furnace reactor. Sixty to 90 percent by weight of the raw black material are injected into the reactor in the first third of the reaction zone, while the remaining amount of the raw black material is injected into the reactor upstream at least in one other point. In addition, the combustible is conducted such that 90 to 100 percent by weight of the combustible are evaporated when first hitting the raw black material and 80 to 99 percent by weight of the combustible are evaporated 5 ms before hitting the raw black material. Said blacks can be used in rubber mixtures.Type: GrantFiled: September 4, 2008Date of Patent: May 27, 2014Assignee: Orion Engineered Carbons GbmHInventors: Thomas Pelster, Burkhard Freund, Joachim Fröhlich, Werner Niedermeier, Conny Vogler
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Patent number: 8735489Abstract: A resin composite material including fine graphite particles including plate-like graphite particles, an aromatic vinyl copolymer which is adsorbed on the plate-like graphite particles and which has a vinyl aromatic monomer unit represented by the following formula: —(CH2—CHX)— (X represents a phenyl group, a naphthyl group, an anthracenyl group, or a pyrenyl group, provided that these groups may have substituents); a fibrous inorganic filler; and a resin matrix.Type: GrantFiled: December 5, 2012Date of Patent: May 27, 2014Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventor: Hiromitsu Tanaka
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Patent number: 8735490Abstract: An aromatic vinyl thermoplastic resin composition includes (A) about 10 to about 99% by weight of a thermoplastic resin (A) including (a1) an aromatic vinyl copolymer resin, (a2) a rubber-modified vinyl graft copolymer, or a combination of (a1) and (a2); and (B) about 1 to about 90% by weight of a branched aromatic vinyl copolymer resin including a silicon based compound. The branched aromatic vinyl copolymer includes a copolymer prepared by copolymerizing (b1) about 10 to about 85% by weight of an aromatic vinyl based monomer; (b2) about 10 to about 85% by weight of an unsaturated nitrile based monomer; (b3) about 1 to about 50% by weight of an aromatic methacrylate, aliphatic methacrylate, or a combination thereof; and (b4) about 0.1 to about 20% by weight of a silicon based compound having two or more unsaturated functional groups.Type: GrantFiled: December 17, 2010Date of Patent: May 27, 2014Assignee: Cheil Industries Inc.Inventors: Jin Hwa Chung, Kee Hae Kwon, Ja Kwan Koo, Il Jin Kim
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Patent number: 8735491Abstract: An essentially halogen-free, plasticizer-free thermoplastic elastomer compound is disclosed. The compound has from 10-80 weight percent of a hydrogenated styrene butadiene copolymer having a styrene content of less than 20 weight percent; from 20-90 weight percent of a polyolefin; and less than about 3 weight percent of antioxidant. The compound is capable of being solvent bonded or welded to another thermoplastic material using cyclohexanone alone or with methyl ethyl ketone. The compound is especially useful as medical tubing connected to other parts of medical equipment. The bond strength of the compound to the other thermoplastic material is properly determined only after multiple days of bonding.Type: GrantFiled: December 1, 2009Date of Patent: May 27, 2014Assignee: PolyOne CorporationInventors: Sehyun Kim, Wayne Thornton
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Patent number: 8735492Abstract: An object of the present invention is to provide a method for producing a fluoropolymer which produces a large number of particles with a small particle size using a specific non-fluorous compound having surfactant ability. The method for producing a fluoropolymer includes aqueous dispersion polymerization of a monomer including at least one fluoroolefin in the presence of a compound (1) represented by the formula: CH2?CR1—R2—O-(AO)p—X (in the formula, R1 is hydrogen or an alkyl group; R2 is an alkylene group having two or more carbon atoms; AO is a linear or branched oxyalkylene group having 2 to 4 carbon atoms; p is a positive integer; X is H or SO3Y wherein Y is NH4 or an alkaline metal; and AO may be the same or different and may form two or more blocks if there is more than one AO.Type: GrantFiled: August 25, 2010Date of Patent: May 27, 2014Assignee: Daikin Industries, Ltd.Inventors: Katsuhiko Imoto, Shumi Nishii, Yoshinari Fukuhara
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Patent number: 8735493Abstract: A method of making a polysiloxane containing polymer is described. The method comprises the steps of the polycondensation of a) 100 parts by weight of oligomers comprising non-cyclic siloxane containing oligomers having at least two condensable groups per molecule alone or in a mixture with one or organic oligomers having at least two condensable groups per molecule in the presence of: b) at least 2 parts by weight per 100 parts of (a) of one or more condensation catalysts comprising a Bronsted acid or a Lewis acid c) at least 15 parts by weight per 100 parts of (a) of one or more liquefied gases or a supercritical fluid therefrom. Subsequent to the reaction completion the polysiloxane containing polymer is recovered by expansion of the liquefied gas(es) or supercritical fluid (c).Type: GrantFiled: March 18, 2010Date of Patent: May 27, 2014Assignee: Dow Corning CorporationInventors: Andreas Stammer, Andreas Wolf
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Patent number: 8735494Abstract: A method for preparing a polydiene polymer, the method comprising: (i) preparing an active polymerization mixture by introducing conjugated diene monomer, and optionally monomer copolymerizable therewith, and a lanthanide-based catalyst system; (ii) adding a nitrile compound containing a protected amino group to the active polymerization mixture; and (iii) adding a co-functionalizing agent to the active polymerization mixture.Type: GrantFiled: November 27, 2012Date of Patent: May 27, 2014Assignee: Bridgestone CorporationInventors: Steven Luo, Eiju Suzuki, Dennis R. Brumbaugh
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Patent number: 8735495Abstract: A two-component urethane system. The first component is a hydroxy-terminated polyester polyol containing polymerized residues of phthalic acid and an aliphatic diol having Mn from 60 to 150, and having no more than 15 wt % polymerized residues of aliphatic acids. The second component is an isocyanate-terminated prepolymer containing polymerized residues of diphenyl methane diisocyanate and/or toluene diisocyanate and a glycol or polyol having Mn from 90 to 1000.Type: GrantFiled: July 12, 2012Date of Patent: May 27, 2014Assignee: Rohm and Haas CompanyInventors: Larry F. Brinkman, David E. Vietti, Joseph James Zupancic
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Patent number: 8735496Abstract: The present invention relates to a process for the production of the largest possible spherical, monodisperse polyvinylpyrrolidone (PVP) seed particles in the micron range by dispersion polymerisation. The particles obtained in this way represent novel starting materials for the production of macroporous polymer particles, which can in turn be employed in preparative and analytical chromatography for protein preparation. They can also be employed as base material for further reactions. The novel process for the polymerisation of N-vinylpyrrolidone, which is inexpensive to carry out, gives particles having optimised quantities, such as monodispersity, sphericity and particle diameter, which can be employed in further reactions and have advantageous, in particular improved, properties for use in chromatographic separation methods.Type: GrantFiled: April 27, 2010Date of Patent: May 27, 2014Assignee: Merck Patent GmbHInventors: Matthias Joehnck, Daniel Scheid
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Patent number: 8735497Abstract: A propylene composition comprising (percent by weight): A) 60%-95%, of a crystalline propylene copolymer containing from 2.0% to 10.0% of ethylene derived units having a melting point ranging from 148° C. to 160° C.; wherein the melting temperature Tm is measured by DSC on the as-reactor polymer; B) 40%-5%, of a copolymer of ethylene containing from 70% to 85%, of ethylene derived units intrinsic viscosity ranging from 0.8 to 3 dl/g.Type: GrantFiled: October 4, 2010Date of Patent: May 27, 2014Assignee: Basell Poliolefine Italia S.r.l.Inventors: Claudio Cavalieri, Fiorella Pradella, Monica Galvan
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Patent number: 8735498Abstract: Soft polyolefin composition with improved processability comprising from 8 to 45% by weight of a polypropylene component (A), from 45 to 82% by weight of a polyolefin component (B), and from 5 to 25% by weight of a butene-1 (co)polymer (C) having a flexural modulus of 60 MPa or less.Type: GrantFiled: November 8, 2010Date of Patent: May 27, 2014Assignee: Basell Poliolefine Italia S.r.l.Inventors: Giampaolo Pellegatti, Paolo Goberti, Johan De Clippeleir, Stefano Spataro
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Patent number: 8735499Abstract: The propylene-based polymer composition includes a specific amount of a propylene-based polymer (A) having a syndiotactic pentad fraction (rrrr fraction) of 85% or more and containing 90 to 100 mol % of a structural unit derived from propylene; a specific amount of a propylene-based copolymer (B) containing 40 to 89 mol % of a structural unit derived from propylene and 11 to 60 mol % of a structural unit derived from an ?-olefin and satisfying a specific equation of intrinsic viscosity [?] and MFR; and specific amount(s) of at least one polymer of an olefin-based thermoplastic elastomer (C), a styrene-based elastomer (D), a propylene/ethylene/?-olefin copolymer (E) and an isotactic propylene-based polymer (F), and optionally an ethylene/vinyl acetate copolymer (G) and/or an ethylene-based polymer (H).Type: GrantFiled: June 28, 2012Date of Patent: May 27, 2014Assignee: Mitsui Chemicals, Inc.Inventors: Naomi Urakawa, Makoto Nakano, Yasuhiro Kitahara, Ryosuke Aburaki, Akihiro Matsuda
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Patent number: 8735500Abstract: A hydrocarbon polymer modifier (HPM) having high softening point and high aromaticity, is an interpolymer of (i) a piperylene component; (ii) an aromatic component; and (iii) a cyclic pentadiene component comprising a dicyclopentadiene fraction (DCPD fraction) and a dimethylcyclopentadiene fraction (MCPD fraction), wherein a weight ratio of the MCPD fraction to the DCPD fraction is from 0.8 to 20, and wherein the MCPD fraction is at least 20 wt % of the cyclic pentadiene component. In a method, the proportions of (i), (ii), (iii), and an optional amylene component are adjusted to control aromaticity, softening point and Mz of the HPM. An elastomeric composition incorporates the HPM.Type: GrantFiled: August 17, 2011Date of Patent: May 27, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Thomas R. Barbee, Edward J. Blok, Anthony J. Dias
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Patent number: 8735501Abstract: A composition contains a cycloolefin polymer and a cross-linked structure of a cross-linkable polymer having a specific structure.Type: GrantFiled: May 25, 2012Date of Patent: May 27, 2014Assignee: Canon Kabushiki KaishaInventors: Ryo Ogawa, Shintetsu Go, Seiji Okada
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Patent number: 8735502Abstract: This invention relates to a functionalized co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)?83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a functionalized homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making functionalized homo- or co-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.Type: GrantFiled: January 29, 2013Date of Patent: May 27, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Patrick Brant, Donna J. Crowther
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Patent number: 8735503Abstract: A composition for a semiconductive rubber, comprising an epichlorohydrin-based rubber (a), an ethylene oxide-modified (meth)acrylate (b), and at least one kind of a crosslinking agent (c) selected from the group consisting of a sulfur-based crosslinking agent, a quinoxaline-based crosslinking agent and a triazine-based crosslinking agent.Type: GrantFiled: October 14, 2010Date of Patent: May 27, 2014Assignee: Daiso Co., Ltd.Inventors: Kohji Ohnuki, Yoritaka Yasuda, Taro Ozaki
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Patent number: 8735504Abstract: Methods are provided for preparing polymer mixtures having low residual monomer content. The methods comprise mixing the at least two polymers in a solvent to form a polymeric mixture, the polymeric mixture comprising at least one residual monomer; and adding an antisolvent to the polymeric mixture so as to separate the at least two polymers from the polymeric mixture, where the residual monomer is soluble in the antisolvent. In some embodiments, methods are provided for preparing at least two polymers having low residual monomer content, the methods comprise adding an antisolvent to a mixture of at least two polymers dissolved in a solvent so as to precipitate the at least two polymers from the solvent and anti-solvent. The methods provided avoid steps in dry blending of polymers and produces polymer blends that have low residual monomer content.Type: GrantFiled: May 2, 2012Date of Patent: May 27, 2014Assignee: Warsaw Orthopedic, Inc.Inventor: Danielle L. Clay
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Patent number: 8735505Abstract: A composition comprising from 10 to 90 weight percent of a copolyetherester elastomer comprising: a modified, random polybutylene terephthalate copolymer block that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate, polyethylene terephthalate copolymers, and combinations thereof; and that contains at least one residue derived from the polyethylene terephthalate component; and a polyalkylene oxide copolymer block that is derived from the polyethylene terephthalate component and a polyalkylene oxide glycol, and that contains polyalkylene oxide and at least one residue derived from the polyethylene terephthalate component; from 10 to 90 weight percent of a polycarbonate; and from 0 to 60 weight percent of a polyester.Type: GrantFiled: September 14, 2012Date of Patent: May 27, 2014Assignee: SABIC Innovative Plastics IP B.V.Inventors: Peter H. Vollenberg, Dhaval Shah, Kenneth F. Miller
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Patent number: 8735506Abstract: A process for making UV curable pressure sensitive adhesive compositions by derivatizing an acrylic polymer with a derivatizing agent prepared from a hydroxy-functional acrylate monomer and a diisocyanate. The derivatizing agent typically has a ratio of hydroxy-functional acrylate monomer to diisocyanate greater than about 1:1. Also disclosed are UV curable pressure sensitive adhesives made with the derivatizing agent and methods for adhering substrates with pressure sensitive adhesive compositions.Type: GrantFiled: March 31, 2010Date of Patent: May 27, 2014Assignee: Ashland Licensing and Intellectual Property LLCInventors: Terry E. Hammond, Xiaochuan Hu
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Patent number: 8735507Abstract: The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.Type: GrantFiled: December 27, 2012Date of Patent: May 27, 2014Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Eric Greyson, John N. Argyropoulos, Paul Foley, Andrew Swartz, Nahrain E. Kamber, Caroline Slone, Manesh N. Sekharan
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Patent number: 8735508Abstract: Storage stable polyorganosiloxane-silicone resin mixtures contain: 1) 100 parts by weight of one or more liquid aminoalkyl-containing polyorganosiloxanes containing at least 80 mol % of units selected from units of the formulae Ia, Ib, II and III R12SiO(4-a-b)/2??(Ia), R1aR2bSiO(4-a-b)/2??(Ib), R33SiO(1/2)??(II), R32R4SiO(1/2)??(III), wherein, in the polydimethylsiloxanes, the average ratio of the sum of units of the formulae Ia and Ib to the sum of units of the formulae II and III is in the range from 0.5 to 500, the average ratio of units II to III in the range of 1.86 to 100, and the polydimethylsiloxanes have an average amine number of ?0.01 mequiv/g, 2) at least 1 part by weight of one or more silicone resins, and 3) at most 5 parts by weight of water.Type: GrantFiled: September 12, 2011Date of Patent: May 27, 2014Assignee: Wacker Chemie AGInventors: Markus Merget, Richard Becker, Franz Wimmer
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Patent number: 8735509Abstract: The invention relates to the use of polyorganosiloxanes having 3 or more siloxane units, which have one or more organic fractions R1, where R1 has one or more carbon-carbon multiple bonds and at least 4 carbon atoms, and wherein the presence of hydrocarbon fractions having a chain length of 5 to 50 carbon atoms is excluded, as additives in the processing of rubber. The polyorganosiloxanes are used in the processing and vulcanization of rubber in a quantity of 0.1 to 10 phr and incorporated by reaction in same. Said polyorganosiloxanes produce a reduction in the viscosity of the rubber during processing and optionally an improvement in the mechanical properties of the vulcanized rubber.Type: GrantFiled: February 3, 2011Date of Patent: May 27, 2014Assignee: Schill + Seilacher “Struktol” GmbHInventors: Volker Borger, Uwe Dittrich, Theresia Klose
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Patent number: 8735510Abstract: A polymer composition comprising: at least one polycondensation polymer having a heat deflection temperature (HDT) of above 80° C. under a load of 1.82 MPa when measured according to ASTM D648 [polymer (P)]; at least one perfluoropolyether block copolymer [polymer (F)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rf) comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain Ra) comprising recurring units of formula: —(CR1R2—CR3R4)—; wherein R1, R2, R3, R4, equal to or different from each other, are selected from the group consisting of H, halogens; C1-C6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, to a process for its manufacture and to its use for manufacturing shaped articles, in particular by extrusion molding or injection molding techniques.Type: GrantFiled: February 22, 2010Date of Patent: May 27, 2014Assignee: Solvay SAInventors: Theodore Moore, Mark G. Reichmann, Marco Avataneo, Giuseppe Marchionni
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Patent number: 8735511Abstract: A curing resin composition that cures in two stages: photo cure and thermal cure, hardly contaminates a liquid or liquid crystals when in contact with, and provides high adhesive strength, particularly a curing composition that photocures sufficiently even when shadowed by TFT wires, a black matrix, etc. in photocuring; and a sealant, a sealant for ODF (one-drop-fill), and an LCD containing the curing resin composition.Type: GrantFiled: April 20, 2011Date of Patent: May 27, 2014Assignee: Adeka CorporationInventors: Hirokatsu Shinano, Hiroya Fukunaga, Kazuyuki Itano
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Patent number: 8735512Abstract: The present invention provides Mannich base derivatives of N,N?-dimethyl secondary diamine polymers including Mannich base derivatives of methylamine-terminated poly-(N-methylazetidine) and Mannich base derivatives of methylamine-terminated poly-(N-methylazacycloheptane). Amine curing agent compositions and amine-epoxy compositions containing Mannich base derivatives of N,N?-dimethyl secondary diamine polymers are also disclosed.Type: GrantFiled: April 9, 2008Date of Patent: May 27, 2014Assignee: Air Products and Chemicals, Inc.Inventors: Frederick Herbert Walker, Michael Ian Cook, Gamini Ananda Vedage, Robert Marjo Theodoor Rasing
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Patent number: 8735513Abstract: A propylene polymerization reaction apparatus and a production method of a propylene-based polymer are capable of producing a continuous multi-stage polymer in low cost, high productivity and stably, and significantly reducing generation amount of an off-specification product accompanying change of polymerization condition, in multi-stage continuous vapor phase polymerization method of a propylene-based polymer using a catalyst for olefin polymerization. A reaction apparatus for producing a propylene-based polymer by a multi-stage continuous vapor phase polymerization method is used. One or more reactor of a horizontal-type reactor having inside a stirring machine which rotates around a horizontal axis, and a continuous stirred tank reactor to be connected to the horizontal-type reactor are provided, and a production method of a propylene-based polymer using the same.Type: GrantFiled: November 5, 2010Date of Patent: May 27, 2014Assignee: Japan Polypropylene CorporationInventors: Takanori Nakashima, Katsuhiko Oono, Kenji Mitsutani, Takao Tayano, Tomoyuki Yoshida, Shigeo Mizukami, Yusuke Yamada
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Patent number: 8735514Abstract: A method for feeding an antistatic compound to a polymerization reactor, the method comprising the steps of: a) dispersing, under mixing conditions, a catalyst powder and an antistatic compound in a liquid medium, so as to form a suspension of the catalyst powder and of the antistatic compound in the liquid medium; b) transferring the obtained suspension to a polymerization reactor.Type: GrantFiled: September 29, 2011Date of Patent: May 27, 2014Assignee: Basell Polyolefine GmbHInventors: Pietro Baita, Paolo Ferrari, Ines Mingozzi, Lorella Pedriali, Maria Di Diego, Roberta Pica
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Patent number: 8735515Abstract: A process is disclosed for producing plastic materials by providing a biology based feedstock and reacting the biology based feedstock to form a feedstock capable of reaction to form the plastic material, wherein the plastic material is selected from polystyrene and polyethylene terephthalate (PET).Type: GrantFiled: July 27, 2011Date of Patent: May 27, 2014Assignee: Fina Technology, Inc.Inventors: Scott Cooper, Olga Khabashesku
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Patent number: 8735516Abstract: Aqueous solutions of acrylic acid polymers are prepared by polymerization of acrylic acid in a feed operation with a free-radical initiator in the presence of hypophosphite in water as solvent, by a process comprising (i) initially charging water and optionally one or more ethylenically unsaturated comonomers, (ii) continuously adding acrylic acid in acidic, unneutralized form, optionally one or more ethylenically unsaturated comonomers, aqueous free-radical initiator solution and aqueous hypophosphite solution, and (iii) adding a base to the aqueous solution on completion of the acrylic acid feed, wherein a comonomer content does not exceed 30% by weight and the aqueous hypophosphite solution is added during a total feed time made up of three consecutive feed time spans ?tI, ?tII, and ?tIII, wherein the average feed rate in the second feed time span ?tII is greater than the average feed rates in the first and third feed time spans ?tI and ?tIII.Type: GrantFiled: February 2, 2012Date of Patent: May 27, 2014Assignee: BASF SEInventors: Howard Roger Dungworth, David Petty, Bolette Urtel, Ruth Wirschem
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Patent number: 8735517Abstract: Provided is a stirred tank polymerization reactor system having a reactor tank, a stirring assembly including a rotatable shaft that extends through a wall of the tank, and a triple barrier mechanical seal. The mechanical seal includes an outer cylinder mounted in the wall of the tank, an inner cylinder that is rotatable relative to the outer cylinder and connected to the shaft, and first, second, and third fluid barrier seals mounted between the outer and inner cylinders at different positions along the axis of rotation of the inner cylinder. First and second sources of pressurized barrier fluid are connected between the first and second pressure fluid barrier seals and the second and third barrier seals, respectively. The three barrier seals advantageously “step down” the differential pressure experienced by the uppermost barrier seals, substantially reducing mechanical stresses experienced by the annular sealing rings and seats.Type: GrantFiled: June 2, 2011Date of Patent: May 27, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Christopher K. Morgan, Shiraz A. H. Pradhan, Michael W. Ackman
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Patent number: 8735518Abstract: Aqueous dispersions of polymers which obtained by free radical suspension polymerization or free radical miniemulsion polymerization of ethylenically unsaturated monomers in an oil-in-water emulsion whose disperse phase comprises at least one fluorescent dye dissolved in at least one ethylenically unsaturated monomer and has an average particle diameter of at least 1?m, in the presence of at least one surface-active compound and at least 0.5% by weight, based on the monomers, of at least one hydrophobic, nonpolymerizable, organic compound, of a hydrophobic polymer of at least one C2- to C6-olefin having a molar mass Mw of up to 10000, of a siloxane having a molar mass Mw of up to 5000 and/or polystyrene having a molar mass Mw of up to 10000, and of the powders obtainable from these polymer dispersions in each case by drying and comprising at least one fluorescent dye for marking of materials.Type: GrantFiled: December 11, 2006Date of Patent: May 27, 2014Assignee: BASF AktiengesellschaftInventors: Sven Holger Behrens, Simon Champ, Ulrike Geissler, Hans-Peter Hentze, Marc Rudolf Jung, Hans-Peter Kaub, Simon Nord
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Patent number: 8735519Abstract: The invention is directed to a metallocene catalyst system and a process for preparing the system. The metallocene catalyst system comprises a support and metallocene bound substantially throughout the support. The selection of certain supports facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized.Type: GrantFiled: April 9, 2013Date of Patent: May 27, 2014Assignee: Fina Technology, Inc.Inventors: Jun Tian, William Gauthier, David Rauscher, Shady Henry
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Patent number: 8735520Abstract: A process for producing vinyl fluoride polymer comprising polymerizing vinyl fluoride in an aqueous polymerization medium containing initiator and halogen-free surfactant with a critical micelle concentration of less than about 0.05 weight percent at 25° C. The halogen-free surfactant is present in the aqueous polymerization medium in an amount less than about 0.1 weight percent based on the weight of the aqueous polymerization medium. The aqueous polymerization medium is essentially free of halogen-containing surfactant. An aqueous dispersion comprising vinyl fluoride polymer particles present in a range of from about 5 to about 40 weight percent based on the weight of the aqueous phase, wherein said vinyl fluoride polymer particles have a Dv(50) of less than about 20 microns, and halogen-free surfactant, wherein said halogen-free surfactant is present in said aqueous dispersion in an amount less than 0.1 weight percent based on the weight of the aqueous phase.Type: GrantFiled: October 19, 2011Date of Patent: May 27, 2014Assignee: E.I. du Pont de Nemours and CompanyInventor: Ronald Earl Uschold
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Patent number: 8735521Abstract: A cycloolefin-based copolymer and a hydrogenation process are disclosed, wherein the cycloolefin-based copolymer is prepared by using: a monomer which can be easily and economically obtained by hydrogenating dicyclopentadiene that occupies much of C5 fractions from naphtha cracking; or a monomer which can be obtained by chemically bonding three molecules of cyclopentadiene via Diels-Alder reactions and then hydrogenating the cyclopentadiene. The copolymer can be used in various fields as an amorphous transparent resin.Type: GrantFiled: February 11, 2009Date of Patent: May 27, 2014Assignee: Kolon Industries, Inc.Inventors: Ik Kyung Sung, Woon Sung Hwang, Jung Hoon Seo, Bun Yeoul Lee, Sung Jae Na, Seung Taek Yu
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Patent number: 8735522Abstract: The present invention provides a Scandium catalyst that can be used in water or water-soluble organic solvent with no leaching of Scandium. Provided is a gold-polymer nanostructure-immobilized Scandium catalyst, which is formed by preparing, in liquid phase, a mixture comprising gold clusters with from 1 to 50 nm of diameter, disulfide monomer, sulfonic acid salt of disulfide and Lewis acid metal compound represented by ScY3, wherein Y is OSO2CF3 etc., and polymerizing the mixture in the presence of a radical polymerization initiator, wherein the disulfide monomer is represented by the formula below: CH2?CH—R1—S—S—R1—CH?CH2 wherein R1 represents a divalent hydrocarbon, which may contain an ether bond, and the sulfonic acid salt of disulfide is represented by the formula below: MO3S—R2—S—S—R2—SO3M wherein R2 represents a divalent hydrocarbon, which may contain an ether bond, and M represents an alkali metal.Type: GrantFiled: February 16, 2011Date of Patent: May 27, 2014Assignee: Japan Science and Technology AgencyInventors: Shu Kobayashi, Hiroyuki Miyamura
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Patent number: 8735523Abstract: One embodiment of the present invention provides polymer crystalline materials containing crystals of the polymer and satisfying the following requirements (I) and (II) or the following requirements (I) and (III): (I) the polymer crystalline materials a crystallinity of 70% or greater; (II) the crystals are 300 nm or less in size; and (III) the crystals have a number density of 40 ?m?3 or greater. This allows an embodiment of the present invention to provide polymer crystalline materials which are excellent in properties such as mechanical strength, heat tolerance, and transparency or, in particular, polymer crystalline materials, based on a general-purpose plastic such as PP, which is excellent in properties such as mechanical strength, heat tolerance, and transparency.Type: GrantFiled: February 27, 2008Date of Patent: May 27, 2014Assignee: Hiroshima UniversityInventors: Masamichi Hikosaka, Kaori Watanabe, Kiyoka Okada
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Patent number: 8735524Abstract: Hydrogen, methyl, acetyl or butyl capped Polyether modified Silicone (PES) containing compositions are disclosed. The PES containing compositions can be used as defoamers or deaerators in coating compositions and, in particular, for airless sprayed compositions.Type: GrantFiled: March 5, 2012Date of Patent: May 27, 2014Assignee: Air Products and Chemicals, Inc.Inventors: Kuo-Tsai Griffin Lai, Christine Anne Suzanne Louis, Suresh Kalpatu Rajaraman
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Patent number: 8735525Abstract: The present invention relates to a curable composition. A curable composition may be provided; which shows excellent processability and workability; which shows excellent light extraction efficiency, crack resistance, hardness, thermal shock resistance and adhesive strength after curing; and which has excellent reliability and long-term reliability under high-temperature and/or high-moisture conditions. Also, turbidity and surface stickiness may be prevented in the cured product.Type: GrantFiled: July 20, 2012Date of Patent: May 27, 2014Assignee: LG Chem, LtdInventors: Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Bum Gyu Choi, Dae Ho Kang, Min Kyoung Kim
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Patent number: 8735526Abstract: A method of making a polymer by providing an imine and reacting the imine with a polyisocyanate in the presence of a hydroxyl group. The imine is a polyaldimine, hydroxyaldimine, polyketimine, or hydroxyketimines. The polymer has urea linkages formed from the imine and polyisocyanate and urethane linkages formed from the hydroxyl group and the polyisocyanate. The polymer has at least as many urea linkages as urethane linkages. A polymer having urea units and urethane units having a molar ratio of at least about 2:1. A polymer comprising a urea-urethane repeat unit.Type: GrantFiled: September 15, 2005Date of Patent: May 27, 2014Assignee: The United States of America, as represented by the Secretary of the NavyInventors: Jozef Verborgt, Arthur Webb
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Patent number: 8735527Abstract: [Solution to Problem] The laminating adhesive of the present invention includes a polyisocyanate component (A) and a polyol component (B), wherein the polyisocyanate component (A) contains a polyisocyanate (A1) that does not contain an aromatic ring, and the polyol component (B) contains a macropolyol (B1) that does not contain an aromatic ring but contains a cyclohexane ring.Type: GrantFiled: March 26, 2012Date of Patent: May 27, 2014Assignee: Mitsui Chemicals, Inc.Inventors: Akihiro Imai, Takeshi Osaki, Shigetoshi Sasano
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Patent number: 8735528Abstract: Two-photon absorbing (2PA), cross-linked polyurethanes were prepared from bis(isocyanato) monomers, tris(isocyanato) monomers or a mixture thereof, in conjunction with novel polyol molecules with donor-acceptor octupolar geometry, whose generic structure is comprised of an electron-accepting 1,3,5-triazine hub with three spokes constituted by electron-donating triarylalkylamine end-groups, which are polyfunctionalized with thermally reactive alcohol functions. The resulting neat glassy or rubbery solids are applicable in a wide range of linear and nonlinear optical applications.Type: GrantFiled: October 1, 2012Date of Patent: May 27, 2014Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Loon-Seng Tan, Matthew J Dalton, Ramamurthi Kannan
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Patent number: 8735529Abstract: A curing catalyst (clathrate compound) for which the curing reaction is suppressed at low temperatures, allowing an improvement in the one-pot stability, but which can effectively cure a resin upon heat treatment. The clathrate compound includes at least an isophthalic acid compound represented by Formula (I), where R1 represents a C1 to C6 alkyl group, a C1 to C6 alkoxy group, a nitro group, or a hydroxyl group, and an imidazole compound represented by a Formula (II) where R2 represents a hydrogen atom, a C1 to C10 alkyl group, a phenyl group, a benzyl group, or a cyanoethyl group, and R3 to R5 each independently represents a hydrogen atom, a nitro group, or a halogen atom, or a C1 to C20 alkyl group, phenyl group, benzyl group, or C1 to C20 acyl group that may have a substituent.Type: GrantFiled: December 20, 2011Date of Patent: May 27, 2014Assignee: Nippon Soda Co., Ltd.Inventors: Masami Kaneko, Natsuki Amanokura
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Patent number: 8735530Abstract: A method for making polyamide is described. More particularly, a method for making a polyamide from at least one diacid and one diamine, that includes a step of concentrating an aqueous solution of diacid and diamine salt up to a salt weight concentration higher than 85%, and a polymerization step up to a desired polymerization degree is described.Type: GrantFiled: March 9, 2010Date of Patent: May 27, 2014Assignee: Rhodia OperationsInventors: Virginie Thieblemont, Jean-Francois Thierry
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Patent number: 8735531Abstract: A diol from which a resin material having high processability and a high refractive index can be manufactured, a polycarbonate resin and a polyester resin which is a polymer of the diol, and a molded article and an optical element formed of the polymer. The diol is represented by the general formula (1) shown below; the polycarbonate resin and the polyester resin are polymers thereof; and the molded article and the optical element are formed of the polymers, wherein R1 and R2 each independently denote one of a hydrogen atom and an alkyl group having 1 or more and 6 or less carbon atoms; Q denotes one of an oxyethylene group, a thioethylene group and a single bond.Type: GrantFiled: March 13, 2013Date of Patent: May 27, 2014Assignee: Canon Kabushiki KaishaInventors: Katsumoto Hosokawa, Takahiro Kojima, Toshikazu Takata, Kazuko Nakazono, Yasuhiro Kohsaka, Yasuhito Koyama, Toshihide Hasegawa, Ryota Seto
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Patent number: 8735532Abstract: A method of: providing a solution of a dichloroaromatic compound having an electron-withdrawing group bound to each aromatic ring containing one of the chloride groups; an excess of a dihydroxyaromatic compound; an organic transition metal complex or a transition metal salt; a base; and a solvent; and heating the solution to a temperature at which the dichloroaromatic compound and the dihydroxyaromatic compound react to form an aromatic ether oligomer that is a dihydroxy-terminated compound or a dimetallic salt thereof. Water formed during the heating is concurrently distilled from the solution. A method of curing a phthalonitrile monomer in the presence of an acid and a curing agent to form a phthalonitrile thermoset.Type: GrantFiled: March 15, 2013Date of Patent: May 27, 2014Assignee: The United States of America, as represented by the Secretary of the NavyInventors: Teddy M Keller, Matthew Laskoski, Andrew Saab