Abstract: A process is provided for polymerizing fluoromonomer in an aqueous medium, wherein a dispersion of essentially surfactant-free hydrocarbon-containing oleophilic nucleation sites is first formed in the aqueous medium, and then polymerization is commenced to form a dispersion of fluoropolymer particles at the oleophilic nucleation sites, wherein the nucleation sites can be derived from hydrocarbon-containing compound. The surfactant used to stabilize the fluoropolymer dispersion can also be hydrocarbon-containing.

Abstract: Embodiments of the invention provide an apparatus for the manufacture of polyethylene and polyethylene copolymers. The apparatus includes a primary compressor in fluid communication with a two-stage secondary compressor, the secondary compressor in fluid communication with a heated conduit in fluid communication with a tubular reactor, the tubular reactor including one or more reaction zones having a heating/cooling jacket, said reactor tube including an inner material and an outer material, said outer material being substantially inert in the presence of water under operating conditions, the tubular reactor in fluid communication with a product separator, and at least one conduit for the transfer of recycled ethylene from the product separator to the secondary compressor. Processes for manufacturing polyethylene and polyethylene copolymers using such an apparatus are also described.

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes use a catalyst system containing three metallocene components, often resulting in polymers having a reverse comonomer distribution and a broad and non-bimodal molecular weight distribution.

Abstract: The invention relates to a polymer derived from: reaction of glycidyl (meth)acrylate, allyl glycidyl ether or [(vinyloxy)methyl]oxirane with ammonia or primary amine to obtain a mixture of monomer compounds; reaction of the mixture of monomer compounds with at least one of acrylic acid, vinyl alcohol, vinyl acetate, acrylamide, methylacrylic acid, and methylacrylamide to obtain an intermediate polymer; and reaction of the intermediate polymer with a dithiocarbamic acid salt. Methods for using the polymer are also described herein.

Abstract: A process for preparing a curing composition of a coordination complex comprising methylenedianiline (MDA) and a salt, and less than 1000 of free MDA. The curing composition may be used in curing polyurethanes and epoxy resins.

Abstract: Polyurethane systems that cure similarly to systems based on mercury catalysts contain 1,4-butanediol and a zinc carboxylate catalyst. These systems cure and develop green strength similarly to systems based on mercury catalysts. These systems are especially useful in making insulated pipe joints for subsea pipeline installations.

Abstract: The invention relates to a composition for producing abrasion-resistant and alkali-resistant layers or molded bodies having a low-energy surface, said composition comprising a) a hardenable binder system containing at least one organic polymer or oligomer comprising at least one functional group, or a precursor thereof, b) at least one fluorine-containing polymer or oligomer containing at least one functional group that can react with a functional group of the binder system, and c) inorganic particles, and to the products thus obtained. The coatings and molded bodies obtained are especially suitable for surfaces to be kept clean.

Abstract: A process for imparting grease, oil and water repellence to a substrate comprises applying by means of a printing process on at least a portion of the surface of such substrate a composition comprising at least one (per)fluoropolyether derivative. By means of such process it is possible to confer suitable grease, oil and water repellence properties to substrates via selective treatment/coating, by significantly reducing total amount of fluoro-containing additive required for the target properties.

Abstract: A Pentamethylene diisocyanate is obtained by phosgenating pentamethylenediamine or its salt obtained by a biochemical method, and contains 5 to 400 ppm of a compound represented by the general formula (1) below and a compound represented by the general formula (2) below in total:

Abstract: An epoxy resin adduct including the reaction product of (A) at least one polyfunctional aliphatic or cycloaliphatic epoxy resin; and (B) at least one reactive compound; wherein the polyfunctional aliphatic or cycloaliphatic epoxy resin is isolated from the epoxy resin formed by the epoxidation of (i) an aliphatic or cycloaliphatic hydroxyl-containing material using (ii) an epi-halohydrin, (iii) a basic-acting substance, (iv) a non-Lewis acid catalyst, and (v) optionally one or more solvents; and wherein the re-active compound (B) comprises one or more compounds having two or more reactive hydrogen atoms per molecule and the reactive hydrogen atoms are reactive with epoxide groups. A curable epoxy resin composition includes the adduct described above. A cured epoxy resin is prepared by a process of curing the curable epoxy resin composition containing the adduct described above.

Abstract: An epoxy resin hardener composition including a reaction product of (i) a compound having at least one vicinal epoxy group, and (ii) an amino alcohol; an epoxy resin composition including the epoxy resin hardener composition and a compound having at least one vicinal epoxy group; and a powder coating composition including particles of the epoxy resin hardener composition and particles of a compound having at least one vicinal epoxy group.

Abstract: An epoxy terminated prepolymer formed as a reaction product of a cycloaliphatic epoxide resin and an amine terminated polymeric polyol, and a catalyst that promotes the reaction of the cycloaliphatic epoxide resin and the aminated polyol. The epoxy terminated prepolymer and an anhydride hardener react to form an epoxy elastomer composition having a microphase separated morphology of hard particles, formed with the anhydride hardener reacted with the epoxy terminated prepolymer, dispersed in a soft continuous phase formed from polymeric polyol in the epoxy terminated prepolymer.

Abstract: A curable composition including (a) at least one divinylarene dioxide; (b) at least one phenol, wherein the phenol is unsubstituted at a 2-, 4-, or 6-phenolic ring position; and (c) at least one acid compound-related cure catalyst; and a cured product made from the above curable composition.

Abstract: A process for copolymerizing selectively i) ethylene carbonate with ii) one or more cyclic esters can include contacting the ethylene carbonate with the one or more cyclic esters in the presence of a catalyst. The catalyst can be a Zn-complex with a diaminophenolate ligand (NNO) or a ?-diiminate ligand (BDI).

Abstract: Provided are a polycarbonate-polyorganosiloxane copolymer having a carbon tetrachloride concentration of less than 4 ppm by mass, and the following production method for producing the polycarbonate-polyorganosiloxane copolymer.

Abstract: There is provided a method for preparing a low-molecular weight poly(alkylene carbonate) of which the molecular weight and chain shape are precisely controlled, by introducing a phosphorous compound having a hydroxyl group as a chain transfer agent in order to regulate the molecular weight, in alternating copolymerizing an epoxide compound and carbon dioxide by using trivalent metal complex prepared from a Salen type ligand containing a quaternary ammonium salt, and a polymer prepared by the method. Since poly(alkylene carbonate) prepared according to the present invention includes a phosphate or phosphonate group in the polymer chain, it has flame-retarding property.

Abstract: A crystalline polyamide ester resin is prepared by copolymerizing (A) a dicarboxylic acid component, (B) a diamine component, and (C) a cyclic aliphatic diol component, and has a structure in which a dicarboxylic acid moiety derived from the dicarboxylic acid component (A), a diamine moiety derived from the diamine component (B) and a cyclic aliphatic diol moiety derived from the cyclic aliphatic diol component (C) are repeated. A molar ratio ((B):(C)) of the diamine component (B) to the cyclic aliphatic diol component (C) is about 80 to about 99:about 1 to about 20. The crystalline polyamide ester resin has a melting point (Tm) ranging from about 280° C. to about 320° C. and a crystallization temperature (Tc) ranging from about 260° C. to about 290° C. The crystalline polyamide ester resin can have excellent heat resistance, discoloration resistance and moldability.

Abstract: A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.

Abstract: The present disclosure generally provides methods and apparatus for efficiently crosslinking silicon carbide fiber precursor polymers with electron beam radiation. The methods and apparatus utilize a platform containing silicon carbide fiber precursor polymer. The temperature of the platform is regulated while the silicon carbide fiber precursor polymer is irradiated to thereby regulate the temperature of the irradiated silicon carbide fiber precursor polymer thereon. In this way, the temperature of the irradiated silicon carbide fiber precursor polymer is regulated via the platform both during and after it is subjected to radiation. At least one of the platform and the e-beam radiation mechanism may be translated with respect to the other to irradiate different portions of the silicon carbide fiber precursor polymer and, ultimately, the entirety of the silicon carbide fiber precursor polymer contained on the platform.

Abstract: The invention relates to a copolymer comprising a main hydrocarbon chain and side groups including carboxylic groups, polyoxyalkylate groups, and gem acetophosphonate groups, an adjuvant for suspensions of mineral particles comprising said copolymer and a method for preparing said copolymer. Finally it also relates to the use of said copolymer for fluidifying and maintaining fluidity of suspensions of mineral particles and for reducing the sensitivity of hydraulic binders to clays and alkali metal sulfates. Finally it relates to a composition of mineral particles comprising this copolymer.

Abstract: The invention pertains to filler modified with functional particles in a dry-blending process through collisions of sufficient energy to bound, adhere, or otherwise associate the pigment particles to the filler, and a filled polymeric material manufactured with the modified filler.

Abstract: Disclosed herein is a composition comprising a crosslinked organic polymer; wherein the composition has a coefficient of friction that is in a range of ±30% of a coefficient of friction for a composition comprising the same organic polymer that is not crosslinked; and wherein the composition has a lower K factor than a K factor of the composition comprising the same organic polymer that is not crosslinked; the coefficient of friction and the K factor being measured in a thrust washer apparatus as per ASTM D-3702, where the counter stationary surface in the thrust washer apparatus comprises carbon steel having a Rockwell C hardness of 18 to 22 and a 12 to 16 micro-inch surface finish.

Abstract: A pattern is formed by forming a first pattern on a first film, forming a block copolymer layer including a first block chain and a second block chain on the first pattern, forming a second pattern, forming a second film on the second pattern, selectively removing the second film until the second pattern is exposed, forming a third pattern, and processing the first film using the third pattern as a mask. The second pattern is formed by microphase-separating the block copolymer layer, and removing the first block chain or the second block chain. The second film is formed by applying a material having an etch rate that is less than an etch rate of a material of the first pattern and the second pattern. The third pattern is formed by selectively removing the second pattern and the first pattern using the second film as a mask.

Abstract: Method for preparing a substrate comprising an anti-adhesive silicone coating obtained from an anti-adhesive silicone composition based on crosslinked silicone oil(s) with adhesion properties that are modified compared with the initial properties thereof, in which provision is made for a substrate at least partly coated with an anti-adhesive silicone coating and the anti-adhesive silicone coating is cold-plasma-treated, approximately at atmospheric pressure, in an optionally doped nitrogen atmosphere or in an optionally doped carbon dioxide atmosphere, substrate at least partially coated with an anti-adhesive silicone composition, silicone-self-adhesive complex and uses.

Abstract: A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.

Abstract: The present invention relates to a plasma polymerized thin film having high hardness and a low dielectric constant and a manufacturing method thereof, and in particular, relates to a plasma polymerized thin film having high hardness and a low dielectric constant for use in semiconductor devices, which has improved mechanical strength properties such as hardness and elastic modulus while having a low dielectric constant, and a manufacturing method thereof.

Abstract: Poly(ether sulfones) (PES) and poly(ether amide sulfones) (PEAS) were prepared from post-consumer polycarbonates and polyesters, respectively, using a single vessel in batch mode (all reactants present when heating was initiated). The depolymerization of the initial polymer occurs concurrently with step growth polymerization to form a product polymer having a number average molecular weight of at least 5000.

Abstract: The invention relates to the use of nanocarbon (carbon nano tubes and/or carbon nano fibers) in the preparation of reinforced natural rubber. It is an object of the invention to provide a simple way to disperse nanocarbon in rubber so as to obtain good physical and mechanical properties, such as hardness, modulus and/or tensile strength. In order to achieve these objects, the invention provides a natural rubber composition comprising 5 parts per hundred of rubber (pphr) or less of nanocarbon, wherein the nanocarbon has not been subjected to an acid treatment before incorporation into the rubber composition.

Abstract: An additive for a marble adhesive is disclosed. The additive is selected from the group consisting of R—(C6H4)—CH2OH, R—O—(CH2)2—O—(CH2)2—OH, R—O—CH2—CH(OH)—CH3, R—O—(CH2)2—OH, and a mixture thereof, where R represents hydrogen or alkyl.

Abstract: Elastomeric compounds having increased cold flow resistance may be obtained by utilizing from 10-100 phr of a functionalized rubbery polymer containing specified types of functionalizing units, at least 0.01 phr of a multivalent metal organic salt and 0-90 phr of at least one additional rubbery polymer.

Abstract: The invention provides a composition comprising: (a) about 0% to 99% by weight of at least one resin wherein the resin is selected from the group consisting of epoxy, latex, polyurethane, polyurea, polyspartic, or alkyd resins; (b) about 1%-99% by weight of tristyrenated phenol or distyrenated phenol; and (c) optionally about 2% to 98% by weight of an additional solvent.

Abstract: The present invention provides a resin composition for golf balls that is excellent in resilience, flexibility, and fluidity. The present invention also provides a golf ball excellent in resilience, shot feeling, and productivity. The present invention includes a resin composition for golf balls including: (A) at least one selected from the group consisting of (a-1) a bipolymer of an olefin and a C3-C8 ?,?-unsaturated carboxylic acid, (a-2) a metal ion-neutralized product of a bipolymer of an olefin and a C3-C8 ?,?-unsaturated carboxylic acid, (a-3) a terpolymer of an olefin, a C3-C8 ?,?-unsaturated carboxylic acid, and an ?,?-unsaturated carboxylic acid ester, and (a-4) a metal ion-neutralized product of a terpolymer of an olefin, a C3-C8 ?,?-unsaturated carboxylic acid, and an ?,?-unsaturated carboxylic acid ester; (B) a compound containing an unsaturated hydrocarbon chain, a cationic moiety, and an anionic moiety in its molecule; and (C) an unsaturated fatty acid.

Abstract: A sheet containing a base layer containing polycarbonate and a flame retardant, wherein the flame retardant contains a compound of formula 1 wherein R1, R2, R3 and R4, represents an optionally halogen-substituted C1-C8 alkyl, C5-C6 cycloalkyl, C6-C10 aryl or C7-C12 aralkyl, R5 and R6, represents a C1-C4 alkyl, and Y represents a C1-C7 alkylidene, C1-C7 alkylene, C5-C12 cycloalkylidene, —O—, —S—, —SO—, —SO2—, —CO— or a residue of formula (2) or (3) wherein Z represents carbon and R21 and R22 can be selected for each Z individually and, represent hydrogen or C1-C6 alkyl, with the proviso that, on at least one Z atom, R21 and R22 are simultaneously alkyl and wherein the polycarbonate comprises a mixture of linear and branched polycarbonate and wherein the linear polycarbonate content is at least 40 wt. %, based on the total polycarbonate weight.

Abstract: Disclosed herein is a method of preparing a high-melting point flame retardant crystal, comprising the steps of: reacting 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide with 1,4-naphthoquinone in an inert solvent having a dielectric constant of 10 or less to reduce a content of by-products, thereby obtaining a reaction composition; and dissolving the reaction composition in any one solvent selected from the group consisting of ethyleneglycol, propyleneglycol, diethyleneglycol, cyclohexanone, benzyl alcohol, acetate ester, benzoate ester and a mixture thereof to recrystallize and refine the reaction composition, thereby obtaining high-melting point retardant crystal, represented by Formula 1, having a start melting point of 280° C. or more and a melting point of 291° C. or more, which are measured by differential thermogravimetric analysis.

Abstract: A composition for protecting a surface of an organic substrate, such as VCT, wood, or a synthetic laminate material, includes a silicate (e.g., an alkali metal polysilicate or colloidal silica) and a siliconate (e.g., a metal siliconate, such as an alkali metal methyl siliconate, etc.). In addition, the composition may include acrylic latex, a silane coupling agent, and a solvent, such as ethylene glycol monobutyl ether. Such a composition may also include a leveling agent, such as a surfactant. Organic substrates, such as VCT, wood, and synthetic laminate materials, with such a composition on their surfaces are also disclosed.

Abstract: The invention relates to a method for producing polyamide 6 wherein the polymerization of ?-caprolactam is performed in the presence of an inorganic material having an open pore structure. The polyamide 6 thus obtained has extremely high impact toughness and is simultaneously elastic.

Abstract: The instant invention provides a polyethylene blend-composition suitable for blown films, and films made therefrom. The polyethylene blend-composition suitable for blown films according to the present invention comprises the melt blending product of: (a) from 0.5 to 6 percent by weight of a bimodal linear low density polyethylene having a density in the range of from 0.935 to 0.970 g/cm3, and a melt index (I2) in the range of from 0.3 to 5 g/10 minutes; (b) 90 percent or greater by weight of a monomodal linear low density polyethylene having a density in the range of from 0.910 to 0.950 g/cm3, and a melt index (I2) in the range of from 0.1 to less than or equal to 5 g/10 minutes; (c) optionally from 0.5 to 4 percent by weight of a low density polyethylene having a density in the range of from 0.915 to 0.935 g/cm3, and a melt index (I2) in the range of from greater than 0.

Abstract: A dual reactor solution process gives high density polyethylene compositions containing a first ethylene copolymer and a second ethylene copolymer and which have good processability, stiffness, and environmental stress crack resistance. The polyethylene compositions are suitable for compression molding or injection molding applications and are particularly useful in the manufacture of caps and closures for bottles.

Abstract: A continuous process for the production of a dynamically vulcanized thermoplastic elastomer comprising a thermoplastic resin and a non-halogenated elastomer with a multiolefin content of greater than 3.5 mol % that has been modified in situ with a carboxylic anhydride. The process provides materials with improved elongation at break and ultimate tensile strength that can be produced economically and with reduced environmental impact.

Abstract: A hardmask composition and a method of forming patterns, the composition including a solvent; and a polymer including a moiety represented by the following Chemical Formula 1,

Abstract: This invention aims at improving the tear strength of a film and a sheet molded from a resin composition containing microorganism-produced aliphatic polyester. This invention relates to a biodegradable polyester resin composition containing polybutylene adipate terephthalate (PBAT) in the proportion of 60 to 400 parts by weight and modified-glycerin in the proportion of 10 to 50 parts by weight based on 100 parts by weight of aliphatic polyester (P3HA) having a repeating unit represented by Formula (1): [—CHR—CH2—CO—O—] (wherein R is an alkyl group represented by CnH2n+1 and n is an integer of 1 or more and 15 or lower) and a film or a sheet obtained by molding the biodegradable polyester resin composition in which the maximum major axis of phases containing the aliphatic polyester (P3HA) measured by a transmission electron microscopy analysis-image analysis method (TEM method) is 18 ?m or lower and the average value is 8 ?m or lower.

Abstract: A monovinylaromatic polymer composition can include a bio-sourced polymer dispersed phase and optionally a rubber dispersed phase. The bio-sourced polymer dispersed phase can be predominantly made of particles having a size of less than 10 ?m. The monovinylaromatic polymer composition can be made by admixing a monovinylaromatic monomer, bio-sourced polymer, and optionally rubber at conditions effective to polymerize at least a part of the monovinylaromatic monomer and generate a compatibilizer. The monovinylaromatic polymer composition can be made by admixing a monovinylaromatic monomer, functionalized bio-sourced polymer(s) or mixtures of bio-sourced polymer(s) and functionalized bio-sourced polymer(s), and optionally rubber at conditions effective to polymerize at least a part of the monovinylaromatic monomer.

Abstract: The disclosure provides a curable silicone resin composition, including 10 to 50 parts by weight of linear polysiloxane (A); 10 to 40 parts by weight of a first silicone resin (B1); 10 to 40 parts by weight of a second silicone resin (B2); and 15 to 25 parts by weight of a Si—H containing polysiloxane (C) having a general formula given as HR42SiO(SiR32O)nSiR42H, and a platinum group metal catalyst (D). The weight ratio of linear (A)/(the first silicone resin (B1)+the second silicone resin (B2)) is in the range of 0.1 to 2.0. The weight ratio of the first silicone resin (B1)/the second silicone resin (B2) is in the range of 0.2 to 4.0.

Abstract: A fluorophore and methods of detecting cations and hydrophobic environments using the fluorophore are disclosed. The fluorophore includes an imidazo[1,5-a]pyridinium ion core and has the formula where R1, R2, R3 and X? are as defined in the specification, and n is an integer from 1 to 4.

Abstract: The invention relates to boron nitride agglomerates, comprising hexagonal boron nitride primary particles, wherein the hexagonal boron nitride primary particles are connected to one another by means of an inorganic binding phase comprising at least one nitride and/or oxynitride. The invention also relates to a method for producing such boron nitride agglomerates, wherein boron nitride starting powder in the form of boron nitride primary particles is mixed with binding-phase raw materials, processed into granules or molded bodies and these are then subjected to a temperature treatment at a temperature of at least 1000° C. in a nitriding atmosphere, and the obtained granules or molded bodies are comminuted and/or fractionated if necessary. The boron nitride agglomerates according to the invention are suitable as a filler for polymers to be used for producing polymer-boron nitride composite materials.

Abstract: A finished flake for a roofing material including a metal flake substrate having an emissivity value up to approximately 0.25 and a reflectivity value up to approximately 0.95. A first coating is provided having unpigmented sodium silicate disposed on the substrate, wherein the first coating increases the emissivity value of the substrate and decreases the reflectivity value of the substrate. A second coating is provided having sodium silicate loaded with reflective pigments non-uniformly disposed about the first coating, wherein the finished flake has an emissivity value in excess of approximately 0.75 and a reflectivity value ranging from approximately 0.4 to approximately 0.5.

Abstract: Disclosed are articles comprising layered nanocrystalline calcite and methods for forming nanocrystalline calcite layers and compositions comprising nanocrystalline calcite layers.

Abstract: An object of the present invention is to provide a method for producing a Group IV metal oxide film useful as a semiconductor element or an optical element at a low temperature. The present invention relates to a method for producing a Group IV metal oxide film, comprising coating a surface of a substrate with a film-forming material dissolved in an organic solvent, and subjecting the substrate to a heat treatment, an ultraviolet irradiation treatment, or both of these treatments, wherein a film-forming material obtained by reacting a vinylenediamide complex having a specific structure with an oxidizing agent such as oxygen gas, air, ozone, water and hydrogen peroxide is used as the film-forming material.

Abstract: The present invention provides a water-based coating system that can be used to form a durable, abrasion resistant, tough, protective coating on a wide range of substrates. The coating system advantageously has excellent adhesion properties and can be directly coated onto stainless steel surfaces without requiring an intervening primer layer. Primer layers or other types of coatings can be used in combination with the coating system of the present invention if desired, however. The coating system is particularly effective for protecting metal-containing substrates such as intermodal, refrigerated cargo containers. The resultant coatings are flexible and impact resistant. Being water-based, the coating compositions have lower VOC emissions and less residual odor than solvent-based compositions.

Abstract: Anticorrosive coating compositions comprise a binding polymer and an amorphous aluminum phosphate corrosion inhibiting pigment dispersed therein. The coating composition comprises 1 to 25 percent by weight aluminum phosphate. The binding polymer can include solvent-borne polymers, water-borne polymers, solventless polymers, and combinations thereof. The aluminum phosphate is made by combining an aluminum source with a phosphorous source to form an amorphous aluminum phosphate solid condensate. The coating composition is specially engineered to provide a controlled delivery of phosphate anions of 50 to 500 ppm, and has a total solubles content of less than 1500 ppm. The amorphous aluminum phosphate is preferably free of alkali metals and alkaline earth metals. The amorphous aluminum phosphate has an oil absorption of less than 50, and a surface area of less than about 20 m2/g, The coating composition has a water adsorption potential of up to 25% by weight water.