Patents Issued in October 25, 2016
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Patent number: 9475726Abstract: A process for manufacturing a one-way vision glass pane, the process including: a) depositing a layer of a compound comprising a mineral pigment over an area of the pane, the compound being free of glass frit; b) depositing a layer of an enamel compound including a glass frit and a mineral pigment of a different color to the pigment of a), by screen printing, in the shape of the one or more desired patterns; c) heating the coated pane to a temperature high enough to bake the enamel; and d) removing pigments that have not been fixed by the enamel, wherein the particles of the pigments and the particles of the glass frits are of similar size, and the thickness of the layer of the deposited enamel compound is larger than the thickness of the pigment layer deposited in a).Type: GrantFiled: June 15, 2012Date of Patent: October 25, 2016Assignee: SAINT-GOBAIN GLASS FRANCEInventors: Jean-Philippe Savary, André Beyrle, Kamel Chahboune
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Patent number: 9475727Abstract: A coated article includes a coating, such as a low emissivity (low-E) coating, supported by a substrate (e.g., glass substrate). The coating includes at least one dielectric layer including zinc oxide that is doped with another metal(s). The coating may also include one or more infrared (IR) reflecting layer(s) of or including material such as silver or the like, for reflecting at least some IR radiation. In certain example embodiments, the coated article may be heat treated (e.g., thermally tempered, heat bent and/or heat strengthened). Coated articles according to certain example embodiments of this invention may be used in the context of windows, including monolithic windows for buildings, IG windows for buildings, etc.Type: GrantFiled: November 24, 2014Date of Patent: October 25, 2016Assignee: Guardian Industries Corp.Inventors: Muhammad Imran, Brent Boyce, Jean-Marc Lemmer, Marcus Frank, Yongli Xu
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Patent number: 9475728Abstract: A toughened glass fabrication method in which the productivity of a large toughened glass and the strength variation of the toughened glass can be improved and a toughened glass fabricated thereby. The toughened glass fabrication method includes the steps of mounting jigs on an upper surface and an undersurface of a raw glass such that an injection space through which a gel-type salt mixture is to be injected is defined between each of the jigs and the raw glass, injecting the gel-type salt mixture into the injection spaces, and heat-treating the raw glass on which the jigs are mounted.Type: GrantFiled: July 8, 2013Date of Patent: October 25, 2016Assignee: Corning Precision Materials Co., Ltd.Inventors: Sang Yoon Oh, Jong Taek Kim, JiYoung Kim, HwaYeon Lee, Jin Sung Lim
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Method for the unidirectional and or bidirectional removal of a cladding layer of an optical preform
Patent number: 9475729Abstract: The invention describes a method for the removal of glass where the parameters of the removal process are set over the length of the substrate (preform) so that a uniform removal can be achieved over the complete substrate length.Type: GrantFiled: October 23, 2015Date of Patent: October 25, 2016Assignee: j-plasma GmbHInventors: Jörg Kötzing, Robert Hanf, Lothar Brehm -
Patent number: 9475730Abstract: Disclosed is a system and method for constructing fibrous mats. In accordance with the disclosure, continuous lengths of filament are pre-coated with a liquefied thermoplastic. The pre-coated filaments are then laid down upon a belt to form a fibrous mat. The filaments can be laid down in continuous lengths or they can be chopped into discontinuous lengths. The filaments are heated after they have been laid down in order to re-liquefy the thermoplastic and facilitate bonding between intersecting fibers. The disclosure further relates to a system and method for incorporating constructed fibrous mats into a composite building board.Type: GrantFiled: June 8, 2012Date of Patent: October 25, 2016Assignee: CertainTeed Gypsum, Inc.Inventors: Robert J. Hauber, Gerald D. Boydston
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Patent number: 9475731Abstract: A dry papercrete mix is formed by preparing a wet pulp of fiber material such as newsprint and sharp sand by mixing sand, fiber material and water in a batch or continuous mixer, drying the pulp to a moisture content below that which will cause a reaction with Portland cement and adding additional sand and/or pumice and Portland cement. The resulting dry mix can then be handled, stored and used in the manner which is conventional for concrete. The dry papercrete mix can also be applied by pouring the dry papercrete mix into a form in a dry state and injecting water into the dry mix until the mix is sufficiently wetted without mixing in the manner common for concrete. Structural modules and a technique for joining them into a structure are particularly appropriate to the use of dry application papercrete.Type: GrantFiled: July 10, 2013Date of Patent: October 25, 2016Inventor: James Robert Brock
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Patent number: 9475732Abstract: An expanded lightweight aggregate has compositional ranges (Wt. % Range) of about: (a) 40 to 60% ground glass or pumice, 40 to 60% water, 3 to 15% sodium silicate, and 0.1 to 5% NaNO3 for the slurry; and (b) 50 to 85% ground glass or pumice, and 15 to 50% slurry for the granulator.Type: GrantFiled: April 24, 2014Date of Patent: October 25, 2016Assignee: The Intellectual Gorilla GmbHInventors: Evan R. Daniels, Per Just Andersen
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Patent number: 9475733Abstract: The present invention provides a ceramic material comprising magnesium, gallium, lithium, and oxygen as main components, wherein a crystal phase of a solid solution attained by dissolving gallium oxide and lithium oxide in magnesium oxide is a main phase. An XRD peak of a (200) plane of the solid solution with CuK? rays preferably appears at 2?=42.91° or more which is larger than an angle at which a peak of a Cubic crystal of magnesium oxide appears, more preferably appears at 2?=42.91° to 43.28°, and further preferably appears at 2?=42.91° to 43.02°. In the ceramic material, a molar ratio Li/Ga of Li to Ga is preferably 0.80 or more and 1.20 or less.Type: GrantFiled: April 22, 2015Date of Patent: October 25, 2016Assignee: NGK Insulators, Ltd.Inventors: Yosuke Sato, Yoshinori Isoda, Yuji Katsuda
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Patent number: 9475734Abstract: A method for reducing shrinkage variability of aluminum titanate honeycombs includes preparing an aluminum titanate-forming batch material that includes least one alkaline earth carbonate having a particle size distribution. The particle size distribution of the at least one alkaline earth carbonate is selected based on the predicted shrinkage during sintering of the aluminum titanate honeycombs.Type: GrantFiled: May 31, 2012Date of Patent: October 25, 2016Assignee: Corning IncorporatedInventors: Daniel Edward McCauley, Patrick David Tepesch, Christopher John Warren, Jeffrey S White
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Patent number: 9475735Abstract: [Problems] To provide a high zirconia fused cast refractory that suffers less cracks in production and on heating, has excellent productivity, is hard to form zircon crystals with the refractory solely and under conditions where the refractory is in contact with molten glass, is hard to suffer cracks on receiving heat cycles in operation of a glass melting furnace, and has durability for a prolonged period of time. [Solution to Problems] A high zirconia fused cast refractory containing, as chemical components, from 85 to 95% by weight of ZrO2, from 0.4 to 2.5% by weight of Al2O3, from 3.5 to 10% by weight of SiO2, from 0.05 to 1% by weight in total of Na2O and K2O, more than 0.04% by weight and 1% by weight or less of B2O3, 0.02% by weight or less of P2O5, 0.05% by weight or less of MgO, from 0.01 to 0.2% by weight of CaO, in the case where any one of SrO and BaO is contained, from 0.3 to 3% by weight of SrO or more than 0.Type: GrantFiled: August 14, 2014Date of Patent: October 25, 2016Assignee: SAINT-GOBAIN TM K.K.Inventors: Toshimitsu Kuboki, Hiroshi Sugiyama, Yasuo Misu, Itaru Hashimoto
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Patent number: 9475736Abstract: A method for fast manufacturing of organic fertilizer is a method utilizing the capability of super water soul of the quick deodorization, sterilization, catalysis, decomposition and transformation of natural plant stem fiber to generate abundant organic, and matters such as minerals and trace elements, and the characteristics of zeolite of the fast absorption and decomposition of harmful matters, the elimination of the sour and odor of corruptive organic matters and removal of toxic heavy metals, containing a composition formed of abundant minerals, extremely scarce trace elements in the cultivated soil of the surface of the earth at present and broken particles of kilned bricks together, and heating, stirring organic waste, decomposing, catalyzing it fast to become organic fertilizer containing a large content of trace elements.Type: GrantFiled: March 17, 2015Date of Patent: October 25, 2016Inventor: Wen Lo Chen
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Patent number: 9475737Abstract: This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a non-acidic germanium zeolite, such as Ge-ZSM-5, on which at least two metals, platinum and at least one other metal selected from Group 7, Group 8, Group 9, Group 10 and tin, are deposited on the germanium zeolite. Examples of the other metal are iridium, rhenium, palladium, ruthenium, rhodium, iron, cobalt and tin. The catalyst is prepared by synthesizing a germanium zeolite; depositing platinum and at least one other metal on the germanium zeolite; and calcining after preparation of the zeolite, before depositing the metals or after depositing the metals. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with a hydrocarbon stream containing alkanes, olefins and mixtures thereof having 2 to 12 carbon atoms per molecule and recovering the product.Type: GrantFiled: May 18, 2011Date of Patent: October 25, 2016Assignee: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Alla K. Khanmamedova, Scott F. Mitchell, Scott A. Stevenson, Gopalakrishnan G. Juttu
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Patent number: 9475738Abstract: Disclosed herein are methods and apparatus for deactivating a catalyst composition in an reaction product stream. One such method and apparatus contact the catalyst composition with a catalyst-deactivating composition and a diluent in a vapor phase of a product-receiving vessel, wherein the boiling point of the diluent is at least 5.0° C. greater than the boiling point of the catalyst-deactivating composition. Also disclosed are oligomerization systems for producing oligomers.Type: GrantFiled: August 23, 2012Date of Patent: October 25, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventors: Michael W. Weber, James R. Lattner, Michael J. Veraa
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Patent number: 9475739Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of a feedstock comprising 1,2,3-trichloropropane and chlorinates the 1,1,2,3-tetrachloropropane generated by the process prior to a dehydrochlorination step. Production of the less desirable pentachloropropane isomer, 1,1,2,3,3-pentachloropropane, is thus minimized. The present processes provide better reaction yield as compared to conventional processes that require dehydrochlorination of 1,1,2,3-tetrachloropropane prior to chlorinating the same. The present process can also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, while limiting the production of waste water, thus providing further time and cost savings.Type: GrantFiled: August 1, 2012Date of Patent: October 25, 2016Assignee: BLUE CUBE IP LLCInventors: Max M. Tirtowidjojo, Barry B. Fish, David S. Laitar
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Patent number: 9475740Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of 1,2-dichloropropane, a by-product in the production of chlorohydrin, as a low cost starting material. 1,1,1,2,2-pentachloropropane produced by the process is subjected to catalytic dehydrochlorination and build-up of the same within the process is avoided.Type: GrantFiled: December 17, 2013Date of Patent: October 25, 2016Assignee: BLUE CUBE IP LLCInventors: Max M. Tirtowidjojo, David S. Laitar, Barry B. Fish, William J. Kruper, Jr.
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Patent number: 9475741Abstract: The invention relates to a method for obtaining higher alcohols from lower alcohols with a catalyst that is a metal oxide comprising gallium and a noble metal selected from the list containing Pd, Pt, Ru, Rh and Re.Type: GrantFiled: July 1, 2013Date of Patent: October 25, 2016Assignee: ABENGOA BIOENERGÍA NUEVAS TECHNOLOGÍAS, S. A.Inventors: Ricardo Arjona Antolín, Juan Luís Sanz Yagüe, Avelino Corma Canós, Marcelo Eduardo Domine, Fernando Vidal Barrero, Francisco Antonio Ladrón de Guevara Vidal
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Patent number: 9475742Abstract: A method for preparing lactic acid is described, having a step of converting glycerol in the presence of a platinum-based heterogeneous catalyst on a zirconia-based support, in basic medium under inert atmosphere.Type: GrantFiled: December 5, 2013Date of Patent: October 25, 2016Inventors: Catherine Pinel, Florian Auneau, Nicolas Villandier, Michele Besson, Laurent Djakovitch
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Patent number: 9475743Abstract: Described is a novel process for the preparation of substituted tris(2-hydroxyphenyl)methane derivatives and the use of tris(2-hydroxyphenyl)methane derivatives for tertiary mineral oil production.Type: GrantFiled: February 28, 2014Date of Patent: October 25, 2016Assignee: Wintershall Holding GmbHInventors: Fabien Jean Brand, Peter Hänggi, Michèle Gerster, Markus Hansch
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Patent number: 9475744Abstract: An object of the present invention is to provide a method for recovering a fluorine-containing ether capable of recovering a fluorine-containing ether used for producing a fluoropolymer, in higher recovery yield and in a shorter time. The present invention relates to a method for recovering a fluorine-containing ether, including the steps of: producing a wet fluoropolymer by suspension polymerization, solution polymerization, or bulk polymerization in the presence of at least a specific fluorine-containing ether; vaporizing and discharging vaporizable substances including the fluorine-containing ether by heating the wet fluoropolymer in a container; and transferring the vaporizable substances in the vaporized state to a cooling means to cool the vaporizable substances.Type: GrantFiled: January 20, 2014Date of Patent: October 25, 2016Assignee: DAIKAN INDUSTRIES, LTD.Inventors: Yumi Zenke, Tadaharu Isaka, Ryouichi Fukagawa, Takeshi Shimono
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Patent number: 9475745Abstract: In a process for producing phenol and cyclohexanone, a cleavage feed containing greater than 40 wt % and no greater than 95 wt % cyclohexyl-1-phenyl-1-hydroperoxide, and at least 5 wt % and less than 60 wt % cyclohexylbenzene is mixed with at least phenol, cyclohexanone, water, and sulfuric acid to produce a cleavage reaction mixture containing from 15 wt % to 50 wt % phenol, from 15 wt % to 50 wt % cyclohexanone, from 1 wt % to 10 wt % cyclohexyl-1-phenyl-1-hydroperoxide, from 5 wt % to 60 wt % cyclohexylbenzene, from 0.1 wt % to 4 wt % water, and from 10 wppm to 1000 wppm sulfuric acid. The cleavage reaction mixture is then reacted at a temperature from 30° C. and to 70° C., and a pressure of at least 1 atmosphere for a time sufficient to convert at least 50% of said cyclohexyl-1-phenyl-1-hydroperoxide in said cleavage reaction mixture and produce a cleavage effluent containing phenol and cyclohexanone.Type: GrantFiled: November 13, 2013Date of Patent: October 25, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventors: Keith H. Kuechler, Charles Morris Smith, Francisco M. Benitez, Kun Wang, Hari Nair, Travis A. Reine, Gabor Kiss, Roberto Garcia, Christopher L. Becker
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Patent number: 9475746Abstract: Processes for producing acetic acid herein generally include contacting methanol and carbon monoxide in the presence of a reaction medium under carbonylation conditions sufficient to form acetic acid, the reaction medium including a carbonylation catalyst selected from rhodium catalysts, iridium catalysts and palladium catalysts; from 1 wt. % to 14 wt. % water; and a plurality of additives, in-situ generated derivatives of the plurality of additives or combinations thereof; the plurality of additives including a first additive including one or more phosphine oxides and a second additive selected from heteropolyacids, metal salts and combinations thereof, the heteropolyacids represented by the formula HnM12XO40, wherein H is hydrogen, M is selected from tungsten and molybdenum, X is selected from phosphorous and silicon and O is oxygen and n is 3 or 4, the metal salts are selected from transition metal salts, lanthanide metal salts and combinations thereof; and recovering acetic acid from the process.Type: GrantFiled: September 22, 2014Date of Patent: October 25, 2016Assignee: LyondellBasell Acetyls, LLCInventors: Noel C. Hallinan, Brian A. Salisbury, Daniel F. White, David L. Ramage, Jared T. Fern
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Patent number: 9475747Abstract: The disclosures herein provide compounds of Formula I, Formula II, Formula III, Formula IV, Formula V, Formula VI and Formula VII or its pharmaceutical acceptable compositions and salts, as well as polymorphs, enantiomers, stereoisomers, solvates, and hydrates thereof. The pharmaceutical compositions may be formulated for oral administration, delayed release or sustained release, transmucosal, syrup, topical, parenteral administration, injection, subdermal, oral solution, rectal administration, nanoparticle, buccal administration or transdermal administration. Such compositions may be used to treatment of urea cycle disorders and gout or its associated complications.Type: GrantFiled: November 11, 2015Date of Patent: October 25, 2016Inventor: Mohan Murali Alapati
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Patent number: 9475748Abstract: Liquid formulations of lactic acid addition salts of 1-[2-(2,4-dimethylphenylsulfanyl)-phenyl]piperazine are provided.Type: GrantFiled: December 11, 2014Date of Patent: October 25, 2016Assignee: H. Lundbeck A/SInventors: Svend Treppendahl, Heidi Lopez De Diego
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Patent number: 9475749Abstract: This invention is directed to novel compounds isolated or derived from Alpiniae oxyphyllae fructus, chemically synthesized novel compounds, methods of preparing the novel compounds and uses thereof as neuroprotectants or drugs for treating neurodegenerative diseases such as Parkinson's disease.Type: GrantFiled: March 14, 2014Date of Patent: October 25, 2016Assignee: University of MacauInventors: Ming Yuen Lee, Zaijun Zhang, Guohui Li
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Patent number: 9475750Abstract: Phenylketone carboxylate compounds of Formula I, wherein n=2-6; R?C(0); —OC(O)— or —CH(OH)—; A is (CH2)mCOOH, W(CH2)mCOOH or YCH(COOH)((CH2)pCH3) when B is Ft B is (CH2)mCOOH, W(CH2)mCOOH or YCH(COOH)((CH2)pCH3) when A is Ft or A and B form a 5-7 membered cycloalkyl substituted with COOFt W=0, S or NFt Y=0,S,NH or CH2; m=0-2; p=1-7; have been prepared. These compounds and their pharmaceutically acceptable salts have beneficial therapeutic effects to prevent or treat a condition related to (l) blood disorders, (ii) inflammation related diseases, (iii) renal disorders and/or renal disorders complications, or (iv) fibrosis-related organ dysfunction.Type: GrantFiled: October 26, 2011Date of Patent: October 25, 2016Assignee: PROMETIC BIOSCIENCES INC.Inventors: Boulos Zacharie, Christopher Penney, Shaun Abbott, Lyne Gagnon, Brigitte Grouix, Pierre Laurin, Jean-François Bienvenu
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Patent number: 9475751Abstract: The present invention relates to a continuous process for producing lower dialkyl carbonates as a main product and alkylene glycol as a by-product by transesterification of a cyclic alkylene carbonate (e.g. ethylene or propylene carbonate) with lower alkyl alcohols in the presence of a catalyst and also the necessary purification of the dialkyl carbonate in a subsequent process step. For optimization of the economic efficiency and energy efficiency of the process, additional devices are used for intermediate heating of the internal liquid streams within the apparatus.Type: GrantFiled: November 19, 2013Date of Patent: October 25, 2016Assignee: Covestro Deutschland AGInventors: Pieter Ooms, Friedhelm Risse, Andre Düx, Carsten Buchaly, Thomas Pancur, Arthur Susanto, Georg Ronge, Johan Vanden Eynde, Wim Wuytack
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Patent number: 9475752Abstract: Provided are a method for manufacturing 3,4,5-tricaffeoylquinic acid, which can produce 3,4,5-tricaffeoylquinic acid with high efficiency by a simple operation in a short process using inexpensive raw materials, and intermediate compounds.Type: GrantFiled: October 7, 2015Date of Patent: October 25, 2016Assignee: FUJIFILM CorporationInventors: Kozo Sato, Hiroyuki Naito, Takeshi Murakami
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Patent number: 9475753Abstract: The present invention also relates to a process for preparing a diamine/dicarboxylic acid salt wherein the dicarboxylic acid comprises an aromatic dicarboxylic acid and is provided in a powder form; the diamine is provided in a liquid form gradually dosed to the dicarboxylic acid powder, while keeping the dicarboxylic acid powder in constant movement; the processing temperature is above 0° C. and below the boiling temperature of the diamine and the melting temperature of the acid and the salt, and the reaction mixture comprises at most 5 wt. % of water. The present invention also relates to an anhydrous diamine/dicarboxylic acid salt obtainable by the process according to invention, or any embodiment thereof as described above.Type: GrantFiled: July 26, 2012Date of Patent: October 25, 2016Assignee: DSM IP ASSETS B.V.Inventors: Eric Grolman, Rudy Rulkens
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Patent number: 9475754Abstract: Amines and amine derivatives that improve the buffering range, and/or reduce the chelation and other negative interactions of the buffer and the system to be buffered. The reaction of amines or polyamines with various molecules to form polyamines with differing pKa's will extend the buffering range, derivatives that result in polyamines that have the same pKa yields a greater buffering capacity. Derivatives that result in zwitterionic buffers improve yield by allowing a greater range of stability.Type: GrantFiled: June 5, 2016Date of Patent: October 25, 2016Inventor: Thomas P. Daly
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Patent number: 9475755Abstract: A method for ameliorating and/or preventing chronic kidney disease includes administering to a subject in need thereof an agent containing 5-aminolevulinic acid (ALA) or a derivative thereof, or a salt thereof as an active ingredient. Preferably, these ALAs contain a metal-containing compound, such as sodium ferrous citrate. The above-mentioned ALAs, ALA; various esters, such as ALA methylester, ALA ethylester, ALA propylester, ALA butylester, and ALA pentylester; and hydrochlorides, phosphates, and sulfates, and the like of these ALA esters are preferred examples.Type: GrantFiled: October 5, 2012Date of Patent: October 25, 2016Assignee: SBI Pharmaceuticals Co., LtdInventors: Tohru Tanaka, Motowo Nakajima, Fuminori Abe, Satofumi Kawata, Takeo Kohda
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Patent number: 9475756Abstract: Selectively fluorinated molecules are important as materials, pharmaceuticals, and agrochemicals, but their synthesis by simple, mild, laboratory methods is challenging. We report a straightforward method for the cross-coupling of a difluoromethyl group with readily available reagents to form difluoromethylarenes. The reaction of electron-neutral, electron rich, and sterically hindered aryl and vinyl iodides with the combination of CuI, CsF and TMSCF2H leads to the formation of difluoromethylarenes in high yield with good functional group compatibility. This transformation is surprising, in part, because of the prior observation of the instability of CuCF2H.Type: GrantFiled: March 5, 2013Date of Patent: October 25, 2016Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: John Hartwig, Patrick Fier
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Patent number: 9475757Abstract: The present invention relates to an improved process for synthesis of anti-Parkinson compound of formula (I) from commercially available (R)-benzyl glycidyl ether, wherein the compound obtained has enantiopurity greater than >98%. Formula (I) wherein R1 and R2 are each independently selected from hydrogen or halogen.Type: GrantFiled: May 2, 2014Date of Patent: October 25, 2016Assignee: Council of Scientific & Industrial ResearchInventors: Murugan Muthukrishnan, Mohammad Mujahid
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Patent number: 9475758Abstract: The invention relates to a compound of the following formula (I): to its method for making it and to its uses for preparing a polymer useful for increasing the heat resistance of polymeric compositions.Type: GrantFiled: November 9, 2011Date of Patent: October 25, 2016Assignee: Faurecia Interieur IndustrieInventors: Laurence Dufrancatel, Pauline Kannengiesser, Gregory Yhuel, Sinisa Marinkovic, Boris Estrine, Patrice Dole
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Patent number: 9475759Abstract: Provided are a Tigecycline crystalline hydrate, and a preparation method therefor and use thereof. The crystalline hydrate has high stability for storage, and is used for the manufacture of a medicament for treating or preventing the infection of respiratory system, hepatobiliary system, facial features, urogenital system, bone and joint, skin and soft tissue and endocarditis, septicemia, meningitis caused by susceptible strains of Gram-positive or Gram-negative bacteria, anaerobic bacteria, chlamydia, and mycoplasma in human or animal.Type: GrantFiled: April 20, 2012Date of Patent: October 25, 2016Inventor: Lifang Hu
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Patent number: 9475760Abstract: A preparation method of an aldehyde compound of the present invention includes a step of reacting the compound represented by the following general formula (a1) or (a2) with hydrogen and carbon monoxide in the presence of a metal compound including 0.01 ppmmol to 10 ppmmol of a metal belonging to Groups 8 to 10 with respect to 1 mole of the compound and a phosphorus compound, and the amount of a chlorine portion in the reaction system in the step is equal to or less than 1.5 parts by weight with respect to 1 part by weight of the metal belonging to Groups 8 to 10.Type: GrantFiled: November 8, 2013Date of Patent: October 25, 2016Assignee: MITSUI CHEMICALS, INC.Inventors: Koichi Tokunaga, Naoyuki Kakinuma, Shigetoshi Kuma
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Patent number: 9475761Abstract: A method for efficiently producing a cyanogen halide with suppressed side effects, and a method for producing a high-purity cyanate ester compound at a high yield includes contacting a halogen molecule with an aqueous solution containing hydrogen cyanide and/or a metal cyanide, so that the hydrogen cyanide and/or the metal cyanide is allowed to react with the halogen molecule in the reaction solution to obtain the cyanogen halide, wherein more than 1 mole of the hydrogen cyanide or the metal cyanide is used based on 1 mole of the halogen molecule, and when an amount of substance of an unreacted hydrogen cyanide or an unreacted metal cyanide is defined as mole (A) and an amount of substance of the generated cyanogen halide is defined as mole (B), the reaction is terminated in a state in which (A):(A)+(B) is between 0.00009:1 and 0.2:1.Type: GrantFiled: October 25, 2013Date of Patent: October 25, 2016Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Masayuki Katagiri, Yuuichi Sugano, Taketo Ikeno, Makoto Tsubuku, Keita Tokuzumi, Kenj Arii, Takashi Kobayashi, Masanobu Sogame, Yoshinori Mabuchi, Yoshihiro Kato
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Patent number: 9475762Abstract: Urethanes are prepared by oxidative carbonylation of at least one amino compound in the presence of carbon monoxide, oxygen and organic, at least one hydroxyl-group-carrying compound. The carbonylation is carried out in the absence of halogen-containing promoters. The carbonylation is also carried out in the presence of a metal complex catalyst which contains neutral bidentate N-chelate ligands of the (N˜N) type, two monoanionic N,O-chelate ligands of the general type (N˜O)? or tetradentate dianionic chelate ligands (O˜N˜N˜O)2?.Type: GrantFiled: February 4, 2016Date of Patent: October 25, 2016Assignee: Covestro Deutschland AGInventors: Andreas Jacob, Stefan Wershofen, Stephan Klein, Jorg Sundermeyer, Fuming Mei
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Patent number: 9475763Abstract: New nitrogen-containing compounds are provided that comprise multiple hydroxyl moieties and photoresist compositions that comprise such nitrogen-containing compounds. Preferred nitrogen-containing compounds comprise 1) multiple hydroxyl substituents (i.e. 2 or more) and 2) one or more photoacid-labile groups.Type: GrantFiled: January 5, 2015Date of Patent: October 25, 2016Assignee: Rohm and Haas Electronic Materials LLCInventors: Cong Liu, Chunyi Wu, Gerhard Pohlers, Gregory P. Prokopowicz, Cheng-Bai Xu
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Patent number: 9475764Abstract: The present invention is directed to methods comprising adding ammonia, either as an ammonium salt or as a gas at pressures below 0.01 MPa, to a sulfuryl fluoride solution to form the anion of bis(fluorosulfonyl)amine under conditions well suited for large-scale production. The bis(fluorosulfonyl)amine so produced can be isolated by methods described in the prior art, or isolated as an organic ion pair, such as an alkylammonium solid salt, or as an ionic liquid.Type: GrantFiled: October 14, 2015Date of Patent: October 25, 2016Assignee: Trinapco, Inc.Inventor: Martin Reid Johnson
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Patent number: 9475765Abstract: The present invention relates to solid forms of herbicide safeners, to processes for their preparation, compositions comprising the solid forms and methods of their use as safeners.Type: GrantFiled: February 4, 2016Date of Patent: October 25, 2016Assignee: Syngenta LimitedInventors: Ian Kevin Jones, Neil George, John Hone
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Patent number: 9475766Abstract: Compounds of formula II are described: wherein D, n, Ra, Rb, and Rc are as herein defined, along with pharmaceutical compositions and methods of using compounds of formula II for treating or reducing the risk of peritoneal carcinomatosis in a patient.Type: GrantFiled: August 26, 2013Date of Patent: October 25, 2016Assignees: Cephalon, Inc., University of Utah Research Foundation, University of HawaiiInventors: Bruce D. Dorsey, Scott K. Kuwada, Jay P. Theroff, Craig A. Zificsak
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Patent number: 9475767Abstract: The invention provides intermediates of the formula: as well as a method of their preparation by reacting a thiol having at least two hydroxyl groups with a mono-unsaturated organic compound in the presence of a base catalyst. A polymerizable urethane acrylate oligomer or urethane methacrylate oligomer is formed by reacting a polyisocyanate with the intermediate. The polymerizable urethane acrylate oligomer or urethane methacrylate is blended with a polymerization initiator to form a composition which is useful in such applications as adhesives.Type: GrantFiled: May 6, 2015Date of Patent: October 25, 2016Assignee: Dymax Oligomers and Coatings LLCInventors: James H. Aerykssen, Ahmet Nebioglu, Richard D. Zopf, Igor Khudyakov
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Patent number: 9475768Abstract: Provided herein are a luminogen compound of formula (I) including a AIE luminophore moiety conjugated with a maleimide moiety and a use of the same for detecting thiol groups in biomolecules. Also provided is a dye molecule, a biosensor or a bioprobe comprising the luminogen compound of formula (I) in use for detecting thiol groups in biomolecules. The detection method of the present subject matter not only has high thio-selectivity and sensitivity, but also is rapid, convenient and handy.Type: GrantFiled: March 16, 2012Date of Patent: October 25, 2016Assignee: THE HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Benzhong Tang, Yang Liu, Wing Yip Lam, Yong Yu
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Patent number: 9475769Abstract: The present invention relates to a method for the production of tricyclic indole compounds comprising a cyclization step wherein this step is improved over known methods.Type: GrantFiled: November 29, 2013Date of Patent: October 25, 2016Assignee: GE Healthcare LimitedInventors: Sondre Nilsen, Umamaheshwar P. Mokkapati
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Patent number: 9475770Abstract: The present invention describes a process for the preparation of methylphenidate hydrochloride. The process involves the esterification of ritalinic acid and methanol in the presence of an acid catalyst at a low temperature. The process may optionally involve the addition of an orthoester.Type: GrantFiled: December 16, 2011Date of Patent: October 25, 2016Assignee: Rhodes TechnologiesInventors: C. Frederick M. Huntley, Erik Wayne Kataisto, Knicholaus Dudley La Lumiere, Helge Alfred Reisch
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Patent number: 9475771Abstract: 4,6-Dibromo-3-hydroxypicolinonitrile may be prepared from furfural in a series of chemical steps selected from cyano-amination, amine salt formation and bromination-rearrangement. 4-Alkoxy-3-hydroxypicolinic acids may be conveniently prepared from 4,6-dibromo-3-hydroxypicolinonitrile in a series of chemical steps selected from bromo substitution, nitrile hydrolysis and halogen reduction.Type: GrantFiled: July 8, 2015Date of Patent: October 25, 2016Assignee: Dow AgroSciences LLCInventors: James M. Renga, Yuanming Zhu, Gregory T. Whiteker, Nakyen Choy
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Patent number: 9475772Abstract: The invention relates to new and improved processes for the preparation of Indacaterol and pharmaceutically acceptable salts thereof as well as intermediates for the preparation of Indacaterol. The new process avoids the use of the epoxide compound known in the art and the impurities associated therewith and results in a higher yield.Type: GrantFiled: September 9, 2013Date of Patent: October 25, 2016Assignee: Crystal Pharma S.A.U.Inventors: Antonio Lorente Bonde-Larsen, Yolanda Fernández Sainz, Jesús Iglesias Retuerto, Javier Gallo Nieto
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Patent number: 9475773Abstract: A method for treating polycystic ovarian syndrome and related conditions with a compound (I): or a pharmaceutically acceptable salt thereof.Type: GrantFiled: April 14, 2014Date of Patent: October 25, 2016Assignee: ASTRAZENECA ABInventors: Peter Stewart Gilmour, Tony Ho, Rahul Kakkar, Lorraine Webber
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Patent number: 9475774Abstract: Novel alpha-hydrogen substituted nitroxyl compounds and their corresponding oxidized (oxoammonium cations) and reduced (hydroxylamine) forms, and the use of such compounds, inter alia, for oxidation of primary and secondary alcohols to aldehydes and ketones, respectively; resolution of racemic alcohols; desymmetrization of meso-alcohol; as radicals and spin trapping reagents; and as polymerization agents. Processes for preparing the novel nitroxyl/oxoammonium/hydroxylamine compounds from the corresponding amines, and certain novel amine derivatives and their uses. The compounds and amine precursors are useful as ligands for transition metals and as organocatalysts in e.g., aldol reactions.Type: GrantFiled: August 6, 2014Date of Patent: October 25, 2016Assignee: Technion Research and Development Foundation Ltd.Inventors: Alex M. Szpilman, Michal Amar
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Patent number: 9475775Abstract: This invention relates to novel benzazepine dicarboxamide compounds of the formula wherein R1 to R4 are as defined in the description and in the claims, as well as pharmaceutically acceptable salts thereof. These compounds are TLR agonists and may therefore be useful as medicaments for the treatment of diseases such as cancer, autoimmune diseases, inflammation, sepsis, allergy, asthma, graft rejection, graft-versus-host disease, immunodeficiencies, and infectious diseases.Type: GrantFiled: March 4, 2016Date of Patent: October 25, 2016Assignee: Hoffmann-La Roche Inc.Inventors: Sabine Hoves, Lisha Wang, Hongying Yun, Weixing Zhang, Wei Zhu