Patents Issued in December 13, 2016
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Patent number: 9518128Abstract: This invention relates to isolated antibodies which recognize the exosite 1 epitope of thrombin and selectively inhibit thrombin without promoting bleeding. These antibody molecules may be useful in the treatment and prevention of thrombosis, embolism and other conditions mediated by thrombin.Type: GrantFiled: June 19, 2014Date of Patent: December 13, 2016Assignee: Janssen Pharmaceuticals, Inc.Inventors: James Andrew Huntington, Trevor Baglin, Jonathan Langdown
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Patent number: 9518129Abstract: This invention relates to isolated antibodies which recognize the exosite 1 epitope of thrombin and selectively inhibit thrombin without promoting bleeding. These antibody molecules may be useful in the treatment and prevention of thrombosis, embolism and other conditions mediated by thrombin.Type: GrantFiled: December 14, 2012Date of Patent: December 13, 2016Assignee: Janssen Pharmaceuticals, Inc.Inventors: James Andrew Huntington, Trevor Baglin, Jonathan Langdown
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Patent number: 9518130Abstract: Provided are methods of suppressing growth of triple negative breast tumors and basal-like breast tumors by contacting tumor cells with an ErbB3 inhibitor, e.g., an anti-ErbB3 antibody. Also provided are methods for treating triple negative breast cancer or basal-like breast cancer in a patient by administering to the patient an ErbB3 inhibitor, e.g., an anti-ErbB3 antibody. The treatment methods can further comprise selecting a patient having a triple negative breast cancer or basal-like breast cancer and then administering an ErbB3 inhibitor to the patient. The treatment methods also can further comprise administering at least one additional anti-cancer agent to the patient in combination with the ErbB3 inhibitor.Type: GrantFiled: October 20, 2014Date of Patent: December 13, 2016Assignee: Merrimack Pharmaceuticals, Inc.Inventors: Victor Moyo, Gabriela Garcia
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Patent number: 9518131Abstract: The present invention provides for a method for generating a metal ion binding protein, the method comprising a) integrating the amino acid sequence DDD into CDR1 of a light chain variable region of an antibody or fragment thereof; and b) combining the sequence of step a) with a heavy chain variable region of an antibody or fragment thereof; and c) isolating the protein. Also provided is the use of metal ion binding proteins generated by the method of the present invention for isolation and purification of proteins and for the reversible labeling of a target molecule. Also provided is a metal ion binding anti-CD8 protein.Type: GrantFiled: April 1, 2014Date of Patent: December 13, 2016Assignee: Miltenyi Biotech GmbHInventors: Holger Thie, Kristina Reck, Volker Nolle
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Patent number: 9518132Abstract: Provided herein in certain embodiments are polypeptide complexes capable of binding to an antigen. Pharmaceutical compositions, method of using the polypeptide complexes are also provided.Type: GrantFiled: November 9, 2011Date of Patent: December 13, 2016Assignee: Altimab Therapeutics, Inc.Inventors: Zijuan Li, Chun Wu, Jun Bao, Bo Chen
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Patent number: 9518133Abstract: The physical properties of a water-absorbing resin with low residual monomer content are improved or stabilized, without sacrifices in productivity, production cost, stability, etc. Provided is a water-absorbing resin with low residual monomer content and excellent whiteness, wherein a water-absorbing resin consumed in large quantities in disposable diapers, etc., is preferably a sustainable and renewable water-absorbing resin that does not require excessive purification of the acrylic acid, particularly acrylic acids derived from non-fossil sources, that is the starting material of the water-absorbing resin. Disclosed is a method of manufacturing a hydrophilic polyacrylic acid (salt) resin, which is a method of manufacturing a water-absorbing polyacrylic acid resin that comprises a step in which a monomer is prepared from acrylic acid, a step in which said monomer is polymerized, and a step in which the resulting hydrous gel is dried.Type: GrantFiled: February 8, 2010Date of Patent: December 13, 2016Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Shinichi Fujino, Satoshi Matsumoto, Kunihiko Ishizaki
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Patent number: 9518134Abstract: An aqueous acidic polymerization liquid comprising polymerizable monomers or oligomers with carboxylate and/or carboxylic acid moiety or moieties, and basal surface modified clay that is homogenously dispersable in said liquid is provided, and also methods for making such liquids, and also surface-modified-clay linked water-absorbing polymers made with said liquids and methods, and disposable absorbent articles comprising such surface-modified-clay linked water-absorbing polycarboxylate/polycarboxylic acid polymers.Type: GrantFiled: December 15, 2011Date of Patent: December 13, 2016Assignee: The Procter & Gamble CompanyInventors: Torsten Lindner, Axel Meyer, Michael Moeller, Josef Breu, Manuela Stirner
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Patent number: 9518135Abstract: The invention relates to a catalyst system for the production of ultrahigh molecular weight polyethylene comprising I. a solid reaction product obtained by reaction of: (a) a hydrocarbon solution comprising (1) an organic oxygen containing magnesium compound or a halogen containing magnesium compound and (2) an organic oxygen containing titanium compound and (b) a mixture comprising a metal compound having the formula MeRnX3-n wherein X is a halogenide, Me is a metal of Group III of Mendeleev's Periodic System of Chemical Elements, R is a hydrocarbon radical containing 1-10 carbon atoms and 0?n?3 and a silicon compound of formula RmSiCl4.m wherein 0?m?2 and R is a hydrocarbon radical containing 1-10 carbon atoms wherein the molar ratio of metal from (b): titanium from (a) is lower than 1:1 II. an organo aluminium compound having the formula AIR3 in which R is a hydrocarbon radical containing 1-10 carbon atoms and III.Type: GrantFiled: December 10, 2012Date of Patent: December 13, 2016Assignee: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Aurora Alexandra Batinas-Geurts, Nicolaas Hendrika Friederichs, Tom Schoffelen, Erik Zuidema
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Patent number: 9518136Abstract: A procedure for improved temperature control in controlled radical polymerization processes is disclosed. The procedure is directed at controlling the concentration of the persistent radical in ATRP and NMP polymerizations procedures and the concentration of radicals in a RAFT polymerization process by feeding a reducing agent or radical precursor continuously or intermittently to the reaction medium through one of more ports.Type: GrantFiled: March 23, 2015Date of Patent: December 13, 2016Assignee: ATRP SOLUTIONS, INC.Inventors: Wojciech Jakubowski, James Spanswick
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Patent number: 9518137Abstract: The present disclosure is directed to a composition and articles containing the composition. The composition includes an ethylene-propylene-diene interpolymer (EPDM) having a rheology ratio greater than 33. The EPDM also has a molecular weight distribution greater than 3.0. The composition has a dissipation factor less than or equal to 0.01 radians as measured in accordance with ASTM D 150 (130° C., 60 Hz).Type: GrantFiled: November 30, 2012Date of Patent: December 13, 2016Assignee: Dow Global Technologies LLCInventors: Brian W. Walther, Susan M. Song, Paul J. Caronia, Lin Fu
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Patent number: 9518138Abstract: A liquid random copolymer of ethylene and alpha-olefin prepared by using specific metallocene catalyst and ionic compound and a method for preparing the same are disclosed. The liquid random copolymer has high viscosity index and shear stability so that it is useful as synthetic lubricants. The liquid random copolymer of ethylene and alpha-olefin (1) comprises 60 to 40 mol % of ethylene units and 40 to 60 mol % of alpha-olefin unit having 3 to 20 carbon atoms, (2) has number average molecular weight (Mn) of 500 to 10,000 and a molecular weight distribution (Mw/Mn, Mw is the weight average molecular weight) of 3 or less measured by Gel Permeation Chromatography (GPC) (3) has Kinematic Viscosity at 100° C. of 30 to 5,000, (4) has pour point of 30 to ?45° C., and (5) has Bromine Number of 0.1 or less.Type: GrantFiled: November 15, 2013Date of Patent: December 13, 2016Assignee: DAELIM INDUSTRIAL CO., LTD.Inventors: Jae Hoon Uhm, Sang-Deok Mun, Jin-Hun Ju, Hee-Sun Bae, Sah-Mun Hong, Byung-Keel Sohn
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Patent number: 9518139Abstract: This invention relates to a rubbery or elastomeric polymer material taking up more than 5% by weight of water and at most 500% by weight of water after immersion in demineralized water at room temperature for a sufficient time to reach saturation, comprising: (a) repeating units from one or more hydrophobic organic monomers, and (b) repeating units from one or more monomers (a) being modified with one or more hydrophilic side groups. The rubbery or elastomeric polymer material may be in the form of a sheet, a foam, a coating adapted for adhesion to a substrate, or a fiber. This invention also relates to processes, polymerizable compositions, and foaming compositions for producing such rubbery or elastomeric polymer materials.Type: GrantFiled: June 28, 2012Date of Patent: December 13, 2016Assignee: KONINKLIJKE PHILIPS N.V.Inventors: Dirk Burdinski, Joyce Van Zanten, Lucas Johannes Anna Maria Beckers, Cornelis Petrus Hendriks, Willem Franke Pasveer, Nicholaas Petrus Willard, Mareike Klee, Biju Kumar Sreedharan Nair, David W. Smith
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Patent number: 9518140Abstract: Provided is a process for the production of a fluorine-containing block copolymer, which suppresses the formation of a homopolymer as a by-product and which, regardless of whether the chain transfer constant of the iodine end is large or small, achieves nearly 100% conversion into a block copolymer. The process is characterized by reacting (A) a fluorine-containing polymer which has an iodine atom or a bromine atom at either or both terminals of the backbone chain and/or at a side-chain terminal with (M) a radical-polymerizable monomer in the presence of (C) a sulfur compound represented by general formula (2): (Y1)nH2-nS2O4 (wherein Y1 is a mono- or divalent metal ion or an ammonium ion; and n is an integer of 0 to 2).Type: GrantFiled: February 11, 2016Date of Patent: December 13, 2016Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Yuzo Komatsu, Kenichi Katsukawa, Haruhiko Mohri, Takashi Kanemura
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Patent number: 9518141Abstract: A resol-type para-octylphenol-formaldehyde co-condensation resin and a method for producing the same are provided, the resol-type para-octylphenol-formaldehyde co-condensation resin having a content of a para-octylphenol monomer of 1 wt. % or less, having a total content of an aliphatic hydrocarbon, a halogenated aliphatic hydrocarbon, an aromatic hydrocarbon, a halogenated aromatic hydrocarbon, and an alcohol having 1 to 8 carbon atoms of 1 wt. % or less, the aliphatic hydrocarbon, the halogenated aliphatic hydrocarbon, the aromatic hydrocarbon, the halogenated aromatic hydrocarbon, and the alcohol having a boiling point of 60° C. or more, having a softening point of 70 to 105° C., and having an acid value of 20 to 28 KOHmg/g. The resol-type para-octylphenol-formaldehyde co-condensation resin can be used as a resin cross-linking agent for a rubber.Type: GrantFiled: February 28, 2013Date of Patent: December 13, 2016Assignee: TAOKA CHEMICAL CO., LTD.Inventors: Fumiya Ozaki, Hiroyuki Kashimoto, Nobuyuki Sato, Takafumi Yamamoto
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Patent number: 9518142Abstract: The present invention relates to a process for preparing isocyanate homopolymers containing uretdione groups, in which the phosphinoboron compound of formula (I) are used as catalysts to catalyze the homopolymerization reaction of raw isocyanates, thereby obtaining a solution of isocyanate homopolymers having uretdione groups, then separating the solution and thus obtaining the isocyanate homopolymers containing uretdione groups. The isocyanate homopolymers containing uretdione groups prepared by this process have a high amount of the uretdione groups, wherein the dependence of the amount on the conversion rate of raw isocyanates is significantly ameliorated, with low chromaticities.Type: GrantFiled: March 3, 2014Date of Patent: December 13, 2016Assignee: Wanhua Chemical Group Co., Ltd.Inventor: Lidong Sun
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Patent number: 9518143Abstract: A “no-bake” process allows the forming of larger metal castings, by providing longer work times, in the range of about 45 to about 60 minutes. This is achieved using a liquid curing catalyst that is a pyridine, substituted at the second or third position with a moiety having a molecular weight in the range of about 30 to about 100 mwu. Examples of the liquid curing catalyst include 2-ethanolpyridine, 3-chloropyridine and 2-methoxypyridine. When combined with a two-part polyurethane binder precursor and a foundry aggregate, the liquid curing catalyst provides not only the longer work time, but also a strip time that is less than about 167% of the work time, as measured from the point of activating the polyurethane precursors by mixing them in the presence of the curing catalyst.Type: GrantFiled: June 7, 2013Date of Patent: December 13, 2016Assignee: ASK Chemicals, L.P.Inventors: Michael R. Nocera, Gregory P. Sturtz, Jörg Kroker
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Patent number: 9518144Abstract: The invention relates to polyurethane resin compositions and, in particular, stable, ready-to-use polyurethane resin compositions comprising: a masked polyisocyanate having formula (I), wherein B represents alkyl and A represents a group comprising a number of isocyanate functions of between 1.5 and 2.2, preferably between 1.5 and 2.1 and, more preferably, between 1.5 and 2; or a masked pre-polymer that is the product of a reaction between the above-mentioned masked polyisocyanate and a polyol having between 1.5 and 3 OH functions and a molecular mass of between 900 and 3,000 g/mol, in a ratio such that the number of NCO functions of the masked polyisocyanate in relation to the number of OH functions of the polyol is between 1.5 and 2.5 approximately; or a mixture of the aforementioned masked polyisocyanate and masked pre-polymer.Type: GrantFiled: October 18, 2012Date of Patent: December 13, 2016Assignee: SopremaInventors: Louis Durot, Pierre-Etienne Bindschedler, Virginie Francois Barseghian, Remi Perrin
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Patent number: 9518145Abstract: Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a zinc catalyst that contains at least one zinc atom associated with a polydentate ligand that contains at least one nitrogen-containing complexing site.Type: GrantFiled: September 9, 2015Date of Patent: December 13, 2016Assignee: Dow Global Technologies LLCInventors: Richard Keaton, Peter Margl, Duane Romer, Nathan Wilmot, Rajat Duggal, Rashmi Chamsarkar
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Patent number: 9518146Abstract: Phosphoric acid derivatives, which are present as urea urethanes and contain a radical with an affinity for the binder in addition to at least one phosphoric acid ester group. Said phosphoric acid derivatives are especially suitable as wetting agents and dispersants. The derivatives are present according to the general formula (I) Y(—O—CO—NH—R1—NH—CO—X—Z1)g??(I) wherein Y is represented by a branched or unbranched, saturated or unsaturated organic radical containing 1 to 1000 carbon atoms, q is represented by an integer from 1 to 10, R1 is represented by a saturated or unsaturated, branched or unbranched organic radical containing 6 to 20 carbon atoms, X is represented by NH and/or NZ2, Z2 is represented by a branched or unbranched, saturated or unsaturated organic radical, Z1 is represented by a branched or unbranched, saturated or unsaturated organic radical, which contains at least two carbon atoms and at least one phosphoric acid ester group.Type: GrantFiled: May 4, 2012Date of Patent: December 13, 2016Assignee: BYK-Chemie GmbHInventors: Bernd Göbelt, Rene Nagelsdiek, Jürgen Omeis, Frederik Piestert, Wolfgang Pritschins, Natasa Meznaric, Daniela Schröder, Werner Tiegs
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Patent number: 9518147Abstract: An amine endcapped adduct composition including an amine endcapped adduct formed from a monofunctional epoxide and a polyether amine. The monofunctional epoxide and the polyether amine are combined in a molar ratio of 1.0:2.0 to 1.0:8.0 moles of epoxide functionalities to moles of polyether amine functionalities.Type: GrantFiled: September 24, 2013Date of Patent: December 13, 2016Assignee: Dow Global Technologies LLCInventors: Angela I. Padilla-Acevedo, Nathan Wilmot, Rajat Duggal, Harshad M. Shah, Kwanho Chang
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Patent number: 9518148Abstract: An oxygen-absorbing resin composition comprising a polyester compound having a constitutional unit (a), which has at least one tetralin ring selected from the group consisting of the following general formulas (1) to (4) and a constitutional unit (b) comprising residue of tetrahydrophthalic anhydride derivative which is represented by the following general formula (5) and/or general formula (6).Type: GrantFiled: October 9, 2013Date of Patent: December 13, 2016Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Shinpei Iwamoto, Satoshi Okada, Shinichi Ikeda, Kenichiro Usuda
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Patent number: 9518149Abstract: Disclosed are a highly purified polylactic acid or a derivative thereof, or a salt thereof, and a method for purifying the same. The polylactic acid or a derivative thereof, or a salt thereof may be applied to various medical and drug carrier systems, or the like.Type: GrantFiled: June 23, 2009Date of Patent: December 13, 2016Assignee: SAMYANG BIOPHARMACEUTICALS CORPORATIONInventors: Bong Oh Kim, Min Hyo Seo
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Patent number: 9518150Abstract: The invention relates to a resin composition which comprises a polymer having a divalent oligofluorene as a repeating unit therein, wherein the divalent oligofluorene contains at least two fluorene units optionally having a substituent, and the 9-positioned carbon atoms of the fluorene units bond to each other via a direct bond or via an alkylene group optionally having a substituent, an arylene group optionally having a substituent, or an aralkylene group optionally having a substituent, and a ratio of a retardation measured at a wavelength of 450 nm (Re450) to a retardation measured at a wavelength of 550 nm (Re550) satisfies the following formula (2): Re450/Re550?1.0.Type: GrantFiled: April 14, 2015Date of Patent: December 13, 2016Assignee: MITSUBISHI CHEMICAL CORPORATIONInventors: Hisatoshi Uehara, Hiroyuki Hayashi, Naoko Sumitani, Haruhiko Kusaka, Shingo Namiki, Yuuichi Hirami
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Patent number: 9518151Abstract: The present invention belongs to the field of preparation of high performance polymers, and specifically relates to a low dielectric constant polymer containing dinaphthyl and hexafluorocyclobutyl ether units, and preparation method and use thereof. The polymer is prepared as follows: under the effect of an alkali, 1-naphthol bromotetrafluoroethane ether is prepared from 1-naphthol and tetrafluorodibromoethane in an organic solvent, and then reduced by a zinc powder so as to obtain 1-naphthol trifluorovinyl ether. 1-naphthol trifluorovinyl ether is treated at a high temperature to obtain a bisnaphthol hexafluorocyclobutyl ether monomer. The monomer is subjected to oxidative coupling in the presence of ferric trichloride so as to obtain a thermal polymer containing dinaphthyl and hexafluorocyclobutyl structural units with a good film-forming property, and in a nitrogen atmosphere, the temperature for 5% weight loss (Td5%) of the obtained film is 437° C., and the carbon residue yield at 1000° C. is 54.24%.Type: GrantFiled: November 20, 2013Date of Patent: December 13, 2016Assignee: Shanghai Institute of Organic Chemistry, Chinese Academy of SciencesInventors: Qiang Fang, Chao Yuan, Kaikai Jin, Yingchun Liu, Shen Diao, Kai Li
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Patent number: 9518152Abstract: The object of the present invention is to provide a fundamental therapy to mitochondrial genetic diseases caused by mutation of the mitochondrial (mt)DNA, and a pharmaceutical composition used for the same. The object can be solved by a polyamide compound binding to a target double-stranded mtDNA comprising A/T pair consisting of first A of the following sense-stranded DNA and the corresponding T, A/T pair consisting of 8th A of the following sense-stranded DNA and the corresponding T, G/C pair consisting of 9th G of the following sense-stranded DNA and the corresponding C, G/C pair consisting of 14th G of the following sense-stranded DNA and the corresponding C, T/A pair consisting of 15th T of the following sense-stranded DNA and the corresponding A, or the like, in the double-stranded DNA consisting of the sense-stranded DNA having base sequence of 5?-ATGGCAGAGCCCGGTAATCGCATAA-3? (SEQ ID NO: 1) and the antisense-stranded DNA having base sequence of 5?-TTATGCGATTACCGGGCTCTGCCAT-3? (SEQ ID NO: 2).Type: GrantFiled: April 2, 2012Date of Patent: December 13, 2016Inventor: Takamitsu Yano
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Patent number: 9518153Abstract: The present invention addresses the problem of providing: a catalyst for preliminary reaction and a preliminary reaction method, which are suitable for a composition that is obtained by adding a thiol compound and an isocyanate compound to an episulfide compound; and a polymerizable composition for optical materials, which is capable of preventing yellowing of an optical material which contains a composition that is obtained by adding a thiol compound and an isocyanate compound to an episulfide compound.Type: GrantFiled: February 27, 2013Date of Patent: December 13, 2016Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Eiji Koshiishi, Hitoshi Okazaki, Motoharu Takeuchi
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Patent number: 9518154Abstract: The invention provides a surface treatment agent wherein a fluorooxyalkylene group-containing polymer or a fluorooxyalkylene group-containing polymer composition comprising the polymers, which is controlled of a temperature range of vaporization of fluorooxyalkylene group-containing polymer(s). The fluorooxyalkylene group-containing polymer has a fluorooxyalkylene structure represented by —(OCF2)p(OCF2CF2)q— and hydrolysable groups bond to a silicon atom represented by the formula at least one terminal. The polymer composition shows a decrease of 75% or more in weight, relative to the total weight of the polymer, in a temperature range of from 150 to 350 degrees C. when this is heated at a rate of 2 degrees C. per minute and a pressure of 0.1 Pa or less. The present surface treatment agent forms a coating having water- and oil-repellency and scratch resistance regardless of a vapor deposition conditions, in particularly by a vapor deposition at a mild temperature such as 350 degrees C.Type: GrantFiled: June 13, 2014Date of Patent: December 13, 2016Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Yuji Yamane, Noriyuki Koike
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Patent number: 9518155Abstract: The present invention relates to a composition for solubilizing a fluoropolymer, comprising a solvent blend of a) compound of formula (I) R1—C(?O)—NR2R3 wherein R1 and R2 and R3 are defined as in the specification and b) dimethylsulfoxide (DMSO). The invention also relates to the process for the preparation of the composition and its uses. The invention is also the use of the fluoropolymer composition for coating applications.Type: GrantFiled: April 16, 2012Date of Patent: December 13, 2016Assignee: Rhodia OperationsInventors: Shujing Cheng, Arnaud Bourdette
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Patent number: 9518156Abstract: A method includes heating a sulfonated polyester resin in an organic-free solvent, adding a solution of silver (I) ion to the heated resin in water to form a mixture, reducing silver (I) to silver (0) by heating the mixture from about 65° C. to about 90° C., thereby forming an emulsion of composite particles comprising a sulfonated polyester matrix and a plurality of silver nanoparticles disposed within the sulfonated polyester matrix, and allowing the silver nanoparticles to agglomerate into a silver nanodendrite structure.Type: GrantFiled: January 23, 2015Date of Patent: December 13, 2016Assignee: XEROX CORPORATIONInventors: Valerie M. Farrugia, Alana Desouza, Sandra J. Gardner
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Patent number: 9518157Abstract: Preparation of a rubber composition containing a dispersion of aligned exfoliated graphite platelets. Such rubber composition is prepared by a method comprised of a sequential combination of concentrated solvent or dry masterbatching of elastomer and exfoliated graphite platelets, followed by blending the masterbatch (after removing the solvent from the solvent based masterbatch) with additional elastomer(s) and then followed by processing the resulting rubber composition to align the dispersed exfoliated graphite platelets in a substantially parallel relation to each other. Such processing may comprise as least one of extrusion and calendaring the rubber composition. The invention further relates to a tire containing a component comprised of such rubber composition containing a dispersion of aligned exfoliated graphite platelets prepared by the aforesaid method.Type: GrantFiled: October 24, 2013Date of Patent: December 13, 2016Assignee: The Goodyear Tire & Rubber CompanyInventors: Junling Zhao, Xiaoping Yang, Carl Trevor Ross Pulford
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Patent number: 9518158Abstract: The invention relates to a pneumatic rubber truck tire having a circumferential stratified dual cap rubber tread comprised of an outer tread cap and underlying tread sub cap. The underlying tread sub cap rubber layer is provided to support the outer tread cap rubber layer with similar physical properties. Both of the tread cap rubber compositions are comprised of a combination of natural cis 1,4-polyisoprene and dual cis 1,4-polybutadiene elastomers and contain reinforcing fillers comprised of precipitated silica and rubber reinforcing carbon black. The tread cap rubber compositions differ from each other by containing different levels of the individual cis 1,4-polybutadiene rubbers and by containing different rubber reinforcing carbon blacks and precipitated silica.Type: GrantFiled: July 7, 2015Date of Patent: December 13, 2016Assignee: The Goodyear Tire & Rubber CompanyInventors: Roberto Cerrato Meza, Junling Zhao, Leandro Forciniti, Warren James Busch
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Patent number: 9518159Abstract: This disclosure relates to multilayer films having improved caulkability. These multilayer films have at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Yd) greater than 0; total catalytic metal ?3.0 ppm; ?0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The ethylene interpolymer products have a melt index from about 0.4 to about 100 dg/minute, a density from about 0.950 to about 0.970 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 55% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.Type: GrantFiled: October 21, 2015Date of Patent: December 13, 2016Assignee: NOVA Chemicals (International) S.A.Inventors: Daniel Ward, Michael Li, Xiaochuan Wang, Tieqi Li, Christopher John Brooke Dobbin, Fazle Sibtain, Kenneth Edward Taylor, Hamidreza Khakdaman
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Patent number: 9518160Abstract: Composite materials are augmented with functionalized graphene having added amine groups, benzoxazine groups, imide groups, or a combination of amine groups and imide groups on a surface of the graphene, epoxide groups formed on at least one edge of the graphene and/or holes formed through the graphene. The functionalized graphene is integrated into a composite material as a supplement to or as a replacement for either the carbon reinforcement material or the resin matrix material to increase strength of the composite materials, and may be in the form of a functionalized graphene nanoplatelet, a flat graphene sheet or film, or a rolled or twisted graphene sheet or film.Type: GrantFiled: September 25, 2015Date of Patent: December 13, 2016Assignee: The Boeing CompanyInventor: Keith Daniel Humfeld
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Patent number: 9518161Abstract: The present disclosure is directed to compositions and methods for improving the cling performance in stretch-cling films. Compositions include: (a) 80.0 to 99.5 wt. % of a propylene-based elastomer, the propylene-based elastomer comprising at least about 60.0 wt. % propylene-derived units and about 5.0 to about 25.0 wt. % ethylene-derived units, based on total weight of the propylene-based elastomer, wherein the propylene-based elastomer has a heat of fusion of less than about 80.0 J/g; and (b) 0.5 to 20.0 wt. % of a polyalphaolefin, wherein the amounts of the propylene-based elastomer, and the polyalphaolefin are based on the weight of the composition. Methods of making such compositions as well as compositions including an ethylene-based polymer and films and methods of making films are also disclosed.Type: GrantFiled: May 22, 2014Date of Patent: December 13, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventor: Paul M. German
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Patent number: 9518162Abstract: The invention provides a process of making a continuous freeform thermoplastic dielectric film (25) that is evenly loaded with dispersed nanoparticles comprising the steps of; feeding thermoplastic granules (21) into an extruder (23), injecting a secondary feed (27) comprising a suspension of nanoparticles in a liquid carrier to create a nanocomposite, and extruding said composite onto cooled rollers (26) at a preset rate thereby enabling the crystalline structure of the nanocomposite film (25) to be controlled wherein the secondary feed (27) is mixed continuously by an ultrasonicator (29) whilst being injected into the extruder (23).Type: GrantFiled: July 12, 2013Date of Patent: December 13, 2016Assignee: The Secretary of State for DefenceInventors: Matthew Adrian Brown, Michelle Silverstone Lang
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Patent number: 9518163Abstract: A cellular foamed article is provided, including a polymeric foam material and a micro- or nano-sized reinforcement material embedded in the foam material. Also, methods of making a reinforced cellular foamed articles are provided, including preparing a dispersion comprising a reinforcement material and a polymer precursor; processing the reinforcement material so that it has a volume average length ranging from about average cross sectional diameter of from about 1 to about 500 nm and a volume average length of from about 10 nm to about 10 ?m; reacting the polymer precursor to form a foamable polymer; and foaming the foamable polymer.Type: GrantFiled: May 26, 2009Date of Patent: December 13, 2016Assignee: Semmes, Inc.Inventor: Edmund Bernard Semmes
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Patent number: 9518164Abstract: A method for recycling vulcanized rubber provided the use of a reactor and a glycerol and hydrochloric acid solution. A quantity of vulcanized rubber is reduced in size, and submerged into a reactor containing the glycerol and hydrochloric acid solution. The quantity of vulcanized rubber is simultaneously heated and agitated to chemically break sulfide bonds within the quantity of vulcanized rubber. A solid residue, byproduct of the reaction, is separated from the quantity of vulcanized rubber, glycerol, and hydrochloric acid mixture. After separation, an additional quantity of hydrochloric acid is added into the aforementioned mixture to wash the mixture and further the reaction to an optimal yield. The quantity of vulcanized rubber, glycerol and hydrochloric acid mixture is reheated and agitated to produce a full quantity of de-vulcanized rubber. The full quantity of de-vulcanized rubber is recovered through a solid-liquid separation process.Type: GrantFiled: April 29, 2015Date of Patent: December 13, 2016Inventors: Hysen Blloshmi, Kastriot Blloshmi
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Patent number: 9518165Abstract: A tire component comprising a rubber composition having a highly unsaturated diene elastomer and a reinforcing filler with a methylene acceptor selected from 3-hydroxydiphenyl-amine, 4-hydroxydiphenyl-amine or combinations thereof. Such rubber compositions further include a methylene donor, wherein a ratio of the methylene acceptor to the methylene donor may be greater than 10:1 or in other embodiments greater than 10:1 but no more than 50:1 or between 15:1 and 30:1. A method for manufacturing a tire component includes mixing together components of a rubber composition into a non-productive mix, the components including a highly unsaturated diene elastomer, a reinforcing filler and a methylene acceptor selected from 3-hydroxydiphenyl-amine, 4-hydroxydiphenyl-amine or combinations thereof; and mixing a methylene donor and a vulcanizing agent into the non-productive mix to convert the non-productive mix to a productive mix.Type: GrantFiled: September 19, 2013Date of Patent: December 13, 2016Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.Inventors: Xiaofeng Shaw Yang, Jesse J. Arnold
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Patent number: 9518166Abstract: A film forming auxiliary agent composition for an emulsion resin in accordance with the present invention is characterized in that containing a specific ester compound (A) and a specific fatty acid (B), and having an acid value of 0.05 to 5 mg KOH/g, said composition has low odor, a high boiling point and good film forming ability, and the emulsion resin that is blended with said composition has good long-term storage stability.Type: GrantFiled: October 24, 2013Date of Patent: December 13, 2016Inventors: Takashi Ono, Hiroaki Shirai, Masaki Hosaka
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Patent number: 9518167Abstract: A bioderived based plasticizer is produced by reacting a bioderived diol (and/or a bioderived alcohol) and a bioderived carboxylic acid in the presence of N,N?-dicyclohexylcarbodiimide (DCC), wherein the bioderived carboxylic acid includes a hydrolyzed oil. The bioderived carboxylic acid (e.g., linoleic acid, ?-linolenic acid, oleic acid, and mixtures thereof) may be produced by hydrolyzing a triglyceride, such as canola oil, linseed oil, soybean oil, and mixtures thereof. In one embodiment of the present invention, a bioderived based plasticizer is produced by reacting 2,5-bis-(hydroxymethyl)furan and ?-linolenic acid in the presence of DCC. In some embodiments of the present invention, the bioderived based plasticizer is blended into one or more polymers.Type: GrantFiled: March 3, 2015Date of Patent: December 13, 2016Assignee: International Business Machines CorporationInventors: Dylan J. Boday, Joseph Kuczynski, Jason T. Wertz, Jing Zhang
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Patent number: 9518168Abstract: Provided are a polylactic acid resin composition excellent in transparency, heat resistance, and migration resistance, and excellent in productivity at the time of the mold forming thereof, and a resin molded article thereof. The polylactic acid resin composition includes a polylactic acid; a reaction product of at least one selected from the group consisting of sorbitol, mannitol, and dehydration condensates thereof, an alkylene oxide mainly formed of ethylene oxide, and a fatty acid having 8 to 24 carbon atoms; and a fatty acid amide having a hydroxyl group.Type: GrantFiled: January 22, 2015Date of Patent: December 13, 2016Assignee: DAI-ICHI KOGYO SEIYAKU CO., LTD.Inventors: Hideaki Onishi, Ken Morishita
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Patent number: 9518169Abstract: Provided are a polylactic acid resin composition excellent in impact resistance, migration resistance, and heat resistance, and excellent in productivity at the time of the mold forming thereof, and a resin molded article thereof. The polylactic acid resin composition includes a polylactic acid; a reaction product of at least one of a polyol and a polyol dehydration condensate, an alkylene oxide mainly formed of ethylene oxide, and a fatty acid having 12 to 24 carbon atoms; and a fatty acid amide.Type: GrantFiled: January 22, 2015Date of Patent: December 13, 2016Assignee: DAI-ICHI KOGYO SEIYAKU CO., LTD.Inventors: Hideaki Onishi, Ken Morishita
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Patent number: 9518170Abstract: A process is provided for the polymerization of fluoromonomer to an dispersion of fluoropolymer particles in an aqueous medium in a polymerization reactor, by (a) providing the aqueous medium in the reactor, (b) adding the fluoromonomer to the reactor, (c) adding initiator to the aqueous medium, the combination of steps (b) and (c) being carried out essentially free of hydrocarbon-containing surfactant and resulting in the kickoff of the polymerization of the fluoromonomer, and (d) metering hydrocarbon-containing surfactant into the aqueous medium after the kickoff of polymerization, e.g. after the concentration of the fluoropolymer in the aqueous medium is at least 0.6 wt %, the metering being at a rate reducing the telogenic activity of said surfactant while maintaining surface activity.Type: GrantFiled: January 11, 2016Date of Patent: December 13, 2016Assignee: THE CHEMOURS COMPANY FC, LLCInventors: Paul Douglas Brothers, Subhash Vishnu Gangal, Dipti Dilip Khasnis
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Patent number: 9518171Abstract: The present invention relates to polyolefin matrix composites reinforced with continuous carbon fibers, and a process for making them. The polymer-fiber composite material comprises a plurality of continuous fibers; and a polyolefin matrix, wherein, the polyolefin matrix comprises polyolefin polymer chains with a number average molecular weight of at least 1×106 amu, and wherein, the polymer-fiber composite has a notched impact strength greater than the notched impact strength of a neat polyolefin, wherein the neat polyolefin has an equivalent chemical composition and number average molecular weight as the polyolefin of the polyolefin matrix in the polymer-fiber composite material. The present invention also relates to articles of manufacture made substantially from polyolefin matrix composites reinforced with continuous carbon fibers as well as orthopedic implant devices having a wear surface, or bearing comprising a polyolefin matrix composite reinforced with continuous carbon fibers.Type: GrantFiled: September 11, 2015Date of Patent: December 13, 2016Assignee: TDA Research, Inc.Inventor: Michael D Diener
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Patent number: 9518172Abstract: The present invention provides a rubber composition comprising, as blended, a rubber component (A), an amino acid derivative (B) and a filler containing an inorganic filler (C), and further containing, as incorporated therein, at least one selected from sulfur and a sulfur compound. The vulcanization rate of the rubber composition is accelerated and the low-heat-generation property thereof is excellent.Type: GrantFiled: February 26, 2013Date of Patent: December 13, 2016Assignee: BRIDGESTONE CORPORATIONInventors: Takeshi Shiono, Takumi Toda, Satoshi Horie
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Patent number: 9518173Abstract: The present invention provides a tire rubber composition that makes it possible to suppress discoloration of tires, and a pneumatic tire formed from the rubber composition. The present invention relates to a tire rubber composition containing a bluing agent.Type: GrantFiled: July 24, 2013Date of Patent: December 13, 2016Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventor: Toshio Tada
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Patent number: 9518174Abstract: A rubber compound production method including a first mixing step wherein at least one cross-linkable unsaturated-chain polymer base, silica, and a silane bonding agent in the alkoxymercaptoalkyl-silane class are mixed together; and a following mixing step wherein a curing system having at least sulphur and accelerants is added and mixed to the compound being produced. 0.2 to 5 phr of an accelerant, and 0.5 to 6 phr of a zinc salt of a fatty acid with a carbon atom number of C8 to C24 are added at the first mixing step. The accelerant is from the group of benzothiazyl-cyclohexyl-sulphenamide (CBS), benzothiazole disulphide (MBTS), N-tert-butyl-2-benzothiazylsulphenamide (TBBS), 2-mercaptobenzothiazole (MBT), zinc salts of 2-mercaptobenzothiazole (ZMBT), benzothiazyl-2-dicyclohexyl-sulphenamide (DCBS), diphenylguanidine (DPG), triphenylguanidine (TPG), diorthotolyl guanidine (DOTG), o-tolylbiguanidine (OTBG), ethylene thiourea (ETU) and their mixtures.Type: GrantFiled: October 29, 2013Date of Patent: December 13, 2016Assignee: BRIDGESTONE CORPORATIONInventors: Riccardo Ascione, Davide Privitera
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Patent number: 9518175Abstract: A flame-retardant thermoplastic elastomer composition is provided to produce a molded article possessing mechanical properties, flame retardancy and softness inherently possessed by a molted article obtained from a thermoplastic elastomer composition containing a mineral oil-based softening agent and a flame retardant and fails to stain a mold after injection molding. A production method includes step (1) obtaining a thermoplastic elastomer composition by dynamically crosslinking a polymer mixture (A) containing an ethylene-?-olefin-based copolymer rubber (A1) and a propylene-based polymer (A2) in the presence of a mineral oil-based softening agent (C) and a crosslinking agent (D), and step (2) kneading the thermoplastic elastomer composition, a halogen-free flame retardant (E), zinc oxide (F), and a thermoplastic resin with a polar group (G).Type: GrantFiled: December 20, 2014Date of Patent: December 13, 2016Assignee: Sumitomo Chemical Company, LimitedInventors: Ryosuke Kurokawa, Nobuhiro Natsuyama
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Patent number: 9518176Abstract: Geomembrane liners suitable for use at elevated temperatures up to 100° C., as well as master batch compositions suitable for preparing such geomembrane liners.Type: GrantFiled: May 6, 2014Date of Patent: December 13, 2016Assignee: GSE Environmental, LLCInventors: Yongyoot Prachoomdang, Yin Wu
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Patent number: 9518177Abstract: The present invention relates to a composite material for a transport, including a polypropylene resin and a carbon long fiber, and more particularly, to a fiber reinforced composite material composition for a transport including 40-90 wt % of a polypropylene resin, 5-60 wt % of a carbon long fiber having a fiber diameter of 1-50 ?m and a weight average fiber length of 20-150 mm, and 0.3-10 wt % of a compatibilizer. The compatibilizer includes one selected from the group consisting of an ionomer, a copolymer of propylene-polar monomer, a modification water added polymer and combinations thereof. The composite material has improved interface properties between the polypropylene resin and the carbon long fiber owing to a specific compatibilizer, improved rigidity, impact resistance and heat resistance, and may be applied to various fields requiring the fiber reinforced composite material as well as various transports including an automobile.Type: GrantFiled: September 12, 2013Date of Patent: December 13, 2016Assignee: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGYInventors: Dong Hyun Kim, Dae Young Lim, Ki Young Kim, No Hyung Park, Hyo Jin An, Jung Soo Kim, Eun Soo Lee