Abstract: A separator for a separator device, for example a final separator for a final separator device for separating water from a liquid such as oil and/or fuel, may include a filter body including at least one filter material through which the liquid can flow. The filter body may have a first side and a second side. A nanofibre layer may be disposed on the first side in at least one region. The nanofibre layer may be configured hydrophobic. According to an implementation, the nanofibre layer is treated to produce the hydrophobic property. The filter body may have a porosity on the first side that is smaller than on the second side.

Abstract: The present invention provides an air distributing manifold that is positioned and operative within the interior of the debris holding tank of the hydrovac system. The air distributing manifold can be configured to aid in the recirculating of the airflow within the debris holding tank prior to exit from the tank, thereby enhancing the precipitation of entrained particulates within the air stream.

Abstract: A filter element (3), in particular an air filter element, for a filter arrangement (1), having a frame (6) that has at least one contact surface (11) for contacting a clamping surface (30) of at least one clamping element (27, 28) of the filter arrangement (1), wherein the at least one contact surface (11) includes straight segments (12, 13, 14) and oblique segments (15, 16) arranged between the straight segments (12, 13, 14), and wherein the straight segments (12, 13, 14) are arranged such that the clamping surface (30) when the latter is displaced relative to the at least on contact surface (11) essentially exclusively contacts the oblique segments (15, 16).

Abstract: A pulse jet cleaning system is disclosed having at least one diverter device and having at least one control valve configured for receiving pulse air from a pulse air manifold and controllably passing a pulse of pulse air downstream to clean the filter assemblies. The at least one diverter is configured for receiving the pulse from the control valve and diverting the pulse into a plurality of outlet ports for providing pulse air to at least two blowpipes for cleaning a filter assembly.

Abstract: A particulate filter for an exhaust system includes a housing having an exhaust inlet and an exhaust outlet. Arranged in the housing is a porous filter body which has a closed casing and plural flow passages extending in parallel relationship. The filter body defines a longitudinal center axis and has a conical configuration in relation to the longitudinal center axis, with each of the flow passages defining a longitudinal center axis which extends in parallel relationship to the longitudinal center axis of the filter body.

Abstract: A filter element includes a construction of pleated filter media defining an interior volume. First and second opposite end caps are secured to opposite ends of the filter media. A support structure supports the filter media and is operably oriented in the interior volume. The support structure extends from the first opposing interior face to the second opposing interior face. The support structure is provided to extend less than a full extension between the first end cap and second end cap.

Abstract: A volatile liquid vapor recovery system is used to recover vapors produced in the loading of shipping vehicles with volatile liquid product from a storage tank. The recovery system uses a primary vessel with an adsorption bed for adsorbing the volatile liquid vapors and venting clean air including oxygen to the atmosphere. The recovery system regenerates the adsorption bed by recovering the volatile liquid vapors from the adsorption bed and directly delivering said vapors to the storage tank. The system may be adapted to remove oxygen from the primary vessel prior to regeneration, such as by purging and venting the primary vessel with a purge gas or by providing a secondary vessel to receive oxygen and vapors from the primary vessel prior to regeneration of the first adsorption bed. Adsorbed volatile liquid vapor from the secondary vessel can be recycled to the primary vessel for conservation.

Abstract: An absorption type carbon dioxide removal/concentration apparatus has a honeycomb rotor which holds an amine support solid absorbent. The honeycomb rotor is divided into at least a processing zone and a reproduction zone. An enthalpy (temperature and humidity) adjustment device is provided for the air for reproduction and/or the air to be processed. The apparatus can control the carbon dioxide absorbing performance and the concentration performance by passing processing and reproduction air through the corresponding zones. The absorption type carbon dioxide removal/concentration apparatus can remove or condense carbon dioxide, can secure high recovery efficiency and can prevent a thermal deterioration of the amine absorbent to extend the life-span of the apparatus.

Abstract: Carbon dioxide is separated from flue gas by scrubbing the gas with an aqueous solution of ammonia and salt, and the CO2 is therefore released from the solution by heating. The scrubbing step is performed with a co-current stream of an aqueous solution of ammonia and a salt.

Abstract: A solvent system comprising a diluent and a nitrogenous base for the removal of CO2 from mixed gas streams is provided. Also provided is a process for removing CO2 from mixed gas streams using the disclosed solvent system. The solvent system may be utilized within a gas processing system.

Abstract: Disclosed herein is a system and method for sulphur-assisted carbon capture and utilization. The system includes a sulphur depolarized electrolyser (SDE) for receiving electricity, H2O and SO2 and for electrolysing the H2O and SO2 to produce hydrogen and sulphuric acid (H2SO4), a decomposition reactor for receiving and decomposing the H2SO4 into SO3 and H2O, wherein the H2O is recycled to the SDE, a sulphur submerged combustor for converting the SO3 to SO2 and producing Sn vapor, a sulphur power plant for combusting Sn vapor to produce SO2, electricity and heat and for supplying the SO2 and the electricity to the SDE and for supplying the heat to the decomposition reactor. The hydrogen is delivered to a carbon capture and utilization facility. An optional Flue Gas Desulphurisation (FGD) regenerable system removes SO2 from flue gas, a CO2 converter generates COS, and a separator separates the COS from the flue gas.

Abstract: The present invention relates to a method for the catalytic removal of sulfur dioxide from waste gases in two reactors, wherein the first reactor is charged with an activated carbon catalyst. The method comprises: a. provision of a waste gas with a water content of less than 1 g H2O/Nm3 and an SO2 content of at least 5 ppm, b. introduction of the waste gases into a first reactor, c. catalytic conversion of the SO2 into gaseous SO3 in the first reactor by the activated carbon catalyst, wherein catalytic conversion on the activated carbon catalyst proceeds at a temperature of below 100° C., d. introduction of the prepurified waste gases from the first reactor into a second reactor, e. conversion of the SO3 with water into H2SO4 in the second reactor.

Abstract: A simple-cycle gas turbine system includes an injection system including a plurality of injection tubes that may inject a fluid into a duct of an exhaust processing system that may process exhaust gas generated by a gas turbine engine. The exhaust processing system includes a selective catalytic reduction (SCR) system that may reduce a level of nitrogen oxides (NOx) within the exhaust gas; and a mixing system positioned adjacent to the plurality of injection tubes and within the exhaust processing system. The mixing system includes a mixing module having a plurality of turbulators that may swirl the fluid, or the exhaust gas, or both, in a first swirl direction to encourage turbulent flow along an axis of the exhaust processing system and thereby facilitate mixing between the fluid and the exhaust gas.

Abstract: In place of a step of centrifugation during preparation of outer membrane vesicles (OMVs) from bacteria, the invention utilises ultrafiltration. This allows much larger amounts of OMV-containing supernatant to be processed in a much shorter time. Thus the invention provides a process for preparing bacterial OMVs, comprising a step of ultrafiltration. The ultrafiltration step is performed on an aqueous suspension of OMVs after they have been prepared from bacteria and the OMVs remain in suspension after the filtration step. The invention is particularly useful for preparing OMVs from Neisseria meningitidis.

Abstract: The present invention relates to a seawater desalination system for desalinating seawater by removing salinity from the seawater and an energy recovery apparatus which is preferably used in the seawater desalination system. The energy recovery apparatus includes a cylindrical chamber (CH) being installed such that a longitudinal direction of the chamber is placed in a vertical direction, a concentrated seawater port (P1) for supplying and discharging the concentrated seawater, a seawater port (P2) for supplying and discharging the seawater, a flow resistor (23) provided at a concentrated seawater port (P1) side in the chamber (CH), and a flow resistor (23) provided at a seawater port (P2) side in the chamber (CH).

Abstract: A technology that provides various modular biomimetic microfluidic modules emulating varieties of microvasculature in body. These microfluidic-base capillaries and lymphatic Technology modules are constructed as multilayered-microfluidic microchannels of various shapes, and aspect ratios using diverse biocompatible microfluidic polymers. Then, various semipermeable membranes are sandwiched in between these multilayered microfluidic microchannels. These membranes have different chemical, physical characteristics and MWCO values. Consequently, this design will produce much smaller dimension channels similar to human vasculature to achieve biomimetic properties like of human organs and tissues. By interchanging microfluidic-layers or the membranes various diverse modules are designed that act as building blocks for constructing various medical devices, various forms of dialysis devices including albumin and lipid dialysis, water purification, bioreactors, bio-artificial organ support systems.

Abstract: An compact hydraulic manifold for transporting shear sensitive fluids is provided. A channel network can include a trunk and branch architecture coupled to a bifurcation architecture. Features such as tapered channel walls, curvatures and angles of channels, and zones of low fluid pressure can be used to reduce the size while maintaining wall shear rates within a narrow range. A hydraulic manifold can be coupled to a series of microfluidic layers to construct a compact microfluidic device.

Abstract: A testing apparatus employs an interface module removably attached to a filter testing device. The interface module includes a first flowpath communicating with an outlet of the testing device and a housing of the filter device, a first valve disposed in the first flowpath, a second flowpath communicating with the housing of the filter device and an exhaust, a second valve disposed in the second flowpath, and an enclosure enclosing the first flowpath, the first valve, the second flowpath, and the second valve. The interface module is cleanable and/or sterilizable, and replaceable. A filter integrity testing method uses an interface module to prevent contamination of the testing device and cross-contamination of different filter devices and avoid liquid ingress into the testing device.

Abstract: The present disclosure relates to methods for producing large scale nanostructured material comprising carbon nanotubes. Therefore, there is disclosed a method for making nanostructured materials comprising depositing carbon nanotubes onto at least one substrate via a deposition station, wherein depositing comprises transporting molecules to the substrate from a deposition fluid, such as liquid or gas. By using a substrate that is permeable to the carrier fluid, and allowing the carrier fluid to flow through the substrate by differential pressure filtration, a nanostructured material can be formed on the substrate, which may be removed, or may act as a part of the final component.

Abstract: Provided is a post-formation process for preparation of a highly permeable thin film composite membranes for reverse osmosis, particularly for use with brackish water at low energy conditions. The process includes contacting a polyamide discrimination layer of a TFC membrane with a solution containing an oxidizing agent to form a treated membrane, followed by contacting the treated membrane with a solution containing a reducing agent. The resulting membrane exhibits enhanced water flux while maintaining salt rejection. Also provided are reverse osmosis membranes prepared in accord with the method, and modules containing the highly permeable thin film composite membranes, and methods of purifying water using the membranes or modules.

Abstract: A biological fluid separation device adapted to receive a biological fluid sample having a first portion and a second portion is disclosed. The device includes a housing having a first chamber having a first chamber inlet for receiving the biological fluid sample therein and a first chamber outlet. The housing has a second chamber having a second chamber inlet and a second chamber outlet, and a separation member separating at least a portion of the first chamber outlet and the second chamber. The separation member is adapted to restrain the first portion of the biological fluid sample within the first chamber and to allow at least a portion of the second portion of the biological fluid sample to pass into the second chamber. An actuator, such as a vacuum source, draws the biological fluid sample into the first chamber and the second portion into the second chamber.

Abstract: An anion exchange membrane is made by mixing 2 trifluoroMethyl Ketone [nominal] (1.12 g, 4.53 mmol), 1 BiPhenyl (0.70 g, 4.53 mmol), methylene chloride (3.0 mL). trifluoromethanesulfonic acid (TFSA) (3.0 mL) to produce a pre-polymer. The pre-polymer is then functionalized to produce an anion exchange polymer. The pre-polymer may be functionalized with trimethylamamine in solution with water. The pre-polymer may be imbibed into a porous scaffold material, such as expanded polytetrafluoroethylene to produce a composite anion exchange membrane.

Abstract: A static mixer includes at least one flow inverter baffle. The flow inverter baffle includes a first dividing panel to divide the fluid flow into a first flow portion adjacent a first side of the first dividing panel and a second flow portion adjacent a second side of the first dividing panel. The flow inverter baffle also includes a dividing element to divide the second flow portion into first and second perimeter flow portions. Additionally, first, second and third inversion elements to invert the flow layers of the at least two components by shifting the fluid flow to a different portion of a flow cross-section within the mixer while maintaining the general orientation of the flow layers as the fluid flow moves progresses through the flow inverter baffle. The flow inverter baffle also reduces backpressure by limiting the total amount of movement to cause the inversion.

Abstract: A vane for an impeller of an agitator for mixing or agitating a process fluid includes a socket for mounting the vane to an impeller and a blade for mixing or agitating the process fluid, the blade being connected to the socket, the blade having a leading edge, a trailing edge, and a blade tip extending from the leading edge to the trailing edge at the end of the blade facing away from the socket, and the blade having a height and a width. The height is the maximum distance of the blade tip from the socket and the width is the distance of the leading edge from the trailing edge. The blade has a maximum width that is at least 55 percent.

Abstract: The unique shape of the helical beater described herein not only achieves higher mixing performance but also power efficiency. By using high strength plastics instead of metal, the improved helical beater design described herein will lower or fix material and manufacturing costs and will provide a better method of controlling the geometry of the beater body.

Abstract: The invention relates to an agitator for mixing of fluids with different viscosities, wherein the agitator has a main shaft rotatable about an axis of rotation and paddles supported by the main shaft, each paddle comprising a paddle shaft extending at an angle relative to the axis of rotation of the main shaft ranging between 20° and 40°, and the paddles being arranged around the main shaft spaced by an angle of 90° relative to one another, and the paddles with the agitator being rotatable about the axis of rotation of the main shaft and also about the respective paddle shaft axis, wherein a radial first distance of the paddle shaft axes relative to the axis of rotation at a lower end of the paddle shafts facing away from the main shaft is larger than a radial second distance of the paddle shaft axes relative to the axis of rotation at an upper end of the paddle shafts facing the main shaft.

Abstract: An ultrasonic mixing reactor configured for mixing of plant nutrients for greater absorption using cavitation. The reactor includes a venturi nozzle fluidly connected to a nozzle device having at least one annular shaped plate comprised of a plurality of apertures constructed and arranged to create cavitation. The nozzle device is fluidly coupled to a first ultrasonic reactor having a plurality of variable frequency ultrasonic transducers mounted within the first ultrasonic reactor for generating acoustic cavitation of the bulk mixed plant nutrients. The first ultrasonic transducer is fluidly connected to a second ultrasonic reactor having a plurality of variable frequency ultrasonic transducers mounted within the second ultrasonic reactor for generating acoustic cavitation of the bulk mixed plant nutrients. The second ultrasonic reactor discharge is fluidly coupled to a plate static mixer constructed and arranged to create hydrodynamic mixing.

Abstract: A mixing assembly includes a container having a wall that defines an interior chamber within which a product to be mixed is received. A mixing structure is received within the interior chamber and mixes the product. The mixing structure has a body portion that extends along a body axis between a first end of the body portion and a second end of the body portion. The first end of the body portion has a first cross-sectional size. The second end of the body has a second cross-sectional size that is larger than the first cross-sectional size. The body portion has a wall that extends helically about the body axis between the first end and the second end. The wall defines a channel that extends helically about the body axis between the first end and the second end.

Abstract: The present invention provides subsurface irrigation systems and air injection mechanism and microbubble generating mechanism. The systems of the present invention are operable to provide an evenly distributed air microbubbles in a stream of fluid (e.g., subsurface irrigation water) to evenly provide gas therein (e.g., oxygen for plants receiving the irrigation water along an entire length of an irrigation line). The microbubble generating mechanism may use pressure generated from flow of fluid to cavitate the fluid and thereby distribute gas microbubbles in the fluid. In irrigation examples, the resulting air infused water delivers an effective amount of oxygen to the roots of the irrigation crops.

Abstract: A storage and mixing system for pasty two-component polymethyl methacrylate bone cements comprises a tubular cartridge having a cylindrical inner chamber, a dispensing plunger that is axially displaceable in the inner chamber of the cartridge, a partition disposed axially in the tubular cartridge, and a cartridge head which closes one end of the tubular cartridge. The cartridge head has a slot-shaped opening, wherein the partition protrudes from the inner chamber of the cartridge through the slot-shaped opening of the cartridge head, wherein the partition divides the cylindrical inner chamber of the cartridge bounded by the dispensing plunger and the cartridge head into two cavities that are spatially separated from one another.

Abstract: A system for transferring additive particles comprising: the additive particles; a storage container; and a surface modification agent, wherein at least some of the additive particles are treated with the surface modification agent, and wherein the surface modification agent reduces an amount of dust that is produced during transfer of the additive particles into the storage container, from the storage container, or into and from the storage container. A method of reducing an amount of dust produced during transfer of additive particles comprising: treating at least some of the additive particles with a surface modification agent; storing the additive particles; and transferring the additive particles prior to and after storage, wherein the surface modification agent reduces the amount of dust produced during at least one of the transfers of the additive particles.

Abstract: Provided is an oxidation reactor capable of oxidizing hydrocarbons with both good reaction efficiency and good energy efficiency. This oxidation reactor includes a liquid inlet channel, a gas inlet channel, a gas-liquid mixing unit, and a flow reactor. Through the liquid inlet channel, a liquid containing a reaction substrate hydrocarbon is introduced. Through the gas inlet channel, a gas containing oxygen and ozone is introduced. The gas-liquid mixing unit mixes the liquid introduced from the liquid inlet channel with the gas introduced from the gas inlet channel. In the flow reactor, an oxidation catalyst is immobilized or packed. In the oxidation reactor, the flow reactor includes a monolith support and the oxidation catalyst immobilized to or packed in the monolith support. In addition or alternatively, the gas-liquid mixing unit includes a microbubble generator.

Abstract: A heat insulation material is provided that is produced by drying a fibrous matrix impregnated with a solution of pseudo-peptides of formula (I), wherein: R is a side-chain of a natural or synthetic amino acid , R1 is either a linear or branched (C1-C3)alkyl group, or a linear or branched (C1-C3)alcoxy group, or an aryl group, or an aryl(C1-C3)alkyl group, or an aryloxy group, or a saturated or unsaturated heterocycle, n=1 or 2, and A is an aromatic or heteroaromatic group with at least one cycle.

Abstract: A module for emitting radiations for curing and/or drying curable/dryable treatments like paints or glue applied on products includes a UV LED, emitting between 200 and 400 nm, or one IR LED, emitting between 600 and 1400 nm; a control circuit of the UV or IR LED; a supply circuit; a control circuit of the module; and a sensor detecting the product to be cured/dried.

Abstract: Disclosed is a method of modifying a metal-organic framework (MOF), the modified MOF, and methods for using the same. The method of modification can include heating a mixture comprising an azide compound and a MOF to generate a nitrene compound and nitrogen (N2) from the azide compound and covalently bonding the nitrene compound to the MOF to obtain the modified MOF.

Abstract: A transformer oil moisture removing apparatus and fabric may he provided. At least one piece of the fabric may be inserted in a transformer such that it is in contact with the transformer oil. The fabric may chemically interact with the oil to remove water and moisture. The fabric may not affect the electrical insulation and cooling properties of the transformer oil. The fabric may be in a transformer for the duration of the transformer's life.

Abstract: An article of manufacture has an external surface at least partly defined by a material compositionally comprising a polymeric hydrogel that takes up water when wetted. The hydrogel-containing material is effective in reducing soil accumulation on, and/or for reducing soil adhesion to, an article designed for a variety of uses, such as transportation, vehicle safety, storage, recreation, leisure, waste disposal, construction, gardening, or traffic control.

Abstract: The invention relates to a process for regeneration of an adsorber (A) by contact with a stream (S1), wherein the stream (S1) is heated in advance by at least two heat exchange units (HEU1) and (HEU2). As outflow of the adsorber (A) a stream (S2) is obtained, which is passed through at least two heat exchange units (HEU1) and (HEU2) traversed by stream (S1), wherein the temperature of stream (S2) fed into each heat exchange unit is higher than the temperature of stream (S1) fed into the heat exchange units (HEU1) and (HEU2), in order to directly transfer heat from stream (S2) to stream (S1).

Abstract: A silica particle includes a silica particle body and a titania coating layer formed on a surface of the silica particle body through a reaction of a titanium compound having a structure in which a hydrocarbon group bonds to a titanium atom through an oxygen atom. The silica particle has absorption at a wavelength of about 400 nm or more and about 800 nm or less in an ultraviolet-visible absorption spectrum.

Abstract: Disclosed are methods for making monolithic carbon materials as single bodies containing networks of pores in the mesopore and macropores that incorporate nanoparticles of various metals and metal oxides. The disclosed methods have the advantage that such single bodies can be made by mixing the carbon precursors and metal salts together in a single pot followed by appropriate processing. The materials produced are particularly suitable for use as heterogeneous catalysts, particularly in fixed bed and monolithic reactors.

Abstract: The invention concerns a process for preparing a catalyst comprising at least one metal M from the platinum group, tin, a phosphorus promoter, a halogenated compound, a porous support and at least one promoter X1 selected from the group constituted by gallium, indium, thallium, arsenic, antimony and bismuth. The promoter or promoters X1 and the phosphorus are introduced during one or more sub-steps a1) or a2), the sub-step a1) corresponding to synthesis of the precursor of the main oxide and sub-step a2) corresponding to shaping the support. The tin is introduced during at least one of sub-steps a1) and a2). The product is dried and calcined before depositing at least one metal M from the platinum group. The ensemble is then dried in a stream of neutral gas or a stream of gas containing oxygen, and then is dried. The invention also concerns the use of a catalyst obtained by said process in catalytic reforming or aromatics production reactions.

Abstract: The invention relates to Cu—Al—Mn shaped catalyst bodies in extruded form, and to a process for their preparation. The shaped catalyst body is suitable for the hydrogenation of organic compounds containing a carbonyl function, in particular for the hydrogenation of aldehydes, ketones and carboxylic acids and/or their esters. In particular, the shaped catalyst body is suitable for the hydrogenation of fatty acids or their esters, such as fatty acid methyl esters, to form the corresponding alcohols and dicarboxylic acid anhydrides, such as maleic anhydride, or esters of di-acids and di-alcohols, such as butane diol.

Abstract: The invention relates to a process for treating a catalyst for alkane oxidative dehydrogenation and/or alkene oxidation, which catalyst is a mixed metal oxide catalyst containing molybdenum, vanadium and niobium, wherein the process comprises: contacting the catalyst with a gas mixture comprising an inert gas and oxygen (O2), wherein the amount of oxygen is of from 10 to less than 10,000 parts per million by volume (ppmv), based on the total volume of the gas mixture, at an elevated temperature.

Abstract: The present disclosure is directed to novel germanosilicate compositions and methods of producing the same. In particular, this disclosure describes an array of transformations originating from the extra-large-pore crystalline germanosilicate compositions, designated CIT-13, possessing 10- and 14-membered rings. Included among the new materials are the new phyllosilicate compositions, designated CIT-13P, new crystalline microporous germanosilicates including high silica versions of CIT-5 and CIT-13, with and without added metal oxides, and new germanosilicate compounds designated CIT-14 and CIT-15. The disclosure also describes methods of preparing these new germanosilicate compositions as well as the compositions themselves.

Abstract: A molecular sieve material, EMM-25, having in its calcined form an X-ray diffraction pattern including the following peaks: d-spacing (?) Relative Intensity [100 × I/I(o)]% 11.74-11.34 ?60-100 9.50-9.10 30-80 8.68-8.28 10-40 5.64-5.44 20-60 4.52-4.42 10-50 4.28-4.18 10-40 3.96-3.86 40-80 3.69-3.

Abstract: A lower olefin by using a zeolite catalyst, a composite catalyst capable of further extending the lifetime of catalytic activity, a method for producing the composite catalyst, a method for producing a lower olefin by using the composite catalyst, and a method for regenerating a composite catalyst in the method for producing a lower olefin are provided. The composite catalyst is a catalyst for producing a lower olefin from a hydrocarbon feedstock. This composite catalyst is constituted of a zeolite being a crystalline aluminosilicate containing gallium and iron or iron and further having a framework with 8- to 12-membered ring, and of silicon dioxide. By using the composite catalyst, a lower olefin can be continuously produced over a long period of time.

Abstract: A new family of high charge density crystalline microporous silicometallophosphate designated SAPO-79 has been synthesized. These silicometallophosphate are represented by the empirical formula of: Rp+rMm+ExPSiyOz where M is an alkali metal such as potassium, R is an organoammonium cation such as diethyldimethylammonium and E is a trivalent framework element such as aluminum or gallium. The SAPO-79 family of materials represent the first alkali-stabilized phosphate-based molecular sieves to have the ERI topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

Abstract: A new family of crystalline microporous high charge density silicometallophosphates has been synthesized. These silicometallophosphate are represented by the empirical formula of: Rp+rMm+ExPSiyOz where M is an alkali metal such as potassium, R is any quaternary ammonium cation such as ethyltrimethylammonium and E is a trivalent framework element such as aluminum or gallium. This family of high charge density silicometallophosphate molecular sieves has catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

Abstract: A new family of crystalline microporous silicometallophosphate designated SAPO-69 has been synthesized. These silicometallophosphate are represented by the empirical formula of: Rp+rMm+ExPSiyOz where M is an alkali metal such as potassium, R is an organoammonium cation such as ethyltrimethylammonium and E is a trivalent framework element such as aluminum or gallium. The SAPO-69 family of materials represent the first phosphate-based molecular sieves to have the OFF topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

Abstract: This invention is based on the discovery that homogeneous catalysts, [Rh(C2H4)2Cl]2 and/or [Rh(COD)2][BF4], can be used to produce spinetoram in higher yields at lower catalyst loadings as compared to previous methodologies. In addition, one or more phosphorus ligand donors can also be added to further increase yields/efficiency. The methods and/or systems provided herein enable cost-effective ways to produce spinetoram in large quantity with relatively simple procedures.