Patents Issued in August 21, 2018
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Patent number: 10053575Abstract: A binder resin composition for preform production includes thermosetting resin [A], thermoplastic resin [B], and curing catalyst [C], thermosetting resin [A] containing a bifunctional epoxy resin, thermoplastic resin [B] accounting for 10 to 100 parts by mass relative to 100 parts by mass of thermosetting resin [A], and curing catalyst [C] being at least one curing catalyst selected from the group consisting of organic phosphorus compounds, imidazole, and derivatives thereof.Type: GrantFiled: July 3, 2013Date of Patent: August 21, 2018Assignee: Toray Industries, Inc.Inventors: Masanori Hirano, Nobuyuki Tomioka, Shiro Honda
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Patent number: 10053576Abstract: A method of manufacturing a thermoplastic resin for a household plumbing equipment includes: reacting an acid component including a terephthalic acid and a glycol component including a trimethylene glycol derived from a plant to form a poly trimethylene terephthalate resin as a condensation polymer of a formed glycol ester; and combining the poly trimethylene terephthalate resin with a polymethyl methacrylate resin in a mass ratio of 90:10-50:50 to form a thermoplastic resin, wherein the thermoplastic resin includes the polymethyl methacrylate resin and the polytrimethylene terephthalate resin in an amount of 80% or more by mass of a total amount of the formed thermoplastic resin.Type: GrantFiled: January 20, 2017Date of Patent: August 21, 2018Assignee: Panasonic Intellectual Property Management Co., Ltd.Inventors: Takaya Niu, Kazumasa Rokushima
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Patent number: 10053577Abstract: The invention molecularly equips polyester or polyolefin molding compositions in situ with zinc ions before extrusion, enabling direct processing of the molding compositions from the melt even at high temperatures and ensuring a long-term antibacterial action. The inventive molding compositions include at least one polyester polymer or polyolefin polymer and at least one zinc salt-organoligand complex.Type: GrantFiled: June 5, 2017Date of Patent: August 21, 2018Assignee: THUERINGISCHES INSTITUT FUER TEXTIL-UND KUNSTSTOFF-FORSCHUNG E.V.Inventors: Rüdiger Strubl, Klaus Heinemann, Frank Schubert, Ralf-Uwe Bauer, Sabine Riede
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Patent number: 10053578Abstract: A blended wax for lost wax casting comprises a blend of three or more paraffinic or similarly petrochemically derived wax cuts. Preferably each of the three or more wax cuts have a different melting point, the melting point of each wax cut differing from the melting point of another wax cut by between 3 and 6 deg. C.Type: GrantFiled: September 26, 2014Date of Patent: August 21, 2018Assignee: REMET CORPORATIONInventors: John Stanley Paraszczak, Randolph Eugene Morss, Grant Bradley
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Patent number: 10053579Abstract: A method and apparatus for preparing a plurality of coated binder units are disclosed. A coated binder is divided into a plurality of coated binder units by applying a pair of dividing elements to the coated binder and applying a welding element.Type: GrantFiled: June 7, 2012Date of Patent: August 21, 2018Assignee: SHELL OIL COMPANYInventors: João Miguel De Amorim Novais Da Costa Nobrega, José António Colaço Gomes Covas, Chantal Soubigou, Eurico Filipe Dias Pessoa, Bruno Henrigue Rodrigues Barros, Catherine Rodrigues
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Patent number: 10053580Abstract: Compositions and methods of synthesizing near IR, closed chain, sulfo-cyanine dyes are provided.Type: GrantFiled: September 21, 2017Date of Patent: August 21, 2018Assignee: Intuitive Surgical Operations, Inc.Inventors: Jonathan Sorger, Jesudoss Koilpillai, Veerappan Ramesh, Kulandai raj Antony Sekar, Periyadurai Ratheshkumar
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Patent number: 10053581Abstract: The present invention relates to crumbles comprising at least one calcium carbonate-containing material, a process for the preparation of the crumbles, an article comprising the crumbles as well as an use of the crumbles in paper making, paper coating, food, plastic, preferably films, more preferably blown films or breathable films, fibres, polyvinyl chloride, plastisols, thermosetting polymers, more preferably thermosetting unsaturated polyesters or thermosetting unsaturated polyurethanes, agricultural, paint, coatings, adhesives, sealants, pharmaceuticals, agricultural, construction and/or cosmetic applications.Type: GrantFiled: May 21, 2015Date of Patent: August 21, 2018Assignee: Omya International AGInventors: Tazio Fornera, Ola Lindstrøm, Alain Cremaschi, Wolfgang Höpfl, Rolf Endre Orten
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Patent number: 10053582Abstract: The present invention relates to an installation for the purification of minerals, pigments and/or fillers and/or the preparation of precipitated earth alkali carbonate and/or mineralization of water and to the use of such an installation for the purification of minerals, pigments and/or fillers and/or mineralization of water and/or the preparation of precipitated earth alkali carbonate.Type: GrantFiled: January 24, 2013Date of Patent: August 21, 2018Assignee: Omya International AGInventors: Matthias Buri, Samuel Rentsch, Patrick A. C. Gane, René Vinzenz Blum
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Patent number: 10053583Abstract: The invention is directed to an acidic aqueous metal pretreatment solution that comprises amino-functional organosilanes, complex anions of the elements Zr, Ti, Hf and/or Si as well as oxyacids of phosphorus; a process for the treatment of metal substrates, especially selected from zinc and zinc-coated steel substrates, wherein metal pretreatment solutions of this invention are applied to reduce corrosion when applied to metal surfaces and in addition confer good adhesion properties for subsequently coated organic lacquers.Type: GrantFiled: February 4, 2016Date of Patent: August 21, 2018Assignee: Henkel AG & Co. KGaAInventors: Michael Wolpers, Jurgen Stodt, Uta Sundermeier, Qi Zhang, Junjun Wan
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Patent number: 10053584Abstract: A blend of capsaicin or other active ingredients, beeswax and a solid hydrogenated vegetable tri-glyceride is used to produce a crayon-like delivery system that is rubbed on an underwater surface to produce a durable coating that inhibits fouling.Type: GrantFiled: June 6, 2017Date of Patent: August 21, 2018Inventor: Lewis Steven Beckham
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Patent number: 10053585Abstract: The invention relates to a flame-proofed polymeric composition suitable for coating workpieces, containing a vinyl acetate-containing thermoplastic polymer and an unsaturated elastomer containing double bonds as polymeric components, wherein the polymeric components are present in the form of a homogeneous polymeric mixture, and a mixture matrix vulcanized exclusively by a sulphur or sulphur-containing crosslinking system is formed, wherein the sulphur crosslinking system extends across the entire matrix and permeates the matrix completely, and—at least one flame retardant or a combination of flame retardants. The invention further relates to articles produced therefrom, and to composite elements coated with this composition and to a method for producing the same.Type: GrantFiled: July 31, 2013Date of Patent: August 21, 2018Assignee: BATEGU Gummitechnologie GmbHInventor: Gerhard Mestan
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Patent number: 10053586Abstract: A method of applying an elastomeric coating composition to enhance or alter the aesthetic appearance of an automobile. The coating composition can be applied by spraying onto either a vehicle paint job or clear coat and is semi-permanent upon drying. The coating composition can be manually removed from the vehicle by peeling without damaging the underlying paint job or clear coat on the vehicle.Type: GrantFiled: September 27, 2017Date of Patent: August 21, 2018Inventor: Matthew Fontaine
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Patent number: 10053587Abstract: In a conductive film-forming composition including copper oxide particles, water and a dispersant selected from the group consisting of a water-soluble polymer and a surfactant, the copper oxide particles have a volume average secondary particle size of 20 to 240 nm, and the copper oxide particles are contained in an amount of 10 to 70 wt % with respect to a total weight of the conductive film-forming composition.Type: GrantFiled: July 23, 2015Date of Patent: August 21, 2018Assignee: FUJIFILM CorporationInventors: Misato Sasada, Yuuichi Hayata, Yushi Hongo, Toshihiro Kariya
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Patent number: 10053588Abstract: The present invention provides a conductive material including: (A) a ?-conjugated polymer, (B) a dopant polymer which contains one or more repeating units selected from “a1” to “a4” respectively shown by the following general formula (1) and has a weight-average molecular weight in the range of 1,000 to 500,000, and (C) one or more salts selected from the group consisting of a silver salt of carboxylic acid, a silver salt of ?-diketone, a silver salt of ?-ketoester, and silver carbonate. There can be provided a conductive material that has excellent film-formability and also can form a conductive film having high transparency and conductivity, superior flexibility and flatness when the film is formed from the material.Type: GrantFiled: October 26, 2016Date of Patent: August 21, 2018Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Jun Hatakeyama, Takayuki Nagasawa
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Patent number: 10053589Abstract: The present invention relates to a surface treatment composition for forming a self-assembled coating layer which is easily coated and removed and a surface treatment method, where the self-assembled coating layer can be easily formed because of use of a compound having the hydroxyl groups as a diol are attached to an ortho position of a benzene ring and be removed by treatment of Al3+ or Fe3+. Thus, the surface can be reused by forming a new self-assembled coating layer, thereby making the surface treatment composition be applied to various researches and industrial fields of the self-assembly coating layer which are used for reduction in metal abrasion resistance, introduction of a chemical functional group for detecting a biomolecule, the surface hydrophilicity, introduction of an antifouling property to the surface, and the like.Type: GrantFiled: November 26, 2015Date of Patent: August 21, 2018Assignee: POSTECH ACADEMY-INDUSTRY FOUNDATIONInventors: Dong Soo Hwang, Jin Hwa Heo, Dong Yeop Oh
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Patent number: 10053590Abstract: A composition for inkjet is adapted to be discharged by an inkjet method. The composition includes a metal powder having a surface, metal or metal alloy constituting at least the surface of the metal powder, an organic solvent, and a binder resin. The surface of the metal powder is modified by chemical bonding with a fluorinated silane composition and/or a fluorinated phosphate compound as a surface preparation agent.Type: GrantFiled: July 12, 2016Date of Patent: August 21, 2018Assignee: Seiko Epson CorporationInventors: Naoyuki Toyoda, Masaya Shibatani, Minoru Yamada, Tomohiro Ogawa, Hidekazu Moriyama
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Patent number: 10053591Abstract: According to the invention, there is provided an ink set which contains at least one ink selected from a group of a black pigment ink, a self-dispersing color pigment ink, and a resin-dispersion color pigment ink. The moisture quantity of the black pigment ink is from 68 mass % to 75 mass %. The moisture quantity of the self-dispersing color pigment ink is from 62 mass % to 72 mass %. The moisture quantity of the resin-dispersion color pigment ink is from 68 mass % to 75 mass %.Type: GrantFiled: May 31, 2016Date of Patent: August 21, 2018Assignee: Seiko Epson CorporationInventor: Soichi Yamazaki
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Patent number: 10053592Abstract: An ink set includes a water-based ink and a water-based cleaning liquid. The water-based ink and the water-based cleaning liquid each contain at least 1.0% by mass and no greater than 4.0% by mass of a deliquescent agent. The water-based cleaning liquid further contains a nonionic surfactant and a diol. The deliquescent agent that the water-based ink contains and the deliquescent agent that the water-based cleaning liquid contains each include at least one of sorbitol, trimethylolpropane, and 1,3-bis(2-hydroxyethyl)-5,5-dimethylhydantoin. The nonionic surfactant has an HLB value determined by Griffin method of at least 14 and no greater than 16. The diol includes at least one of triethylene glycol and 1,3-propanediol.Type: GrantFiled: October 27, 2017Date of Patent: August 21, 2018Assignee: KYOCERA Document Solutions Inc.Inventors: Noriaki Ozawa, Yasuko Takaori
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Patent number: 10053593Abstract: A starch-based release coating composition and methods of making the same.Type: GrantFiled: March 31, 2015Date of Patent: August 21, 2018Assignee: CARGILL INCORPORATEDInventors: Timothy W. Abraham, Jonas Hartman, Dogan Sahin Sivasligil, Riku Talja, Sauli Vuoti
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Patent number: 10053594Abstract: The present invention includes coating compositions having a microgel, wherein the microgel is prepared from a carboxyl functional polymer and a hybrid crosslinker system, wherein the hybrid crosslinker system has a first crosslinker having an epoxy resin and a second crosslinker having a thermally active crosslinker.Type: GrantFiled: March 11, 2014Date of Patent: August 21, 2018Assignee: Akzo Nobel Coatings International B.V.Inventor: Gary Pierce Craun
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Patent number: 10053595Abstract: A composition comprising a drag reducing latex formulation produced by emulsion polymerization to create solid particles dispersed in an aqueous medium and an additive. The use of the composition results in a decrease of film formation while injected through a pump head when compared to the drag reducing latex formulation injected through the pump head.Type: GrantFiled: November 2, 2011Date of Patent: August 21, 2018Assignee: LiquidPower Specialty Products Inc.Inventors: Ray L. Johnston, Zhiyi Bao, Richard D. Thomas, Timothy L. Burden
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Patent number: 10053596Abstract: The present invention is directed to a curable film-forming composition comprising: (a) a curing agent comprising reactive isocyanate functional groups; (b) a film-forming compound comprising functional groups reactive with the reactive isocyanate functional groups in (a); (c) a photo-latent catalyst; (d) a beta-diketone having a flash point higher than 60° C. (140° F.); and (e) a beta-diketone having a flash point lower than or equal to 60° C. (140° F.). The invention is further directed to methods of controlling the rate of cure and increasing the wet-edge time of a curable film-forming composition comprising an isocyanate functional curing agent, by adding to the curable film-forming composition a catalyst component comprising: (i) a photo-latent catalyst; (ii) a beta-diketone having a flash point higher than 60° C. (140° F.); and (iii) a beta-diketone having a flash point lower than or equal to 60° C. (140° F.).Type: GrantFiled: August 30, 2016Date of Patent: August 21, 2018Assignee: PRC-DeSoto International, Inc.Inventors: Guangliang Tang, Mikhail Khudiakov
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Patent number: 10053597Abstract: Coating compositions and methods for their preparation are described. The coating compositions can include a first copolymer produced by emulsion polymerization and derived from one or more monomers including one or more (meth)acrylates, one or more acid monomers, and optionally styrene. The first copolymer can have a Tg from ?50° C. to ?23° C. and is present in an amount of 10-50% by weight based on the total polymer content. The coating compositions can also include a second copolymer produced by emulsion polymerization and derived from one or more monomers including one or more (meth)acrylates, one or more acid monomers, and optionally styrene. The second copolymer can have a Tg from ?15° C. to 25° C. and is present in an amount of 50-90% by weight based on the total polymer content. Further described herein are dried coatings, methods for coating a substrate, and methods for producing a coating.Type: GrantFiled: January 8, 2014Date of Patent: August 21, 2018Assignee: BASF SEInventors: Luke S. Egan, Robert Michael Calhoun, Armin Burghart, Randall Petrie, Randall Brennan
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Patent number: 10053598Abstract: Siloxane-based pipe coatings include a hot melt processable siloxane-based elastomeric polymer, and may optionally contain fillers and additives. The siloxane-based elastomeric polymer is a urea-containing segmented copolymer or an oxamide-containing segmented copolymer. The coatings are substantially free of tackifying resins and are non-tacky and non-adhesive until heated to a temperature of at least 50 C.Type: GrantFiled: July 1, 2013Date of Patent: August 21, 2018Assignee: 3M Innovative Properties CompanyInventors: Baris Yalcin, Ibrahim S. Gunes, Audrey A. Sherman, Robert W. Hunter
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Patent number: 10053599Abstract: A method for polymerizing a composition including hydridosilanes and subsequently using the polymers to produce silicon containing layers, comprising the following steps: a) providing a substrate; b) providing a composition including at least one hydridosilane that is dissolved in at least one organic and/or inorganic solvent, or including at least one hydridosilane that is already present in liquid form without solvent, wherein the hydridosilanes comprise at least one linear and/or one branched hydridosilane of the general formula SinH2n+2, where n?3, and/or a cyclic hydridosilane of the general formula SinH2n, where n?3; c) polymerizing the composition from step b) by way of acoustic cavitation; and d) coating the surface of the substrate with reaction products from step c).Type: GrantFiled: November 26, 2014Date of Patent: August 21, 2018Assignee: Forschungszentrum Juelich GmbHInventor: Andrew Paolo Cadiz Bedini
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Patent number: 10053600Abstract: Multilayer product comprising at least one layer of an acrylate-based foam carrier (S); and a multiphase polymer composition (P) applied to this layer; the multiphase polymer composition (P) comprising: a comb copolymer (A) which is obtainable by polymerization of at least one (meth)acrylate monomer in the presence of at least one macromer selected from the group consisting of polymerizable ethylene-butylene, ethylene-propylene, ethylene-butylene-propylene and isobutylene macromers, and which forms a continuous acrylate phase and a discontinuous hydrocarbon phase Kw; and at least one hydrocarbon component (B) which is soluble in the hydrocarbon phase Kw of the comb copolymer (A) and comprises at least one plasticizer resin and at least one solid resin; the multiphase polymer composition (P) having a continuous acrylate phase with a static glass transition temperature Tg(Ac), measured by the DSC method, and a discontinuous hydrocarbon phase Kw1, comprising the hydrocarbon component (B) and having a staticType: GrantFiled: November 19, 2014Date of Patent: August 21, 2018Assignee: TESA SEInventors: Marten Papenbroock, Alexander Prenzel
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Patent number: 10053601Abstract: An optical adhesive product and a process for manufacturing an optical adhesive product, laminated film ensembles, and laminated lenses. The optical adhesive product includes a glyoxal water solution that is pH adjusted for use as an optical adhesive that demonstrates a wet peel force strength above about 6 Newtons. A water based polymer, such as PVOH, may be added to the adhesive system. According to the process, the glyoxal adhesive system is manufactured and utilized to laminate TAC-PVA-TAC films together to form a polar film ensemble. The polar film ensemble is laminated to an optical substrate and in the case of an ophthalmic lens, surfaced, coated and edged. The optical adhesive product avoids film separation in the polar TAC-PAV-TAC film ensemble during edging.Type: GrantFiled: August 1, 2013Date of Patent: August 21, 2018Assignee: ESSILOR INTERNATIONALInventors: Peiqi Jiang, Ronald A. Berzon, Steven Weber
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Patent number: 10053602Abstract: An adhesive composition, includes: a block copolymer (X) that includes a block (A) and a block (B), the block (A) having a glass transition point of 75° C. or higher, the block (A) including a monomer unit having a cyclic structure and a carboxyl group-containing monomer unit, the block (B) containing an acrylic acid ester unit represented by the following general Formula (1) in an amount of 70 mass % or more, the block copolymer (X) having an acid value of 8 mgKOH/g or more, in which a mass ratio of the block (A) to the block (B) (block (A)/block (B)) is 10/90 to 30/70, the block (A) is located on at least one end of the block copolymer (X), and the block (B) is sandwiched between blocks (A) at said one end of the block copolymer (X).Type: GrantFiled: September 26, 2014Date of Patent: August 21, 2018Assignee: Fujikura Kasei Co., Ltd.Inventors: Hirokazu Mogami, Masayoshi Inada
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Patent number: 10053603Abstract: A block copolymer comprising: at least one monoalkenyl arene monomer polymer block (A) and copolymer block (B) containing myrcene, said copolymer block B also including: a) at least one conjugated diene monomer having a lower molecular weight than myrcene, or b) at least one monoalkenyl arene monomer, or c) a mixture of a) and b). The polymer block A may be a copolymer block. When the polymer block A is a copolymer block, both block A and the copolymer myrcene block copolymer B can have a random, tapered or a controlled distribution configuration of comonomers. The block copolymer can be selectively or exhaustively hydrogenated. The block copolymer may be used in making adhesives and vibration damping compositions.Type: GrantFiled: April 2, 2014Date of Patent: August 21, 2018Assignee: Kraton Polymers U.S. LLCInventors: Marianne Stol, Martine Dupont
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Patent number: 10053604Abstract: A sensitive device is described including an edge of the sensitive device and a composite material sealing the edge of the sensitive device. The composite material includes a homogeneous dispersion of superficially functionalized nanozeolites in a polymerizable compound. The nanozeolites contain surface modifying organic groups belonging to the same chemical class of at least one functional group of the polymerizable compound.Type: GrantFiled: December 12, 2016Date of Patent: August 21, 2018Assignee: SAES GETTERS S.P.A.Inventors: Antonio Bonucci, Roberto Macchi, Roberto Giannantonio
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Patent number: 10053605Abstract: A fastening system for fixing an object on a base includes a first receptacle storing an aerobic adhesive and includes an associated first withdrawal device. A second receptacle, separate from the first receptacle, stores a free-flowing substance and includes an associated second withdrawal device. The first withdrawal device is configured to generate an aerobic adhesive layer with a height profile on the base. The second withdrawal device is configured to generate a surface layer of the free-flowing substance on the layer of aerobic adhesive with height profile to form a layer, whereby volumetric incorporations or inclusions of the free-flowing substance are formed in the aerobic adhesive when the object is pressed onto the layer structure.Type: GrantFiled: January 17, 2012Date of Patent: August 21, 2018Assignee: GLABETE GMBHInventor: Angelika Ortwein
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Patent number: 10053606Abstract: Compositions comprising thiol-terminated polythioether prepolymers, polyepoxides and non-chromate corrosion inhibitors suitable for use in aerospace sealant applications are disclosed. Sealants prepared using the compositions adhere to a variety of aerospace substrates following exposure to aerospace fluids.Type: GrantFiled: October 26, 2015Date of Patent: August 21, 2018Assignee: PRC-DeSoto International, Inc.Inventors: Bruce Virnelson, Adam Stott, Sean Manion, Brian Bertino, Nagarajan Srivatsan
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Patent number: 10053607Abstract: A working fluid for heat cycle, which has less influence over the ozone layer, has less influence over global warming, and has favorable cycle performance, is provided. The working fluid contains trifluoroethylene and difluoroethylene and the proportion of the difluoroethylene is less than 1.5 mass % based on the working fluid.Type: GrantFiled: September 10, 2015Date of Patent: August 21, 2018Assignee: Asahi Glass Company, LimitedInventors: Mai Hashimoto, Masato Fukushima, Satoshi Kawaguchi, Tomoaki Taniguchi, Yu Takeuchi
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Patent number: 10053608Abstract: A method of fabricating a ceramic component includes processing a hybrid matrix blend formed of a ceramic precursor and a glass powder to form a hybrid matrix composite component. A polymer-derived ceramic component including a hybrid matrix composite formed of a hybrid matrix blend including at least one of a ceramic precursor and a conversion char, and a glass powder.Type: GrantFiled: January 6, 2017Date of Patent: August 21, 2018Assignee: United Technologies CorporationInventors: Wayde R. Schmidt, Paul Sheedy, Neal Magdefrau
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Patent number: 10053609Abstract: Provided herein is a dispersion composition comprising a blend of a semi-crystalline, selectively hydrogenated block copolymer and a low polarity fluid for oilfield applications. The block copolymer comprises blocks of semi-crystalline hydrogenated polybutadiene, blocks of poly(mono alkenyl arenes), and blocks of hydrogenated, non-crystalline conjugated dienes. The dispersions can be converted to thixotropic fluids or cohesive gels and find application as insulating packer fluids, fluid loss pills, drilling fluids and completion fluids.Type: GrantFiled: June 7, 2016Date of Patent: August 21, 2018Assignee: Kraton Polymers U.S. LLCInventors: Robert C. Bening, Erin Murphy, Carl L. Willis
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Patent number: 10053610Abstract: Antifreeze proteins having an ice-binding site, such as those derived from the Marinomonas primoryensis bacterium, may be used in additive compositions, fluid compositions, and methods for depressing the freezing point of the fluid compositions. The fluid composition may include the antifreeze protein and a base fluid, such as drilling fluids, servicing fluids, production fluids, completion fluids, injection fluids, refinery fluids, and combinations thereof.Type: GrantFiled: March 20, 2017Date of Patent: August 21, 2018Assignee: Baker Hughes, a GE company, LLCInventors: Charles David Armstrong, Qi Qu
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Patent number: 10053611Abstract: A method includes adding a clay to water to form a suspension of clay in water, the clay including pieces of clay having an average diameter of at least 2 ?m; adding a dispersant to the suspension of clay in water to form a drilling fluid; and injecting the drilling fluid into a well. In the drilling fluid, the dispersant interacts with the clay to form nanoscale particles of clay having an average diameter of less than 500 nm.Type: GrantFiled: March 22, 2016Date of Patent: August 21, 2018Assignee: Saudi Arabian Oil CompanyInventors: Abdullah Saleh Hussain Al-Yami, Vikrant Bhavanishankar Wagle, Ziad Abdullrahman Saleh AlAbdullatif, Faramak Almassi, Abdulaziz S. Bubshait, Ali Mohammed Hussain Al Safran
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Patent number: 10053612Abstract: The present disclosure relates to a liquid agent that mitigates shrinkage of cement, particularly cement used in a hydrocarbon-producing well. The anti-shrinkage agent includes a slow-setting calcium aluminate cement as well as gypsum and may exhibit shelf-life stability, physical stability, or both. The present disclosure further relates to methods of cementing a hydrocarbon-producing well using the anti-shrinkage agent and to cements containing the anti-shrinkage agent.Type: GrantFiled: November 7, 2014Date of Patent: August 21, 2018Assignee: Halliburton Energy Services, Inc.Inventors: Kyriacos Agapiou, Cody Glenn Harris, Samuel J. Lewis, Thomas Jason Pisklak
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Patent number: 10053613Abstract: A subterranean formation sealant includes a mixture of an aqueous colloidal dispersion including silica nanoparticles and a C6-C12 fatty acid. Heating the sealant above 70° C. initiates gelation of the sealant. Sealing an opening in a water or gas producing zone in a subterranean formation includes providing a sealant including a mixture of a colloidal dispersion including silica nanoparticles and a C6-C12 fatty acid to the water or gas producing zone, initiating gelation of the sealant in situ, and solidifying the sealant in the water or gas producing zone to yield a set gel, thereby sealing the opening in the water or gas producing zone.Type: GrantFiled: May 2, 2017Date of Patent: August 21, 2018Assignee: Saudi Arabian Oil CompanyInventors: Rajendra Arunkumar Kalgaonkar, Vikrant Bhavanishankar Wagle, Jin Huang, Abdullah Saleh Hussain Al-Yami
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Patent number: 10053614Abstract: A cleanup fluid for reducing a viscosity of a residual viscous material in fractures of a hydrocarbon-bearing formation is disclosed. The cleanup fluid includes an acid precursor, the acid precursor operable to trigger an exothermic reaction component and the exothermic reaction component operable to generate heat, where the heat is operable to reduce a viscosity of the residual viscous material to create a reduced viscosity material, the reduced viscosity material operable to flow from the fractures.Type: GrantFiled: July 8, 2016Date of Patent: August 21, 2018Assignee: Saudi Arabian Oil CompanyInventors: Ayman R. Al-Nakhli, Hazim H. Abass, Ahmad S. Al-Otaibi
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Patent number: 10053615Abstract: Methods of delivering a low density solvent into a wellbore include combining an oleaginous solvent and a nonoleaginous fluid to form an emulsion, and injecting the emulsion into a wellbore. Other uses of low density solvent systems may include dissolving waxes and wax-containing residues in a wellbore, on downhole tools, from sand screens, or use in general cleanup operations in and outside of the wellbore.Type: GrantFiled: September 18, 2014Date of Patent: August 21, 2018Assignee: M-I L.L.C.Inventors: Matthew Offenbacher, Balkrishna Gadiyar
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Patent number: 10053616Abstract: A method for increasing production in a liquid hydrocarbon reservoir formation comprising the steps of introducing a nanoencapsulated composition solution capable of reducing the surface tension of a liquid hydrocarbon fraction, where the nanoencapsulated composition solution comprises a nanocapsule and a carrier fluid, such that the nanocapsule is dispersed in the carrier fluid; allowing the nanoencapsulated composition solution to interact with the liquid hydrocarbon fraction such that the surface tension of the liquid hydrocarbon fraction is reduced such that at least a portion of the liquid hydrocarbon fraction is capable of being displaced; introducing a water fraction into the wellbore under conditions such that at least a portion of the liquid hydrocarbon fraction is displaced from the liquid hydrocarbon reservoir formation; and recovering the at least a portion of the liquid hydrocarbon fraction and at least a portion of the nanoencapsulated composition solution using the wellbore.Type: GrantFiled: April 8, 2016Date of Patent: August 21, 2018Assignee: SAUDI ARABIAN OIL COMPANYInventor: Yun Chang
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Patent number: 10053617Abstract: A method of reducing the viscosity of a viscosified fluid in an underground drilling operation comprising, where the introduction of a chelated transition metal catalyzes the viscosity reduction of the viscosified fluid. The chelated transition metal may be ferric methylglycinediacetate. Additionally, an uninhibited oxidizing agent, such as a peroxygen compound, may also be present in combination with the chelated transition metal to catalyze the viscosity reduction of the viscosified fluid.Type: GrantFiled: April 3, 2015Date of Patent: August 21, 2018Assignee: ORIN TECHNOLOGIES, LLCInventors: Adam Mohs, Marc Baures, Larry Kinsman
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Patent number: 10053618Abstract: Methods for treating a shale formation may include injecting a pad fluid including a shale stabilizing agent into a shale formation to generate one or more fractures. The method may also include injecting a fracturing slurry including proppant particulates into the one or more generated fractures such that the proppant particulates form microfractures along shale fracture faces. At least a portion of the proppant particulates may be at least partially coated with at least one oxidizing agent.Type: GrantFiled: March 13, 2014Date of Patent: August 21, 2018Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Corneliu Stanciu, Jesse Clay Hampton
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Patent number: 10053619Abstract: A well treatment additive includes a siloxane surfactant, a solvent and an aqueous phase. The solvent, in some embodiments, is a terpene hydrocarbon. Also disclosed is a method for using the well treatment additive to form and enhance the properties of foams useful for the treatment of oil and gas wells. Methods of using the novel well treatment foams include using the additives in a variety of well treatment processes including, but not limited to, acidizing operations, hydraulic fracturing operations, well remediation operations and water removal operations.Type: GrantFiled: September 17, 2014Date of Patent: August 21, 2018Assignee: Flotek Chemistry, LLCInventors: Hasnain Saboowala, Randal M. Hill
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Patent number: 10053620Abstract: The material for proppant and method for producing the same relate to the chemistry of high-molecular weight compounds, and more particularly, to polymer materials with high requirements for physical and mechanical properties, for instance, for the production of proppants, i.e., propping granules, used in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant material providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The method consists in the following. A mixture of oligocyclopentadienes is obtained by heating dicyclopentadiene (DCPD) to a temperature of 150-220° C. and holding at this temperature for 15-360 minutes. The oligomerization of dicyclopentadiene occurs. The mixture of oligomers is cooled down to 20-50° C.Type: GrantFiled: May 13, 2014Date of Patent: August 21, 2018Assignee: OTKRYTOE AKTSYONERNOE OBSCHESTVO “ROSNEFT OIL COMPANY”Inventors: Vladimir Vladimirovich Afanasiev, Sergey Anatolievich Alkhimov, Nataliya Borisovna Bespalova, Egor Vladimirovich Shutko, Tatyana Modestovna Yumasheva
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Patent number: 10053621Abstract: A method of treating a subterranean formation includes providing capsules comprising at least one of a mineral acid, a Lewis acid, a hydrolysable acid precursor, and mixtures thereof; providing a carrier fluid; placing the capsules and the carrier fluid into a zone in a shale formation, the zone comprising fractures; allowing the capsules to at least partially dissolve. Upon the hydrolysis of the acid, etching of the faces of the fractures occurs.Type: GrantFiled: July 18, 2014Date of Patent: August 21, 2018Assignee: Halliburton Energy Services, Inc.Inventors: Lucas Fontenelle, Enrique Antonio Reyes, Eli Allen Schnoor, Dandan Hu
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Patent number: 10053622Abstract: A composition can include a first moiety capable of being excited to an excited state, and a second moiety capable of accepting excited state energy from the first moiety. The second moiety is capable of emitting light with a FWHM of 15 nm or less when excited. The second moiety can be a J-aggregate and the first moiety can be a semiconductor nanocrystal.Type: GrantFiled: July 4, 2013Date of Patent: August 21, 2018Assignee: MASSACHUSETTS INSTITUTE OF TECHNOLOGYInventors: Jonathan E. Halpert, Jonathan Tischler, Moungi G. Bawendi, Vladimir Bulovic
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Patent number: 10053623Abstract: A scintillator can include a monocrystalline compound having a general formula Na(1-y)LiyX, where 0<y<1 and X is at least one halogen or any combination of halogens. In an embodiment, the scintillator can have a Pulse Shape Discrimination Figure of Merit of at least 1 at a temperature of 25° C., at a temperature of 150° C., or both.Type: GrantFiled: March 30, 2017Date of Patent: August 21, 2018Assignees: SAINT-GOBAIN CERAMICS & PLASTICS, INC., SAINT-GOBAIN CRISTAUX & DETECTEURSInventors: Kan Yang, Julien LeJay, Samuel Blahuta, Vladimir Ouspenski
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Patent number: 10053624Abstract: A scintillation crystal can include Ln(1-y)REyX3, wherein Ln represents a rare earth element, RE represents a different rare earth element, y has a value in a range of 0 to 1, and X represents a halogen. In an embodiment, RE is Ce, and the scintillation crystal is doped with Sr, Ba, or a mixture thereof at a concentration of at least approximately 0.0002 wt. %. In another embodiment, the scintillation crystal can have unexpectedly improved linearity and unexpectedly improved energy resolution properties. In a further embodiment, a radiation detection system can include the scintillation crystal, a photosensor, and an electronics device. Such a radiation detection system can be useful in a variety of radiation imaging applications.Type: GrantFiled: September 20, 2017Date of Patent: August 21, 2018Assignee: SAINT-GOBAIN CERAMICS & PLASTICS, INC.Inventors: Peter R. Menge, Vladimir Ouspenski