Abstract: An industrial air filtration system and associated filter element are provided. The system includes a filter cage which supports its associated filter element or elements. The filter element or elements seal directly against upper and lower plates of the filter cage. Further, the system includes a liquid collection region and a sump region in fluid communication with the liquid collection region. The aforementioned regions are arranged to drain away liquid which coalesces within the system during operation.

Abstract: An antenna including an antenna electrode that transmits or receives microwaves, and a covering layer that supports an oxidation catalyst, that is formed from an inorganic material, and that covers the antenna electrode.

Abstract: A dust collector provided with a shunt guide plate includes a main body, a filter drum, a dust collecting barrel and an induced draft device. A cover plate is fixed between the main body and the dust collecting barrel, having a central portion bored with an insert hole corresponding to the main body, and a guide plate is transversely disposed under the cover plate. Thus, the induced draft device is started to absorb airflow with dust into the main body and, when passing through the insert hole of the cover plate, the airflow will be stopped by the guide plate and forced to flow through two sides of the guide plate to form a shunt effect. Thus, when airflow gets into the dust collecting barrel, the dust in the dust collecting barrel will not be affected to rise, enhancing dust collecting effect of the dust collecting barrel.

Abstract: An air cleaning apparatus with a moist filter is disclosed. More particularly, the present invention relates to an air cleaning apparatus with a moist filter, being operated such that: water stored in a bottom reservoir tank flows upward in a centrifugal manner; water molecules are finely cleaved in a microfine state and injected through multiple injection holes in the same centrifugal manner to become moist; under such conditions, water flowing into a rotational column, to which a centrifugal force is applied, is filtered while circulating a cycle wherein external air inflowing through air input holes formed below a moist layer is adhered to water molecules in the moist layer and drops down, thereby enabling ultrafine dust as well as fine dust to be filtered with high efficiency and excellent economic advantage.

Abstract: The present invention relates to a method for reducing a flow of soil air to the indoor air in a building (1), wherein the building comprises at least one wall (2), which wall comprises a permeable channel (23) connected with soil air, wherein the method comprises achieving a flow stop (24) for the soil air in the permeable channel (23). The invention also pertains to a device to reduce the flow of soil air to indoor air in a building (1).

Abstract: A gas feedstock input is provided to accurately supply a hydrogen source from an input gas feedstock supply. The gas input feedstock will be used for the selective absorption graphene cartridge filter process for the production of 99.9% purity hydrogen gas. The gas feedstock filtration science has shown increases in the concentration of hydrogen at the graphene filter output and that this certified hydrogen production can be used in today's fuel cell technologies, transportation, power plants, and space propulsion technologies, as well as, other technologies. The proposed invention expects the unique hydrogen gas graphene cartridge filter device to be used with any gas input feedstock that contains hydrogen to deliver the purest hydrogen gas of atomic size 1 to 2 Angstroms.

Abstract: An air treatment system for at least partially removing at least one gaseous contaminant contained in indoor air of a room structured for human occupants. The system may comprise an air treatment assembly having an indoor air inlet configured to receive indoor airflow directly from a room, a regenerable adsorbent material configured to adsorb at least one gaseous contaminant contained in the indoor airflow, at least one airflow element for directing the indoor airflow to flow through the air treatment assembly, an indoor air outlet for expelling the indoor air, from the air treatment assembly back into the room, a purge air inlet configured to receive and direct purge air over and/or through the adsorbent material for removal of at least a portion of the at least one gaseous contaminant, and a purge air outlet for expelling the purge air out of the air treatment assembly.

Abstract: Embodiments of the present disclosure are directed to a method for reducing radon contained in indoor air from an indoor area. In some embodiments, indoor air containing radon from indoor air is directed through at least one layer of an adsorbent medium configured for capturing radon from air. In some embodiments, the indoor air is directed through the adsorbent medium at a predetermined flow-rate such that the fraction of radon captured in a single pass though the assembly is very low, approximately 10% or less of the concentration of radon in the incoming air. The low capture rate is offset by multiple passes of the air through the medium.

Abstract: Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve using a selectivation agent to selectivate the adsorbent material. The selectivation agent may be utilized with the swing adsorption process as an in-situ process. The adsorbent material may be utilized for swing adsorption processes to remove one or more contaminants from a feed stream.

Abstract: In a gas separation system, a retentate gas discharge port of a first unit U1 and a gas inlet port of a second unit U2 are connected by a retentate gas discharge line. A permeate gas discharge port of U1 and a gas inlet port of a third unit U3 are connected by a permeate gas discharge line. A feed gas mixture supply line is connected to a gas inlet port of U1. A permeate gas discharge port of U2 and the feed gas mixture supply line are connected by a permeate gas return line. A retentate gas discharge port of U3 and the feed gas mixture supply line are connected by a retentate gas return line. At least in operation, the gas permeability of U2 is higher than that of U3, and the gas selectivity of U3 is higher than that of U2.

Abstract: An undesirable constituent gas from the flue gas stream of a fossil fuel-fired power plant, especially carbon dioxide, CO2, which is a potent greenhouse gas, is captured in a recirculating solvent-based absorption operation such as with an amine-based solvent. The solvent is exposed to flue gases for capture of the undesirable constituent, then heated to extract captured undesirable constituent for disposal, also regenerating the gas-rich solvent to gas-lean solvent for re-use. Absorption is continuous and uses the lean solvent at a rate proportional to the combustion rate. Solvent regeneration and its associated power loading are deferred and time-shifted to periods when the plant is operating below its peak power level. At high or peak power levels, rich solvent from absorption is accumulated in a storage vessel. At off-peak times, rich solvent accumulated in the storage vessel is regenerated together with rich solvent from concurrent absorption.

Abstract: Apparatus and methods for denitrification and desulfurization of and dust removal from an FCC tail gas by an ammonia-based process. The apparatus may include a first-stage waste heat recovery system, a denitrification system, a dust removal and desulfurization system, a tail gas exhaust system, and an ammonium sulfate post-processing system. The dust removal and desulfurization system may include a dedusting tower and an absorption tower disposed separately. The top and the bottom of the absorption tower may be connected respectively to the tail gas exhaust system and the ammonium sulfate post-processing system. The absorption tower may include sequentially, from bottom to top, an oxidation section, an absorption section, and a fine particulate control section. The methods may be implemented with the apparatus.

Abstract: Apparatus and methods for desulfurization of a sulfur-oxide containing gas by treatment with ammonia containing liquids. The apparatus and methods may utilize two distinct circuits of two different ammonia containing liquids which are applied in two distinct chambers. The gas may be cooled prior to entry into the circuits. There may be fluid communication between the two circulation circuits.

Abstract: Active catalysts for the treatment of a low temperature exhaust gas stream are provided containing potassium (K) dispersed on a spinel oxide for the direct, lean removal of nitrogen oxides from the exhaust gas stream. The low temperature (from about 400° C. to about 650° C.), direct decomposition is accomplished without the need of a reductant molecule. In one example, K may be dispersed on a surface of a metal oxide support, such as NiFe2O4 spinel oxide, synthesized using wet impregnation techniques. The K/NiFe2O4 catalyst system converts nitric oxide to nitrogen gas with high product specificity, up to 100%, avoiding the production of a significant concentration of the undesirable N2O product.

Abstract: The present invention is directed toward a dialysis unit that is modular and portable, with improved functionality. In one embodiment, the dialysis system comprises a top unit that is detachably affixed to a base that comprises a reservoir for fluid storage. Among numerous other features, the portable, modular dialysis system of the present invention has improved power door locking, zoned leak detection, fluid handling, and mechanical design features that enable improved modularity.

Abstract: Biomass feedstocks (e.g., plant biomass, animal biomass, and municipal waste biomass) are processed to produce useful products, such as fuels. For example, novel systems, methods and equipment for conveying and/or cooling treated biomass are described.

Abstract: A thin film composite (TFC) forward osmosis (FO) membrane includes a porous support with surfaces having thereon a hydrophilic self-assembled monolayer. An active layer on the support is sufficiently dense to remove an ionic species from a liquid.

Abstract: A zeolite membrane composite for use in separation of a highly-permeative component through permeation from a vapor mixture or a liquid mixture comprising multiple components, the zeolite membrane composite comprising an inorganic porous support and a zeolite membrane provided thereon, wherein the zeolite membrane contains zeolite of a CHA-type aluminosilicate, and in a X-ray diffraction pattern obtained through irradiation to the zeolite membrane surface with X-ray, a peak intensity at around 2?=17.90 has a value of less than 0.5 times a peak intensity at around 2?=20.80 and a peak intensity at around 2?=9.6° has a value of 2.0 times or more and less than 4.0 times a peak intensity at around 2?=20.8°.

Abstract: A method for preparing a polygraphene membrane includes adding graphite and sodium nitrate into sulfuric acid to form a first mixture; adding potassium permanganate solution into the first mixture to form a second mixture; adding hydrogen peroxide solution to the second mixture to form a mixture including soluble manganese ions; filtering the mixture including soluble manganese ions to form an aqueous suspension; centrifuging the aqueous suspension; performing ultrasonication of the suspension to obtain graphene oxide sheets; acylating the graphene oxide sheets to prepare an acylated graphene oxide sheet; and polymerizing the acylated graphene oxide sheets to prepare polygraphene.

Abstract: A gas separation membrane includes a gas separation layer that contains the polyimide compound having the structural portion represented by Formula (1). A gas separation module includes the gas separation membrane, a gas separator includes the gas separation module, and a gas separation method is performed using the gas separation membrane. A1 and A2 represent a linking site, a hydrogen atom, a halogen atom, a carboxy group, a carbamoyl group, an acyl group, an acyloxy group, a sulfo group, a sulfamoyl group, an alkylsulfinyl group, an arylsulfinyl group, an alkylsulfonyloxy group, an alkoxycarbonyl group, a non-fluorinated alkyl group, or an aryl group. Here, at least one of A1 or A2 represents a linking site.

Abstract: A gas separation membrane includes a gas separation layer containing a polyimide compound and the polyimide compound has a repeating unit represented by Formula (I). In Formula (I), Rf1, Rf4, Rf5, and Rf8 each independently represent an alkyl group. Rf2, Rf3, Rf6, Rf7, and Rf9 to Rf16 each independently represent a hydrogen atom or a substituent, and at least one of Rf2, Rf3, Rf6, Rf7, and Rf9, . . . , or Rf16 represents a specific polar group. A represents a single bond or a divalent linking group having a specific structure. R represents a mother nucleus having a specific structure.

Abstract: A system and method of injecting a gas enriched and/or emulsified first liquid into a second liquid is disclosed. The injection can cause generation of a high density of bubbles having a mean diameter of a selected size. The mean diameter of the bubbles can be selected and varied based on the characteristics of the injection system.

Abstract: A mixing unit includes a mixing body having mixing elements that are stacked in a stacking direction and that extend in an extending direction in which the extending direction is perpendicular to the stacking direction. The mixing elements have a plurality of through holes to form a flow path therein, and are arranged such that part or all of the through holes in one of the mixing elements communicate with through holes in the adjacent mixing elements to allow fluid to be passed in the extending direction in which the mixing elements extend. The mixing unit may be employed in an agitation impeller or an adhesive dispensing unit.

Abstract: A system and a method that utilizes wet proppants when creating fracturing fluid by receiving wet fracturing sand at a surge tank, vibrating the wet fracturing sand located within the surge tank, liquefying the wet fracturing sand within the surge tank based on the vibration, and metering the liquefied wet fracturing sand from the surge tank to a blending tub.

Abstract: A nitrous oxide gas mixer includes at least one mixing chamber having at least one nitrous oxide gas connection and at least one oxygen gas connection for introduction of oxygen gas and nitrous oxide gas and at least one flow rate controller, by which a volume flow of the two gases can be respectively adjusted separately and/or together. At least one O2 emergency button is mounted to the mixing chamber for emergency flooding the mixing chamber with oxygen gas and/or with ambient air.

Abstract: A method for producing a dehydrogenated product and a coked catalyst, then introducing an oxygen-containing fluid, combusting at least a portion of the coke disposed on the catalyst in the presence of the oxygen-containing fluid to produce a decoked catalyst. An apparatus for introducing fluid into a reactor, comprising a first inlet conduit configured to convey a first gas, a second inlet conduit configured to convey a second gas, and an outlet conduit configured to convey the first gas and the second gas into a reactor, wherein there is an acute angle between a longitudinal axes of the first inlet conduit and a longitudinal axis of the second inlet conduit and an obtuse angle between a longitudinal axis of the outlet conduit and the longitudinal axis of the second inlet conduit and a pre-distributor disposed, in one embodiment on the inner surface, within the first inlet conduit is disclosed.

Abstract: Disclosed herein is a method for fabricating a flexible colloidal crystal heterostructure. The method may include applying cold plasma treatment on a top surface of a flexible polymer substrate, horizontally depositing monodispersed polystyrene colloidal particles onto the top surface of the flexible polymer substrate, and creating a vertical temperature gradient in layers of monodispersed polystyrene colloidal particles. The vertical temperature gradient may be perpendicular to the top surface and may be created by heating an opposing bottom surface of the flexible polymer substrate.

Abstract: A substrate comprising a coating of a masking material, and a plurality of discrete reaction zones onto which one or more binding agents are intended to be attached, wherein said zones are uncoated areas on the substrate.

Abstract: A solar thermochemical processing system is disclosed. The system includes a first unit operation for receiving concentrated solar energy. Heat from the solar energy is used to drive the first unit operation. The first unit operation also receives a first set of reactants and produces a first set of products. A second unit operation receives the first set of products from the first unit operation and produces a second set of products. A third unit operation receives heat from the second unit operation to produce a portion of the first set of reactants.

Abstract: The present invention discloses the Synthesis and application of MOFs/natural polymers composite beads adsorbents. To overcome the drawback of MOFs, in an embodiment, both novel MOFs/sodium alginate (MOFs/SA) and MOFs/chitosan (MOFs/CS) composite beads were prepared and characterized. Each composite beads include one or more of MIL-101 (Cr), MIL-100 (Cr), MIL-53 (Al), MIL-100 (Al), NH2-MIL-101 (Al), UIO-66, ZIF-8, ZIF-68, ZIF-67, and ZIF-9-67 nanoparticles. Adsorption of anionic contaminants onto the two composite beads was investigated and compared with pristine sodium alginate beads (SA) and chitosan beads (CS). The novel MOFs/SA beads all exhibit much higher adsorption capacity than SA beads; the novel MOFs/CS beads all exhibit much higher adsorption capacity than CS beads, which indicates that MOFs played a key role in the adsorption of anionic contaminants. The porous composite beads disclosed herein and related methods and devices may be used in adsorption technologies.

Abstract: The invention belongs to the field of chemical separation, hydrometallurgy and resource recovery and provides a method for preparing and applying of ion-keeper adsorbent. By adjusting the pH to selective oxidation to achieve the oxidation of ferrous iron into ferric iron. Separates the iron after the hydrothermal reaction; By using of ion imprint “ion keeper” effect and biomass as raw materials, to prepare the adsorbent with internal rules, hierarchical pores and high selectivity. It can be used for deep purification of chromium solution, such as iron, aluminum, vanadium and other impurities in the solution; After the deep purification of chromium solution, then adjusting the pH, adding appropriate hydrating agent, by hydrothermal precipitation treatment of chrome, filtration, acid washing and calcination to obtain chromium oxide crystal. It achieves the purification of chromium, iron, aluminum and chromium. The recycling and comprehensive utilization of waste resources are also realized.

Abstract: The polymer-supported chelating agent is polyisobutylene having a thiol-thioether terminal group. The polymer-supported chelating agent is made by reaction of the terminal carbon double bond of polyisobutylene with 1,2-ethanedithiol in a one-step click reaction, resulting in PIB functionalized with a thiol-thioether sequestering group. In use, the polymer-supported chelating agent is added to a biphasic solvent system containing a transition metal in solution for removal of the transition metal by liquid/liquid extraction. The transition metal is chelated or sequestered by the chelating agent and removed in a nonpolar organic phase, such as heptane.

Abstract: The invention provides a catalyst system comprising: a) one or more silver tungstate-containing species; and b) one or more catalytic species suitable for hydrogenation, wherein the weight ratio of said one or more silver tungstate-containing species to the one or more catalytic species suitable for hydrogenation is greater than 2.5:1, on the basis of the total weight of the catalyst system; and a process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor at a reactor temperature in the range of from 145 to 190 ° C. in the presence of a solvent and said catalyst system.

Abstract: The present disclosure generally provides catalysts, catalytic articles and catalyst systems including such catalytic articles. In particular, the catalyst composition includes a zeolite having a chabazite (CHA) crystal structure ion-exchanged with iron and copper. Methods of making and using the catalyst composition are also provided, as well as emission treatment systems containing a catalyst article coated with the catalyst composition. The catalyst article present in such emission treatment systems is useful to catalyze the reduction of nitrogen oxides in gas exhaust in the presence of a reductant.

Abstract: The present invention relates to a method for preparing an oligomerization catalyst system and the method comprises preparing a catalyst composition by mixing a PNP-based ligand compound and a transition metal compound, and mixing and activating a co-catalyst and the catalyst composition at a temperature from ?40 to 80° C. The oligomerization catalyst system prepared by the method may maintain the activity thereof during an oligomerization reaction at a high temperature, and the reaction temperature of oligomerization may be easily controlled. Various merits in processing may be obtained.

Abstract: A process for combusting coke from catalyst in partial burn mode is disclosed. The regenerator comprises two chambers. The bulk of the combustion is performed in a first chamber. Disengagement of the catalyst from gas is conducted in the second chamber. Heated gas with a low fraction of oxygen fluidizes catalyst in the second chamber.

Abstract: “DIGITAL TITRATOR”, for application in chemical instrumental analysis, comprising a transparent vertical tube (burette) (1), which contains the titrant, monitored by a contact image sensor (CIS) (2), parallel to the tube. A titrant reservoir (3) communicates with said burette, with solution transfer by means of a pump (4). The release of said solution is made by a valve (5) to the reaction flask (6), where a sensor (7) collects and transmits information about the progress of monitored reaction to a computer (8). Analytical data is stored, processed and displayed to the user on a screen, and/or printed. A flexible tube communicates the upper ends of tube and reservoir and transfers saturated internal atmosphere conversely, according as pressure change, caused by meniscus movement, without gas exchange with atmosphere, preventing evaporation of solvent and consequent changes in titrant concentration.

Abstract: The present invention relates to an assay device for determining the presence and/or amount of an analyte of interest in a sample, the assay device comprising: a) a housing that includes a liquid receiving unit that is adapted to accommodate one or more types of liquid; b) a mixing chamber adapted for containing a solution that is a product of one more types of liquid, and for receiving a sample to interact with said solution; c) an actuating lid which is capable of being actuated to enable the transfer of the liquid into the mixing chamber; and d) an assay means that is in fluid communication with said mixing chamber for determining the presence and/or amount of an analyte of interest in the sample after the interaction of said sample with said solution in the mixing chamber.

Abstract: The present invention relates to a fast, simple and very sensitive method for the detection of bacteria, comprising the steps of providing one or more suspensions each comprising at least one species of labeled test bacteriophages which specifically bind to a bacterial species to be detected; adding a sample to be tested for the presence of at least one bacterial species to be detected to the one or more suspensions; filtering the reaction mixture; detecting bacteria-bacteriophages-complexes on the surface of the filter in the retentate, provided that at least one bacterial species to be detected is present, wherein the complexes consist of bacteria of the at least one bacterial species to be detected and test bacteriophages of the at least one species of test bacteriophages bound thereto; detecting unbound test bacteriophages in the filtrate; processor-aided processing of received detection signals and output of detection results.

Abstract: Package assemblies for storing diagnostic cartridges or storing wet/dry reagents are described herein. In some embodiments, an apparatus includes a tray member defining a first volume and a second volume, and a cover member coupled to the tray member covering the first volume and the second volume. The tray member includes a central portion that separates the first volume from the second volume. The first volume is configured to receive a desiccant package and a sample container containing a first reagent. The first reagent has a solid form. The second volume is configured to receive a reagent module containing a second reagent. The second reagent has a liquid form. The cover member and the central portion of the tray member are configured to isolate the first volume from the second volume.

Abstract: A support that comprises a plate having a first side and a second side opposed to the first side. The plate has a sample section including bottle-receiving members defined in the first side and configured for holding the bottles in a fixed position relative to the plate, and first conduit-receiving openings extending from the first side to the second side for receiving conduits extending from the bottles. The plate has a manifold section including second conduit-receiving openings extending from the first side to the second side for receiving the conduits. The plate has a channel section including channels defined in the second side and extending between the first conduit-receiving openings and the second conduit-receiving openings for receiving the conduits therein. The support may be used for example on a shaker. A method for retaining bottles and conduits connected to the bottles is also discussed.

Abstract: The present disclosure relates to automated systems and methods for washing microtiter plates that offer advantages such as increased efficiency and decreased contamination during the washing process. In an exemplary embodiment, an automated system for washing multiwell plates comprises an arm having a metal portion and having a multiwell plate holder for holding a multiwell plate; a first rotational servo configured to rotate the multiwell plate about a first axis; a second rotational servo configured to rotate the arm about a second axis; and a controller configured to operate the system to dispels fluid in the multiwell plate.

Abstract: The invention relates to a device (10; 50) for mechanically comminuting materials, including a vertically extending comminuting chamber (14) having an upwardly extending supply side (15) and a downwardly extending discharge side. The comminuting chamber is enclosed by an in circular cylindrical and/or conical downwardly expanded comminuting chamber wall (12), and in which at least one rotor (16, 18) rotating about a vertical rotor axis (R) is arranged, which is provided with striking tools (38) that extend radially into the comminuting chamber, at least during operation. The rotors(16, 18) are held in a stationary manner with respect to a support base (20) of the device, and the comminuting chamber wall is supported on the support base. According to the invention, the comminuting chamber wall is held in place by way of a lifting device in the direction of the rotor axis (R) in a height adjustable manner relative to the support base (20).

Abstract: An apparatus for processing cannabis plants includes a support-frame, a hopper, a filter-tray, an oscillation means, a weighing station and a power supply. The apparatus for processing cannabis plants is useful for processing, weighing and packaging cannabis after the cannabis has flowered and is harvested.

Abstract: A sorting station is provided with a hopper, at least one conveyor belt, a deck screener, including at least one mesh screen and at least one spray bar, a chute, having a tapering form, a prep screw, a dewatering screen, wherein the deck screener is configured to have vibration applied thereto to separate a matter from a mixture of matters, and where the at least one spray bar is configured to wash the mixture of matter and further separate a selected matter from the mixture of matters. Methods of sorting a particular matter from a mixture of matters, and processes of filtering soil are also provided.

Abstract: A hand-held showerhead mounting bracket is disclosed for releasably holding a hand-held showerhead by cooperating with a hanging member located on a back side of the hand-held showerhead. The hand-held showerhead mounting bracket includes a bracket body having an entry passage for the hanging member to be inserted into the bracket body and an exit passage for the hanging member to exit the bracket body, and an assembly structure including a holding element movable between a retaining position and a release position. In the retaining position, the holding element retaining the hanging member after the hanging member is inserted into the bracket body, and in the release position, the holding element releasing the hanging member to enable the hanging member to exit the hand-held showerhead mounting bracket via the exit passage.

Abstract: Systems for and methods of simultaneously sealing a floor of an attic and ductwork in the attic with an aerosolized sealant are disclosed.

Abstract: A single or dual sided direction-controllable sprinkler comprises two rotatable trigger portions slidably disposed on a main body. When one trigger portion is limited by a fastener, the two trigger portions have the same rotational position, and when the one trigger portion is not limited by the fastener, the rotational positions of the two trigger portions are controlled independently. The fastener is selectively connected to allow the user to selectively control one of the trigger portions or both of the trigger portions together so that various water sprinkling modes are available.

Abstract: A liquid spraying device including a tank configured to store liquid, a spraying device including a discharger configured to discharge the liquid in a form of a mist, a first flow path forming part disposed between the tank and the discharger and forms a first flow path of the liquid, a pump provided midway of the first flow path, and feeds the liquid from the tank toward the discharger, and a second flow path forming part configured to form a second flow path that branches off from the first flow path at a branching position between the pump and the discharger, and returns to tank. The first flow path forming part includes a small sectional-area part between the branching position of the first flow path and the discharger, the small sectional-area part forming a flow path having a sectional area smaller than a sectional area of the second flow path.

Abstract: Container, including a body delimiting a cavity to contain fluid substance. A mobile bottom, inside the cavity, sealedly movable along the body internal wall. The body sealedly coupled to a collar having a surface resting on the body and a tubular member extending from the bottom thereof. The tubular member defining a first passage through which the fluid substance flows in use. An insert housed within the collar and formed of first and second parts, connected by a first breakable portion. A shutter housed, in a sealed manner, inside the insert and formed of first and second sections mutually connected by a second breakable portion. The second section including a surface to cooperate, in a sealed manner, with the tubular member when the second section is fitted thereon and a breakable wall which, when broken, permits access to the cavity.