Abstract: It is an object of the present invention to provide a high-gloss, heat-resistant paint composition that can form a paint film having high gloss, hiding power, heat resistance and adhesion, a method for manufacturing the same, a method for applying a high-gloss, heat-resistant paint, and a high-gloss, heat-resistant paint film. The heat-resistant paint composition is prepared by combining inorganic pigment powder having hiding power and a binder solution chiefly consisting of an alcoholic solution of polysilicon alcoxide; the binder solution containing an effective amount of aluminum ingredient; the composition contains 8˜50 wt. % of hydrophilic organic solvent having a boiling point of not less than 100° C. and not more than 220° C.; the average particle size of primary particles of the inorganic pigment powder dispersed in the binder solution being not more than 0.3 &mgr;m; and the solidified paint film obtained when the composition has been dried and baked contains not less than 60 vol.

Abstract: Silicone compositions are used for treating nonporous surfaces such as glass, porcelain, ceramic, polished or painted metal, plastic, and the like, to render them water, soil and stain repellent. Volatile organic compound (VOC) free cream, paste, powder and solid compositions are provided by the inclusion of stabilizers in the silicone compositions. Solventless silicone compositions provide numerous advantages and improved water/soil repellency qualities.

Abstract: The invention pertains to a coating material on the basis of liquid crystalline polysiloxanes which is obtained via the co-condensation of mesogenous silanes and/or polysiloxanes, that are capable of being hydrolyzed, with sols.

Abstract: An organosilane preparation, comprising a mixture of one or more organosilanes and one or more fillers, has a fines content of less than 2%.

Abstract: A composition for rendering surfaces water repellent is formed by combining water or a solvent; a methylhydrogensiloxane polymer or copolymer; an alkoxysilane having the formula RaSi(OR′)4−a in which R represents an alkyl group containing 1-10 carbon atoms, an alkenyl group containing 2-8 carbon atoms, an aryl group, or an haloalkyl group, a has a value of 1 or 2, and R′ represents an alkyl group containing 1-6 carbon atoms; and a silicone resin. The composition can also contain other components such as a volatile methyl siloxane, a cationic oil-in-water emulsion of an aminofunctional polydimethylsiloxane, a surfactant, a catalyst, a beading agent, an organic wax, a preservative, an antifoam, a mildewcide, an UV absorber/UV light stabilizer, or a freeze-thaw additive.

Abstract: A condensation curable coating composition comprises the following and any reaction product thereof: (A) a room temperature vulcanizable polyorganosiloxane composition; and (B) a marine foul release-enhancing proportion of at least one organic compatible silicone fluid free from silanol groups and being capable of blooming to the surface of a cured product of component A.

Abstract: The invention concerns a dispersion of photocatalytic titanium dioxide particles, wherein the liquid phase comprises at least a cross-linking catalyst and at least a polyorganosiloxane either of formula (I) M&agr;D&bgr;Q&dgr;(O1/2Ri)&egr;, or of formula (II): M&agr;D&bgr;T&ggr;(O1/2Ri)&egr;. The invention also concerns the use of this dispersion for treating substrates.

Abstract: A precursor composition for forming a zirconium and/or hafnium silicate film on a substrate, e.g., by chemical vapor deposition (CVD). Illustrative precursor compositions include (1) a first precursor metal compound or complex including a silicon alcoxide (siloxide) ligand coordinated to a metal M, wherein M=Zr or Hf and (2) a second precursor metal compound or complex including an aliphatic alcoxide ligand coordinated to a metal M, wherein M=Zr or Hf, wherein the relative proportions of the first and second precursors relative to one another are employed to controllably establish the M/Si ratio in the deposited silicate thin film. The precursor composition may contain a solvent medium, so that the composition is adapted for liquid delivery CVD, to form stable thin-film gate dielectrics for fabrication of microelectronic devices.

Abstract: The present invention is directed to a light-transmitting color film comprising oxides which have high chemical resistance and excellent light-absorption effect, making them available in a wide color range; a method for producing the same; and a coating solution used for forming the color film. In the light-transmitting color film comprising an oxide of an element which serves as a network former and oxides of transition metal elements serving as coloring components, the element serving as a network former is at least one selected from Si, Al, and B, and the transition metal elements comprise Cu, Mn, and Ni; and the two types of oxides form a complex oxide.

Abstract: The present invention provides a plastic cover plate for motor vehicle lights, such as motor vehicle headlights. The plastic cover plate is characterized in that the plate has, on the surface facing towards the light, a transparent coating to prevent specks from forming through the non-homogeneous deposition of dust.

Abstract: A photocatalytic titanium dioxide powder comprised of finely divided titanium dioxide particles each having supported on the surface thereof a first supported layer of a calcium compound and further having on the surface of the first supported layer-formed particles a porous second supported layer of a photocatalytically inactive and substantially water-insoluble substance. The photocatalytic titanium dioxide powder is produced by allowing a calcium compound to be supported on the surface of finely divided titanium dioxide particles to form the first supported layer; and then, allowing a precursor material capable of forming the photocatalytically inactive and substantially water-insoluble substance to be supported on the surface of the first supported layer-formed particles, followed by converting the precursor a material to said water-insoluble substance to thereby form the porous second supported layer.

Abstract: A siliceous substrate having a face which is at least partly provided with a water-repellent layer having a thickness of no greater than 5000 Angstroms, said layer being a layer of at least one fluoro aliphatic silane compound having at least one silicon atom chemically bound to the siliceous substrate and chemically bound to the silicon atom of another fluoro silane compound of the layer.

Abstract: The present invention provides a coating composition comprising: A coating composition comprising: TEOS; a surfactant; at least one organosilane; HCl; water; and ethanol. The present invention also provides films made from such a coating composition and a method for making such films.

Abstract: A sol-gel process for producing layers of zirconium oxide is described which comprises the following stages:

Abstract: A composition for film formation which is useful as an interlayer insulating film material in the production of semiconductor devices and the like, and gives a coating film having excellent uniformity, low dielectric constant, low leakage current and excellent storage stability; and a material for insulating film formation using the composition. The composition comprises (A) a product of hydrolysis and condensation obtained by hydrolyzing and condensing at least one compound selected from the group consisting of (A-1) compounds represented by the formula (1): R1aSi(OR2)4−a, and (A-2) compounds represented by the formula (2): R3b(R4O)3−bSi—(R7)d—Si(OR5)3−cR6c; and (B) a compound represented by the formula (3): R8O (CHCH3CH2O)eR9.

Abstract: The present invention provides a coating for inkjet media, which includes at least one hydrophobic filler particle; and a binder. Another embodiment of the invention provides an inkjet media, which includes the above-described coating coated on a substrate. Another embodiment of the invention provides a method of inkjet printing, which includes inkjet printing at least one inkjet ink onto a substrate coated with the above-described coating.

Abstract: The present invention provides stable epoxy silane emulsions and methods for the preparation of such compositions comprising (I) a water insoluble or slightly soluble epoxysilane; (II) an emulsifier; (III) water; and (IV) a water dispersible polymer containing a functional group with an active hydrogen. Also provided are two part systems such that an epoxysilane emulsion comprising components (I)-(III) are combined and the component (IV) may be added upon use of components (I)-(III). Moreover, additional components (V), such as catalysts and pH buffers, may be added. Such compositions may be used for, among other things, coatings, adhesives and sealants.

Abstract: A process for producing surface-sealed hollow glass containers, wherein as part of the production process the hollow glass containers are coated with a water-based cold end coating composition in the region of the exit from the annealing lehr, which is arranged following a machine for producing hollow glass containers, where the cold end coating composition comprises the following components: I. a water-based organopolysiloxane-containing composition prepared from alkoxysilanes which carry a functional group and alkoxysilanes which are selected from trialkoxysilanes, dialkoxysilanes and tetraalkoxysilanes, and II. a silicon-free component selected from a wax, a partial fatty acid ester, a fatty acid and/or a surfactant. The hollow glass containers produced in this way feature an enhanced long-term service strength.

Abstract: The invention relates to a substrate provided, on at least a portion of one of its faces, with a coating with a photocatalytic property based on titanium dioxide which is at least partially crystalline and which is incorporated in the said coating partly in the form of particles predominantly crystallized in the anatase form. The invention also relates to a process for the preparation of this substrate and organic dispersions of titanium dioxide particles used in the said process for the preparation of the substrate.

Abstract: The invention relates to a coating material comprising condensates of at least one compound (A) of the general formula RaMZb (a=0-3; b=1-4; a+b=3, 4), where R is a non-hydrolyzable organic group, and at least one compound (B) of the general formula R′xMZy(x=1-3; y=1-3; x+y=3, 4), where R is a non-hydrolyzable organic group and at least one R′ contains a perfluoro polyether structure separated from M by at least two atoms, where M is an element from the periodic table of elements selected from the main groups III-V or from the subgroups II-IV and Z is a hydrolyzable organic group, and where at least one R is not equal to at least one R′.

Abstract: A solution comprising a composition and a volatile silicone solvent overcomes the environmental disadvantages associated with volatile organic compounds. The invention particularly provides for a primer composition for bonding silicone elastomers to metals that is free of volatile organic compounds comprises an epoxy alkoxy silane, a titanium ortho alcoholate or ortho ester, a silicon ortho alcoholate or ortho ester and a volatile silicone compound.

Abstract: The present invention provides a coating composition which comprises at least one silicon compound (A) which has at least one radical which is bonded directly to Si, is not able to be separated hydrolytically and contains an epoxy group, a particulate material (B) which is selected from among oxides, oxide hydrates, nitrides and carbides of Si, Al and B and of transition metals and has a particle size within the range 1 to 100 nm, a Si, Ti, Zr, B, Sn or V compound (C) and at least one hydrolysable Ti, Zr or Al compound (D), which comprises the following ratio 1 mol of the silicon compound (A), 0.42 to 0.68 mol of the particulate material (B), 0.28 to 1.0 mol of the compound (C) and 0.23 to 0.68 mol of the compound (D).

Abstract: A curable silicone-based coating composition, curable to a flexible coating at a coat weight of up to 15 g/m2 when cured, comprises an organopolysiloxane polymer having at least two silicon-bonded olefinically unsaturated hydrocarbon substituents, alkoxy groups or hydroxyl groups and having a degree of polymerization of no more than 150, a cross-linking organosilicon material having at least 3 silicon-bonded reactive groups and a catalyst. The coating composition optionally contains non-reinforcing filler but contains no more than 3% by weight of reinforcing filler. The coating is preferably used on a textile fabric that has an elastomeric coating on it, and reduces friction. It is particularly useful for airbags.

Abstract: An ultraviolet radiation resistant coating is disclosed comprising cerium oxide in an inorganic oxide matrix formed by the hydrolysis and condensation of an organoalkoxysilanie and/or other metal alkoxide in combination with the reaction product of cerium oxide and tetraalkylsilicate.

Abstract: A curable slurry for forming ceramic microstructures on a substrate using a mold. The slurry is a mixture of a ceramic powder, a fugitive binder, and a diluent. The ceramic powder has a low softening temperature in a range of about 400° C. to 600° C. and a coefficient of thermal expansion closely matched to that of the substrate. The fugitive binder is capable of radiation curing, electron beam curing, or thermal curing. The diluent promotes release properties with the mold after curing the binder or quick and complete burn out of the binder during debinding.

Abstract: A sol-gel catalyst composition for electroless plating includes a metal alkoxide in a polar organic solvent, an acid, a chloride salt or acid chloride, and a catalytic metallic salt. The sol-gel catalyst adheres to smooth surfaces without the preconditioning normally associated with other sol-gel smooth surface catalyst, as well as a method for coating a substrate with the sol-gel catalyst composition, and then a metallic platting solution.

Abstract: The invention relates to a composition for a hydrophobic/oleophobic coating containing at least one alkoxysilane and at least one halosilane, each having a perfluorinated group at at least one end of their molecule; it also relates to a process for forming a coating of this type on a substrate, as well as to this substrate itself when provided with its coating and, in particular, monolithic, laminated or multiple glazing at least in part provided with its coating.

Abstract: The invention relates to a novel hybrid lacquer composition, which can be obtained by treating an organosilane compound with water in the presence of a polycarboxylic acid which functions both as a catalyst and as a crosslinking agent. The lacquer composition can be prepared, in a simple manner in a short period of time and has a good pot life. Lacquer coatings obtained by thermally curing the lacquer composition exhibit good optical properties as well as a good wear-resistance and chemical resistance. The lacquer composition adheres well to polar synthetic-resin substrates. Apolar synthetic resin substrates require the use of a primer, which, after it has been treated with water, yields a lacquer composition in accordance with the invention.

Abstract: A composition for rendering surfaces water repellent is formed by combining water or a solvent; a methylhydrogensiloxane polymer or copolymer; an alkoxysilane having the formula RaSi(OR′)4-a in which R represents an alkyl group containing 1-10 carbon atoms, an alkenyl group containing 2-8 carbon atoms, an aryl group, or an haloalkyl group, a has a value of 1 or 2, and R′ represents an alkyl group containing 1-6 carbon atoms; and a silicone resin. The composition can also contain other components such as a volatile methyl siloxane, a cationic oil-in-water emulsion of an aminofunctional polydimethylsiloxane, a surfactant, a catalyst, a beading agent, an organic wax, a preservative, an antifoam, a mildewcide, an UV absorber/UV light stabilizer, or a freeze-thaw additive.

Abstract: The process for simultaneously molding and rendering water-repellent molded components made of concrete, mortar, cement or the like consists, before pouring the concrete, cement or the like, in covering the interior of the mold with a composition comprising a resin which is a silicone copolymer in the absence of crosslinking agent of hydrolysable silane type and of curing catalyst in the composition. Molded component thus obtained and compositions for removing from the mold and rendering water-repellent.

Abstract: The present invention relates to a method for producing titanium oxide (TiO2)-tin oxide (SnO2) composite sol, a titanium oxide (TiO2)-zirconium oxide (ZrO2)-tin oxide (SnO2) composite sol, and a titanium oxide (TiO2)-cerium oxide (CeO2)-tin oxide (SnO2) composite sol. Further, the present invention relates to a coating composition containing any of the above-mentioned composite sols for forming coating films that are excellent in marring resistance, surface hardness, wearing resistance, transparency, heat resistance, light-resistant, weatherability, or water resistance on optical elements such as lenses for glasses and cameras, automotive windowpane, or optical filters attached to liquid-crystal displays, plasma displays, etc. and to optical elements having a cured film of the coating composition on the surfaces.

Abstract: Aqueous emulsions contain the components (A) organosilicon compounds which are selected from (A1) C1-C20-hydrocarbon-C1-C6-alkoxysilanes and (A2) branched organopolysiloxanes containing C1-C6-alkoxy groups, (B) organosilicon compounds which are selected from (B1) C1-C6-alkoxysilanes containing aminoalkyl groups and (B2) branched organosiloxanes containing aminoalkyl groups and (C) an emulsifier. The aqueous emulsions are suitable for imparting water repellency to porous mineral building materials and building coatings and to wood. .

Abstract: A highly weathering-resistant coating material exhibits an excellent water resistance and water repellency. The coating material contains a vinyl-type polymer that contains a pendant carbosiloxane dendrimer structure. The coating material is used on construction materials, buildings and structures undercoated with an organic coating material, automobiles, railroad rolling stock, ships, aircraft, and bridges, commercial and industrial plants, and electrical and electronic instruments and devices.

Abstract: An improved anti-corrosive zinc coating composition for application on a metal substrate is provided. The coating is comprised of a siloxane polymer resin in combination with zinc dust and ceramic microspheres, the microspheres having diameters of 45 microns or less. At this reduced diameter, the microspheres act as spacers for the zinc particles without interfering with the conductivity of the coating, thereby reducing the amount of zinc necessary to achieve cathodic protection of the substrate. The coating is economical to produce, provides excellent corrosion protection, and resists mud-cracking.

Abstract: An aqueous organopolysiloxane-containing composition comprising organopolysiloxanes of formula I: HO [Si(A)(CH3)z(OH)1−zO]a[Si(B)(R2)y(OH)1−yO]b[Si(C)(CH3)O]c[Si(D)(OH)O]dH.

Abstract: It is an object of the present invention to provide an aqueous dispersion and a waterproofing agent, which are of the aqueous one-component type and easy and simple to apply and have both a decorative effect and enough waterproofing effect. The aqueous dispersion of the present invention comprises an organosilicon compound (1) represented by the general formula (I): and a fluorine-containing resin (2) comprising an aqueous fluororesin dispersion, and the weight ratio, on the solid basis, between said organosilicon compound (1) and said fluorine-containing resin (2) is (organosilicon compound (1)):(fluorine-containing resin (2))=60:40 to 97:3.

Abstract: The methods of forming a chemically adsorbed film by contacting a substrate with a solution mixture containing an alkoxysilane surface active agent, a non-aqueous solvent and a silanol-condensing catalyst to form a film covalently bonded to the substrate via siloxane bonds. These methods do not generate hydrochloric acid gas in forming the films and allow practical reaction rates.

Abstract: A film for cutting off heat rays having a high transmittance and a low reflectivity of visible light, a low transmittance and a high reflectivity of near infrared radiation and a surface resistivity of at least about 106 ohms/square is formed from a coating liquid is a dispersion containing fine particles of borides having an average diameter not exceeding 100 nm. The liquid disperison is coated on a surface and heated. The dispersion may further contain fine particles of at least one ruthenium or iridium oxide having an average diameter not exceeding 100 nm.

Abstract: An antisoiling coating for an antireflective surface, particularly the outer surface of an antireflective film stack, wherein the antisoiling coating includes a fluorinated siloxane, preferably prepared by applying a coating composition of a fluorinated silane, having a number average molecular weight of at least about 1000, of the following formula: Rƒ—[—R1—SiY3−xR2x]y  (I) wherein: Rƒ is a monovalent or divalent polyfluoropolyether group; R1 is a divalent alkylene group, arylene group, or combinations thereof, R2 is a lower alkyl group; Y is a halide, a lower alkoxy group, or a lower acyloxy group; x is 0 or 1; and y is 1 or 2.

Abstract: An aqueous glass fiber sizing composition comprising at least one diol-organosilane coupling agent and at least one triol-organosilane coupling agent.

Abstract: Anti-reflective coating materials for deep ultraviolet photolithography include one or more organic dyes incorporated into spin-on-glass materials. Suitable dyes are strongly absorbing over wavelength ranges around wavelengths less than 260 nm such as 248 nm and 193 nm, that may be used in photolithography. A method of making dyed spin-on-glass materials includes combining one or more organic dyes with alkoxysilane reactants during synthesis of the spin-on-glass materials.

Abstract: An ultraviolet radiation resistant coating is disclosed comprising cerium oxide in an inorganic oxide matrix formed by the hydrolysis and condensation of an organoalkoxysilane and/or other metal alkoxide in combination with the reaction product of cerium oxide and tetraalkylsilicate.

Abstract: Objects of the present invention are to provide colored coating compositions which can form easily a colored glass gel coating film being excellent in water resistance, boiling water resistance, alkali resistance, weather resistance, etc. at low temperatures on the outer surface of glass products, metal products, etc. and to provide colored coating compositions with which colored bottles having no haze can be obtained even if the bottles are coated in a high-humidity environment. The colored coating compositions according to the present invention comprise a sol-gel liquid obtained by polycondensation of phenyltrialkoxysilane or an oligomer thereof, acryl polyol, polyester polyol, polyether polyol and/or lower alkyl polyol (or the acryl polyol, the polyester polyol and/or the polyether polyol and a polyisocyanate resin), and an organic coloring agent.

Abstract: The invention proposed is an aqueous emulsion comprising the components (A) organosilicone compositions selected from (A1) C1-C20-alkyl-C2-C6-alkoxysilanes and (A2) organopolysiloxane containing alkoxy groups, (B) organopolysiloxane containing, one or more siloxane units having SiC-bonded radicals containing basic nitrogen, with the proviso that the amine number of the organopolysiloxane is at least 0.01, and (C) an emulsifier. The said emulsions are used for making porous mineral building materials hydrophobic.

Abstract: Low surface energy functionalized surfaces on solid supports are provided by treating a solid support having hydrophilic moieties on its surface with a derivatizing composition containing a mixture of silanes. A first silane provides the desired reduction in surface energy, while the second silane enables functionalization with molecular moieties of interest, such as small molecules, initial monomers to be used in the solid phase synthesis of oligomers, or intact oligomers. Molecular moieties of interest may be attached through cleavable sites. Derivatizing compositions for carrying out the surface functionalization process are provided as well.

Abstract: A glazing made of at least one glass layer and at least one transparent layer of ionomer resin, wherein at least a portion of one face of the at least one transparent layer of ionomer resin is adhered to at least a portion of one face of another layer of the glazing using at least one metal chelate, preferably a metal chelate based primer composition, and the primer composition for use in such a glazing are described, to provide laminated glazings which have improved chock resistance, good optical properties, improved resistance to lamination even during cutting operations, and is economical to produce.

Abstract: The methods of forming a chemically adsorbed film by contacting a substrate with a solution mixture containing an alkoxysilane surface active agent, a non-aqueous solvent and a silanol-condensing catalyst to form a film covalently bonded to the substrate via siloxane bonds. These methods do not generate hydrochloric acid gas in forming the films and allow practical reaction rates.

Abstract: A water repellent for treating solids provides an durable and robust water repellency. The active ingredient in the water repellent is a pendant carbosiloxane dendrimer-functional vinyl-type polymer. A spray-formulated water repellent for treating solids contains 0.5 to 20 weight % of the pendant carbosiloxane dendrimer-functional vinyl-type polymer, 30 to 98.5 weight % of an organic solvent, and 1 to 50 weight % of a propellant gas.

Abstract: A water-repellent solution for forming a superior water-repellent film on a glass substrate is produced by subjecting a fluoroalkyl-group contained silane compound to a hydrolysis and a condensation polymerization. With this, at least dimers and trimers of the silane compound are produced. In case wherein the fluoroalkyl-group contained silane compound is of a type having the following general formula, satisfied performance of the formed water-repellent film is expected: CF3(CF2)m(CH2)2SiX3 wherein “m” is equal to or greater than 7 (seven) and “X” represents halogen, isocyanate-group or alkoxy-group, said alkoxy-group including methoxy-group [OCH3], ethoxy-group [OC2H5] or isopropoxy-group [OC3H5]. When the “m” is equal to or greater than 9 (nine), the performance of the film is much increased.

Abstract: The present invention provides a photocatalyst-carrying structure which has a structure, wherein an adhesive layer is provided in between a photocatalyst layer and a substrate, the adhesive layer is composed of silicon-modified resin, polysiloxane-containing resin or colloidal silica-containing resin, and for forming the photocatalyst layer a composition comprising a metal oxide gel or a metal hydroxide gel and a photocatalyst is used. Further, the present invention also provides a photocatalyst coating agent for producing a photocatalyst-carrying structure which contains silicon compound, at least one metal oxide sol or metal hydroxide sol, and at least one photocatalyst powder or sol.