Group Iva Or Ivb (ti, Zr, Hf, Ge, Sn, Pb) Patents (Class 106/287.19)
  • Patent number: 8088451
    Abstract: The present invention includes compositions and methods for synthesis of composite materials involving gas phase plasma polymerization to covalently plasma graft an organic molecule onto particles; covalently binding an organic monomer to the functionalized particles; and, polymerizing the organic monomers into hybrid polymer composite materials.
    Type: Grant
    Filed: March 13, 2009
    Date of Patent: January 3, 2012
    Assignee: Board of Regents, The University of Texas System
    Inventors: Richard B. Timmons, Dattatray Wavhal, Dhiman Bhattacharyya, Narayan Mukherjee
  • Patent number: 8062754
    Abstract: The invention relates to the use of waterproofing liquid silicon compositions for impregnating porous construction materials, for example mineral or (ligno)cellulose materials.
    Type: Grant
    Filed: July 5, 2006
    Date of Patent: November 22, 2011
    Assignee: Bluestar Silicones France
    Inventors: Yves Giraud, Martial Deruelle, Henri Chauffriat, Sandrine Millot, Jair Maggioni
  • Patent number: 8038786
    Abstract: Disclosed are heat-ray cutoff compounds, films and method using them. The heat-ray compound is produced by dispersing conductive nanoparticles in an amphoteric solvent with acids and dispersion sol, which provides a low cost production for the heat-ray cutoff films because it is able to any resin binder without sorting the kinds of resin binders (hydrolic or alcoholic, or anti-hydrolic).
    Type: Grant
    Filed: March 17, 2003
    Date of Patent: October 18, 2011
    Assignee: Hae-Wook LEE
    Inventors: Hae-Wook Lee, Jin-Hong Park
  • Publication number: 20110244220
    Abstract: Metal parts, especially parts made from aluminium, aluminium alloys, steel and stainless steel, are described which comprise a coating containing TiOF2 or titanyl hydroxyfluorides. The coating protects against corrosion. Titanium oxyfluoride and titanyl hydroxyfluorides in the form of a gel are also disclosed, as well as particulate Ti0.85O0.55(OH)1.1F1.2 having a specific particle size.
    Type: Application
    Filed: December 14, 2009
    Publication date: October 6, 2011
    Applicant: SOLVAY FLUOR GMBH
    Inventors: Placido Garcia-Juan, Ulrich Seseke-Koyro, Dagmar Bonhage
  • Publication number: 20110206909
    Abstract: A coating is formed by depositing the coating on a metallic feature at a deposition temperature. Subsequently, the deposited coating and the metallic feature are cooled below the deposition temperature. The coating is chosen such that this cooling step causes the coating to induce a tensile stress in the metallic feature sufficient to substantially suppress the growth of metallic whiskers on that metallic feature. The coating thereby acts to suppress the growth of metallic whiskers.
    Type: Application
    Filed: October 29, 2009
    Publication date: August 25, 2011
    Applicant: SUNDEW TECHNOLOGIES LLC
    Inventor: Ofer Sneh
  • Publication number: 20110189403
    Abstract: A coating material includes an amorphous alkali titanate.
    Type: Application
    Filed: September 15, 2009
    Publication date: August 4, 2011
    Applicant: SACHTLEBEN CHEMIE GMBH
    Inventors: Bernd Proft, Angela Classen, Jochen Winkler
  • Patent number: 7988778
    Abstract: A method of making a composite coating includes the steps of: adding a proper quantity of inorganic metal salt into an organic dissolvent to form a first mixed solution and then stirring the first mixed solution for 30-60 minutes; adding a proper quantity of SiO2 precursor into the first mixed solution to form a second mixed solution and then stirring the second mixed solution for 30-60 minutes; adding a proper quantity of catalyzer and water into the second mixed solution for being reacted with each other so as to form a coating solution via being stirred for 4-8 hours; and putting the coating solution under the room temperature for 24 hours so as to obtain the composite coating. A product formed with the foregoing composite coating includes a base body and a layer of composite protective film formed by the composite coating on surfaces of the base body.
    Type: Grant
    Filed: December 16, 2008
    Date of Patent: August 2, 2011
    Assignee: Cheng Uei Precision Industry Co., Ltd.
    Inventor: Chih-Hao Huang
  • Publication number: 20110171533
    Abstract: This invention pertains to mesoporous oxide of titanium and processes of making mesoporous oxide of titanium particularly crystalline oxide of titanium.
    Type: Application
    Filed: March 22, 2011
    Publication date: July 14, 2011
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventor: Carmine Torardi
  • Publication number: 20110151244
    Abstract: The disclosure provides a coating composition for outdoor applications having improved solar reflectivity and UV protection comprising a coating base, wherein the coating base comprises: (a) a colorant; and (b) an ultrafine-TiO2 having a median primary particle size (MPPS) of greater than about 70 nm.
    Type: Application
    Filed: September 29, 2009
    Publication date: June 23, 2011
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Dan Qing Wu, Joy Sawyer Bloom, John D. Connolly, JR.
  • Publication number: 20110135878
    Abstract: Dispersoids having metal-oxygen groups that are suitable for the production of metal oxide thin-films at a low temperature of 200° C. or below and for the production of homogeneous organic-inorganic hybrid materials. The dispersoid having metal-oxygen bonds may be obtained by mixing a metal compound having at least three hydrolyzable groups with at least 0.5 mole but less than 2 moles of water per mole of the metal compound in an organic solvent, in the absence of an acid, a base, and/or a dispersion stabilizer, and at a temperature at or below the temperature at which the metal compound begins to hydrolyze, then raising the temperature to at least the temperature at which hydrolysis begins.
    Type: Application
    Filed: February 2, 2011
    Publication date: June 9, 2011
    Applicant: NIPPON SODA, CO., LTD.
    Inventors: Nobuo Kimura, Yoshitaka Fujita, Norifumi Nakamoto, Motoyuki Toki, Akiji Higuchi, Kazuo Ono, Tomoya Hidaka, Hiroyuki Takeda
  • Publication number: 20110126734
    Abstract: The present disclosure relates to surface-modified zirconia nanoparticles, methods for making and using the same, and high index of refraction films made therefrom. The provided zirconia nanoparticles are surface modified with ligands that include N-hydroxyurea functionalities. The provided ligands also can contain compatibilizing groups that allow the provided surface-modified zirconia nanoparticles to be incorporated into an organic matrix. High index of refraction films can be made using these organic matrices.
    Type: Application
    Filed: November 16, 2010
    Publication date: June 2, 2011
    Inventors: Guy D. JOLY, Nathan E. Schultz, Encai Hao
  • Patent number: 7935653
    Abstract: A metal oxide nanoporous material comprises two or more kinds of first metal oxides selected from the group consisting of alumina, zirconia, titania, iron oxide, rare-earth oxides, alkali metal oxides and alkaline-earth metal oxides. The metal oxide nanoporous material has nanopores, each with a diameter of 10 nm or smaller, in which the metal oxides are dispersed homogeneously in the wall forming the nanopores.
    Type: Grant
    Filed: June 9, 2005
    Date of Patent: May 3, 2011
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Takashi Shimazu, Ryusuke Tsuji, Hideo Sobukawa, Yoshiki Seno, Yoriko Hasegawa
  • Patent number: 7935274
    Abstract: Compositions for preparing coatings on metal substrates include a phosphonic acid, polyvinyl alcohol, an optional catalyst, and optionally an organo-functional silane. The catalyst may be a group IV-B compound, a boron compound, a vanadium compound, or a molybdenum compound. The compositions may be applied from an aqueous carrier to a metal surface and then dried to form a coating imparting good paint adhesion and corrosion resistance to the metal substrate.
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: May 3, 2011
    Assignee: Bulk Chemicals, Inc.
    Inventor: Ted M. Schlosser
  • Publication number: 20110094417
    Abstract: Coating compositions of the present invention comprise hydrophobic particles, an alcohol, a solvent, and an effective amount of water such that coatings formed therefrom are hydrophobic. The hydrophobic particles may comprise a metal oxide, such as silica (SiO2), alumina (Al2O3), titania (TiO2), or zinc oxide (ZnO), or combinations thereof. In one embodiment, the hydrophobic particles comprise fumed silica. The amount of hydrophobic particles is in the range of from about 0.3 wt. % to about 2 wt. %. In one embodiment, the effective amount of water is at least about 0.066 wt. %. The ratio of the amount of the solvent to the amount of the alcohol is slightly less than 100, and, in another embodiment, is at least about 50 to 50. A surface treated with the composition is characterized by a water contact angle of 115° or more, and more particularly 135° or more.
    Type: Application
    Filed: October 26, 2009
    Publication date: April 28, 2011
    Applicant: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
    Inventors: Richard J. Baumgart, Subbareddy Kanagasabapathy
  • Patent number: 7927517
    Abstract: Disclosed herein are a coating solution for the formation of a dielectric thin film and a method for the formation of a dielectric thin film using the coating solution. The coating solution comprises a titanium alkoxide, a ?-diketone or its derivative, and a benzoic acid derivative having an electron donating group. The method comprises spin coating the coating solution on a substrate to form a thin film and drying the thin film at a low temperature to crystallize the thin film. The titanium-containing coating solution is highly stable. In addition, the coating solution enables formation of a thin film, regardless of the kind of substrates, and can be used to form dielectric thin films in an in-line mode in the production processes of PCBs.
    Type: Grant
    Filed: May 8, 2009
    Date of Patent: April 19, 2011
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Jun Hee Bae, Seung Hyun Kim, Yul Kyo Chung, Won Hoon Song, Sung Taek Lim, Hyun Ju Jin
  • Patent number: 7909929
    Abstract: The invention provides dispersoids having metal-oxygen groups which are suitable for the production of metal oxide thin-films at a low temperature of 200° C. or below and for the production of homogeneous organic-inorganic hybrid materials. The invention also provides metal oxide thin-films and organic-inorganic hybrid materials endowed with various capabilities, particularly organic-inorganic hybrid materials having a high refractive index and high transparency. Use is made of a dispersoid having metal-oxygen bonds which is obtained by mixing a metal compound having at least three hydrolyzable groups with at least 0.5 mole but less than 2 moles of water per mole of the metal compound in an organic solvent, in the absence of an acid, a base and/or a dispersion stabilizer, and at a temperature at or below the temperature at which the metal compound begins to hydrolyze, then raising the temperature to at least the temperature at which hydrolysis begins.
    Type: Grant
    Filed: November 12, 2003
    Date of Patent: March 22, 2011
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Nobuo Kimura, Yoshitaka Fujita, Norifumi Nakamoto, Motoyuki Toki, Akiji Higuchi, Kazuo Ono, Tomoya Hidaka, Hiroyuki Takeda
  • Patent number: 7897259
    Abstract: Silicon compounds useful as coating reactants for the chemical vapor deposition of silicon oxide are disclosed, along with compounds useful as accelerants to increase the deposition rate of silicon oxide. The silicon-containing precursor comprises the structural formula wherein R1 is an alkyl, alkenyl, alkynyl or aryl radical which may be substituted, and R2 is a functional group which increases the reactivity of the silicon compound by withdrawing electron density away from the silicon atom, such as hydrogen, halogen, alkenyl, alkynyl, halogenated alkyl and perhalogenated alkyl radicals. The accelerant is a compound selected to take advantage of the partial positive charge on the silicon atom. Such accelerant compounds include Lewis acids and bases; water; ozone; trivalent compounds of nitrogen, boron and phosphorus; tetravalent compounds of sulfur and selenium; pentavalent compounds of phosphorus and a variety of metal compounds.
    Type: Grant
    Filed: April 9, 1998
    Date of Patent: March 1, 2011
    Assignee: PPG Industries Ohio, Inc.
    Inventors: David E. Lococq, George A. Neuman, Royann L. Stewart-Davis
  • Patent number: 7897202
    Abstract: A process using environmentally friendly materials for restoring a surface of an epoxy graphite composite material that has been degraded by exposure to ultraviolet radiation. An example process includes steps of providing a gelled solvent composition, applying the gelled solvent composition to a degraded surface of an epoxy graphite composite material, and thereafter removing the gelled solvent composition to produce a restored surface. The process uses a novel gelled solvent composition comprising one or more non-halogenated organic solvents, a thickening agent, an abrasive agent, and water; wherein the gelled solvent composition has an evaporative weight loss that is lower than the evaporative weight loss of the one or more non-halogenated solvents.
    Type: Grant
    Filed: May 18, 2007
    Date of Patent: March 1, 2011
    Assignee: The Boeing Company
    Inventors: Gregory J. Werner, Burt Shah
  • Publication number: 20110041726
    Abstract: A coloured composition comprising: a) NIR scattering TiO2 particulate material with an average crystal size of greater than 0.40 ?m and a particle size distribution such that 30% or more of the particles are less than 1 ?m; b) one or more non-white colorant; wherein the particulate material and the non-white colorant are dispersed within a vehicle. This material with a large crystal size has unusually high reflection of NIR radiation and, simultaneously, noticeably diminished reflectance of visible light. Also disclosed is a coated particulate TiO2 material, wherein the material has an average crystal size of greater than 0.40 ?m, and the coating comprises one or more oxide material; this provides low levels of photocatalytic activity that were previously unattainable. This coated TiO2 material may be provided in a composition.
    Type: Application
    Filed: May 1, 2009
    Publication date: February 24, 2011
    Applicant: Tioxide Europe Limited
    Inventors: John Robb, John L. Edwards, John Temperley, Robert Bird, Paul C. Bradley, Anthony G. Jones
  • Patent number: 7892343
    Abstract: A manufacturing method for a slurry for the production of a precision casting mold that includes a zirconia sol and a refractory powder, and a manufacturing method for a precision casting mold that uses the slurry is provided. The present invention relates to a manufacturing method for a slurry for the production of a precision casting mold for a metal that includes a step in which an alkaline zirconia sol (A1) and a refractory powder (D) are mixed, the alkaline zirconia sol (A1) being obtained by a manufacturing method that includes a step (i), in which a zirconium salt (B1) is heated at 60 to 110° C. in an aqueous medium that includes a carbonate of quaternary ammonium, and a step (ii), in which a hydrothermal treatment is carried out at 100 to 250° C.
    Type: Grant
    Filed: June 21, 2006
    Date of Patent: February 22, 2011
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Kiyomi Ema, Yutaka Ohmori, Hirokazu Kato, Kenji Yamaguchi
  • Publication number: 20110036269
    Abstract: Surface-modified agglomerate of indium tin oxohydrate with a proportion of indium of 80 to 98.9% by weight, of tin of 2 to 20% by weight and of carbon of 0.01 to 1% by weight. Process for preparing a surface-modified agglomerate of indium tin oxide, in which the surface-modified agglomerate of indium tin oxohydrate is dried under air at temperatures of more than 150° C. and less than 310° C., and is then calcined under reducing conditions. Surface-modified agglomerate of indium tin oxide obtainable by this process. Process for preparing a surface-modified powder of indium tin oxide and a dispersion thereof, in which the surface-modified agglomerate and one or more solvents are combined to give a mixture, the mixture is converted to a dispersion by means of a dispersing unit and liquid constituents are optionally removed from the dispersion in order to obtain a powder.
    Type: Application
    Filed: April 16, 2009
    Publication date: February 17, 2011
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Sven Hill, Willibald Wombacher, Katharina Dauth
  • Patent number: 7862857
    Abstract: A novel lead zirconium titanate (PZT) material having unique properties and application for PZT thin film capacitors and ferroelectric capacitor structures, e.g., FeRAMs, employing such thin film material. The PZT material is scalable, being dimensionally scalable, pulse length scalable and/or E-field scalable in character, and is useful for ferroelectric capacitors over a wide range of thicknesses, e.g., from about 20 nanometers to about 150 nanometers, and a range of lateral dimensions extending to as low as 0.15 ?m. Corresponding capacitor areas (i.e., lateral scaling) in a preferred embodiment are in the range of from about 104 to about 10?2 ?m2. The scalable PZT material of the invention may be formed by liquid delivery MOCVD, without PZT film modification techniques such as acceptor doping or use of film modifiers (e.g., Nb, Ta, La, Sr, Ca and the like).
    Type: Grant
    Filed: April 27, 2010
    Date of Patent: January 4, 2011
    Assignee: Advanced Technology Materials, Inc.
    Inventors: Peter C. Van Buskirk, Jeffrey F. Roeder, Steven M. Bilodeau, Michael W. Russell, Stephen T. Johnston, Daniel J. Vestyck, Thomas H. Baum
  • Publication number: 20100297430
    Abstract: The invention relates to a processes and compositions for preparing anti-reflective coatings.
    Type: Application
    Filed: February 12, 2007
    Publication date: November 25, 2010
    Inventors: Jens Christoph Thies, Guido Jozefina Wilhelmus Meijers, Patrick Wilhelmus Antonius Vrijaldenhove, Nanning Joerg Arfsten, Hermanus Adrianus Langermans
  • Patent number: 7833340
    Abstract: To provide a coating material capable of forming a film having both a sufficiently high film strength and a photocatalytic function by an easy method, there is provided a coating material comprising a particle group A, a particle group B and a solvent, wherein the number of necking particles of the particle group A is larger than the number of necking particles of the particle group B, wherein “the number of necking particles” here is referred to the total number of particles constituting all necking particles with each constituting particle being considered as the unit particle.
    Type: Grant
    Filed: April 25, 2005
    Date of Patent: November 16, 2010
    Assignee: Showa Denko K.K.
    Inventors: Yasuaki Wakizaka, Masayuki Sanbayashi, Jun Tanaka
  • Patent number: 7820723
    Abstract: A method of preparing a sol of lead zirconium titanate, known as PZT, of formula PbZrxTi(1?x)O3 with 0.45?x?0.7, comprises the steps of: (a) preparing a concentrated sol in a diol, the sol comprising a titanium-based precursor, a zirconium-based precursor, and a lead-based precursor; (b) placing the concentrated sol at ambient temperature without agitation, until a sol is obtained having a constant viscosity as a function of time; (c) diluting the sol obtained in (b) with a solvent compatible with the diol used in step (a). The sol is useful for preparing PZT-based films for use in the electronics field.
    Type: Grant
    Filed: September 19, 2002
    Date of Patent: October 26, 2010
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Philippe Belleville, Philippe Boy, Yves Montouillout
  • Patent number: 7819965
    Abstract: A coating formulation contains the following components (A), (B) and (C): (A) an organic acid-titanium compound having at least one titanium atom and at least one C2-12 aliphatic organic acid residual group as essential constituents and having no constituent other than the essential constituents, (B) fine particles of a titanate-based compound, said fine particles having an average particle size of from 10 to 100 nm, and (C) an organic solvent. A content of the components (A) is from 0.1 to 1.5 mol/kg in terms of titanium atoms, and a content of the component (B) is from 0.1 to 1.5 mol/kg in terms of titanium atoms. A production process for a titanate-based ceramic film, which makes use of the coating formulation, is also disclosed.
    Type: Grant
    Filed: October 2, 2007
    Date of Patent: October 26, 2010
    Assignee: Adeka Corporation
    Inventors: Atsuya Yoshinaka, Daisuke Takagi
  • Patent number: 7811374
    Abstract: A composition for coating a surface includes a carrier and an indicator distributed throughout the carrier. The indicator is configured to modify an appearance of the coating. The indicator facilitates determining a thickness of the coating in response to the appearance of the coating.
    Type: Grant
    Filed: August 30, 2005
    Date of Patent: October 12, 2010
    Assignee: The Boeing Company
    Inventors: Joseph H. Osborne, Ronald R. Stephenson, Kenneth A. Krienke, Larry K. Olli
  • Publication number: 20100251936
    Abstract: A method of fabricating a liquid for an oxide thin film is provided, which includes mixing at least two kinds of dispersoids selected from the group consisting of a Zinc compound, an Indium compound, a Gallium compound, a Tin compound and a Thallium compound, with dispersion media corresponding to the selected dispersoids to form a dispersion system, and stirring and aging the dispersion system at a predetermined temperature for a predetermined time, wherein a molar ratio of the Zinc compound to each of the Indium compound, Gallium compound, Tin compound and Thallium compound is 1:0.1 to 1:2. According to the present invention, the liquid for the oxide thin film may be fabricated by a sol-gel method making it capable of being implemented in mass production in a simple and low-cost manner as opposed to the conventional vacuum deposition method.
    Type: Application
    Filed: February 14, 2008
    Publication date: October 7, 2010
    Applicant: INDUSTRY-ACADEMIC COOPERATION FOUNDATION ,
    Inventors: Hyun Jae Kim, Kyung Ho Kim, Gun Hee Kim, Tae Hoon Jeong, Hyun Soo Shin, Won Jun Park, Yun Jung Choi, Ka Young Lee
  • Publication number: 20100222481
    Abstract: A product is used in creating an active capping layer across submerged (and optionally exposed) surfaces of contaminated sediment, with the product including multiple, dry particles composed of variable types and amounts of inert material, reactive material and binding material. To create optimal characteristics for controlled and relatively rapid settling through a water column, the dry particles can selectively comprise different sizes, size gradations and shapes (as a function of procedures for manufacturing and processing) as well as different density, or specific gravity (as a function of optionally including relatively very dense minerals). The dry particles are manufactured by implementing the sequential steps of material mixing into a flowable paste, paste drying, crushing and optionally sieving.
    Type: Application
    Filed: September 18, 2008
    Publication date: September 2, 2010
    Applicant: BIOLOGGE AS
    Inventors: Joseph Jersak, Tore Lundh
  • Publication number: 20100221518
    Abstract: Disclosed is an organic dispersion comprising a flaky titanium oxide particle having a high crystallinity and high light permeability contained in an organic solvent. The dispersion can be prepared by a method comprising preparing an aqueous dispersion of a flaky titanium oxide particle containing an organic cation, centrifuging the aqueous dispersion to produce a precipitate, and adding the precipitate to an organic solvent, or a method comprising lyophilizing the aqueous dispersion to produce a lyophilized material and mixing the lyophilized material to an organic solvent. When the organic dispersion is used, it becomes possible to form a film comprising a monolayer of a titanium oxide nanosheet densely arranged therein by such a simple manner that the dispersion is coated on a base material and drying the dispersion. The film thus produced has a photocatalytic activity and a super-hydrophilic property.
    Type: Application
    Filed: September 4, 2008
    Publication date: September 2, 2010
    Inventors: Takayoshi Sasaki, Yasuo Ebina, Hirofumi Taniguchi, Yusuke Uesusuki
  • Patent number: 7780777
    Abstract: An aqueous dispersion that can be used in the coating of glass, ceramics and metal surfaces is prepared by placing, in water, an aggregated titanium dioxide powder having a specific surface area of from 20 to 150 m2/g in such an amount that the desired dispersion contains at least 20 wt. % titanium dioxide, and at least one amino alcohol having from 1 to 6 carbon atoms, and at least one carboxylic acid selected from dibasic carboxylic acids and/or hydroxycarboxylic acids having from 2 to 6 carbon atoms. A pre-dispersion is produced by introducing energy in an amount of less than 200 kJ/m3. Then a dispersion is produced in which the aggregated titanium dioxide powder has a mean, volume-related aggregate diameter of less than 150 nm by grinding the pre-dispersion with a high-energy mill at a pressure of at least 500 bar.
    Type: Grant
    Filed: July 5, 2005
    Date of Patent: August 24, 2010
    Assignee: Evonik Degussa GmbH
    Inventors: Gabriele Perlet, Wolfgang Lortz, Christoph Batz-Sohn, Werner Will, Sascha Reitz
  • Publication number: 20100209610
    Abstract: A metal precursor, selected from among: (i) precursors of the formula (NR1R2)4-xM(chelate)x, and (ii) precursors of the formula (NR10R11)4-2yM(12RN(CH2)zNR13)y, wherein: x=1, 2, 3, or 4; M=Ti, Zr, or Hf; each chelate is independently selected from among guanidinate, amidinate, and isoureate ligands of specific formula; y is 0, 1, or 2; and each of R1, R2, R10, R11, R12 and R13 is independently selected from among H, C1-C12 alkyl, C1-C12 alkylamino, C1-C12 alkoxy, C3-C10 cycloalkyl, C2-C12 alkenyl, C7-C12 aralkyl, C7-C12 alkylaryl, C6-C12 aryl, C5-C12 heteroaryl, C1-C10 perfluoroalkyl, and silicon-containing groups selected from the group consisting of silyl, alkylsilyl, perfluoroalkylsilyl, triarylsilyl and alkylsilylsilyl, aminoalkyl, alkoxyalkyl, aryloxyalkyl, imidoalkyl, acetylalkyl, and N-bonded functionality between two different nitrogen atoms of the precursor can be C1-C4 alkylene, silylene (—SiH2—), or C1-C4 dialkylsilylene.
    Type: Application
    Filed: July 16, 2008
    Publication date: August 19, 2010
    Applicant: ADVANCED TECHNOLOGY MATERIALS, INC.
    Inventors: Thomas M. Cameron, Chongying Xu
  • Patent number: 7776148
    Abstract: Curable compositions with at least one hydrolyzis products from an organosilane of a general formula R1aR2bSiX(4-a-b, or oligomer therefrom, wherein R1 represents a non-hydrolyzable radical, R2 represents a non-hydrolyzable radical that includes a functional group and X represents similar or different radicals that are hydroxyl-groups and hydrolyzable products of substitution reactions of hydroxyl groups and wherein a is 0 or 1, b is 0 to 3 and the sum of a and b can be 1, 2 or 3, and at least one substituent R2 is an epoxy group and at least one blocked polyisocyanate. The invention also includes mixtures which contain pigments and/or fillers, the process for the production of crosslinked masses through reaction of the hydrolyzis products, namely modified polysiloxanes, with blocked polyisocyanates as well as therewith produced coatings and molded bodies.
    Type: Grant
    Filed: October 19, 2002
    Date of Patent: August 17, 2010
    Assignee: NTC Nano Tech Coatings GmbH
    Inventor: Georg Wagner
  • Publication number: 20100203271
    Abstract: The present invention relates to a process for increasing the abrasion resistance of a pre-determinable part of the surface of an annealed glass container comprising the following operative phases: a) applying a liquid composition comprising an organo-titanate compound on a pre-determinable part of the annealed glass container surface by spraying at room temperature; b) selectively heat-treating the surface on which the liquid composition of step a) has been applied at a temperature between the glass annealing temperature and glass softening temperature, said selective heat treatment resulting in the formation of a titanium oxide coating layer on said surface. The present invention also relates to the use of a liquid composition comprising tetraisopropyl-titanate dissolved in isopropyl alcohol with a concentration of titanium ranging from 0.
    Type: Application
    Filed: February 12, 2010
    Publication date: August 12, 2010
    Applicant: Bormioli Luigi S.p.A.
    Inventors: Vincenzo DI GIUSEPPANTONIO, Ivano Davoli, Antonio Bruscella
  • Patent number: 7772748
    Abstract: Provided are a composite for forming a ferroelectric thin film which is a colloidal solution applicable to the MOD method and capable of maintaining excellent dispersion stability and preservation stability of an organometallic compound over a long term, a ferroelectric thin film, a method of manufacturing a ferroelectric thin film, and a liquid-jet head. A composite for forming a ferroelectric thin film, which is made of a colloidal solution applicable to the MOD method containing an organometallic compound including metal constituting a ferroelectric thin film, and contains water other than water of crystallization in the organometallic compound is used when forming a ferroelectric thin film in accordance with the MOD method.
    Type: Grant
    Filed: June 29, 2005
    Date of Patent: August 10, 2010
    Assignee: Seiko Epson Corporation
    Inventor: Koji Sumi
  • Publication number: 20100178308
    Abstract: The invention relates to pigment based on (multiple) coated platelet-shaped substrates comprising an outer layer which is obtained by treatment with a metal oxide/hydroxide and then a phosphate ester, or phosphonate, or a salt thereof, with the proviso that the phosphate ester, or phosphonate do not contain fluorine, to a method for producing said pigments and the use thereof. The outer layer provides a very good photo-stabilisation of the TiO2coated platelet-shaped substrates, such as mica, combined with a good water resistance and an anti-yellowing performance.
    Type: Application
    Filed: November 26, 2007
    Publication date: July 15, 2010
    Applicant: CIBA CORPORATION
    Inventors: Kazuhisa Iwasa, Marcel Hahn, Philippe Bugnon
  • Patent number: 7741376
    Abstract: A dispersed ingredient having metal-oxygen bonds which is obtained by hydrolyzing a metal alkoxide in an organic solvent in the absence of an acid, a base, and/or a dispersion stabilizer, either with 0.5 to less than 1 mol of water per mol of the metal alkoxide or at ?20° C. or lower with 1.0 to less than 2.0 mol of water per mol of the metal alkoxide. In the organic solvent, the dispersed ingredient is stably dispersed without aggregating. Use of the dispersed ingredient enables a thin metal oxide film and a homogeneous organic/inorganic composite to be produced at a temperature as low as 200° C. or below.
    Type: Grant
    Filed: December 11, 2008
    Date of Patent: June 22, 2010
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Motoyuki Toki, Akiji Higuchi, Nobuo Kimura, Yoshitaka Fujita
  • Publication number: 20100152347
    Abstract: Provided herein are mixtures, emulsions and other additives for use in manufacturing gypsum wallboard. The mixtures and emulsions may be wax-based emulsions or wax-free mixtures or emulsions, with wax-based emulsions including water, at least one wax, a dispersant which may include sulfur or a sulfur-containing group, and an additive comprising an organic titanium compound or organic zirconium compound. Mixtures may also be prepared including water, a dispersant; and an additive comprising an organic titanium compound or organic zirconium compound. Gypsum slurries may be prepared using such emulsions and mixtures and/or through addition of an organic titanium compound or organic zirconium compound.
    Type: Application
    Filed: December 9, 2009
    Publication date: June 17, 2010
    Inventors: Dennis Michael Mahoney, Jonathan Stuart, John H. Burns
  • Publication number: 20100143607
    Abstract: Described herein are Group 4 metal-containing precursors, compositions comprising Group 4 metal-containing precursors, and deposition processes for fabricating conformal metal containing films on substrates. In one aspect, the Group 4 metal-containing precursors are represented by the following formula I: wherein M comprises a metal chosen from Ti, Zr, and Hf; R and R1 are each independently selected from an alkyl group comprising from 1 to 10 carbon atoms; R2 is an alkyl group comprising from 1 to 10 carbon atoms; R3 is chosen from hydrogen or an alkyl group comprising from 1 to 3 carbon atoms; R4 is an alkyl group comprising from 1 to 6 carbon atoms and wherein R2 and R4 are different alkyl groups. Also described herein are methods for making Group 4 metal-containing precursors and methods for depositing films using the Group 4 metal-containing precursors.
    Type: Application
    Filed: December 2, 2009
    Publication date: June 10, 2010
    Applicant: Air Products and Chemicals, Inc.
    Inventors: Xinjian Lei, Daniel P. Spence, Moo-Sung Kim, Iain Buchanan, Laura M. Matz, Sergei Vladimirovich Ivanov
  • Patent number: 7727322
    Abstract: A method for manufacturing a precursor solution for forming a PZTN compound oxide with Pb, Zr, Ti and Nb as constituent elements by a sol-gel method includes: a step of dissolving at least lead carboxylate with an organic solvent having an alkoxy group, to thereby form a first solution; a step of heat treating the first solution to remove crystallization water of the lead carboxylate and to form lead alkoxide by a ligand replacement reaction between the lead carboxylate and the organic solvent having the alkoxy group, to thereby form a second solution including the lead alkoxide; a step of mixing an alkoxide of a metal selected from at least one of Zr, Ti and Nb excluding Pb with the second solution, to thereby form a third solution including metal alkoxides of Pb, Zr, Ti and Nb, respectively; and a step of adding water to the third solution to cause hydrolysis-condensation of the metal alkoxides, to thereby form a fourth solution including a precursor of PZTN compound oxide.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: June 1, 2010
    Assignee: Seiko Epson Corporation
    Inventor: Motohisa Noguchi
  • Publication number: 20100129555
    Abstract: A nanocomposite coating and a method of coating for protecting a product with the nanocomposite coating are presented. Firstly, the nanocomposite coating is prepared, wherein the nanocomposite coating is formed by mixing 22.5˜49.5% nanometer inorganic oxide gel made by a sol-gel method, 45˜74.25% organic solvent and 1˜10% nanometer powder together. Next, the nanocomposite coating is coated onto surfaces of the product evenly by way of spraying, dipping or roll-to-rolling. Lastly, the product coated with the nanocomposite coating is subjected to a room temperature or a heating environment lower than 170 degrees centigrade to make the nanocomposite coating dry for forming nanometer protective films on the surfaces of the product.
    Type: Application
    Filed: November 21, 2008
    Publication date: May 27, 2010
    Applicant: CHENG UEI PRECISION INDUSTRY CO., LTD.
    Inventor: Chih-Hao Huang
  • Publication number: 20100126851
    Abstract: An anode provided with an electrocatalytic coating comprising tin, preferably tetravalent and in form of mixed oxide, prepared by the method for the manufacturing of an electrode, comprising applying a solution of a precursor for the pyrolytic formation of a tin-containing coating to a substrate of a valve metal, followed by the execution of thermal treatment, wherein the precursor solution comprises stannic hydroxychioride and a method of preparing the same.
    Type: Application
    Filed: December 30, 2009
    Publication date: May 27, 2010
    Inventors: Alexander Morozov, Achille De Battisti, Sergio Ferro, Gian Nicola Martelli
  • Patent number: 7713348
    Abstract: A precursor composition including a precursor for forming a ferroelectric, the ferroelectric being shown by a general formula AB1-XCXO3, an element A including at least Pb, an element B including at least one of Zr, Ti, V, W, and Hf, an element C including at least one of Nb and Ta, the precursor including at least the element B and the element C and part of the precursor including an ester bond, the precursor being dissolved or dispersed in an organic solvent, and the organic solvent including at least a first alcohol and a second alcohol having a boiling point and viscosity higher than a boiling point and viscosity of the first alcohol.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: May 11, 2010
    Assignee: Seiko Epson Corporation
    Inventors: Takeshi Kijima, Setsuya Iwashita, Yasuaki Hamada
  • Publication number: 20100112211
    Abstract: Zirconium, hafnium, titanium and silicon precursors useful for atomic layer deposition (ALD) and chemical vapor deposition (CVD) of corresponding zirconium-containing, hafnium-containing, titanium-containing and silicon-containing films, respectively. The disclosed precursors achieve highly conformal deposited films characterized by minimal carbon incorporation.
    Type: Application
    Filed: April 13, 2008
    Publication date: May 6, 2010
    Applicant: ADVANCED TECHNOLOGY MATERIALS, INC.
    Inventors: Chongying Xu, Jeffrey F. Roeder, Tianniu Chen, Bryan C. Hendrix, Brian Benac, Thomas M. Cameron, David W. Peters, Gregory T. Stauf, Leah Maylott
  • Patent number: 7709540
    Abstract: The present invention belongs to a method for preparing organic ligand-capped titanium dioxide nanocrystals, wherein the method comprises steps of using methyl titanate, ethyl titanate, n-propyl titanate, iso-propyl titanate, butyl titanate or titanium tetrachloride as a titanium source, and with capping by oleic acid or an organic capping agent, reacting the titanium source in an organic non-polar solvent with an aqueous alkaline substance solution in the interface at a temperature of 25 to 280° C. for 0.5 to 240 hrs, thus a transparent sol containing titanium dioxide nanocrystals is obtained, said the titanium dioxide nanocrystals have particle diameters of 1-20 nm. The preparing process has the features of mild reaction conditions and is a simpler and easier method with a shorter preparation period, thereby facilitating the industrialization.
    Type: Grant
    Filed: December 2, 2005
    Date of Patent: May 4, 2010
    Assignee: Changchun Institute of Applied Chemistry Chines Academy of Sciences
    Inventors: Daocheng Pan, Nana Zhao, Qiang Wang, Xiangling Ji, Shichun Jiang, Lijia An
  • Patent number: 7705382
    Abstract: A novel lead zirconium titanate (PZT) material having unique properties and application for PZT thin film capacitors and ferroelectric capacitor structures, e.g., FeRAMs, employing such thin film material. The PZT material is scalable, being dimensionally scalable, pulse length scalable and/or E-field scalable in character, and is useful for ferroelectric capacitors over a wide range of thicknesses, e.g., from about 20 nanometers to about 150 nanometers, and a range of lateral dimensions extending to as low as 0.15 ?m. Corresponding capacitor areas (i.e., lateral scaling) in a preferred embodiment are in the range of from about 104 to about 10?2 ?m2. The scalable PZT material of the invention may be formed by liquid delivery MOCVD, without PZT film modification techniques such as acceptor doping or use of film modifiers (e.g., Nb, Ta, La, Sr, Ca and the like).
    Type: Grant
    Filed: October 26, 2007
    Date of Patent: April 27, 2010
    Assignee: Advanced Technology Materials, Inc.
    Inventors: Peter C. Van Buskirk, Jeffrey F. Roeder, Steven M. Bilodeau, Michael W. Russell, Stephen T. Johnston, Daniel J. Vestyck, Thomas H. Baum
  • Patent number: 7699916
    Abstract: A corrosion resistant, electrically-conductive, durable plate at least partially coated with an anchor coating and a corrosion resistant coating. The corrosion resistant coating made of at least a polymer and a plurality of corrosion resistant particles each having a surface area between about 1-20 m2/g and a diameter less than about 10 microns. Preferably, the plate is used as a bipolar plate in a proton exchange membrane (PEMFC) fuel cell stack.
    Type: Grant
    Filed: May 28, 2008
    Date of Patent: April 20, 2010
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: J. David Carter, Jennifer R. Mawdsley, Suhas Niyogi, Xiaoping Wang, Terry Cruse, Lilia Santos
  • Patent number: 7687150
    Abstract: The thermal barrier composition of the present invention provides a glassy matrix comprising an alkoxy-functionalized siloxane and a functionally-terminated silane or siloxane, polymethylsilsesquioxane dissolved in a crosslinking agent, and optionally a filler and/or hollow glass microspheres.
    Type: Grant
    Filed: January 3, 2006
    Date of Patent: March 30, 2010
    Assignee: Microphase Coatings, Inc.
    Inventors: William H. Simendinger, III, David William Garrett
  • Patent number: 7686881
    Abstract: Flame-hydrolytically produced titanium dioxide powder that is present in the form of aggregates of primary particles, and has a BET surface of 20 to 200 m²/g, a half width (HW) [nm] of the primary particle distribution of HW = a×BETf where a = 670×10?9 m³/g and ?1.3 ≤ f ≤ ?1.0 and the proportion of particles with a diameter of more than 45 &mgr;m lies in a range from 0.0001 to 0.05 wt. %. The powder is produced by a process in which a titanium halide is vapourised at temperatures of less than 200°C.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: March 30, 2010
    Assignee: Degussa AG
    Inventors: Kai Schumacher, Andreas Schild, Martin Moerters
  • Patent number: 7686879
    Abstract: Embodiments of the present invention provide coating materials including at least one binder and at least one photocatalytically-active substance adapted to absorb light at one or more absorption wavelengths in the range of about 380 nm to about 500 nm. Other embodiments may be described and claimed.
    Type: Grant
    Filed: April 6, 2005
    Date of Patent: March 30, 2010
    Assignee: STO AG
    Inventors: Peter Grochal, Werner Duttlinger, Michael Troll, Josef Ermuth