Erasable, Purified, Correctable, Fugitive, Indicator, Conductive, Fluorescent, Chromogenic, Or Magnetic Composition Patents (Class 106/31.32)
  • Patent number: 7524366
    Abstract: The present invention pertains to a cyan dye-based inkjet ink having substantially no absorption in the near-infrared region of the spectrum (near-IR transparent). The invention further pertains to a dye-based inkjet ink set comprising this near-IR transparent cyan ink.
    Type: Grant
    Filed: May 4, 2007
    Date of Patent: April 28, 2009
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Michael J. Eiseman, Kuo Hsiung Kung
  • Patent number: 7494537
    Abstract: A thermochromic coloring color-memory composition comprising a homogeneous solubilized mixture of (A) an electron donative coloring organic compound, (B) an electron accepting compound and (C) a compound represented by the specific formula as a reaction medium which controls color reactions of the components (A) and (B).
    Type: Grant
    Filed: November 15, 2005
    Date of Patent: February 24, 2009
    Assignee: The Pilot Ink Co., Ltd.
    Inventors: Yoshiaki Ono, Katsuyuki Fujita
  • Patent number: 7488380
    Abstract: A highlighting (or marking) composition, such as an ink, including a non-eradicable colorant, an eradicable colorant; a kit including a first marking instrument comprising the highlighting mixture and a second marking instrument comprising an eradicator fluid; a colorant complex including a colorless or substantially colorless eradicable dye, a non-eradicable dye, and an eradicator; and methods of applying an eradicator to at least a portion of a marking made with a highlighting composition, are described herein.
    Type: Grant
    Filed: May 11, 2006
    Date of Patent: February 10, 2009
    Assignee: Sanford, L.P.
    Inventors: Wing Sum Vincent Kwan, Cindy Duong
  • Publication number: 20090036304
    Abstract: A thermochromic ink composition comprises at least one thermochromic optical-state change material, at least one thermally responsive pH modifier, at least one solvent, and at least one binder material, wherein the thermochromic ink composition has a viscosity between about 0.1 centipoise (cPs) and about 10,000 cps, and a maximum optical absorbance in a range from about 200 nm (nanometers) to about 800 nm, and wherein the thermochromic ink composition is capable of transforming from a first optical state to a second optical state upon exposure to a thermal stimulus. The thermochromic ink composition may be used to deposit a thermochromic coating composition which may be used as part of an anti-theft system for optical articles. Methods for thermal activation of the compositions are also provided.
    Type: Application
    Filed: July 31, 2007
    Publication date: February 5, 2009
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Matthew Jeremiah Misner, Ben Purushotam Patel, Marc Brian Wisnudel, Andrea Jeannine Peters, James Mitchell White, Kasiraman Krishnan
  • Patent number: 7455724
    Abstract: The disclosure is generally related to a decoder system and, more particularly, to a decoder system comprising a coding composition, a decoding composition and optionally, an erasing composition. The disclosure also provides decoder writing instrument systems comprising a coding writing point in fluid communication with a coding composition, a decoding writing point in fluid communication with a decoding composition and optionally, an erasing writing point in fluid communication with an erasing composition.
    Type: Grant
    Filed: August 18, 2005
    Date of Patent: November 25, 2008
    Assignee: Sanford, L.P.
    Inventors: Wing Sum Vincent Kwan, Leighton Davies-Smith
  • Publication number: 20080267811
    Abstract: An object of the present invention is to provide a material for more easily and accurately detecting treatment status using gas exposure. The present invention relates to an ink composition for detecting an oxidizing gas, or the like, comprising at least one type of azo dye, methine dye, triarylmethane dye and thiazine dye.
    Type: Application
    Filed: March 30, 2005
    Publication date: October 30, 2008
    Applicant: SAKURA COLOR PRODUCTS CORPORATION
    Inventors: Norihiro Yamaguchi, Kyoko Sano, Hiroshi Inoue
  • Patent number: 7429291
    Abstract: The present invention provides a fluorescence ink having a high fluorescence intensity, and an ink jet recording method using the same. The ink contains a first fluorescent coloring material that emits fluorescence at a predetermined fluorescence wavelength to be used for measurement or determination with excitation at a predetermined excitation wavelength, a second fluorescent coloring material that emits fluorescence on excitation at the predetermined excitation wavelength, where the excitation spectrum of the first coloring material in the ink to obtain the fluorescence at the predetermined emission wavelength has a peak wavelength range next to the predetermined fluorescence wavelength, and the emission fluorescence spectrum of the second coloring material has an emission wavelength region substantially including at least the above peak wavelength range.
    Type: Grant
    Filed: October 13, 2006
    Date of Patent: September 30, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masako Udagawa, Sadayuki Sugama, Shoji Koike, Makoto Aoki, Akira Nagashima, Shinichi Hakamada
  • Patent number: 7427318
    Abstract: A highlightable mixture, such as an ink, including a colored pigment, an eradicable colorant, and a non-eradicable colorant; a kit including the highlightable mixture and an eradicator solution; colorant complex including a colorless or substantially colorless eradicable dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, and methine dyes, and a colored pigment; and methods of applying an eradicator to at least a portion of a marking made with a highlightable mixture, are described herein.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: September 23, 2008
    Assignee: Sanford, L.P.
    Inventors: Leighton Davies-Smith, Vincent Wing Sum
  • Publication number: 20080149894
    Abstract: New ink-jet printing inks provide red printed images with high-intensity fluorescence emission and are capable of printing images that can be used for high density bar code applications (2D bar codes) having high readability. The inks are aqueous and capable of producing machine-readable markings exhibiting fluorescence when exposed to fluorescent-exciting radiation. They exhibit a peak of fluorescence between about 500 nm and about 700 nm and a fluorescent strength of the ink diluted by 100 times of more than about 70 by excitation of ultraviolet radiation. The inks exhibit a peak of absorbance of between about 400 nm and about 600 nm, and an absorbance of the ink diluted by 100 times and measured in 1 mm cell of more than about 0.6. The preferred inks are characterized by a color of the ink diluted by 100 times with water and measured in 1 mm cell is t L*: about 80±10, a*: about 45±20, b*: about 20±35 and a color of the printed image of L*: about 65±10, a*: about 55±10, b*: about 5±20.
    Type: Application
    Filed: December 22, 2006
    Publication date: June 26, 2008
    Inventors: Judith D. Auslander, Richard A. Bernard, Shunichi Higashiyama, Michiko Aoyama
  • Patent number: 7364613
    Abstract: A fluorescent water base ink for ink-jet recording includes water, a first fluorescent dye, and a second fluorescent dye. The first fluorescent dye absorbs light in a first absorption wavelength region in an ultraviolet region to emit fluorescence, and the first fluorescent dye absorbs light in a second absorption wavelength region to emit no fluorescence. The second fluorescent dye absorbs light in an absorption wavelength region in the ultraviolet region, which is different from the first absorption wavelength region of the first fluorescent dye, to emit fluorescence. A wavelength region of the fluorescence of the second fluorescent dye is not overlapped with the first absorption wavelength region of the first fluorescent dye, but at least a part of the wavelength region of the fluorescence of the second fluorescent dye is overlapped with the second absorption wavelength region. The fluorescence intensity of the ink is increased.
    Type: Grant
    Filed: March 16, 2005
    Date of Patent: April 29, 2008
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Michiko Aoyama, Masashi Tsuda, Hiromitsu Sago, Mayuko Umemura, Hideto Yamazaki, Shunichi Higashiyama
  • Patent number: 7365107
    Abstract: The invention relates to a marking liquid which contains a polymer dispersion with particles which are colored with marking agent, optionally further dyes and marking agents, one or more salts of a polyvalent, in particular bi- or trivalent cation, water and optionally moisture retaining agents and further usual additives, wherein the polymer forming the polymer particles is selected from the group of polyesters, polyester amides, polymers and copolymers based on acrylate or methacrylate with a proportion of free carboxylic acid groups of less than 10% by weight, melamine-formaldehyde-sulfonamide resins and mixtures thereof.
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: April 29, 2008
    Assignee: Schwan-STABILO Schwanhausser GmbH & Co. KG
    Inventors: Hans-Dieter Denninger, Thomas Spengler, Ivan Horvat, Klaus-Dieter Schröder
  • Publication number: 20080087190
    Abstract: Disclosed is a phase change ink containing a fluorescent colorant that upon exposure to activating energy fluoresces such that an image that was not visible prior to exposure to the activating energy becomes visible. Also disclosed are an ink jet system and a process for authenticating a color document using the disclosed phase change ink.
    Type: Application
    Filed: October 12, 2006
    Publication date: April 17, 2008
    Applicant: XEROX CORPORATION
    Inventors: Gabriel IFTIME, Christopher A. WAGNER, C. Geoffrey ALLEN, Peter M. KAZMAIER, Peter G. ODELL, Paul F. SMITH
  • Patent number: 7351277
    Abstract: The present invention pertains to a cyan dye-based inkjet ink having substantially no absorption in the near-infrared region of the spectrum (near-IR transparent). The invention further pertains to a dye-based inkjet ink set comprising this near-IR transparent cyan ink.
    Type: Grant
    Filed: August 22, 2005
    Date of Patent: April 1, 2008
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Christian Jackson
  • Patent number: 7347891
    Abstract: A water base ink set for ink-jet recording includes a black ink containing water, a black pigment and a water-soluble organic solvent and a color ink containing water, a dye, and a water-soluble organic solvent. The black pigment is a negatively-chargeable and self-dispersible pigment. The dye has a fluorescein structure. The color ink further contains an alkylamine ethylene oxide adduct. The water-soluble organic solvent contained in the black ink is same as that contained in the color ink. With the ink set, not only the bleeding hardly occurs but also satisfactory discharge stability is obtained even when an ink-jet recording is performed on a regular paper.
    Type: Grant
    Filed: June 16, 2005
    Date of Patent: March 25, 2008
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Akihiko Taniguchi, Kazuma Goto, Hideo Ohira, Masaya Fujioka, Shunichi Higashiyama
  • Patent number: 7344587
    Abstract: The invention provides tissue markings (such as tattoos) comprising magnetic particles, e.g., magnetite, and methods for making and altering, e.g., removing them.
    Type: Grant
    Filed: August 6, 2004
    Date of Patent: March 18, 2008
    Assignee: The General Hospital Corporation
    Inventors: Misbah H. Khan, Richard Rox Anderson
  • Patent number: 7341334
    Abstract: An ink supply system for a printer including an inner chamber comprising a controlled security ink; an outer chamber comprising a chemical; an ink conduit from the inner chamber through and out of the outer chamber; and a rupture wall at a junction between the inner chamber and the outer chamber. The ink conduit keeps the chemical away from the ink when the ink travels from the inner chamber out of the ink supply system. When the rupture wall is ruptured, the chemical is adapted to interact with the controlled security ink to indicate that the rupture has occurred.
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: March 11, 2008
    Assignee: Pitney Bowes Inc.
    Inventors: Judith D. Auslander, Douglas B. Quine
  • Patent number: 7338553
    Abstract: A process for printing an image on a substrate comprising applying to the substrate an ink comprising a compound of Formula (1) or a salt thereof: wherein: R1 and R2 are each independently H or a substituent; each X and Y independently is a substituent; and a and b are each independently 0, 1, 2, 3 or 4. The compounds used in the process have particularly good ozone fastness and are suitable for preparing inks which can be ink jet printed.
    Type: Grant
    Filed: September 21, 2006
    Date of Patent: March 4, 2008
    Assignee: Fujifilm Imaging Colorants Limited
    Inventor: Clive Edwin Foster
  • Patent number: 7329314
    Abstract: An ink for ink-jet recording includes a solvent dye in which a xanthene structure and a phthalide structure are spiro bound to each other. When the ink is stored in an ink cartridge containing a polyurethane foam and ink-jet recording is performed, a stable printing density may be achieved and changes in hue may be avoided.
    Type: Grant
    Filed: March 2, 2007
    Date of Patent: February 12, 2008
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Hiromitsu Sago, Michiko Aoyama
  • Publication number: 20070263057
    Abstract: The present invention pertains to a cyan dye-based inkjet ink having substantially no absorption in the near-infrared region of the spectrum (near-IR transparent). The invention further pertains to a dye-based inkjet ink set comprising this near-IR transparent cyan ink.
    Type: Application
    Filed: May 4, 2007
    Publication date: November 15, 2007
    Inventors: Michael J. Eiseman, Kuo Hsiung Kung
  • Patent number: 7294182
    Abstract: The present invention provides a composition for water-removable ink with an effect of coupling retardation by using an aliphatic alcohol as a solvent, which is selected from a group comprising n-butyl alcohol, n-propyl alcohol, isopropyl alcohol and pentanol, so that the curiosity of infants or juveniles can be stimulated to enhance the learning effect and also various desires of students or adults can be satisfied in terms of ornamental purposes.
    Type: Grant
    Filed: July 15, 2005
    Date of Patent: November 13, 2007
    Assignee: Artech Plus Co., Ltd.
    Inventors: Dong Kyun Jang, Dong Joo Kwon
  • Publication number: 20070245925
    Abstract: A no-mess water-based ink including a composition including water, an organic solvent, a coloring agent dissolved in the organic solvent, an emulsifier and a thickening agent for use in conjunction with a specially treated substrate containing a color developer.
    Type: Application
    Filed: August 3, 2006
    Publication date: October 25, 2007
    Inventors: Jie Li, Leena Vadaketh, Jacqueline Aseng
  • Patent number: 7285158
    Abstract: An image forming method, device and a recording agent for forming an image through subtractive color mixing by using ink of plural color components different in hue. The ink is created by mixing a first coloring agent expressing one of the color components and a second coloring agent identical in hue to the first coloring agent. The ink has a higher spectral reflectance than a spectral reflectance of the first coloring agent.
    Type: Grant
    Filed: March 25, 2004
    Date of Patent: October 23, 2007
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Takuya Iwanami, Haruo Yamamoto, Satoshi Nishigaki, Tohru Sakuwa
  • Publication number: 20070236550
    Abstract: An ink for ink-jet recording may contain a coloring agent and a marker. The coloring agent may contain a dye. The marker may contain at least one of a dye and a pigment, and has a detector absorption peak for detecting the marker at a wavelength that is different from a wavelength of the maximum absorption peak of the coloring agent. The coloring agent and the marker are contained in the ink in amounts that satisfy the following conditions (I) to (III): (I) about 1.2?A2/ A3; (II) color difference (?E)?about 3; and (III) about 0.001?A2?about 5 in terms of a measurement optical path length of 1 mm, where A2 denotes an absorbance at the wavelength of the detector absorption peak of the marker, A3 denotes a baseline absorbance at the wavelength of the detector absorption peak of the marker.
    Type: Application
    Filed: April 10, 2007
    Publication date: October 11, 2007
    Applicant: BROTHER KOGYO KABUSHIKI KAISHA
    Inventor: Tatsunosuke Hoshi
  • Patent number: 7252708
    Abstract: A fluorescent water base ink for ink-jet recording contains a first fluorescent dye and a second fluorescent dye. The first fluorescent dye has a first ultraviolet absorption wavelength region in an absorption spectrum and a first fluorescence emission wavelength region in a fluorescence spectrum. The second fluorescent dye has a second ultraviolet absorption wavelength region which is different from the first ultraviolet absorption wavelength region in an absorption spectrum and a second fluorescence emission wavelength region in a fluorescence spectrum. The first fluorescent dye further has an absorption wavelength region which is different from the first ultraviolet absorption wavelength region and which overlaps at least a part of the second fluorescence emission wavelength region.
    Type: Grant
    Filed: September 24, 2004
    Date of Patent: August 7, 2007
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Michiko Aoyama, Masashi Tsuda, Hiromitsu Sago, Mayuko Umemura, Hideto Yamazaki, Shunichi Higashiyama
  • Patent number: 7244300
    Abstract: An inkjet recording ink of giving an image having high image quality and excellent weather resistance is provided, which is an inkjet recording ink comprising a specific phthalocyanine dye, wherein the total amount of cations in the ink except for a lithium ion, a hydrogen ion, an ammonium ion, an organic quaternary nitrogen ion and an ion produced by the proton addition to a nitrogen atom in a basic organic material is 0.5 wt % or less.
    Type: Grant
    Filed: September 24, 2003
    Date of Patent: July 17, 2007
    Assignee: Fujifilm Corporation
    Inventor: Toshiki Taguchi
  • Patent number: 7229487
    Abstract: Improved eradicating fluids and eradicable inks are disclosed. A color changing eradicating fluid is disclosed which includes a volatile base, a pH sensitive dye and an eradicating agent whereby the dye changes color as the volatile base evaporates thereby provided a visual indication to the user when the eradicating fluid is sufficiently dry and ready to receive a corrected marking. A non-color changing eradicating fluid having a more moderate pH is also disclosed. The combination eradicable and re-write ink is disclosed which features phosphoric acid (or phosphorus pentoxide in solution) along with an eradicable dye. A combination writing and correction instrument that combines a disclosed eradicating fluid and a combination eradicable and re-write ink is also disclosed.
    Type: Grant
    Filed: January 14, 2004
    Date of Patent: June 12, 2007
    Assignee: Sanford, L.P.
    Inventor: David Godbout
  • Patent number: 7220301
    Abstract: Disclosed herein is an ink comprising (i) first and second organic compounds which are incompatible with each other; (ii) at least one of a compound exhibiting fluorescence properties and a coloring material exhibiting fluorescence properties; and (iii) a liquid medium dissolving or dispersing the components (i) and (ii) therein.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: May 22, 2007
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akira Nagashima, Shinichi Hakamada
  • Patent number: 7214259
    Abstract: An ink comprising a liquid medium and a colorant, wherein the liquid medium comprises water and a water-miscible organic solvent and the colorant is of Formula (1), wherein the colorant is dissolved in the liquid medium: Formula (1) wherein: each independently is a water-solubilising group selected from sulfo, carboxy, phosphato and poly(ethylene oxide); each Z independently is optionally substituted alkyl, optionally substituted aryl or optionally substituted aralkyl; each Q independently is a direct bond or —NR— wherein R is H, optionally substituted aryl or optionally substituted alkyl; rings A,B,C and D are each independently unsubstituted or carry a substituent selected from optionally substituted alkyl, optionally substituted aryl and optionally substituted aralkyl; each n independently is from 1 to 3; and each m independently is 0, 1 or 2; provided that when either or both of the groups represented by Q is a direct bond then at least one n has a value of at least 2.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: May 8, 2007
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: Clive Edwin Foster, David Schofield, Helen Ava O'Shaughnessy
  • Patent number: 7192476
    Abstract: A fluorescent water base ink for ink-jet recording contains a fluorescent dye having a xanthene skeleton, and a glycol. In the fluorescent dye, the difference in hydrophilic index log P is not less than 2.6 between a substituent bonded to C-9 carbon atom of the xanthene skeleton and other portion of the fluorescent dye than the substituent bonded to the C-9 carbon atom. The glycol has a distance between hydroxyl groups substantially equivalent to or longer than an interatomic distance between atoms directly bonded to C-3 and C-6 carbon atoms of the xanthene skeleton of the fluorescent dye, respectively. It is assumed that the glycol is coordinated with the xanthene skeleton in a bridge form to increase the fluorescence intensity by increasing the electron density of the xanthene skeleton. The ink having high fluorescence intensity and in which the fluorescence intensity is not lowered in a time-dependent manner is provided.
    Type: Grant
    Filed: October 21, 2004
    Date of Patent: March 20, 2007
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Mayuko Umemura, Masashi Tsuda, Hideto Yamazaki, Hiromitsu Sago, Michiko Aoyama, Shunichi Higashiyama
  • Patent number: 7192474
    Abstract: Water-soluble, photosensitive, optically variable (POV) inks exhibit improved OCR readability due to improved infrared absorption properties. The inks can produce images that can be viewed with both visible and ultraviolet light to have physically coincident positive and negative images. The new inks contain at least two types of colorants in addition to the IR absorber and other suitable ingredients. The first colorant comprises a fluorescent dye or pigment emitting light within a characteristic emission band when excited by fluorescent-exciting radiation. The second colorant comprises a carbon black infrared radiation absorbing composition alone or with one or more dyes or pigments having a light absorption band at longer wavelengths than the characteristic emission band of the first colorant or also overlapping the emission wavelength of the first colorant in such a way as to result in a dark color.
    Type: Grant
    Filed: June 22, 2004
    Date of Patent: March 20, 2007
    Assignee: Pitney Bowes Inc.
    Inventors: Judith D. Auslander, Mike Y. R. Chen
  • Patent number: 7163575
    Abstract: Improved combination eradicable ball-pen and re-write inks are disclosed. The combination eradicable and re-write ball-pen inks disclosed include water, glycerol, one or more acids and an eradicable dye. Glycerol is present in an amount greater than the water content, which is relatively low and the eradicable dye is provided in substantial amounts so that the glycerol and eradicable dye provide the requisite viscosity for a ball-pen ink. The combination of the high dye content and acid content also enables the eradicable ball-pen ink to be used as the re-write ink.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: January 16, 2007
    Assignee: Sanford, L.P.
    Inventors: Wing Sum Vincent Kwan, David Allen Godbout
  • Patent number: 7153350
    Abstract: In accordance with one embodiment of the present invention, a colorant in an ink jet ink formulation is disclosed. The colorant comprises an organic dye chromophore with at least one functional group Y containing one or more primary, secondary or tertiary amino groups, which in the presence of an acid provides a water soluble, cationic ink jet ink colorant with increased water fastness when applied to paper.
    Type: Grant
    Filed: December 10, 2003
    Date of Patent: December 26, 2006
    Assignee: Pitney Bowes Inc.
    Inventors: Judith D. Auslander, John Griffiths, John Mama
  • Patent number: 7147801
    Abstract: Disclosed is an ink composition suitable for ink jet printing comprising a luminescent compound, a solvent, and an energy active compound, and optionally a non-luminescent colorant. The energy active compound, when exposed to energy, generates one or more active species that can react with the luminescent compound to alter one or more of the characteristics of the luminescent compound. The luminescent compound can be colored or colorless. Also disclosed is a method for marking substrates comprising providing a mark comprising a luminescent compound and an energy active compound. Further disclosed is a jet ink composition suitable for printing on substrates authentication or security marks which can be rendered unreadable. The luminescence of the mark is quenched and the visible color is changed when irradiated with a light.
    Type: Grant
    Filed: March 12, 2004
    Date of Patent: December 12, 2006
    Assignee: Videojet Technologies Inc.
    Inventors: Michael Kozee, Steven D. Looman, John P. Folkers
  • Patent number: 7147696
    Abstract: A fluorescent water base ink for ink-jet recording to be used for an ink-jet printer contains water, a pigment, a compound having primary or secondary amide group, and a fluorescent dye represented by the following formula (1): wherein R1 represents OH or N(R3)R4, R2 represents hydrogen atom or halogen atom, and each of R3 and R4 represents hydrogen atom or alkyl group. A sufficient OD value and a fluorescence value are obtained while securing the vivid color development and the excellent water resistance principally in accordance with the interaction of the fluorescent dye and the compound having the amide group.
    Type: Grant
    Filed: August 12, 2004
    Date of Patent: December 12, 2006
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Michiko Aoyama, Masashi Tsuda, Hideto Yamazaki, Hiromitsu Sago, Mayuko Umemura, Shunichi Higashiyama
  • Patent number: 7144105
    Abstract: Disclosed herein is an ink including (i) first and second organic compounds which are incompatible with each other; (ii) at least one of a compound exhibiting fluorescence properties and a coloring material exhibiting fluorescence properties; and (iii) a liquid medium dissolving or dispersing the components (i) and (ii) therein.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: December 5, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akira Nagashima, Shinichi Hakamada
  • Patent number: 7144449
    Abstract: The present invention provides a fluorescence ink having a high fluorescence intensity, and an ink jet recording method using the same. The ink contains a first fluorescent coloring material that emits fluorescence at a predetermined fluorescence wavelength to be used for measurement or determination with excitation at a predetermined excitation wavelength, a second fluorescent coloring material that emits fluorescence on excitation at the predetermined excitation wavelength, where the excitation spectrum of the first coloring material in the ink to obtain the fluorescence at the predetermined emission wavelength has a peak wavelength range next to the predetermined fluorescence wavelength, and the emission fluorescence spectrum of the second coloring material has an emission wavelength region substantially including at least the above peak wavelength range.
    Type: Grant
    Filed: June 14, 2004
    Date of Patent: December 5, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masako Udagawa, Sadayuki Sugama, Shoji Koike, Makoto Aoki, Akira Nagashima, Shinichi Hakamada
  • Patent number: 7141103
    Abstract: New photosensitive optically variable inks are capable of printing images having improved resistance to water. The inks produce images which can be viewed with both visible and ultraviolet light to have physically coincident positive and negative images. They contain at least two types of colorants and other suitable ingredients to enable preparation for printing. The first colorant comprises a fluorescent dye emitting light within a characteristic emission band when excited by fluorescent-exciting radiation. The second colorant, which comprises a colloidal pigment alone or with a dye, has a light absorption band at longer wavelengths than the characteristic emission band of the first colorant or overlapping the emission wavelength of the first colorant, effectively to result in a dark color.
    Type: Grant
    Filed: June 22, 2004
    Date of Patent: November 28, 2006
    Assignee: Pitney Bowes Inc.
    Inventors: Judith D. Auslander, Mike Y. R. Chen
  • Patent number: 7141105
    Abstract: The present invention relates to a water-based fluorescent ink for the purpose of measurement or judgment of the fluorescence emission in a visible light region by an excitation wavelength in a predetermined ultraviolet range, containing water, a coloring material dissolved or dispersed in water, and an organic solvent, having a plurality of fluorescent groups in the coloring material structure of the coloring material, and using a water-soluble coloring material having a sulfonic acid group as the water-soluble group in the state of a free acid, capable of improving the water resistance and the light resistance, dramatically increasing the content of the fluorescent coloring material in the ink, which has conventionally been included only by a small amount in the ink due to the concentration quenching problem, obtaining preferable fluorescence emission and water resistance of the recorded image, and providing preferable adhesion resistance to the recording medium of the coloring material and reliability.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: November 28, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masako Udagawa, Shoji Koike, Makoto Aoki, Akira Nagashima, Shinichi Hakamada
  • Patent number: 7138009
    Abstract: Signature protected photosensitive optically variable (POV) inks are provided, which are capable of providing a unique signature in addition to other security features of POV inks. The inks contain at least two types of colorants, and a third, signature component and other ingredients to enable printing. A first colorant comprises a fluorescent dye and/or pigment emitting light within a characteristic emission band when excited by fluorescent-exciting radiation. A second colorant comprises a dye and/or pigment having a light absorption band at overlapping or longer wavelengths than the characteristic emission band of the first colorant in such a way as to result in a dark color. The third component is a fluorescent/phosphorescent rare earth composition. The inks give dark visible ink images, which also produce detectable coincident fluorescent and phosphorescent images. The inks can be used with detectors of red phosphorescence to achieve a new level of security in high speed sorting operations.
    Type: Grant
    Filed: June 22, 2004
    Date of Patent: November 21, 2006
    Assignee: Pitney Bowes Inc.
    Inventor: Judith D. Auslander
  • Patent number: 7118618
    Abstract: The colored liquid composition of the invention for a highlighter comprises a coloring element and water, the water content by weight lies in the range 10% to 30%. In addition, it comprises at least 40% of a liquid component having surface tension greater than 40 mN/m. In a variant, the coloring element is a tracer solvent having a fluorescent appearance under basic pH, in particular hydroxypyrenetrisulfonic acid, the pH of the composition lying in the range 8 to 9, and the component having surface tension greater than 40 mN/m is triethanolamine. Under such circumstances, the composition contains an acid to neutralize the triethanolamine in part in order to obtain the basic pH, for example hydrochloric acid.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: October 10, 2006
    Assignee: Conte
    Inventors: José Duez, Carine Bethouart
  • Patent number: 7083666
    Abstract: An inkjet ink comprising a dye, water, a water-soluble organic solvent and a betaine compound, wherein the total weight of inorganic ions in the ink is 2 wt % or less based on the ink.
    Type: Grant
    Filed: March 23, 2004
    Date of Patent: August 1, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiki Taguchi, Manabu Ogawa
  • Patent number: 7083665
    Abstract: A highlightable ink including a colored pigment and an eradicable colorant; a kit including the highlightable ink and an eradicator solution; an ink complex including a colorless or substantially colorless eradicable dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, and methine dyes, and a colored pigment; and methods of applying an eradicator to at least a portion of a marking made with a highlightable ink, are disclosed herein.
    Type: Grant
    Filed: October 7, 2003
    Date of Patent: August 1, 2006
    Assignee: Sanford, L.P.
    Inventors: Leighton Davies-Smith, Vincent Wing Sum Kwan
  • Patent number: 7063806
    Abstract: The present invention relates to fluorescent diketopyrrolopyrroles (“DPPs”) of the formula characterized in that that at least two adjacent substituents R5 to R11 form an aromatic or aliphatic fused ring system, or at least one substituent R5 to R11 is cycloalkyl, aralkyl, alkenyl, cycloalkenyl, alkynyl, a hydroxyl group, a mercapto group, alkylthio, an aryl thioether group, a heterocyclic group, halogen, haloalkyl, haloalkenyl, haloalkynyl, a cyano group, an aldehyde group, a carbonyl group, a carboxyl group, an ester group, a carbamoyl group, a nitro group, a silyl group, a siloxanyl group, a substituted or unsubstituted vinyl, arylamino or diarylamino group; a process for their preparation and their use for the preparation of inks, colorants, pigmented plastics for coatings, non-impact-printing material, color filters, cosmetics, or for the preparation of polymeric ink particles, toners, dye lasers and electroluminescent devices.
    Type: Grant
    Filed: June 20, 2002
    Date of Patent: June 20, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Hiroshi Yamamoto, Norihisa Dan, Olof Wallquist
  • Patent number: 7060123
    Abstract: A novel fluorescent ink is provided which contains at least a coloring material and an aqueous liquid medium for dissolving the coloring material, wherein the coloring material comprises C.I. Acid Red 52 and at least one direct dye, the content of the C.I. Acid Red 52 ranging from 0.1 to 0.4% by weight based on the total amount of the ink, and the content of the direct dye ranging from 0.15 to 0.4% by weight based on the total amount of the ink, and the weight ratio of the direct dye to the C.I. Acid Red 52 is not higher than 1.6. This fluorescent ink is capable of forming prints with fluorescence of high intensity and with high water resistance.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: June 13, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shinichi Hakamada, Shoji Koike, Akira Nagashima
  • Patent number: 6946023
    Abstract: In general, a smear-resistant ink composition according to the present invention comprises: (1) water; (2) at least one glycol selected from the group consisting of diethylene glycol, ethylene glycol, glycerol, and propylene glycol; (3) a pyrrolidone selected from the group consisting of 2-pyrrolidone and 3-pyrrolidone; and (4) at least one colorant that produces a detectable fluorescent color when the ink composition is applied to paper. Preferably, the pyrrolidone is 2-pyrrolidone. In one preferred embodiment, the at least one glycol comprises diethylene glycol and ethylene glycol. In another preferred embodiment, the at least one glycol comprises diethylene glycol, ethylene glycol, and propylene glycol. The composition can comprise other ingredients, such as a basic color stabilizer, a resin, a resin modifier that is a carbonate salt, a biocide, and a nonionic surfactant. The colorants can be formulated to produce a pink, yellow, blue, green, purple, or orange color; other colors are possible.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: September 20, 2005
    Assignee: Avery Dennison Corporation
    Inventors: Thomas Mammen, Robert Valadez
  • Patent number: 6936096
    Abstract: The invention relates to an ink composition which is solid at room temperature and liquid at a higher temperature, comprising a non-aqueous carrier composition and two compatible dyes, one of which is fluorescent and one non-fluorescent, wherein the said dyes are of the same type. In one embodiment, the dyes in the ink are both of the anthraquinone type.
    Type: Grant
    Filed: April 20, 2004
    Date of Patent: August 30, 2005
    Assignee: Oce-Technologies B.V.
    Inventor: Marcus P. L. Huinck
  • Patent number: 6913860
    Abstract: An image forming material for forming an image on an image recording material with an image binding force being established between the image and the image recording material, the image forming material containing an image forming substance, and a binding force reducing substance which reduces the image binding force when the image is heated. A method of removing an image formed on an image recording material with a binding force being established between the image and the recording material by contacting a stripping member with the image with heating under pressure. A binding force reducing substance may be contained in the surface of the stripping member or in the image recording material.
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: July 5, 2005
    Assignee: Ricoh Company, Ltd.
    Inventors: Hidehiro Mochizuki, Tadashi Saitou
  • Patent number: 6905538
    Abstract: Water-based invisible red fluorescent inks provide machine-readable, inverse contrast invisible images and can be printed using conventional ink jet printers. The inks employ rare earth complexed ligand fluorophores having narrow excitation and emission spectra. In one embodiment the images are printed with an ink comprising water and a water-soluble organic fluorescent fluorophore, which when printed and dried on paper is invisible to the eye and fluoresces in the green to infrared range, e.g., from about 550 to 1200 nm, when irradiated with short wave length UV radiation, e.g., from 230 nm to 280 nm. The highly specific excitation and emission rates, coupled with a high inverse contrast on papers of all colors, makes them particularly useful as ink jet inks for postal and other purposes.
    Type: Grant
    Filed: December 30, 2002
    Date of Patent: June 14, 2005
    Assignee: Pitney Bowes Inc.
    Inventor: Judith D Auslander
  • Patent number: 6906019
    Abstract: A method of making a printing plate in which the uncoated surface of a substrate is treated with a pre-treatment solution prior to the deposition of ink on the surface. The pre-treatment liquid comprises a polyvalent metal salt, and at least one of an organic swelling reagent and/or a coalescence reagent. The pre-treatment liquid is applied to form a thin, homogenous layer of approximately 4 ?m to the entire upper surface of the recording plate. The swelling reagent and/or the coalescence reagent and the polyvalent metal cations are physically well localized in the porous structure of the plate's surface. After partial drying of the pretreated anodized aluminum plate, CTP liquid is deposited onto the surface to form an image. The CTP liquid solids react with the pre-treatment liquid and are, therefore, chemically bound to the surface. This allows all data to be deposited in a single pass of the inkjet head without the problem of clustering.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: June 14, 2005
    Assignee: Aprion Digital Ltd.
    Inventors: Boaz Nitzan, Moshe Frenkel
  • Patent number: 6905539
    Abstract: A shear-thinning eradicable ink including water, a dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, methine dyes, and a solvent, wherein the ink has a shear-thinning index in the range of about 0.35 to about 1.0; a kit including the ink and an eradicator solution; an ink complex including a colorless or substantially colorless dye selected from the group consisting of oxidized diarylmethane derivatives, oxidized triarylmethane derivatives, and oxidized methine dyes, and at least one or a gelling agent and thickener; and methods of using the ink as part of an eradicable ink system, are disclosed herein.
    Type: Grant
    Filed: July 15, 2003
    Date of Patent: June 14, 2005
    Assignee: Sanford L.P.
    Inventors: Sanjay Patel, David Godbout, Wing Sum Vincent Kwan