Mica, Shell, Scale, Platelet, Or Lamellate Patents (Class 106/415)
  • Patent number: 5885342
    Abstract: Colored lustrous pigments of superior quality are prepared by dry blending a metal oxide-coated mica nacreous pigment and a colorant lake with a blend adjuvant. The resulting blend exhibits a well dispersed, stable coloration, increased hydrophobicity and is particularly useful in cosmetic applications.
    Type: Grant
    Filed: May 9, 1997
    Date of Patent: March 23, 1999
    Assignee: Engelhard Corporation
    Inventors: Jeannine M. Gale, Betty F. Aucar, James D. Christie
  • Patent number: 5871827
    Abstract: This application discloses two-coat and three-coat automotive finishes, articles coated by an automotive finish and a process for their preparation wherein polychromism is achieved in the finish by incorporating an opaque, light interference pigment into the topcoat or a midcoat. The invention further relates to a coating composition which contains an opaque interference pigment at a pigment to binder ratio of less than 7/100.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: February 16, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Edward Ephraim Jaffe, Franklin Roberts Hilfiker, Milton John Misogianes
  • Patent number: 5858078
    Abstract: Plateletlike, substrate-free titanium dioxide pigment obtainable by solidifying an aqueous solution of a thermally hydrolyzable titanium compound on a continuous belt, detaching the resulting layer, coating the resulting titanium dioxide platelets, with or without drying in between, with further titanium dioxide by a wet method, and separating off, drying and calcining the material obtained.
    Type: Grant
    Filed: January 9, 1998
    Date of Patent: January 12, 1999
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Stefanie Andes, Gerd Bauer, Gunter Brenner, Dieter Bruckner, Andrea Heyland, Matthias Kuntz, Karl Osterried, Gerhard Pfaff, Michael Schmelz
  • Patent number: 5855660
    Abstract: The invention relates to a pigment comprising(a) a flat core and(b) at least one coating consisting of at least two different substances that is applied to the surface of the core,whereinthe coating (b) has a substantially continuously variable composition in the axis lying perpendicular to its surface, andthe refractive indices of the coating (b) at the surface facing the core (a) and at the surface remote from the core (a) are different.An outer coating (c) may additionally have been applied to the coating (b). The pigment may be embedded in a high molecular weight organic material, the refractive index of the coating (b) at its surface that is remote from the core (a) and the refractive index of the high molecular weight organic material being different. Preferred embodiments relate to specific refractive index ranges and differences.
    Type: Grant
    Filed: April 22, 1998
    Date of Patent: January 5, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Patrice Bujard, Natacha Bonnard, Ryuichi Takahashi
  • Patent number: 5849817
    Abstract: The present invention relates to a metal pigment, comprising a particle, preferably a flake, of iron or an alloy thereof, having on its surface a colored coating, formed by exposing the said particle to an elevated temperature in an oxygen-containing atmosphere. The product finds use in surface coatings and in the mass coloration of plastics, especially where a colored "glitter" effect is required.
    Type: Grant
    Filed: November 7, 1997
    Date of Patent: December 15, 1998
    Assignee: Silberline Limited
    Inventors: William Innes Green, Jonathan Joseph Whistler Knox
  • Patent number: 5843220
    Abstract: The present invention relates to a process for preparing a pigment composition whereby a mixture of an organic pigment and an inorganic filler is subjected to an air jet milling step. The inventive process is an environmentally friendly process which yields pigments having outstanding dispersibility and wetting characteristics when incorporated in plastics, aqueous or solvent based coatings and inks.
    Type: Grant
    Filed: December 1, 1997
    Date of Patent: December 1, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Babler
  • Patent number: 5827361
    Abstract: The invention relates to carbon-containing pigments having improved abrasion resistance and dispersibility and to their production.
    Type: Grant
    Filed: March 29, 1995
    Date of Patent: October 27, 1998
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Klaus Bernhardt, Reiner Vogt, Gerhard Pfaff
  • Patent number: 5824144
    Abstract: A pigment in the form of metallic platelets is mixed with a sticky viscous liquid. The resulting pigment can be combined with a powdery film-forming polymer to produce a film-forming composition which can be applied by electrostatic coating.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: October 20, 1998
    Assignee: Engelhard Corporation
    Inventors: Mingbo He, Michael T. Venturini
  • Patent number: 5772747
    Abstract: A sealant composition especially useful for stopping punctures in vehicle tires includes: (a) a viscous fluid such as propylene glycol or polypropylene glycol; (b) one or more fibrous materials such as cellulose, wool, nylon, rayon, hair, wollastonite, rock-wool, glass wool fibers, polyester, polypropylene, or other material of like nature; and (c) flat plate-like particles, such as mica. In one embodiment, the composition is too viscous to be readily passed through a pneumatic tire valve stem, so the viscous product is installed into the tire while the tire is dismounted from the wheel. In another embodiment, the composition is made of two parts, each of which is sufficiently low in viscosity to pass readily through the valve stem, but which react on mixing inside the tire form a liquid of higher viscosity.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: June 30, 1998
    Assignee: Peter Chun
    Inventors: Ronald L. Turner, John A. Elverum
  • Patent number: 5766335
    Abstract: The invention relates to colored luster pigments consisting of a transparent or metallic reflecting core, of a coating consisting of at least one silicon oxide of the composition SiO.sub.0.25 to SiO.sub.0.95 and of further optional coatings, to coating processes by coating metallic silicon in the presence of oxygen, if required with changing its partial pressure, as well as to the use of these luster pigments for pigmenting plastic materials, paints and printing inks, and to pigmented compositions comprising these luster pigments.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: June 16, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Patrice Bujard, Natacha Bonnard
  • Patent number: 5759257
    Abstract: The present invention relates to color pigments based on substrates which are coated with a doped layer of iron(III) oxide, to processes for their preparation and to their use, especially in aqueous coating systems.
    Type: Grant
    Filed: May 10, 1996
    Date of Patent: June 2, 1998
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Klaus Ambrosius, Matthias Schraml-Marth
  • Patent number: 5753371
    Abstract: A pearlescent pigment consists essentially of C glass flakes having a layer comprising rutile titanium dioxide or iron oxide thereon. A hydrous layer of the rutile forming titanium dioxide or iron oxide is formed on the glass flakes and the resulting coated flakes are calcined.
    Type: Grant
    Filed: June 3, 1996
    Date of Patent: May 19, 1998
    Assignee: The Mearl Corporation
    Inventors: William J. Sullivan, Patricia Elliot, Dana Fleming
  • Patent number: 5753023
    Abstract: A method for manufacture of a small dimension product using a dissolvable crystal. The crystal is coated with at least one layer of vacuum deposited material to form a coated crystal. The coated crystal is mixed with a liquid to dissolve the crystal and permit the layer of material to break into flakes. The flakes are separated from the liquid.
    Type: Grant
    Filed: April 30, 1996
    Date of Patent: May 19, 1998
    Assignee: Flex Products, Inc.
    Inventor: Charles A. Bishop
  • Patent number: 5753024
    Abstract: Tin-containing grey pigments of high opacity, processes for their preparation and use thereof.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: May 19, 1998
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Reiner Vogt, Klaus Bernhard, Gerhard Pfaff, Matthias Kuntz, Susanne Rudolph, Sylvia Schmidt
  • Patent number: 5749946
    Abstract: A pigment preparation comprising(i) 10-80% by wt. of a platelet-shaped substrate coated with a metal oxide, and(ii) 20-90% by wt. of an active pigment.
    Type: Grant
    Filed: May 3, 1996
    Date of Patent: May 12, 1998
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Ralf Glausch, Georg Reinhard, Renate Jircik, Ursula Rammelt
  • Patent number: 5749957
    Abstract: Effect powder coating compositions which contain 0.1-10% by weight of conductive pigments, the process for their preparation and their use.
    Type: Grant
    Filed: November 22, 1995
    Date of Patent: May 12, 1998
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Manfred Kieser, Afred Hennemann, Otto Stahlecker
  • Patent number: 5735939
    Abstract: A pigment preparation for anti-corrosion coating materials, comprising(i) 3-40% by weight of a monomeric or polymeric, metal-free or metal-containing chelate-forming compound, preferably a phthalocyanine,(ii) 3-40% by weight of a material in flake form, preferably mica, and(iii) 25-80% by weight of a hydroxide ion-binding material, preferably a metaphosphate, di- or triphosphate. In a further embodiment, the pigment preparation additionally contains 5-65% by weight of a conductive pigment.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: April 7, 1998
    Assignee: Merck Patent Gesellschaft MIT Beschrankter Haftung
    Inventors: Ralf Glausch, Georg Reinhard, Renate Jircik, Ursula Rammelt
  • Patent number: 5733364
    Abstract: Goniochromatic luster pigments based on multiply coated platelet-shaped metallic substrates comprising at least one layer packet ofA) a layer consisting essentially of silicon oxide, silicon oxide hydrate, aluminum oxide and/or aluminum oxide hydrate, andB) a metallic layer which consists essentially of aluminum and is at least partially transparent to visible light,and also, if desired, additionallyC) an outer layer which consists essentially of colorless or selectively absorbing metal oxide and/or is phosphate-, chromate- and/or vanadate-containing,are useful for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: March 31, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga, Jorg Adel
  • Patent number: 5707439
    Abstract: Novel silicate minerals that have undergone a cation exhange with at least one heteroaromatic cation comprising a positively charged organo-substituted heteroatom and/or at least one positively charged heteroatom not part of an aromatic ring with at least one bond having a bond order greater than one and compositions comprising the same are described.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: January 13, 1998
    Assignee: General Electric Company
    Inventors: Tohru Takekoshi, Farid Fouad Khouri, John Robert Campbell, Therese Coste Jordan, Kevin Hsingtao Dai
  • Patent number: 5702518
    Abstract: Gold pigments of high opacity and processes for their preparation and use.
    Type: Grant
    Filed: June 21, 1996
    Date of Patent: December 30, 1997
    Assignee: Merck Patent Gesellschaft mit ceschrankter Haftung
    Inventors: Reiner Vogt, Klaus Bernhard, Gerhard Pfaff
  • Patent number: 5693134
    Abstract: An interference pigment comprising a platelet-shaped substrate coated with titanium dioxide and additionally oxidic compounds of copper and manganese, whereby the pigment powder color is dark gray.
    Type: Grant
    Filed: December 29, 1994
    Date of Patent: December 2, 1997
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventor: Alfred Stephens
  • Patent number: 5693135
    Abstract: Interference pigments based on titanium dioxide-coated silicatic platelets which have been heated in a reducing atmosphere are useful for producing forgeryproof documents and packaging.
    Type: Grant
    Filed: December 2, 1996
    Date of Patent: December 2, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga, Claus Kaliba, Werner Ostertag, Helmut Schmidt
  • Patent number: 5672200
    Abstract: A pigment composition containing one or more luster pigments, a phosphate derivative and spherical particles having a particle size of 0.05-150 .mu.m useful, especially, in printing inks.
    Type: Grant
    Filed: December 26, 1995
    Date of Patent: September 30, 1997
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Dieter Heinz, Heinz Mohr, Joachim Weitzel
  • Patent number: 5667580
    Abstract: The disclosure describes pigment compositions containing an organic pigment and a transparent filler having a mean particle size less than 10 .mu.m and a narrow particle size distribution; as well as methods of preparing the pigment compositions. The pigment compositions are useful for pigmenting high-molecular-weight organic materials; especially coating compositions, curable ink systems, plastics, as well as for use in laser marking applications.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 16, 1997
    Assignee: Ciba-Geigy Corporation
    Inventor: Fridolin Babler
  • Patent number: 5653792
    Abstract: An article with a surface with a paint film adherent thereto having a liquid medium hardened into a solid to form said paint film and having first and second parallel surfaces with the first parallel surface being adhered to the surface of the article and the second surface exposed to be viewed by the human eye. A plurality of flakes are provided having first and second planar parallel surfaces lying in said paint film with the first and second planar parallel surfaces being parallel to the first and second parallel surfaces of the paint film. The flakes are characterized in that they have physical dimensions such that when the dimensions of the flakes are measured parallel to and perpendicular to the respective first and second planar parallel surfaces, an aspect ratio of at least two-to-one is provided.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: August 5, 1997
    Assignee: Flex Products, Inc.
    Inventors: Roger W. Phillips, Thomas Mayer, Gary S. Ash
  • Patent number: 5628932
    Abstract: An electroconductive composition comprising a two-dimensional network of antimony-containing tin oxide crystallites in association with amorphous silica, the composition according to one aspect of the invention comprising a powder of submicron to tens of micron size particles capable of forming a conductive network within a carrier matrix, such as a thin film matrix, and a process for preparing the composition.
    Type: Grant
    Filed: June 15, 1994
    Date of Patent: May 13, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Howard R. Linton
  • Patent number: 5624486
    Abstract: Luster pigments based on multiply coated plateletlike metallic substrates comprisingA) a first layer consisting essentially of silicon oxide, aluminum oxide and/or aluminum oxide hydrate,B) a second layer consisting essentially of metal and/or nonselectively absorbing metal oxide, andC) if desired, a third layer consisting essentially of colorless or selectively absorbing metal oxide.
    Type: Grant
    Filed: August 30, 1994
    Date of Patent: April 29, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga
  • Patent number: 5624487
    Abstract: Preparation of bluish luster pigments by treating titania-coated silicatic platelets with a reducing gas mixture, which comprises treating titania-coated silicatic platelets whose titania coating has a geometric layer thickness of from 10 to 60 nm at from 800.degree. to 900.degree. C. with a gas mixture comprising a vaporized organic compound and ammonia, and also bluish luster pigments based on silicatic platelets comprising a reduced titania coating with a geometric layer thickness of from 10 to 60 nm and CIELAB color coordinates -2.ltoreq.a*.ltoreq.2 and b*.ltoreq.-20 (measuring angle 20.degree., standard illuminant D65).
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: April 29, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Schmidt, Werner Ostertag, Hermann Bidlingmaier, Norbert Mronga, Juan A. G. Gomez, Claus Kaliba, Raimund Schmid, Raymond Ellinghoven
  • Patent number: 5618343
    Abstract: The present invention relates to pigment and coating compositions that are used to prepare pigmented coatings that exhibit geometric metamerism or metallic flop. The pigment compositions comprise a small particle size pigment and a flop-enhancing agent, which flop-enhancing agent is a copper phthalocyanine, an indanthrone or a carbazole dioxazine compound. A method of enhancing the flop of a pigmented polymeric coating by incorporating one or more flop-enhancing agents into the composition is also disclosed.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: April 8, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Shivakumar B. Hendi, Edward E. Jaffe
  • Patent number: 5618342
    Abstract: The invention relates to a non-dusting, homogeneous pigment preparation containingat least 70% by weight of one or more flaky pigments,1-30% by weight of water,0.1-20% by weight of a humectant, andless than 1.00% by weight of one or more preservatives.
    Type: Grant
    Filed: June 2, 1994
    Date of Patent: April 8, 1997
    Assignee: Merck Patent Gesellschaft MIT Beschrankter Haftung
    Inventors: Gerhard Herget, Otto Stahlecker, Manfred Kieser
  • Patent number: 5611852
    Abstract: A stabilized conductive pigment based on aluminum-doped zinc oxide which, for stabilizing the electric conductivity, contains an alkaline earth metal titanate or an oxide of an element from group III or IV.
    Type: Grant
    Filed: August 16, 1994
    Date of Patent: March 18, 1997
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Gerhard Pfaff, Hans-Dieter Bruckner
  • Patent number: 5611851
    Abstract: A nacreous pigment is prepared by subjecting a metal oxide-coated mica nacreous pigment to an acid extractive dissolution using a combination of a mineral acid and phosphoric acid followed by an extractive dissolution using an alkali.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: March 18, 1997
    Assignee: The Mearl Corporation
    Inventors: Carmine DeLuca, William P. Kurtenbach
  • Patent number: 5585037
    Abstract: An electroconductive composition comprising a two-dimensional network of antimony-containing tin oxide crystallites in association with amorphous silica, the composition according to one aspect of the invention comprising a powder of submicron to tens of micron size particles capable of forming a conductive network within a carrier matrix, such as a thin film matrix, and a process for preparing the composition.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: December 17, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Howard R. Linton
  • Patent number: 5580377
    Abstract: A plate barium sulfate is described, which has a particle size of from 1 to 100 .mu.m or from 5 to 150 .mu.m, wherein neither a sulfide nor a soluble barium salt is detected by an analysis method based on the Japanese Cosmetics Material Standard. The process of the plate barium sulfate is also described.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 3, 1996
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Koichi Ohtsu, Hirobumi Yoshida, Noriaki Sato
  • Patent number: 5575957
    Abstract: The invention provides acicular electroconductive tin oxide fine particles which has a mean diameter of 0.005-1 .mu.m and a mean length of 0.05-10 .mu.m and an aspect ratio of 3 or higher. The invention further provides a process for producing the acicular electroconductive tin oxide fine particles, which comprises firing a starting material containing tin, silicon and an alkali metal halide at 700.degree.-1200.degree. C. and removing soluble salts from the resulting fired product.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: November 19, 1996
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Haruo Okuda, Hideo Futamata, Hideo Takahashi, Norihiko Sanefuji
  • Patent number: 5573584
    Abstract: Interference pigments based on multiply coated plateletlike silicatic substrates comprisingA) a first layer comprising a colorless or selectively absorbing metal oxide with a high refractive index,B) a second, non-selectively absorbing, semitransparent layer consisting essentially of carbon, a metal or a metal oxide, and optionallyC) a third layer comprising a colorless or selectively absorbing metal oxide in combination with scattering color pigments which are complementary in color to the reflection color of the interference pigments are useful for preparing valuable documents that are forgeryproof.
    Type: Grant
    Filed: April 21, 1995
    Date of Patent: November 12, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Werner Ostertag, Helmut Schmidt
  • Patent number: 5573585
    Abstract: Crystalline molecular sieves useful as colorants contain one or more chromophores of the class of the mono- or polyazo dyes that are devoid of acidic groups.
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: November 12, 1996
    Assignee: Wolfgang Hoelderich
    Inventors: Guenter Lauth, Wolfgang Hoelderich, Gerhard Wagenblast, Bernhard Albert, Gunther Lamm, Helmut Reichelt, Clemens Grund, Sabine Gruettner-Merten
  • Patent number: 5570847
    Abstract: A method of heat-treating multilayer interference platelets to improve the durability of the platelets comprising subjecting the platelets at a temperature of 200.degree.-300.degree. C. for 10 minutes to 24 hours. The platelets are formed from a multilayer interference thin film construction comprising a metal reflecting layer having a multilayer interference thin film structure on both sides of the metal reflecting layer wherein the multilayer interference thin film structure comprises a pair of layers consisting of a dielectric layer and a semi-opaque metal layer with the dielectric layer of the pair being directly adjacent to the metal reflecting layer.
    Type: Grant
    Filed: December 15, 1994
    Date of Patent: November 5, 1996
    Assignee: Flex Products, Inc.
    Inventors: Roger W. Phillips, Shari P. Fisher, Paul G. Coombs
  • Patent number: 5571624
    Abstract: A color-shifting paint comprising a polymeric paint medium and a plurality of colored interference thin film platelets dispersed in the paint medium. Each platelet being characterized in that platelets has first and second generally planar outer surfaces and an edge thickness perpendicular to the first and second generally planar outer surfaces. Each platelet is comprised of a metal reflecting layer having first and second surfaces. A multilayer interference structure is disposed on each of the first and second surfaces of the metal reflecting layer to provide a symmetrical platelet. The multilayer interference thin film structure comprises a pair of layer consisting of a dielectric layer formed of a dielectric material and a semi-opaque layer. with the dielectric layer directly adjacent to the metal reflecting layer. The thickness of the dielectric layer determines the color and the dielectric material determines the degree of color shift.
    Type: Grant
    Filed: December 15, 1994
    Date of Patent: November 5, 1996
    Assignee: Flex Products, Inc.
    Inventors: Roger W. Phillips, Shari P. Fisher, Paul G. Coombs
  • Patent number: 5569535
    Abstract: A collection of color-shifting interference thin film platelets of high chroma characterized in that the platelets are comprised of a metal reflecting layer having first and second surfaces and a multilayer interference thin film structure disposed on both surfaces of the metal reflecting layer. The multilayer interference thin film structure comprises a pair of layers consisting of a dielectric layer and a semi-opaque metal layer with the dielectric layer being directly adjacent to a surface of the metal reflecting layer. The layers of the multilayer interference thin film structure lie in parallel planes. Each platelet has an aspect ratio of at least 2:1, respectively, for surfaces parallel to the planes of layers and surfaces perpendicular to the planes of the layers. The platelets have a maximum dimension on any surface ranging from approximately 2-200 microns.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: October 29, 1996
    Assignee: Flex Products, Inc.
    Inventors: Roger W. Phillips, Shari P. Fisher, Paul G. Coombs
  • Patent number: 5565024
    Abstract: The present invention relates to color luster pigments which, through the incorporation of glass formers, exhibit enhanced luster and also high color strength and transparency.
    Type: Grant
    Filed: April 21, 1995
    Date of Patent: October 15, 1996
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventor: Matthias Schraml-Marth
  • Patent number: 5565025
    Abstract: The invention relates to surface-modified pigments based on TiO.sub.2 pigments or TiO.sub.2 -coated platelet-shaped substrates and overcoated with a layer consisting of borates of alkaline earth metals and/or double borates of alkali and/or alkaline earth metals and to the use thereof as yellowness inhibitors in plastics and plastics systems.
    Type: Grant
    Filed: September 1, 1994
    Date of Patent: October 15, 1996
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventor: Matthias Schraml-Marth
  • Patent number: 5562763
    Abstract: The invention relates to a process for the preparation of composite pigments containing a substrate having an average diameter of 3-200 .mu.m as support for small organic or inorganic pigment particles having an average diameter of less than 1 .mu.m, characterized in that the pigment particles are applied by spray-drying an aqueous suspension containing the substrates and the pigment particles without addition of additives.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: October 8, 1996
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Hans-Dieter Bruckner, Ines Subrod
  • Patent number: 5540769
    Abstract: Platelet-shaped colored pigments containing titanium dioxide, one or more suboxides of titanium and an oxide or oxides of one or more metals other than titanium or non-metals and a process for the preparation thereof is disclosed.
    Type: Grant
    Filed: September 23, 1994
    Date of Patent: July 30, 1996
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Klaus-Dieter Franz, Klaus Ambrosius, Stefan Wilhelm, Katsuhisa Nitta
  • Patent number: 5540770
    Abstract: Luster pigments based on coated plateletlike substrates comprising nitrogen-containing metal layers and if desired additionally one or more layers consisting essentially of colorless or selectively absorbing metal oxide, are prepared and used for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.
    Type: Grant
    Filed: June 16, 1995
    Date of Patent: July 30, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga, Harald Ochmann, J org Adel
  • Patent number: 5522923
    Abstract: A red pigment comprising: an iron oxide plate type particle, an aluminum compound layer which contains at least aluminum oxide and which is formed on the iron oxide particle, and the optical thickness of the aluminum compound layer being 150-500 nm. The red pigment according to the present invention has excellent color tone with high chroma from the orange to the blue red and moreover, and excellent stability.
    Type: Grant
    Filed: September 22, 1993
    Date of Patent: June 4, 1996
    Assignee: Shiseido Co., Ltd.
    Inventors: Asa Kimura, Fukuji Suzuki, Akiko Sato
  • Patent number: 5501731
    Abstract: Luster pigments comprising coated, plateletlike, silicatic substrates wherein the coating comprises a layer consisting essentially of carbon and aluminum oxide, chromium oxide, cerium oxide, zirconium oxide, antimony oxide or mixtures thereof, are obtainable by applying carbon-containing compounds of the metals aluminum, chromium, cerium, zirconium, antimony or mixtures thereof with or without further carbon-containing compounds of the molecular formula (CH.sub.2 O).sub.n, where n is from 1 to 6 for one monomeric unit, to the substrate particles and then thermally decomposing the carbon-containing compounds on the surface of the substrate particles under oxygen-excluding conditions.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: March 26, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga, Werner Ostertag, Helmut Schmidt
  • Patent number: 5500043
    Abstract: The object of the present invention is to provide a lustrous pigment free from the defects of conventional platelike or flaky iron oxide pigments that a mechanical strength is poor, adjustable colors are restricted and that a pigment lustrous is weak even if colors can adjusted variously and a method of producing the same. The present invention relates to a flaky iron oxide lustrous pigment having a hematite structure characterized by containing at least one of the elements selected from Zn, Sb and Sn and Al in solid solution and its platelike crystal having an average thickness of 0.8 .mu.m or more, preferably the content of at least one of the elements selected from Zn, Sb and Sn being in the range of 0.05 to 0.5 weight % as oxides and the content of Al being in the range of 0.5 to 3 weight % as Al.sub.2 O.sub.3.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 19, 1996
    Assignee: Titan Kogyo Kabushiki Kaisha
    Inventors: Hidefumi Harada, Takanori Yamasaki, Eizi Sadanaga, Teruyoshi Okazaki
  • Patent number: 5478388
    Abstract: There is disclosed a paper coating pigment comprising:(a) from 10% to 100% by weight of a first paper coating pigment having a particle size distribution such that at least 75% by weight of the particles have an equivalent spherical diameter smaller than 2 .mu.m and at least 60% by weight have an equivalent spherical diameter smaller than 1 .mu.m, the average particle aspect ratio of the size fraction having an equivalent spherical diameter predominantly smaller than 1 .mu.m being 25 or greater; and(b) up to 90% by weight of a second paper coating pigment.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: December 26, 1995
    Assignee: ECC International Limited
    Inventors: Patrick A. C. Gane, Philip M. McGenity
  • Patent number: 5472640
    Abstract: The application relates to conductive lamellar pigments in which lamellar substrate is coated with an electrically conductive layer, characterized in that a lamellar metal oxide or a lamellar material coated with one or more metal oxides is present as the lamellar substrate and that an optionally hydrated silicon dioxide layer or a layer of another insoluble silicate is arranged between the metal oxide layer and the conductive layer.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: December 5, 1995
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Hans D. Bruckner, Reiner Esselborn