Clay Containing Or Derived Therefrom Patents (Class 106/416)
  • Patent number: 7413599
    Abstract: The invention relates to pearlescent pigments with a platelet-shaped substrate comprising metal oxide and having a first and a second protective layer, said metal oxide having a refractive index of greater than 1.8, there being on the platelet-shaped substrate a first protective layer comprising cerium oxide and/or cerium hydroxide and a second protective layer of SiO2, applied to which is an organic chemical aftercoat comprising at least one silane having at least one functional bond group and at least one silane without a functional bond group, it being possible for metal oxide layers other than cerium oxide and SiO2 to be disposed between the first and the second protective layer. The invention further relates to a process for preparing these pigments, and to the use thereof.
    Type: Grant
    Filed: August 26, 2005
    Date of Patent: August 19, 2008
    Assignee: Eckart GmbH & Co. KG
    Inventors: Frank Henglein, Ulrich Schmidt, Peter Krüger, Günter Kaupp
  • Publication number: 20080035017
    Abstract: The present invention relates to a process for preparing a pearl pigment, comprising the steps of (a) adding an aqueous solution of metal oxide to a substrate in a reactor and (b) adding ammonium bicarbonate aqueous solution as a precipitating agent.
    Type: Application
    Filed: December 11, 2006
    Publication date: February 14, 2008
    Applicant: Hyundai Motor Company
    Inventor: Eun Young Chung
  • Publication number: 20080028989
    Abstract: A method for removing organic-related compounds from a naturally-occurring or synthetic target material containing at least one permeable inorganic material capable of mineral or mineral phase change or dehydration and at least one amorphous carbon, graphite or another organic compound comprising exposing the material to microwave or radio frequency radiation so as to remove at least a portion of the organic ingredients through combustion while limiting the modification of the structure or mineral composition or mineral phase of the inorganic component.
    Type: Application
    Filed: July 20, 2006
    Publication date: February 7, 2008
    Inventor: Scott Kevin Palm
  • Patent number: 7261770
    Abstract: In various embodiments, a pigment composition is provided comprising a base particle and a dispersing agent, the dispersing agent comprising a salt and/or ester of: (i) an amine, alcohol, and/or alkanol amine and (ii) a polyprotic acid, wherein the mole ratio of the amine, alcohol, and/or alkanol amine to the polyprotic acid is greater than 3:1. In various embodiments, the pigments have improved stability, hiding power, tint strength, and/or gloss.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: August 28, 2007
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Modasser El-Shoubary, Robert M. Hopkins, Karen L. Bowen, David E. Bell
  • Patent number: 7208039
    Abstract: The present invention relates to a hydrous kaolin product having improved optical properties, for example, when used in the production of paper products. The present invention comprises an improved barrier coating for paper and a method of making the coated paper. The present invention also comprises an improved method from making filled and coated paper products. The present invention uses a composition comprising kaolin having a shape factor of at least about 70:1, such as at least about 80:1 or at least about 100:1.
    Type: Grant
    Filed: March 23, 2005
    Date of Patent: April 24, 2007
    Assignee: Imerys Pigments, Inc.
    Inventors: J. Philip E. Jones, Robert J. Pruett, Jun Yuan, Michael J. Garska, David O. Cummings, Bomi M. Bilimoria, Robin Wesley
  • Patent number: 7160375
    Abstract: An aqueous glittering color material composition of the present invention is an aqueous glittering color material composition comprising a glittering pigment having a water repellent particle surface and it includes the following ingredients. The aqueous glittering color material composition of the present invention is used for an ink for writing instruments, for cosmetics, and the like. (a) As said glittering pigment, a metal coated glass flake pigment having a particle surface with water repellent treatment with a titanate or a silane coupling agent. (b) A colorant, and (c) A fixing resin.
    Type: Grant
    Filed: February 4, 2003
    Date of Patent: January 9, 2007
    Assignee: Sakura Color Products Corporation
    Inventor: Yuki Yamamoto
  • Patent number: 7091262
    Abstract: A treatment for particulate inorganic solids is provided. This treatment, which uses certain organophosphinic compounds, imparts improved physical and chemical qualities including lacing resistance, improved dispersion and decreased chemical reactivity when these treated particulate inorganic solids are incorporated into polymeric matrices. The addition of the organophosphinic compounds of the present invention may flexibly be incorporated into known processes at varying points, and are preferably added downstream of any filtering steps or to a dry particulate inorganic solid.
    Type: Grant
    Filed: August 1, 2003
    Date of Patent: August 15, 2006
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Modasser El-Shoubary, Robert Kostelnik
  • Patent number: 7077897
    Abstract: The invention relates to a multilayered interference pigment consisting of a transparent carrier material which is coated with alternating layers of colorless, non-absorbent metal oxides having a high and a low refractive index, the difference between the refractive indices being at least 0.1. The inventive pigment can be obtained by alternately coating the transparent carrier material with a metal oxide having a high refractive index and a metal oxide having a low refractive index according to the wet method, by hydrolysing the corresponding water-soluble, inorganic metal compounds, and separating, drying and optionally calcinating the obtained pigment.
    Type: Grant
    Filed: September 18, 2001
    Date of Patent: July 18, 2006
    Assignee: Merck Patent GmbH
    Inventors: Hans-Dieter Brueckner, Matthias Kuntz
  • Patent number: 7014700
    Abstract: Highly reflective interference effect pigments with dark absorption color are obtained by reducing platy titanium dioxide. The present effect pigments may be used in cosmetics, plastics, inks, and coatings including solvent and water borne automotive paint systems.
    Type: Grant
    Filed: January 13, 2004
    Date of Patent: March 21, 2006
    Assignee: Engelhard Corporation
    Inventors: Carmine V. DeLuca, Jr., William Howard
  • Patent number: 6997981
    Abstract: The invention provides an optical structure with low chroma and brightness in the visible region and low emissivity in the infrared region. The optical structure includes an interference structure having an infrared reflective layer and an infrared absorbing thin film layer. These layers are in turn separated by a thin film spacer of a dielectric or semiconductor material. The reflectivity and transmission of the layers are selectively controlled through the thickness of the layers such that the visual reflectivity and color is independent of the infrared properties of the absorber and reflector layers.
    Type: Grant
    Filed: May 20, 2002
    Date of Patent: February 14, 2006
    Assignee: JDS Uniphase Corporation
    Inventors: Paul G. Coombs, Charles T. Markantes, Roger W. Phillips
  • Patent number: 6994746
    Abstract: The present invention relates to a process for preparing satin white, wherein aluminum sulfate and calcium hydroxide are brought together batchwise in a planetary kneader mixer and react to form satin white. The satin white obtained by the present process has a superior quality and can be prepared in a very efficient manner.
    Type: Grant
    Filed: January 14, 2002
    Date of Patent: February 7, 2006
    Assignee: Ankerpoort, N.V.
    Inventors: Alois Johannes Gerardus Aarts, Jurgen Johannes Adrianus Broekman, Jan Maria Joseph Thewissen, Geert Dijkstra
  • Patent number: 6858072
    Abstract: This invention provides a highly orientated surface-modified pearl pigment excellent in plane orientation (leafing effect). Disclosed are: a surface-modified pearl pigment wherein fine polymer particles adhere, without being mutually aggregated, to hydrated metal oxides via chemical bonding; a process for producing the same: and use thereof for inks, coatings and plastics.
    Type: Grant
    Filed: January 31, 2001
    Date of Patent: February 22, 2005
    Assignee: Merck Patent GmbH
    Inventors: Bangyin Li, Katsuhisa Nitta
  • Patent number: 6837925
    Abstract: A coloring pearlescent flake pigment capable of providing pearl-like luster caused by interference color and a vivid color caused by a tar color is provided as a new material which contributes to the diversification of cosmetics and paints thanks to its powdery smoothness and the visual effect as well as covering protection effect in an application layer. The coloring pearlescent flake pigment having a double coating layer which is formed on inorganic flake-like particles and which is composed of a high-refraction-index metal oxide (e.g.
    Type: Grant
    Filed: May 29, 2003
    Date of Patent: January 4, 2005
    Assignees: Daito Kasei Kogyo Co., Ltd.
    Inventors: Yasushi Kubo, Hideji Kagawa
  • Patent number: 6758895
    Abstract: A particulate hydrous mineral suitable for use as an opacifying pigment, filler or extender has a shape factor which is greater than S, where S is defined by Equation 1 as follows: S=(d50/0.036)+20  Equation 1; where d50 is the mean particle size of the particles of the mineral measured in microns. The particulate mineral is preferably a kaolin, which is particularly suitable for use in aqueous matt paint compositions.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: July 6, 2004
    Assignee: Imerys Minerals Limited
    Inventor: Robin Wesley
  • Publication number: 20040112252
    Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective layer which acts as a reflector to light directed thereon and a spacer pigment layer which is selectively transparent to light directed thereon.
    Type: Application
    Filed: December 13, 2002
    Publication date: June 17, 2004
    Inventors: Curtis J. Zimmermann, James D. Christie, Vivian K. Doxey, Daniel Stevenson Fuller
  • Publication number: 20040106701
    Abstract: The invention relates to the technological sector of mineral fillers used in the sector which manufactures polyurethane foams and in particular fillers of the carbonate, hydroxide, silicate, sulphate type and similar mineral fillers.
    Type: Application
    Filed: October 29, 2003
    Publication date: June 3, 2004
    Applicant: Omya S.A.
    Inventors: Jean Pierre Fichou, Maurice Husson, Georges Ravet, Pierre Blanchard
  • Patent number: 6719837
    Abstract: The present invention relates to pearlescent pigments based on substrates coated with one or more layers of nitrides or oxynitrides to a method for the production of such pigments and their use in plastics, paints, coatings, powder coatings, inks, printing inks, glasses, ceramic products, agriculture foils, for lasermarking of papers and plastics, security applications and in cosmetic formulations.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: April 13, 2004
    Assignee: Merck Patent Gesellschaft mit beschränkter Haftung
    Inventors: Stéphane Bertaux, Peter Reynders, Jens-Uwe Wichmann, Eberhard Schweda
  • Patent number: 6676743
    Abstract: The present invention provides a lightweight clay which can be easily molded into a given shape, exhibits proper lightweight characteristics and storing characteristics, and can be manufactured at a low cost, and a manufacturing method thereof. In such a lightweight clay and the manufacturing method thereof, an average particle size of the organic hollow micro spheres is set to a value which falls within a range of 15 to 150 &mgr;m and, an addition quantity of the organic hollow micro spheres is set to a value which falls within a range of 0.1 to 6 weight % with respect to a total quantity of the lightweight clay, and whiteness degree (WL) measured in accordance with JIS L 0803 is set to not less than 50.
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: January 13, 2004
    Inventor: Toshiyuki Yamamuro
  • Patent number: 6676741
    Abstract: Methods and apparatus are provided for uniformly depositing a coating material from a vaporization source onto a powdered substrate material to form a thin coalescence film of the coating material that smoothly replicates the surface microstructure of the substrate material. The coating material is uniformly deposited on the substrate material to form optical interference pigment particles. The thin film enhances the hiding power and color gamut of the substrate material. Physical vapor deposition process are used for depositing the film on the substrate material. The apparatus and systems employed in forming the coated particles utilize vibrating bed coaters, vibrating conveyor coaters, or coating towers. These allow the powdered substrate material to be uniformly exposed to the coating material vapor during the coating process.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: January 13, 2004
    Assignee: Flex Products, Inc.
    Inventors: Roger W. Phillips, Vladimir Raksha
  • Publication number: 20040003758
    Abstract: The invention relates to a multilayered interference pigment consisting of a transparent carrier material which is coated with alternating layers of colourless, non-absorbent metal oxides having a high and a low refractive index, the difference between the refractive indices being at least 0.1. The inventive pigment can be obtained by alternately coating the transparent carrier material with a metal oxide having a high refractive index and a metal oxide having a low refractive index according to the wet method, by hydrolysing the corresponding water-soluble, inorganic metal compounds, and separating, drying and optionally calcinating the obtained pigment.
    Type: Application
    Filed: April 9, 2003
    Publication date: January 8, 2004
    Inventors: Hans-Dieter Bruckner, Matthias Kuntz
  • Publication number: 20030213409
    Abstract: Optically variable interference pigments are composed of platelets of at least partly core-free titanium dioxide-coated substrate of about 1-25 mm particle size and an interference thickness of about 5-600 nm which have an oxide coating thereon.
    Type: Application
    Filed: May 14, 2002
    Publication date: November 20, 2003
    Inventor: Carmine V. DeLuca
  • Publication number: 20030177949
    Abstract: Methods and apparatus are provided for uniformly depositing a coating material from a vaporization source onto a powdered substrate material to form a thin coalescence film of the coating material that smoothly replicates the surface microstructure of the substrate material. The coating material is uniformly deposited on the substrate material to form optical interference pigment particles. The thin film enhances the hiding power and color gamut of the substrate material. Physical vapor deposition process are used for depositing the film on the substrate material. The apparatus and systems employed in forming the coated particles utilize vibrating bed coaters, vibrating conveyor coaters, or coating towers. These allow the powdered substrate material to be uniformly exposed to the coating material vapor during the coating process.
    Type: Application
    Filed: February 20, 2003
    Publication date: September 25, 2003
    Applicant: Flex Products, Inc.
    Inventors: Roger W. Phillips, Vladimir Raksha
  • Patent number: 6616749
    Abstract: A pigment product suitable for use in a coating composition to provide a gloss coating on paper, the pigment product comprising a processed particulate kaolin whose particles have a particle size distribution such that at least 80% by weight of the particles have an equivalent spherical diameter less than 2 &mgr;m and not less than 8%, preferably not less than 12%, by weight of the particles have an equivalent spherical diameter less than 0.25 &mgr;m and whose particles have a shape factor of at least 45, preferably at least 50.
    Type: Grant
    Filed: October 4, 2000
    Date of Patent: September 9, 2003
    Assignee: Imerys Pigments, Inc.
    Inventors: John Claude Husband, Desmond Charles Payton, Michele Susan Renals
  • Patent number: 6610136
    Abstract: Aggregated mineral pigments (such as kaolin clay pigments) having a high surface area and useful in coating and filling compositions for ink jet printing media are manufactured by dry grinding an unground mineral composition starting material and then optionally acid treating the ground material.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: August 26, 2003
    Assignee: Thiele Kaolin Company
    Inventors: Prakash B. Malla, Siva Devisetti
  • Publication number: 20030150357
    Abstract: A composition for improving grip between the hands and a tool or implement is provided, which comprises a chlorinated paraffin, a dispersing agent, and a solvent in an amount up to and including about 3.0% by weight relative to the total weight of the composition. A method of making the composition in the form of a dry powder, as well as a method of using the dry powder to improve friction or grip on the hands, are also provided.
    Type: Application
    Filed: February 12, 2002
    Publication date: August 14, 2003
    Inventor: Robert S. Cohen
  • Patent number: 6596061
    Abstract: Inorganic anti-corrosive pigments consist of surface-coated solids having a grain size of 0.1 to 75 &mgr;m. In order to improve the resistance of the paints and coatings containing such pigments, firstly Mn3(PO4)2 and secondly aluminium oxides and/or aluminium hydroxides are precipitated onto the solids.
    Type: Grant
    Filed: May 4, 2001
    Date of Patent: July 22, 2003
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventor: Thomas Rentschler
  • Patent number: 6596071
    Abstract: Organic and inorganic composite pigments having an average particle diameter of 0.01 to 10.0 &mgr;m composed of a white inorganic particle, an organosilane compound obtained from alkoxysilanes, or polysiloxanes coating on the white inorganic particle, and an organic pigment coat formed on said coating. An ultraviolet light-absorbing agent is present in any portion from the surface of the white inorganic particle to surface of the organic pigment coat. These composite pigments have reduced amounts of organic pigments desorbed from their surface and exhibit excellent light resistance due to their ultraviolet absorbing property.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: July 22, 2003
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Mineko Ohsugi, Yusuke Shimohata, Hiroko Morii
  • Patent number: 6585822
    Abstract: Novel nanosized kaolin clay particles are prepared by agitating a fine particle size fraction of kaolin clay in a Netzsch mill until the particle size is reduced, aspect ratio is decreased and surface area is increased. The ultrafine kaolin particles are especially useful as a pigment to provide high surface gloss to ink jet printing papers.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: July 1, 2003
    Assignee: Engelhard Corporation
    Inventors: Richard R. Berube, Michael G. Londo, Sathanjheri A. Ravishankar
  • Patent number: 6564199
    Abstract: A paper coating pigment manufactured from kaolin crude containing minor amounts of minerals is used in lightweight coated and ultra-lightweight coated applications. The pigments comprise a phyllosilicate assemblage of minerals that yield a final pigment MgO content ranging between 0.04 to 0.3 weight percent and a K2O content ranging between 0.12 and 0.8 weight percent based on the dry weight of the kaolin crude. The mica in the pigment product is 1.0% to 6.7% by weight, and smectite is 1.2% to 9.1% by weight of the kaolin. The presence of these weight percentages can be identified by a shape factor of 15 or greater. The viscous clay content of the feed to produce the pigment product is between 70 and 100 weight percent based on the dry weight of the kaolin clay. The pigment has a shape factor ranging between 35 and 60 or greater, and greater than 80% by weight of the particle are less than 2 microns, and greater than 12% are less than 0.25 microns.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: May 13, 2003
    Assignee: Imerys Pigments, Inc.
    Inventors: Robert J. Pruett, Jun Yuan, Harry Vincent Brown, Jr., David O. Cummings
  • Patent number: 6554892
    Abstract: Coarse platey, high brightness kaolin products and methods for making the same, including combining a coarse kaolin fraction and a fine kaolin fraction, where each coarse or fine kaolin fraction may be produced by processing one or more crude kaolin samples through different stages of the methods of the present invention, by blending of one or more crude kaolin samples so processed, or as a by-product of a coarse or fine kaolin product.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: April 29, 2003
    Assignee: Imerys Kaolin, Inc.
    Inventors: John A. Manasso, Bomi M. Bilimoria, Leslie A. McLain, Milton Constantin
  • Publication number: 20030070586
    Abstract: The present invention relates to a process for preparing satin white, wherein aluminum sulfate and calcium hydroxide are brought together batchwise in a planetary kneader mixer and react to form satin white. The satin white obtained by the present process has a superior quality and can be prepared in a very efficient manner.
    Type: Application
    Filed: January 14, 2002
    Publication date: April 17, 2003
    Applicant: Ankerpoort N.V.
    Inventors: Alois Johannes G. Aarts, Jurgen Johannes A. Broekman, Jan Maria J. Thewissen, Geert Dijkstra
  • Patent number: 6547870
    Abstract: The invention relates to a non-dusting, homogeneous pigment preparation, comprising ≧40% by weight of one or more effect pigments, 0.5-60% by weight of a polyalkylene glycol and/or one or more polyalkylene glycol derivatives, 0-10% by weight of a redispersing auxiliary, 0-40% by weight of water or an organic solvent or solvent mixture, 0-40% by weight of at least one further hydroxyl-rich resin, and to its use as a precursor for printing inks.
    Type: Grant
    Filed: December 13, 2000
    Date of Patent: April 15, 2003
    Assignee: Merck Patent Gesellschaft mit beschränkter Haftung
    Inventors: Carsten Griessmann, Gerhard Herget
  • Patent number: 6544327
    Abstract: The invention relates to a non-dusting homogeneous pigment preparation which is notable in that it comprises at least 40% by weight of one or more effect pigments, from 0.5 to 60% by weight of an aldehyde resin and/or ketonic resin and from 0.1 to 10% by weight of a redispersant.
    Type: Grant
    Filed: September 14, 2000
    Date of Patent: April 8, 2003
    Assignee: Merck Patent GmbH
    Inventors: Carsten Griessmann, Wolfgang Hechler, Gerhard Herget
  • Patent number: 6540823
    Abstract: The present invention relates to a novel zinc magnesium titanate represented by formula (I): Zn2−xMgx.yTiO4 in which x denotes a real number of 0.5 to 1.5; and y denotes an integer of 1 or 2, and to a process for preparing the same and a thermoregulating functional composition which comprises zinc magnesium titanate of formula (I).
    Type: Grant
    Filed: December 28, 2000
    Date of Patent: April 1, 2003
    Assignee: LG Chemical Ltd.
    Inventors: Dong Sung Seo, Hong Ha Sohn, Ji Ho Park, Seh Hoon Kang, Young Chang Yoo
  • Patent number: 6537363
    Abstract: A pigment product suitable for use in a coating composition to provide a gloss coating on paper, the pigment product comprising a processed particulate kaolin produced from a naturally platy kaolin clay having a particle size distribution such that about 50% to 60% by weight of the particles have an esd less than 2 &mgr;m and less than 25% by weight of the particles have an esd less than 0.25 &mgr;m and a shape factor of at least 15. This platy clay can be blended with b-fraction clay component. In processing, the crude kaolin is ground to a shape factor greater than 50 to produce even greater “platy” clay. The pigment product has a particle size distribution such that at least 80% by weight of the particles have an esd less than 2 &mgr;m and greater than 12% and less than 35% by weight of the particles have an esd less than 0.25 &mgr;m and whose surface area is greater than 12 m2/g when measured by the BET method.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: March 25, 2003
    Assignee: Imerys Pigments, Inc.
    Inventors: Christopher R. L. Golley, Daniel John Panfil, Harry Vincent Brown, Jr., John Claude Husband
  • Patent number: 6533858
    Abstract: Non-bleeding, non-agglomerated, lustrous colored combination pigments constitute a platy substrate and absorption colorant bound thereto with metal hydroxides and one or more hydrolyzed silane coupling agents.
    Type: Grant
    Filed: October 10, 2000
    Date of Patent: March 18, 2003
    Assignee: Engelhard Corporation
    Inventors: Deborah Cacace, Daniel S. Fuller
  • Patent number: 6524381
    Abstract: Methods and apparatus are provided for uniformly depositing a coating material from a vaporization source onto a powdered substrate material to form a thin coalescence film of the coating material that smoothly replicates the surface microstructure of the substrate material. The coating material is uniformly deposited on the substrate material to form optical interference pigment particles. The thin film enhances the hiding power and color gamut of the substrate material. Physical vapor deposition processes are used for depositing the film on the substrate material. The apparatus and systems employed in forming the coated particles utilize vibrating bed coaters, vibrating conveyor coaters, or coating towers. These allow the powdered substrate material to be uniformly exposed to the coating material vapor during the coating process.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: February 25, 2003
    Assignee: Flex Products, Inc.
    Inventors: Roger W. Phillips, Vladimir Raksha
  • Publication number: 20030019399
    Abstract: Aggregated mineral pigments (such as kaolin clay pigments) having a high surface area and useful in coating and filling compositions for ink jet printing media are manufactured by dry grinding an unground mineral composition starting material and then optionally acid treating the ground material.
    Type: Application
    Filed: March 21, 2002
    Publication date: January 30, 2003
    Inventors: Prakash B. Malla, Siva Devisetti
  • Patent number: 6478865
    Abstract: Aggregated mineral pigments (such as kaolin clay pigments) having a high surface area and useful in coating compositions for ink jet printing media are manufactured by dry grinding an unground mineral composition starting material and then optionally acid treating the ground material.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: November 12, 2002
    Assignee: Thiele Kaolin Company
    Inventors: Prakash B. Malla, Siva Devisetti
  • Patent number: 6475274
    Abstract: Fine-grained Tertiary kaolin clay pigments providing improved opacity, sheet gloss and print gloss to paper coated with these pigments are produced by removing fine and coarse particles to produce pigments having a narrow particle size distribution.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: November 5, 2002
    Assignee: Thiele Kaolin Company
    Inventors: R. Andrew Lowe, Prakash B. Malla, William M. McClarin III, Don R. Black
  • Patent number: 6468343
    Abstract: Paper coating composition comprising an engineered kaolin pigment containing stacks and platelets of unground coarse particles where greater than 96% by weight is less than 5 microns, of which some kaolinite books or stacks are concentrated in the greater than 1 micron size fraction; 88% to 95% by weight is less than 2 microns; 65% to 85% by weight is less than 1 micron; and 15% to 25% by weight is less than 0.25 micron. A first embodiment comprises particles with a shape factor Ad between 7 and 9 which represents a significant number of stacks and some platelets. A second embodiment comprises particles with a shape factor of 11 or 12 which represents the presence of some stacks with a majority of platelets. The kaolin clay pigments form clay-water slurries of 69% solids or greater. As a coating, the composition gives a G. E. brightness between 88 and 94. The engineered pigment is processed so that the desired shape factor is met, which shape factor is equated to the aspect ratio or morphology of the pigment.
    Type: Grant
    Filed: November 21, 2000
    Date of Patent: October 22, 2002
    Assignee: Imerys Pigments, Inc.
    Inventors: Robert J. Pruett, David O. Cummings, Anthony V. Lyons, Steven M. Fortier, William L. Garforth, Daniel J. Panfil, Jun Yuan
  • Patent number: 6461423
    Abstract: Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant monomer having a hydroxyl and/or an aromatic ring functionality to sorb or intercalate the intercalant monomer between adjacent platelets of the layered material. Sufficient intercalant monomer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 Å (as measured after water removal to a maximum of 5% by weight water), up to about 100 Å and preferably in the range of about 10-45 Å, so that the intercalate easily can be exfoliated into individual platelets. The intercalated complex can be combined with an organic liquid into a viscous carrier material, for delivery of the carrier material, or for delivery of an active compound; or the intercalated complex can be combined with a matrix polymer to form a strong, filled polymer matrix.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: October 8, 2002
    Assignee: AMCOL International Corporation
    Inventors: Gary W. Beall, Semeon Tsipursky, Anatoliy Sorokin, Anatoliy Goldman
  • Patent number: 6402826
    Abstract: A kaolin clay pigment comprises a coarse kaolin clay or a blend of a coarse kaolin clay with a fine kaolin clay. The coarse kaolin clay is a delaminated and defined pigment product with an overall shape factor greater than about 12. If the coarse kaolin clay is fluid at about 65% to about 75% solids, then it is used by itself as the kaolin pigment. If it is not fluid, it is blended with a fine kaolin clay in amounts ranging from about 0.1% to about 30.0% by weight of the blend. The coarse kaolin clay fraction has a Hinckley Crystallinity Index greater than about 0.6 and the fine kaolin clay has a Hinckley Crystallinity Index less than about 0.5. The pigment has a G.E. brightness of about 90.5 and a particle size distribution such that at least about 90% by weight of the particles has an e.s.d. less than about 2 &mgr;m and about 30% by weight of the particles has an e.s.d. less than about 0.25 microns.
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: June 11, 2002
    Assignee: Imerys Pigments, Inc.
    Inventors: Jun Yuan, Christopher R. L. Golley, Christopher Nutbeem, Rajan R. Iyer, William H. Pope, William L. Garforth, Anthony V. Lyons, Robert J. Pruett
  • Patent number: 6402827
    Abstract: A coating composition for paper or paperboard products comprising a structured pigment. The structured pigment includes a plurality of chemically treated mineral particles. The mineral particles have a Malvern median particle size of about 0.3 microns to about 3.5 microns. The Malvern median particle size of the treated particles is less than 20% greater than the Malvern median particle size of the mineral particles prior to treatment.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: June 11, 2002
    Assignee: J.M. Huber Corporation
    Inventors: Gary M. Freeman, Sung-Tsuen Liu
  • Patent number: 6372036
    Abstract: The present invention relates to a pigment preparation containing a mixture of coated or uncoated Al2O3 flakes, and one or more special-effect pigments, and a phosphate derivative, and to the use thereof, especially in printing inks.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: April 16, 2002
    Assignee: Merck Patent Gesellschaft Beschraenkter Haftung
    Inventors: Gerhard Pfaff, Sabine Schoen, Norio Takahashi
  • Patent number: 6358312
    Abstract: Porous calcined clay sports field conditioners exhibit excellent playability while also displaying excellent drainage, freedom from compaction, and moisture retention under hot, dry conditions. The conditioners are non-hydrating granulates of narrow particle size distribution and are preferably of a red to brown coloration.
    Type: Grant
    Filed: May 4, 2000
    Date of Patent: March 19, 2002
    Assignee: Aimcor Corporation
    Inventors: James D. Tanner, Mark E. Lewry
  • Patent number: 6352952
    Abstract: In the preparation of aqueous cement compositions containing a plasticizer, such as an EO/PO polymer-containing plasticizer, or EO/PO comb polymer-containing plasticizer, and further containing clay, such as a smectite clay, which expands when in contact with water, the step of providing an agent operative to modify the clay whereby the plasticizer absorbing capability of the clay is reduced. In exemplary methods of the invention, the plasticizer is an EO/PO (e.g., oxyalkylene) plasticizer and preferably an EO/PO comb polymer, and the clay-activity-modifying agent may comprise an inorganic cation, an organic cation, a polar organic molecule capable of being absorbed by the clay, a clay dispersant (such as a polyphosphate), or a mixture thereof. For clay-activity-modifying agents which comprise a cation or a polar organic molecule, the agent is preferably added to the clay before water is introduced to the clay.
    Type: Grant
    Filed: December 21, 1999
    Date of Patent: March 5, 2002
    Assignee: W. R. Grace & Co. - Conn.
    Inventors: Leslie A. Jardine, Hideo Koyata, Kevin J. Folliard, Chia-Chih Ou, Felek Jachimowicz, Byong-Wa Chun, Ara A Jeknavorian, Christon L. Hill
  • Patent number: 6339040
    Abstract: An absorbing composition containing alumino silicate containing schistose particles having at least partially a layered structure with substantially parallel layers, whereby at least for 30 percent by weight of the alumino silicate containing schistose particles the distance between two structurally adjacent layers is greater than 5 &mgr;m, but less than 100 &mgr;m, wherein at least 25 percent by weight of the alumino silicate containing schistose particles consist of aluminum containing di-octahedric layers, wherein the particles are provided with metallic flakes, whereby these metallic flakes are at least partially bound onto and between two structurally adjacent layers of the alumino silicate containing schistose particles, and in which at least 50 percent by weight of these metallic flakes have a thickness of 2 to 5 &mgr;m, a maximum length or diameter between 6 and 60 &mgr;m, and a specific surface area greater than 100 m2/g.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: January 15, 2002
    Assignee: Metal Adsorbens Promotion Company N.V.
    Inventor: Marcel De Boodt
  • Patent number: 6334894
    Abstract: A method of heat treating kaolin particles which includes the steps of establishing in a furnace a heating zone suitable to calcine the particles and passing the particles rapidly through the heating zone whereby the particles are flash calcined in the heating zone, wherein the furnace is of the kind in which a toroidal fluid flow heating zone is established and the particles are heated in the said heating zone to a temperature of at least 800° C. but not greater than 1100° C. by application to the particles of a temperature increase rate greater than 103 Celsius degrees per second to give a rapid blistering of the particles caused by rapid dehydroxylation of the kaolin and wherein the particles have a residence time of less than 1 second in the said toroidal fluid flow heating zones.
    Type: Grant
    Filed: July 12, 1999
    Date of Patent: January 1, 2002
    Assignee: Imerys Minerals Limited
    Inventor: Jacek Antoni Kostuch
  • Patent number: 6287634
    Abstract: Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant monomer ether and/or ester to sorb or intercalate the intercalant monomer between adjacent platelets of the layered material. Sufficient intercalant monomer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 Å (as measured after water removal to a maximum of 5% by weight water), up to about 100 Å and preferably in the range of about 10-45 Å, so that the intercalate easily can be exfoliated into individual platelets. The intercalated complex can be combined with an organic liquid into a viscous carrier material, for delivery of the carrier material, or for delivery of an active compound; or the intercalated complex can be combined with a matrix polymer to form a strong, filled polymer matrix. Alternatively, the intercalated complex can be exfoliated prior to combination with the organic liquid or the matrix polymer.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: September 11, 2001
    Assignee: AMCOL International Corporation
    Inventors: Gary W. Beall, Semeon Tsipursky, Anatoliy Sorokin, Anatoliy Goldman