Mica Containing Patents (Class 106/417)
  • Publication number: 20140335348
    Abstract: A bright pigment of the present invention is a bright pigment including flaky particles and a metal oxide layer covering each surface of the flaky particles. The bright pigment has a particle diameter corresponding to a 90% volume-cumulative particle diameter from a small particle diameter side, in a particle size distribution, of 55 ?m or less. The flaky particles are formed of a material having a refractive index of 1.4 to 1.8. The flaky particles have an average thickness of 0.35 to 0.55 ?m and substantially do not contain flaky particles having a thickness of 0.15 ?m or less.
    Type: Application
    Filed: December 7, 2012
    Publication date: November 13, 2014
    Inventor: Takeaki Kitamura
  • Patent number: 8876965
    Abstract: A composite comprising a silicate material, such as, a sodium aluminosilicate, and titanium dioxide disposed on the surface thereof is disclosed, together with formulations comprising the composite and methods for preparing the same.
    Type: Grant
    Filed: March 11, 2013
    Date of Patent: November 4, 2014
    Assignee: J.M. Huber Corporation
    Inventors: Hilary Ellen Matthews, Ronald Louis Romer
  • Publication number: 20140290536
    Abstract: The process relates to mineral material slurries used in concrete, sealants, paper, paint or plastic applications, wherein the surface of the wet mineral matter slurry displays an increased whitening.
    Type: Application
    Filed: December 22, 2011
    Publication date: October 2, 2014
    Inventors: Matthias Buri, Samuel Rentsch, Claudia Pudack
  • Publication number: 20140261084
    Abstract: A pigment is disclosed wherein the pigment includes a platy substrate or uniform platy substrate coated with an odd number of layers of alternating layers of high or low refractive index material, wherein each layer has a refractive index that differs from adjacent layers by at least 0.2; and the pigment has from about 40 to about 100% reflectance of light having a wavelength of 280 nm to 400 nm. Processes for making and using the pigments are also disclosed. These pigments can find application in paints, plastics, cosmetics, glass, printing inks, and glazes.
    Type: Application
    Filed: March 12, 2014
    Publication date: September 18, 2014
    Inventors: Steven Jones, Markus Rueckel, Thomas Servay, Stefan Dahmen, Geoffrey Johnson
  • Publication number: 20140251184
    Abstract: This invention relates to synthetically derived zinc phlogopite platelets, of superior aspect ratio, effect pigments comprising such synthetically derived platelets and methods of forming said platelets. More specifically the disclosure describes an improved hydrothermal synthesis of zinc phlogopite suitable as a platelets for interference pigments, barrier and flame retardant applications.
    Type: Application
    Filed: March 11, 2014
    Publication date: September 11, 2014
    Inventors: Meaghan Clark McGuire, Ivor Bull, Geoffrey Mark Johnson, Enzo Cordola
  • Publication number: 20140255459
    Abstract: The subject matter of the invention is a method of surface modification of a pigment or of a composite pigment comprising at least a metal oxide, a metal complex or a derivative thereof, and the use of these pigments or composite pigments thus obtained for cosmetics, paint or inks.
    Type: Application
    Filed: October 5, 2012
    Publication date: September 11, 2014
    Inventors: Franck Martin, Johanne Moineau, Aude Mezy, Guillaume Gracy
  • Publication number: 20140255328
    Abstract: This invention relates to a synthetically derived zinc phlogopite platelets, of superior platelet diameter, effect pigments comprising such synthetically derived platelets and methods of forming said substrates. More specifically the disclosure describes an improved hydrothermal synthesis of zinc phlogopite suitable as a platelets for interference pigments, barrier and flame retardant applications.
    Type: Application
    Filed: March 11, 2014
    Publication date: September 11, 2014
    Inventors: Meaghan Clark McGuire, Ivor Bull, Geoffrey Mark Johnson
  • Patent number: 8808447
    Abstract: The present invention relates to a pigment paint for an exterior material and to a method for manufacturing the same. The pigment paint comprises: a flake matrix, a first metal oxide layer coated on the upper portion of the transparent matrix, an oxide layer containing MgO—SiO2 coated on the upper portion of the first metal oxide layer, and a second metal oxide layer coated on the upper portion of the oxide layer. In order to ensure humidity resistance and weather resistance required for a lustrous pigment paint for exterior materials, a cerium layer and an aluminum oxide layer are further coated. Properties such as high luminance, high chromaticity, and high gloss, which could not be achieved using conventional techniques, can be achieved and a pigment paint having a multi-colored pearl luster can be provided.
    Type: Grant
    Filed: March 8, 2012
    Date of Patent: August 19, 2014
    Assignee: CQV Co., Ltd.
    Inventors: Jae-Il Jeong, Nam-Il Lee, Sang-Keun Park, Jin-Hyung Lee, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang
  • Patent number: 8728226
    Abstract: Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the optically active coating includes at least a) an absorbing high-index layer A having a refractive index n?1.8 b) a low-index layer B having a refractive index n<1.8 c) a high-index layer C having a refractive index n?1.8 and also d) optionally at least one outer protective layer D and where the multilayer pearlescent pigments have a cumulative frequency distribution of a volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D in a range from 0.7-1.4, the span ?D being calculated in accordance with formula (I) ?D=(D90?D10)/D50??(I). The disclosure further relates to a method for producing these multilayer pearlescent pigments, and also to their use.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: May 20, 2014
    Assignee: Eckart GmbH
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Patent number: 8728227
    Abstract: Multilayer pearlescent pigments with a silver interference color, based on platelet-shaped transparent substrates with an optically active coating, where the optically active coating includes at least a) a high-index layer A having a refractive index n ?1.8 b) a low-index layer B having a refractive index n <1.8 c) a high-index layer C having a refractive index n ?1.8 and also d) optionally an outer protective layer D. The multilayer pearlescent pigments have the indices D10, D50, D90 from the cumulative frequency distribution of the volume-averaged size distribution function, with a span ?D of 0.7 -1.4, the span ?D being calculated in accordance with the formula ?D =(D90 - D10)/D50. The invention further relates to a method for producing these multilayer pearlescent pigments, and also to their use.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: May 20, 2014
    Assignee: Eckart GmbH
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Patent number: 8728228
    Abstract: Multilayer pearlescent pigments based on platelet-shaped transparent substrates with an optically active coating, where the optically active coating includes at least a) a nonabsorbing high-index layer A having a refractive index n?1.8, b) a low-index layer B having a refractive index n<1.8 having an optical layer thickness >150 nm, c) an absorbing high-index layer C having a refractive index n?1.8 and also, d) optionally an outer protective layer D, wherein the multilayer pearlescent pigments have a cumulative frequency distribution of the volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D of 0.7-1.4, the span ?D being calculated in accordance with the formula ?D=(D90?D10)/D50. The disclosure further relates to a method for producing these multilayer pigments, and to their use.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: May 20, 2014
    Assignee: Eckart GmbH
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Patent number: 8715407
    Abstract: Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the coating includes at least (a) a nonabsorbing high-index layer A having a refractive index n?1.8, (b) a low-index layer B having a refractive index n<1.8, (c) a nonabsorbing high-index layer C having a refractive index n?1.8 and also (d) optionally at least one outer protective layer D where the pigments have a cumulative frequency distribution of a volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D in a range from 0.7-1.4, the span ?D being calculated in accordance with formula (I) ?D=(D90?D10)/D50??(I). The disclosure further relates to a method for producing these multilayer pearlescent pigments, and also to their use.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: May 6, 2014
    Assignee: Eckart GmbH
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Publication number: 20140102332
    Abstract: Disclosed are a functional reinforcing filler including inorganic particles surface-modified with an alkenylsilanol obtained by hydrolyzing an alkenylalkoxysilane compound, and a method for preparing the same. Since the disclosed functional reinforcing filler has a functional group having a double bond, it has good reactivity for styrene-butadiene rubber and sulfur. Thus, when used as a functional reinforcing filler in the manufacture of rubber, it allows improvement of physical properties through adjustment of the addition amount of sulfur without additional use of the coupling agent. In addition, because of superior hydrolysis reactivity, the problem of alcohol can be solved and a rubber mixture with long scorch time can be prepared. In particular, when the functional reinforcing filler of the present invention is used in the manufacture of tires, improvement in modulus, tensile strength, rotational resistance and wet traction performance can be expected.
    Type: Application
    Filed: September 18, 2013
    Publication date: April 17, 2014
    Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Bok Ryul YOO, Joon Soo HAN, Dong Euy JUNG
  • Patent number: 8647429
    Abstract: The present invention relates to effect pigments based on uncoated or coated flake-form substrates having an outer coating comprising a) TiO2 and b) Al2O3, MgO and/or CaO and c) SiO2 and d) ZnO and/or e) at least one mixed oxide of the elements mentioned under a) to d), and to the use thereof, inter alia in paints, coatings, printing inks, plastics and cosmetic formulations.
    Type: Grant
    Filed: February 2, 2011
    Date of Patent: February 11, 2014
    Assignee: Merck Patent GmbH
    Inventors: Sabine Melson, Volker Wilhelm, Ulrich Schoenefeld
  • Publication number: 20140018439
    Abstract: The present invention relates to a weather-resistant pearlescent pigment which consists of a platelet-shaped substrate coated with one or more highly refractive metal oxides, the platelet-shaped substrate being selected from the group consisting of synthetic mica flakes, glass flakes, SiO2 flakes, Al2O3 flakes, synthetic boehmite flakes, BiOCl flakes and mixtures thereof, and a top layer, wherein the top layer consists of the following layers: a) a cerium-containing layer, selected from the group consisting of cerium oxide, cerium hydroxide, hydrated cerium oxide, and mixtures thereof, the cerium-containing layer being applied directly to the highly refractive metal oxide layer, and b) an organic-chemical compatibilizing layer, which comprises the reaction products of oligomeric silanes, wherein the oligomeric silanes have one or more amino groups, the organic-chemical compatibilizing layer being applied directly to the cerium-containing layer a).
    Type: Application
    Filed: March 28, 2012
    Publication date: January 16, 2014
    Applicant: ECKART GMBH
    Inventors: Michael Gruner, Thomas Schneider, Gunter Kaupp
  • Patent number: 8613800
    Abstract: The present invention relates to pigment preparations comprising one or more effect pigments in platelet form, at least one antioxidant and a wax or wax mixture, and to the use thereof for pigmentation of application media, especially paints, coating materials, powder coating materials, polymers, and for production of masterbatches.
    Type: Grant
    Filed: April 9, 2009
    Date of Patent: December 24, 2013
    Assignee: Merck Patent GmbH
    Inventors: Volker Wilhelm, Hans Jurgen Brehm
  • Publication number: 20130164356
    Abstract: The present invention relates to effect pigments which are based on flake-form substrates having a circular form factor of 1.2-2 and are coated with at least one high-refractive-index layer, and to the use thereof, inter alia in paints, coatings, printing inks, plastics and in cosmetic formulations.
    Type: Application
    Filed: December 20, 2012
    Publication date: June 27, 2013
    Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNG
    Inventor: Merck Patent Gesellschaft Mit Beschrankter Haftung
  • Publication number: 20130149363
    Abstract: The present invention relates to five-layered pigments based on multicoated platelet-shaped substrates which comprise a layer sequence comprising (A) a layer of SnO2 having a layer thickness of 0.1-50 nm, (B) a high-refractive-index coating consisting of TiO2 in the rutile modification having a layer thickness of 10-800 nm, (C) a colorless coating having a refractive index n?1.8 having a layer thickness of 20-800 nm, (D) a high-refractive-index coating consisting of SnO2 having a layer thickness of 0.1-50 nm, (E) a layer of TiO2 in the rutile modification having a layer thickness of 10-800 nm, and optionally (F) an outer protective layer, and to the use thereof in paints, coatings, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, as dopants for the laser marking of papers and plastics, in cosmetic formulations and for the preparation of pigment preparations and dry preparations.
    Type: Application
    Filed: February 8, 2013
    Publication date: June 13, 2013
    Applicant: MERCK PATENT GMBH
    Inventor: MERCK PATENT GMBH
  • Publication number: 20130118380
    Abstract: A system of N?3 interference pigments, which is distinguished in that it exhibits a maximum color gamut through specification of the optimum pigment hue angle hu?v?i (i=1 to N) in the CIELUV system.
    Type: Application
    Filed: August 9, 2012
    Publication date: May 16, 2013
    Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNG
    Inventors: Michael ROESLER, Adalbert HUBER
  • Patent number: 8337611
    Abstract: Disclosed are yellowing-stable, silver-white effect pigments having high whiteness based on synthetic mica flakes and to the use thereof in paints, lacquers, printing inks, plastics, button pastes, ceramic materials, glasses, for coloring seed, as dopant in laser markings of plastics and papers, as additive for laser welding of plastics, as additive for coloring in the foods and pharmaceuticals sectors and in cosmetic formulations, and for the preparation of pigment compositions and dry preparations.
    Type: Grant
    Filed: February 17, 2010
    Date of Patent: December 25, 2012
    Assignee: Merck Patent GmbH
    Inventors: Gerhard Pfaff, Johann Dietz, Sabine Schoen, Doreen Warthe
  • Publication number: 20120282311
    Abstract: The present invention relates to pigments with improved and adjustable sparkling effect comprising A) a plate-like substrate of perlite coated with (a) dielectric material, and/or metal; and B) a plate-like substrate of mica, coated with (a) dielectric material, and/or a metal; and a process for their production and their use in paints, ink jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass. The pigments show an improved sparkle effect; in particular an attractive high sparkle intensity.
    Type: Application
    Filed: October 18, 2010
    Publication date: November 8, 2012
    Applicant: BASF SE
    Inventors: Raimund Schmid, Norbert Mronga, Patrice Bujard, Steven Jones, Paul Cao
  • Patent number: 8303864
    Abstract: Flame-retardant plastics mouldings composed of polyphenyl sulphones (PPSUs) or of polycarbonates (PCs) are coloured with Iridoin® pigments in such a way as to have a metallic effect. The effect is resistant to the usual stresses present in an aircraft cabin and complies with the respective fire-protection requirements.
    Type: Grant
    Filed: June 16, 2005
    Date of Patent: November 6, 2012
    Assignee: Evonik Rohm GmbH
    Inventor: Detlef Bumann
  • Patent number: 8273171
    Abstract: A pearlescent pigment (100) includes: a flaky substrate (10); a titanium dioxide layer (20) that is formed on the flaky substrate (10); and an oxazoline compound layer (40) that is formed on the titanium dioxide layer (20) with the titanium dioxide layer (20) being interposed between the flaky substrate (10) and the oxazoline compound layer (40), and serves as a top surface of the pearlescent pigment (100).
    Type: Grant
    Filed: August 29, 2007
    Date of Patent: September 25, 2012
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Takeaki Kitamura, Juichi Ino
  • Publication number: 20120227627
    Abstract: The present invention relates to a nacreous pigment and a method of preparing the same. The nacreous pigment includes a flake substrate, a first metal oxide layer coated on the substrate, and an oxide layer coated on the first metal oxide layer and containing MgO.SiO2, and a second metal oxide layer coated on the oxide layer. The pigment exhibits high brightness, high chroma, high gloss, and multi-color effects.
    Type: Application
    Filed: June 22, 2011
    Publication date: September 13, 2012
    Applicant: CQV CO., LTD.
    Inventors: Jae-Il JEONG, Kwang-Choong KANG, Byung-Ki CHOI, Kwang-Soo LIM, Kil -Wan CHANG
  • Publication number: 20120219607
    Abstract: The invention relates to pearlescent pigments comprising a largely transparent platelet-shaped synthetic substrate having a density ?S and at least one optically active coating having a density ?m, the substrate having an average size d50 from a range from 2.0 ?m to 8.0 ?m and an average height hS from a range from 40 nm to 110 nm and the total lead content of the pearlescent pigments is ?10 ppm. The invention further relates to a method for producing the pearlescent pigments, and also to the use thereof.
    Type: Application
    Filed: October 12, 2010
    Publication date: August 30, 2012
    Applicant: Eckart GmbH
    Inventors: Ulrich Schmidt, Michael Gruner, Dirk Schumacher, Gunter Kaupp, Barbara Mendler
  • Patent number: 8197591
    Abstract: The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.
    Type: Grant
    Filed: February 23, 2007
    Date of Patent: June 12, 2012
    Assignee: Eckart GmbH
    Inventors: Günter Kaupp, Ulrich Schmidt
  • Publication number: 20120136093
    Abstract: A two step method for preparing a filler composition, the filler composition useful to prepare a nanocomposite polymer and an epoxy nanocomposite coating. First, disperse a water dispersible filler material in a liquid comprising water, but without any added intercalation agent, to form a dispersion. Second, replace at least a portion of the water of the liquid with an organic solvent so that the water concentration of the liquid is less than six percent by weight to form the filler composition, the average size of at least one dimension of the filler material being less than two hundred nanometers upon examination by transmission electron microscopy of a representative freeze dried sample of the dispersion of the first step. A nanocomposite polymer can be prepared by mixing the filler composition with one or more polymer, polymer component, monomer or prepolymer to produce a polymer containing the filler composition.
    Type: Application
    Filed: January 16, 2012
    Publication date: May 31, 2012
    Applicants: THE TEXAS A & M UNIVERSITY, DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Luyi Sun, Woong Jae Boo, Hung-Jue Sue, Maurice J. Marks, Richard F. Fibiger, Michael S. Paquette
  • Patent number: 8187589
    Abstract: The present invention relates to a process for stabilizing aqueous preparations of minerals by adding reuterin to the aqueous preparations, to the use of reuterin for the stabilization of such aqueous mineral preparations, and the aqueous mineral preparations containing reuterin.
    Type: Grant
    Filed: August 19, 2009
    Date of Patent: May 29, 2012
    Assignee: Omya Development AG
    Inventors: Patrick Schwarzentruber, Nicola Di Maiuta
  • Patent number: 8153163
    Abstract: The present invention relates to a pearl pigment obtained by coating the surface of a flaky powder with a colored metal or a colored metal oxide and further coating the surface of the above colored metal- or colored metal oxide-coated flaky powder with a colorless metal or a colorless metal oxide, wherein when the pearl pigment is applied onto the surface of black artificial leather in an average amount of 0.05 mg/cm2 and the intensity of light reflected from the pearl pigment is measured using illuminant C at a 2° viewing angle with a spectrophotometric colorimeter which is provided with a sheet polarizer S on the light incident side and a sheet polarizer P on the light receiving side, the powder reflection light which is incident to the pearl pigment as a measurement sample at an angle of 45° to the direction normal to the surface of the sample and is received in the direction normal to the surface of the sample has absolute values a* and b* of 10 or less, and make-up cosmetics containing the pearl pigment.
    Type: Grant
    Filed: June 28, 2011
    Date of Patent: April 10, 2012
    Assignees: Kao Corporation, Nihon Koken Kogyo KK
    Inventors: Eiichiro Misaki, Hiroyuki Shiomi, Maoya Adachi, Takahiro Kaida
  • Publication number: 20120073473
    Abstract: The invention concerns a new synthetic mineral matter containing carbonate, the decomposition of which reduces the rate of fossil fuel carbon dioxide emission. It also concerns its manufacture in batches, or in a batch-continuous manner, or in a continuous manner, together with its uses in the pharmaceutical field, the field of human or animal foodstuffs, or again the papermaking field with, notably, manufacture of paper, filler or coating, or again every other paper surface treatment, together with the fields of water-based or non-water-based paints, together with the field of plastics, such as that of breathable polyethylene films, or again the field of printing inks.
    Type: Application
    Filed: September 28, 2011
    Publication date: March 29, 2012
    Inventors: Matthias Buri, Thoralf Gliese
  • Patent number: 8114252
    Abstract: A composition for treating paper products comprising protein particulate, colloidal pigment, synthetic latex polymer, and preservative is described, as well as methods and an apparatus using the composition for such treatments, and products obtained thereby. The treated paper products preferably have improved strength, water holdout, and/or ink holdout, amongst other advantages and benefits.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: February 14, 2012
    Assignee: Buckman Laboratories International, Inc.
    Inventor: Gerald M. Dykstra
  • Publication number: 20120034178
    Abstract: The present invention relates to novel pigment mixtures comprising at least two different particulate components A and B. The first component A comprises titanium suboxide(s), a titanium oxynitride or a titanium nitride species. Component B particle comprises inorganic, or organic pigments. The titanium suboxide particles display a bluish metallic luster, are new and form a further aspect of the present invention. When combined with particles from component B such as variously coated micas, for example, the bluish or bluish/black metallic color effect from component A leads to special color effects in the various mixtures.
    Type: Application
    Filed: October 21, 2011
    Publication date: February 9, 2012
    Inventors: Patrice Bujard, Philippe Bugnon, Marc Mamak, Urs Leo Stadler
  • Publication number: 20110318570
    Abstract: A paint composition producing paint films which change from an achromatic color to a chromatic color when the angle of incidence of the light with respect to the normal to the paint film plane is changed. The paint composition comprises (A) glitter material which has an angle-dependent interference effect and (B)metal oxide coated mica and/or metal oxide coated alumina flakes in proportions where the content ratio ((A)/(B)) of the (A) component with respect to the (B) component, as the solid fraction mass ratio, is from 2.5/1 to 1/6 and in which the interference color of the (A) component and the interference color of the (B) component at a face angle of the paint film have a complementary color relationship.
    Type: Application
    Filed: January 28, 2010
    Publication date: December 29, 2011
    Applicant: BASF COATINGS JAPAN LTD.
    Inventors: Haruko Ryuzaki, Kaori Notoya, Shigeo Misawa
  • Patent number: 8083846
    Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective layer which acts as a reflector to light directed thereon and a spacer pigment layer which is selectively transparent to light directed thereon.
    Type: Grant
    Filed: August 18, 2004
    Date of Patent: December 27, 2011
    Assignee: BASF Corporation
    Inventors: Curtis J. Zimmermann, James D. Christie, Vivian K. Doxey, Daniel Stevenson Fuller
  • Publication number: 20110301273
    Abstract: Pigment granules including a support material which is coated with one or more flake-form effect pigments by means of an adhesion promoter. The effect pigments may be, for example, pearlescent pigments, interference pigments, metal-effect pigments, multilayered pigments having one or more transparent, semi-transparent or opaque layers, goniochromatic pigments, holographic pigments, coated BiOCL flakes, uncoated BiOCl flakes, and LCP pigments, and mixtures thereof. A process for the production of pigment granules includes mixing one or more flake-form effect pigments, a support material, at least one adhesion promoter, and optionally one or more additives simultaneously or successively with one another. The pigment granules may be used for the pigmenting of application media, in particular paints, plasters, coatings, powder coatings, plastics, and in particular as scatter and effect granules, for example for the decoration of wallcoverings.
    Type: Application
    Filed: December 18, 2009
    Publication date: December 8, 2011
    Applicant: Merck Patent GmbH
    Inventors: Thomas Rathschlag, Carsten Griessmann
  • Patent number: 8066811
    Abstract: The invention disclosed a pigment having angle dependence of the interference colors and its production process, in which mica is used as the substrate and the first metal oxide coating with high refractive index has the optical thickness of silver to golden interference color. And the second metal oxide coating with low refractive index has the optical thickness of the second circle green to the fourth circle interference color. The third coating is a highly refractive metal oxide. The lowly refractive metal oxide is SiO2 and the highly refractive metal oxide is TiO2, SnO2, Fe2O3, Fe3O4, CoO, Co2O3, ZrO2, Cr2O3 or their mixtures as well as complexes. The mica substrate is wet-milled mica powders with a thickness of 0.1-0.9 micrometers and a diameter of 5-250 micrometers.
    Type: Grant
    Filed: April 18, 2005
    Date of Patent: November 29, 2011
    Inventors: Jiansheng Fu, Yiting Peng, Xiaohui Tian
  • Publication number: 20110265689
    Abstract: Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the optically active coating includes at least a) an absorbing high-index layer A having a refractive index n?1.8 b) a low-index layer B having a refractive index n<1.8 c) a high-index layer C having a refractive index n?1.8 and also d) optionally at least one outer protective layer D and where the multilayer pearlescent pigments have a cumulative frequency distribution of a volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D in a range from 0.7-1.4, the span ?D being calculated in accordance with formula (I) ?D=(D90?D10)/D50??(I). The disclosure further relates to a method for producing these multilayer pearlescent pigments, and also to their use.
    Type: Application
    Filed: August 9, 2010
    Publication date: November 3, 2011
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Publication number: 20110265690
    Abstract: Multilayer pearlescent pigments based on platelet-shaped transparent substrates with an optically active coating, where the optically active coating includes at least a) a nonabsorbing high-index layer A having a refractive index n?1.8, b) a low-index layer B having a refractive index n<1.8 having an optical layer thickness >150 nm, c) an absorbing high-index layer C having a refractive index n?1.8 and also, d) optionally an outer protective layer D, wherein the multilayer pearlescent pigments have a cumulative frequency distribution of the volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D of 0.7-1.4, the span ?D being calculated in accordance with the formula ?D=(D90?D10)/D50. The disclosure further relates to a method for producing these multilayer pigments, and to their use.
    Type: Application
    Filed: August 9, 2010
    Publication date: November 3, 2011
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Publication number: 20110259243
    Abstract: Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the coating includes at least (a) a nonabsorbing high-index layer A having a refractive index n?1.8, (b) a low-index layer B having a refractive index n<1.8, (c) a nonabsorbing high-index layer C having a refractive index n?1.8 and also (d) optionally at least one outer protective layer D where the pigments have a cumulative frequency distribution of a volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D in a range from 0.7-1.4, the span ?D being calculated in accordance with formula (I) ?D=(D90?D10)/D50??(I). The disclosure further relates to a method for producing these multilayer pearlescent pigments, and also to their use.
    Type: Application
    Filed: August 9, 2010
    Publication date: October 27, 2011
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Publication number: 20110237683
    Abstract: The present invention relates to pigment compositions with improved and adjustable sparkling effect comprising A) a platelet-like perlite; and B) an effect pigment; and a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass. The pigment compositions show an improved sparkle effect; in particular an attractive high sparkle intensity.
    Type: Application
    Filed: February 1, 2011
    Publication date: September 29, 2011
    Applicant: BASF SE
    Inventors: Raimund Schmid, Carolyn Lavallee, Steven A. Jones, James Carroll
  • Publication number: 20110226161
    Abstract: Multilayer pearlescent pigments with a silver interference color, based on platelet-shaped transparent substrates with an optically active coating, where the optically active coating includes at least a) a high-index layer A having a refractive index n?1.8 b) a low-index layer B having a refractive index n<1.8 c) a high-index layer C having a refractive index n?1.8 and also d) optionally an outer protective layer D. The multilayer pearlescent pigments have the indices D10, D50, D90 from the cumulative frequency distribution of the volume-averaged size distribution function, with a span ?D of 0.7-1.4, the span ?D being calculated in accordance with the formula ?D=(D90?D10)/D50. The invention further relates to a method for producing these multilayer pearlescent pigments, and also to their use.
    Type: Application
    Filed: August 9, 2010
    Publication date: September 22, 2011
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Publication number: 20110223218
    Abstract: A combination pigment having a mica and/or metal oxide-coated mica substrate, an absorption colorant coating, and a waxy film bonding the absorption colorant coating to the substrate.
    Type: Application
    Filed: March 9, 2010
    Publication date: September 15, 2011
    Inventors: Steven Alan Jones, Gabriel E. Uzunian, Betty F. Aucar
  • Patent number: 8016934
    Abstract: The present invention relates to a pearl pigment obtained by coating the surface of a flaky powder with a colored metal or a colored metal oxide and further coating the surface of the above colored metal- or colored metal oxide-coated flaky powder with a colorless metal or a colorless metal oxide, wherein when the pearl pigment is applied onto the surface of black artificial leather in an average amount of 0.05 mg/cm2 and the intensity of light reflected from the pearl pigment is measured using illuminant C at a 2° viewing angle with a spectrophotometric colorimeter which is provided with a sheet polarizer S on the light incident side and a sheet polarizer P on the light receiving side, the powder reflection light which is incident to the pearl pigment as a measurement sample at an angle of 45° to the direction normal to the surface of the sample and is received in the direction normal to the surface of the sample has absolute values a* and b* of 10 or less, and make-up cosmetics containing the pearl pigment.
    Type: Grant
    Filed: December 15, 2005
    Date of Patent: September 13, 2011
    Assignees: Kao Corporation, Nihon Koken Kogyo KK
    Inventors: Eiichiro Misaki, Hiroyuki Shiomi, Maoya Adachi, Takahiro Kaida
  • Publication number: 20110203485
    Abstract: Methods for treating lignocellulosic material or pigment with a reductive bleaching solution generally include washing the lignocellulosic material or pigment with a reducing agent of magnesium dithionite. The method includes at least one reductive stage and at least one peroxide stage. Also disclosed are methods for preparing dithionite solution wherein magnesium bisulfite is reduced with borohydride solution to obtain dithionite. Bleached lignocellulosic material or pigment obtained with the treatment methods are also disclosed.
    Type: Application
    Filed: October 30, 2009
    Publication date: August 25, 2011
    Applicant: KEMIRA OYJ
    Inventors: Risto Rahkola, Birgitta Peltopakka, Hannu Hämäläinen, Jonas Konn, Sari Vahlroos-Pirneskoski
  • Publication number: 20110197782
    Abstract: A gold color metallic pigment with coating of manganese oxide nanoparticles and a method to produce the gold color pigment are described. The disclosed coated pigment includes a platelet shaped substrate, a passivation layer applied to the substrate with surface anchoring groups and a manganese oxide nanoparticles layer. The coated pigment further includes an encapsulation layer or a surface property modification layer. The disclosed method provides pigments that exhibit brilliant gold color and a highly desirable appearance of real gold without the environmental issues causing by heavy metals.
    Type: Application
    Filed: February 18, 2010
    Publication date: August 18, 2011
    Applicant: SILBERLINE MANUFACTURING COMPANY, INC.
    Inventors: Wei WANG, Hai Hui LIN, Parfait Jean Marie LIKIBI
  • Patent number: 7993444
    Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack. The present effect pigments may be used in cosmetic and industrial applications.
    Type: Grant
    Filed: October 19, 2006
    Date of Patent: August 9, 2011
    Assignee: BASF Catalysts LLC
    Inventors: Daniel S. Fuller, Curtis J. Zimmermann
  • Patent number: 7993443
    Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack. The present multilayer effect pigment may be used in cosmetics or personal care products.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: August 9, 2011
    Assignee: BASF Catalysts LLC
    Inventors: Daniel S. Fuller, Curtis J. Zimmermann
  • Publication number: 20110144251
    Abstract: A coated particulate solid composition includes a particulate inorganic solid having deposited on its surface a treatment oil comprising lipids. The particulate inorganic solid can include a base particle of titanium dioxide, zinc sulfide, zinc oxide, iron oxide, lead oxide, aluminum oxide, silicon dioxide, zirconium oxide and/or chromium oxide. The treatment oil is optionally a vegetable oil. The treatment oil containing lipids optionally contains glycerides such as triglycerides, and diglycerides, and can contain phospholipids. In one embodiment, the coated particulate solid composition includes particulate titanium dioxide, wherein the treatment oil provides increased bulk density, and enhanced dispersibility in plastic as well as improved lacing resistance.
    Type: Application
    Filed: December 16, 2009
    Publication date: June 16, 2011
    Inventor: Modasser El-Shoubary
  • Patent number: 7951420
    Abstract: A method of preparing a pigment exhibiting a color-shifting effect, including at least heating mica powder suspension in water, adjusting the pH value of the mixture to between 2 and 9, adding a first inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 6 and 14, adding a second inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 2 and 9, adding a third inorganic salt solution, maintaining the pH value of the mixture constant, and stirring the mixture at constant temperature.
    Type: Grant
    Filed: September 26, 2009
    Date of Patent: May 31, 2011
    Inventors: Jiansheng Fu, Yiting Peng, Xiaohui Tian
  • Publication number: 20110064779
    Abstract: Pearlescent pigments including a largely transparent platelet-shaped substrate having a density ?S and at least one optically active coating having a density ?M, the substrate having an average size d50 of 3 to 8 ?m and an average height hS of 40 to 110 nm. The disclosure further relates to a method for producing the pearlescent pigments, and also to the use thereof.
    Type: Application
    Filed: April 15, 2009
    Publication date: March 17, 2011
    Inventors: Michael Gruener, Ulrich Schmidt, Günter Kaupp, Peter Krueger, Jens Depner, Katrin Steinbach, Ralph Schneider, Frank Henglein