Mica Containing Patents (Class 106/417)
  • Patent number: 6958091
    Abstract: Inorganic pigments treated with at least one amide of a fatty acid and an aliphatic amine possess improved processibility and dispersibility in thermoplastic materials, and impart improved properties to thermoplastic compositions containing said surface-treated pigments.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: October 25, 2005
    Assignee: Kerr-McGee Chemical LLC
    Inventor: Daniel H. Craig
  • Patent number: 6946028
    Abstract: Inorganic pigments treated with one or more of the ?,?-dialkyl substituted linear or branched carboxylic acids and the salts thereof possess improved processibility and dispersibility in thermoplastic materials, and impart improved properties to thermoplastic compositions containing said surface-treated pigments.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: September 20, 2005
    Assignee: Kerr-McGee Chemical LLC
    Inventor: Daniel H. Craig
  • Patent number: 6929690
    Abstract: A pigment with a metallic luster, comprising a wafer-like substrate made of aluminium dioxide having a thickness of more than 250 nm and less than 1 ?m, which is fully enveloped by a metal layer.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: August 16, 2005
    Assignee: Merck Patent GmbH
    Inventors: Reiner Vogt, Gerhard Pfaff, Stephanie Andes, Michael Uhlig, Martin Friz, Katsuhisa Nitta
  • Patent number: 6899757
    Abstract: Disclosed is a method for preparing a pearlescent pigment by coating metal oxides on the synthesized mica, involving the steps of grinding the synthesized mica by agitating the mica with water in a water mixer to a particle size between 100 and 500 ?m and separating the mica, dispersing the separated particles of the synthesized mica in water and adding acid thereto to adjust pH between 1 and 4, adding the metal oxide precursors and a basic aqueous solution thereto while maintaining said pH range until the desired color is attained, and thereby forming at least one hydrous metal oxide layer on the particles of the synthesized mica, and filtering, water-washing, drying and calcining the synthesized mica coated with the metal oxide layer. The method may further involve the step of further pulverizing the synthesized mica roughly ground in a water mixer by using a conventional wet pulverizer so that less than 100 ?m of the synthesized mica may be used as a base material.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: May 31, 2005
    Assignee: Sky Chemical Co., Ltd.
    Inventors: Kil-Wan Chang, Kwang-su Lim
  • Patent number: 6858072
    Abstract: This invention provides a highly orientated surface-modified pearl pigment excellent in plane orientation (leafing effect). Disclosed are: a surface-modified pearl pigment wherein fine polymer particles adhere, without being mutually aggregated, to hydrated metal oxides via chemical bonding; a process for producing the same: and use thereof for inks, coatings and plastics.
    Type: Grant
    Filed: January 31, 2001
    Date of Patent: February 22, 2005
    Assignee: Merck Patent GmbH
    Inventors: Bangyin Li, Katsuhisa Nitta
  • Patent number: 6840993
    Abstract: The present invention relates to silver-colored luster pigments based on multiply coated platelet-shaped substrates, which has at least one layer sequence of TiO2, a colorless coating and another TiO2 layer. The pigment can optionally have an outer protective layer. These luster pigments are useful and to the use thereof in paints, coatings, printing inks, including security printing inks, plastics, ceramic materials, glasses, cosmetic formulations and for producing pigment preparations and dry product forms such as granules, chips, pellets and briquettes.
    Type: Grant
    Filed: April 21, 2003
    Date of Patent: January 11, 2005
    Assignee: Merck Patent GmbH
    Inventors: Christoph Schmidt, Andrea Heyland, Claudia Fornoff, Hans-Dieter Brückner
  • Patent number: 6821333
    Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective layer which acts as a reflector to light directed thereon and a spacer pigment layer which is selectively transparent to light directed thereon.
    Type: Grant
    Filed: December 13, 2002
    Date of Patent: November 23, 2004
    Assignee: Engelhard Corporation
    Inventors: Curtis J. Zimmermann, James D. Christie, Vivian K. Doxey, Daniel Stevenson Fuller
  • Publication number: 20040194666
    Abstract: The present invention relates to pigment and coating compositions that are used to prepare pigmented coatings that exhibit geometric metamerism or metallic flop. The inventive pigment compositions comprise a small particle size pigment, at least one flop-enhancing agent, optionally one or more pigment property enhancing compounds. The flop-enhancing agent is selected from the group consisting of a halogenated copper phthalocyanines, indanthrones or carbazole dioxazines or mixtures thereof that are unsubstituted or substituted in the benzene rings by halogen, —NR1R2, C1-C10alkyl and —X—NR1′R2′, wherein R1 and R2 are independently hydrogen, C1-C10alkyl or —X—NR1′R2′, R1′ and R2′ are independently hydrogen or C1-C10alkyl, and X is C1-C10alkylene. The pigment property enhancing compounds may be a texture improving agent, a rheology improving agent, an antiflocculating compound and a dispersibility improving compound.
    Type: Application
    Filed: March 29, 2004
    Publication date: October 7, 2004
    Inventor: Shivakumar Basalingappa Hendi
  • Patent number: 6800125
    Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective silver layer which acts as a reflector to light directed thereon and an iron oxide layer.
    Type: Grant
    Filed: December 13, 2002
    Date of Patent: October 5, 2004
    Assignee: Engelhard Corporation
    Inventors: Curtis J. Zimmermann, Steven A. Jones
  • Patent number: 6794037
    Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective silver layer which acts as a reflector to light directed thereon, a spacer layer which is selectively transparent to light directed thereon, and an iron oxide layer on the spacer layer.
    Type: Grant
    Filed: December 13, 2002
    Date of Patent: September 21, 2004
    Assignee: Engelhard Corporation
    Inventors: Curtis J. Zimmermann, Steven A. Jones
  • Publication number: 20040177788
    Abstract: Interference pigments having a mass tone based on multicoated flake-form substrates, which have on the substrate:
    Type: Application
    Filed: March 10, 2004
    Publication date: September 16, 2004
    Inventors: Norbert Rick, Lilia Heider, Manuela Loch, Nicole Schupp, Ralf Anselmann
  • Patent number: 6776835
    Abstract: The present invention relates to multilayer pigments based on platelet-shaped metal substrates coated with two or more metal oxide layers by a one-pot process in an exclusively aqueous medium. The invention further relates to the use of the multilayer pigments in paints, varnishes, printing inks, including security printing inks, plastics, ceramic materials and cosmetic and for the laser formulations marking of plastics.
    Type: Grant
    Filed: June 4, 2003
    Date of Patent: August 17, 2004
    Assignee: Merck Patent Gesellschaft MIT Beschrankter Haftung
    Inventors: Stephanie Andes, Sabine George, Margarete Herbski, Peter Reynders, Reiner Vogt, Johann Dietz, Helge Kniess, Elke Steudel
  • Patent number: 6770689
    Abstract: The glittering ink of the present invention contacts scaly glittering particles, a water-soluble resin, a water-soluble organic solvent, colorant and water. The said scaly glittering particles have a median diameter of at least 10 &mgr;m, a ratio of smoothness on the particle surface to a median diameter of not greater than 0.011, and a surface coating ratio of the said colorant in a written mark of not greater than 80% in a state of a dried written mark. In addition, the aqueous glittering ink of the present invention has the thixotropy index (T.I. value) of not less than 1.3, represented by the ratio of V0.5 to V1.0 (V0.5/V1.0), wherein V0.5 is the viscosity with the rotation speed of 0.5 rpm and V1.0 is the viscosity with the rotation speed of 1.0 rpm when the ink is measured by an ELD-typed viscometer (3° R14 cone, at the temperature of 20° C.) and the ink has the V0.5, the viscosity with the rotation speed of 0.5 rpm, of 1000˜15000 mPa·s.
    Type: Grant
    Filed: September 19, 2000
    Date of Patent: August 3, 2004
    Assignee: Sakura Color Products Corp.
    Inventors: Yasuyuki Yoshimura, Naoshi Murata, Yuki Yamamoto, Tomohiro Sawa
  • Publication number: 20040123778
    Abstract: An effect pigment is constituted by coated laminar platelets in which the platelets are a mixture of different platelet materials, one of which is platy glass or platy aluminum oxide, and in which the pigment exhibits visual homogeneity.
    Type: Application
    Filed: December 31, 2002
    Publication date: July 1, 2004
    Inventor: Frank Bagala
  • Publication number: 20040112253
    Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective silver layer which acts as a reflector to light directed thereon and an iron oxide layer.
    Type: Application
    Filed: December 13, 2002
    Publication date: June 17, 2004
    Inventors: Curtis J. Zimmermann, Steven A. Jones
  • Patent number: 6743285
    Abstract: The present invention relates to pigment mixtures in the form of a dispersion or powder, consisting of at least two components, where component A comprises coated or uncoated BiOCl pigments in the form of a powder or dispersion, and component B comprises pearlescent pigments, platelet-shaped, needle-shaped or spherical colorants and/or fillers, and to the use thereof in paints, coatings, printing inks, plastics, powder coatings, plastic films, for the finishing of seed and in particular in cosmetic formulations.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: June 1, 2004
    Assignee: Merck Patent GmbH
    Inventors: Ralf Anselmann, Uta Hillgärtner, Sabine Schoen
  • Publication number: 20040096579
    Abstract: Disclosed is a method for preparing a pearlescent pigment by coating metal oxides on the synthesized mica, involving the steps of grinding the synthesized mica by agitating the mica with water in a water mixer to a particle size between 100 and 500 &mgr;m and separating the mica, dispersing the separated particles of the synthesized mica in water and adding acid thereto to adjust pH between 1 and 4, adding the metal oxide precursors and a basic aqueous solution thereto while maintaining said pH range until the desired color is attained, and thereby forming at least one hydrous metal oxide layer on the particles of the synthesized mica, and filtering, water-washing, drying and calcining the synthesized mica coated with the metal oxide layer. The method may further involve the step of further pulverizing the synthesized mica roughly ground in a water mixer by using a conventional wet pulverizer so that less than 100 &mgr;m of the synthesized mica may be used as a base material.
    Type: Application
    Filed: April 9, 2003
    Publication date: May 20, 2004
    Inventors: Chang Kil-Wan, Kwang-su Lim
  • Patent number: 6719837
    Abstract: The present invention relates to pearlescent pigments based on substrates coated with one or more layers of nitrides or oxynitrides to a method for the production of such pigments and their use in plastics, paints, coatings, powder coatings, inks, printing inks, glasses, ceramic products, agriculture foils, for lasermarking of papers and plastics, security applications and in cosmetic formulations.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: April 13, 2004
    Assignee: Merck Patent Gesellschaft mit beschränkter Haftung
    Inventors: Stéphane Bertaux, Peter Reynders, Jens-Uwe Wichmann, Eberhard Schweda
  • Patent number: 6719838
    Abstract: The present invention relates to colored interference pigments based on multicoated, platelet-shaped substrates, which are distinguished in that they comprise (A) a colored coating having a refractive index of n>1.8, (B) a colorless coating having a refractive index of n>1.8, (C) a colorless coating having a refractive index of n≦1.8, (D) a colorless coating having a refractive index of n>1.8, and optionally (E) an outer protective layer, and to their use in paints, surface coatings, printing inks, plastics, ceramic materials, glasses, for laser marking, in cosmetic formulations and for the production of pigment preparations and dry preparations.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: April 13, 2004
    Assignee: Merck Patent GmbH
    Inventors: Lilia Heider, Manuela Loch, Nicole Schupp, Helge Kniess
  • Patent number: 6706109
    Abstract: Optically variable interference pigments are composed of platelets of at least partly core-free titanium dioxide-coated substrate of about 1-25 mm particle size and an interference thickness of about 5-600 nm which have an oxide coating thereon.
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: March 16, 2004
    Assignee: Engelhard Corporation
    Inventor: Carmine V. DeLuca, Jr.
  • Patent number: 6702885
    Abstract: The present invention relates to a pigment preparation comprising a mixture of coated and/or uncoated SiO2 flakes, one or more special-effect pigments, and a phosphate derivative, and to the use thereof, especially in printing inks.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: March 9, 2004
    Assignee: Merck Patent Gesellschaft Mit Beschrankter
    Inventors: Sabine Schoen, Reiner Vogt, Norbert Schül, Karl Osterried, Gerhard Herget
  • Patent number: 6692561
    Abstract: The invention relates to intensely colored interference pigments based on multi-layered plate-like substrates with at least two sequences of layers consisting of (A) a colorless layer with a refraction index n≦1,8; (B) a high-index layer consisting of a mixture of TiO2 and Fe2O3 in a ratio of 1:0.1 to 1:5 and optionally, one or more metal oxides in quantities of to layer (B); and optionally (C) an outer protective layer.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: February 17, 2004
    Assignee: Merck Patent Gesellschaft mit beschränkter Haftung
    Inventors: Sabine Schoen, Klaus Bernhardt, Christoph Schmidt
  • Patent number: 6689205
    Abstract: Multilayer interference pigment consisting of a transparent carrier material coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by alternate coating of the transparent carrier material with a metal oxide of high refractive index and with a metal oxide of low refractive index in a wet process by hydrolysis of the corresponding water-soluble metal compounds, separation, drying and, if desired, calcination of the resulting pigment.
    Type: Grant
    Filed: October 24, 2000
    Date of Patent: February 10, 2004
    Assignee: Merck Patent Gesellschaft
    Inventors: Hans-Dieter Brückner, Andrea Heyland, Christoph Schmidt, Christina Schank, Claudia Seibel
  • Patent number: 6686042
    Abstract: Pigment flakes are provided which can be used to produce colorant compositions having color shifting properties. The pigment flakes can have a symmetrical coating structure on opposing sides of a reflector layer, can have an asymmetrical coating structure with all of the layers on one side of the reflector layer, or can be formed with encapsulating coatings around a reflector layer. The coating structure includes a selective absorbing layer on one or more sides of the reflector layer, a dielectric layer on the selective absorbing layer, and an absorber layer on the dielectric layer. The pigment flakes exhibit a discrete color shift such that the pigment flakes have a first color at a first angle of incident light or viewing and a second color different from the first color at a second angle of incident light or viewing. The pigment flakes can be interspersed into liquid media such as paints or inks for subsequent application to objects or papers.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: February 3, 2004
    Assignee: Flex Products, Inc.
    Inventor: Charlotte R. LeGallee
  • Patent number: 6676741
    Abstract: Methods and apparatus are provided for uniformly depositing a coating material from a vaporization source onto a powdered substrate material to form a thin coalescence film of the coating material that smoothly replicates the surface microstructure of the substrate material. The coating material is uniformly deposited on the substrate material to form optical interference pigment particles. The thin film enhances the hiding power and color gamut of the substrate material. Physical vapor deposition process are used for depositing the film on the substrate material. The apparatus and systems employed in forming the coated particles utilize vibrating bed coaters, vibrating conveyor coaters, or coating towers. These allow the powdered substrate material to be uniformly exposed to the coating material vapor during the coating process.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: January 13, 2004
    Assignee: Flex Products, Inc.
    Inventors: Roger W. Phillips, Vladimir Raksha
  • Publication number: 20040003758
    Abstract: The invention relates to a multilayered interference pigment consisting of a transparent carrier material which is coated with alternating layers of colourless, non-absorbent metal oxides having a high and a low refractive index, the difference between the refractive indices being at least 0.1. The inventive pigment can be obtained by alternately coating the transparent carrier material with a metal oxide having a high refractive index and a metal oxide having a low refractive index according to the wet method, by hydrolysing the corresponding water-soluble, inorganic metal compounds, and separating, drying and optionally calcinating the obtained pigment.
    Type: Application
    Filed: April 9, 2003
    Publication date: January 8, 2004
    Inventors: Hans-Dieter Bruckner, Matthias Kuntz
  • Publication number: 20030213409
    Abstract: Optically variable interference pigments are composed of platelets of at least partly core-free titanium dioxide-coated substrate of about 1-25 mm particle size and an interference thickness of about 5-600 nm which have an oxide coating thereon.
    Type: Application
    Filed: May 14, 2002
    Publication date: November 20, 2003
    Inventor: Carmine V. DeLuca
  • Patent number: 6648956
    Abstract: The invention relates to a nondusting, solvent-containing homogeneous pigment preparation that includes ≧70% by weight of one or more effect pigments 0.1-30% by weight of an organic solvent or solvent mixture having an evaporation number (EN) of 10 to 100 and a surface tension (ST) of ≦35 mN/m and optionally 0-5% by weight of a surface-active substance.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: November 18, 2003
    Assignee: Merck Patent Gesellschaft mit beschraenkter Haftung
    Inventors: Wolfgang Hechler, Gerhard Herget, Brigitte Husseini, Sabine Schoen
  • Patent number: 6646037
    Abstract: A treatment for pigments is provided. This treatment, which uses certain organosulfonic compounds, imparts improved physical and chemical qualities including lacing resistance, improved dispersion and decreased chemical reactivity when these treated pigments are incorporated into polymeric matrices. The addition of organosulfonic compounds may flexibly be incorporated into known processes at varying points, and are preferably added downstream of any filtering steps.
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: November 11, 2003
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Modasser El-Shoubary, Robert Kostelnik, Charles Wheddon
  • Patent number: 6645286
    Abstract: The present invention is concerned with soft-magnetic iron effect pigments with metallic luster, which are produced by grinding reductively treated carbonyl iron powder, and which are passivated either during grinding or subsequent to the grinding. The products find application in the decorative and functional fields in paint and lacquer coatings, coloring of plastics, in printing, cosmetics, and glass and ceramics.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: November 11, 2003
    Assignee: Eckart GmbH & Co. KG
    Inventors: Werner Ostertag, Stefan Trummer, Frank Henglein, Klaus Greiwe
  • Publication number: 20030205170
    Abstract: The present invention relates to silver-colored luster pigments based on multiply coated platelet-shaped substrates, which has at least one layer sequence of TiO2, a colorless coating and another TiO2 layer. The pigment can optionally have an outer protective layer. These luster pigments are useful and to the use thereof in paints, coatings, printing inks, including security printing inks, plastics, ceramic materials, glasses, cosmetic formulations and for producing pigment preparations and dry product forms such as granules, chips, pellets and briquettes.
    Type: Application
    Filed: April 21, 2003
    Publication date: November 6, 2003
    Applicant: Merck Patent GmbH
    Inventors: Christoph Schmidt, Andrea Heyland, Claudia Fornoff, Hans-Dieter Bruckner
  • Patent number: 6638353
    Abstract: The invention relates to a non-dusting homogeneous pigment preparation notable in that it comprises at least 40% by weight of one or more effect pigments, from 0.5 to 50% by weight of water and/or an organic solvent or solvent mixture and from 0.5 to 59.5% by weight of a styrene-modified maleate resin having an acid number >90 mg KOH/g, and to its use in particular to produce dry preparations.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: October 28, 2003
    Assignee: Merck Patent GmbH
    Inventors: Thomas Rathschlag, Carsten Griessmann
  • Patent number: 6632276
    Abstract: The invention relates to electrically conductive pigments which have, as conductive layer on a substrate, a tin oxide layer doped with phosphorus.
    Type: Grant
    Filed: November 28, 1997
    Date of Patent: October 14, 2003
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventor: Reiner Vogt
  • Patent number: 6630022
    Abstract: A mechanically activated pozzolan prepared from granitic quarry fines. Quarry fines are milled by a high-energy milling process to convert the essentially inert raw granitic fines into a chemically reactive state. When added to a portland cement mortar mixture, mechanically activated fines combined with calcium hydroxide to improve the strength of the cured mortar compared to a similar mixture prepared with raw fines. Mortars prepared with mechanically activated granitic fines typically show strength values comparable to or exceeding similar mortars made using fly ash as a pozzolan. In some instances, the strength of a mortar prepared with mechanically activated granitic quarry fines exceeded a mortar prepared using 100% portland cement as the cementitious component.
    Type: Grant
    Filed: May 12, 1999
    Date of Patent: October 7, 2003
    Assignee: Granite Rock Company
    Inventors: Paul C. Lessard, Michael Havens-Cook
  • Patent number: 6630018
    Abstract: The invention relates to a platelet-shaped pigment having high luster and high covering power or high transparency, consisting of a transparent, inorganic, platelet-shaped matrix which can contain an additional constituent, characterized in that the additional constituent is a soluble or insoluble colorant and in that the matrix is coated at least on one side with one or more thin, transparent or semi-transparent reflective layers of metal oxides or metals to achieve the luster.
    Type: Grant
    Filed: April 15, 1994
    Date of Patent: October 7, 2003
    Assignee: Merck Patent Gesellschaft mit beschränkter Haftung
    Inventors: Gerd Bauer, Karl Osterried, Christoph Schmidt, Reiner Vogt, Helge-Bettina Kniess, Michael Uhlig, Norbert Schül, Günther Brenner
  • Patent number: 6626989
    Abstract: A pearlescent pigment comprising substrate particles having an adherent layer of rutile titanium dioxide thereon is prepared by effecting the deposition of hydrous titanium dioxide on the substrate particles after contacting the particles at elevated pH with titanium tetrachloride.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: September 30, 2003
    Assignee: Engelhard Corporation
    Inventors: Carmine V. DeLuca, Jr., Louis R. Cerce, Jr.
  • Publication number: 20030177950
    Abstract: The present invention relates to pigment mixtures consisting of at least two components, component A being SiO2 flakes coated with one or more metal oxides and/or metals and component B being special-effect pigments, and to their use in varnishes, paints, printing inks, masterbatches, plastics and cosmetic formulations.
    Type: Application
    Filed: March 24, 2003
    Publication date: September 25, 2003
    Applicant: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Sabine Schoen, Reiner Vogt, Norbert Schul, Karl Osterried, Johann Munz
  • Publication number: 20030177949
    Abstract: Methods and apparatus are provided for uniformly depositing a coating material from a vaporization source onto a powdered substrate material to form a thin coalescence film of the coating material that smoothly replicates the surface microstructure of the substrate material. The coating material is uniformly deposited on the substrate material to form optical interference pigment particles. The thin film enhances the hiding power and color gamut of the substrate material. Physical vapor deposition process are used for depositing the film on the substrate material. The apparatus and systems employed in forming the coated particles utilize vibrating bed coaters, vibrating conveyor coaters, or coating towers. These allow the powdered substrate material to be uniformly exposed to the coating material vapor during the coating process.
    Type: Application
    Filed: February 20, 2003
    Publication date: September 25, 2003
    Applicant: Flex Products, Inc.
    Inventors: Roger W. Phillips, Vladimir Raksha
  • Patent number: 6620233
    Abstract: Goniochromatic luster pigments are based on titanium dioxide-coated silicatic platelets which have been heated in a reducing atmosphere and which comprise at least one layer packet comprising A) a colorless coating having a refractive index n≦1.8 and B) a coating which has a refractive index n≧2.0, which includes iron(III) oxide and which selectively absorbs visible light.
    Type: Grant
    Filed: April 23, 2002
    Date of Patent: September 16, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Oliver Seeger, Raimund Schmid, Norbert Mronga, Jörg Adel
  • Patent number: 6616745
    Abstract: A metal oxide-coated mica pearlescent pigment having a coating of copper chromite thereon is provided.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: September 9, 2003
    Assignee: Engelhard Corporation
    Inventors: Samuel F. Narvarti, Mark E. Gall, Thomas V. Edwards, Frank A. Mazzella, William L. Howell, Jr.
  • Patent number: 6605146
    Abstract: Systems and methods of making and using fine particle materials in pigment blends and for using the aforementioned pigment blends in paint, coating, or coloring compositions are provided. This invention further provides systems and methods of enhancing the visual appearance of a variety of substrates by introducing a paint, coating, or coloring composition to the substrate. The fine particle materials of the present invention have a substantially random geometric shape, a particle size less than about 100 microns, and help provide both functional and visual enhancing properties to compositions and substrates containing these fine particle materials.
    Type: Grant
    Filed: July 16, 2002
    Date of Patent: August 12, 2003
    Assignee: Ameritech Holding Corporation
    Inventors: Guido Greco, Vincent Pernice, Barry E. Scheetz
  • Publication number: 20030147820
    Abstract: The present invention relates to pearlescent pigments based on substrates coated with one or more layers of nitrides or oxynitrides to a method for the production of such pigments and their use in plastics, paints, coatings, powder coatings, inks, printing inks, glasses, ceramic products, agriculture foils, for lasermarking of papers and plastics, security applications and in cosmetic formulations.
    Type: Application
    Filed: January 31, 2003
    Publication date: August 7, 2003
    Applicant: MERCK PAPTENTGESELLSCHAFT MIT BESCHRANKTER HAFTUNG
    Inventors: Stephane Bertaux, Peter Reynders, Jens-Uwe Wichmann, Eberhard Schweda
  • Patent number: 6599355
    Abstract: The invention relates to interference pigments with a great color strength that are based on multicoated platelet-shaped substrates that have at least one series of layers from (A) a highly refractive coating that consists of a mixture of TiO2 and Fe2O3 in ratio of 1:0.1 to 1:5 and optionally one or more metal oxides in amounts of ≦20% by weight based on layer (A), (B) a colorless coating with a refractive index n≦1.8, (C) a colorless coating with a refractive index of n 1.8, (D) an absorptive coating with a refractive index of n 1.8, and optionally (E) an outer protective layer.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: July 29, 2003
    Assignee: Merck Patent GmbH
    Inventors: Christoph Schmidt, Klaus Bernhardt, Sabine Schoen, Dieter Heinz
  • Patent number: 6596070
    Abstract: The present invention relates to interference pigments on the basis of multiply coated, platelet-shaped substrates which comprise at least one layer sequence comprising (A) a coating having a refractive index n≧2.0, (B) a colorless coating having a refractive index n≦1.8, and (C) a nonabsorbing coating of high refractive index, and, if desired, (D) an external protective layer.
    Type: Grant
    Filed: April 17, 2000
    Date of Patent: July 22, 2003
    Assignee: Merck Patent Gesellschaft
    Inventors: Christoph Schmidt, Gerhard Pfaff, Christina Schank, Sabine Schoen
  • Patent number: 6596061
    Abstract: Inorganic anti-corrosive pigments consist of surface-coated solids having a grain size of 0.1 to 75 &mgr;m. In order to improve the resistance of the paints and coatings containing such pigments, firstly Mn3(PO4)2 and secondly aluminium oxides and/or aluminium hydroxides are precipitated onto the solids.
    Type: Grant
    Filed: May 4, 2001
    Date of Patent: July 22, 2003
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventor: Thomas Rentschler
  • Patent number: 6596071
    Abstract: Organic and inorganic composite pigments having an average particle diameter of 0.01 to 10.0 &mgr;m composed of a white inorganic particle, an organosilane compound obtained from alkoxysilanes, or polysiloxanes coating on the white inorganic particle, and an organic pigment coat formed on said coating. An ultraviolet light-absorbing agent is present in any portion from the surface of the white inorganic particle to surface of the organic pigment coat. These composite pigments have reduced amounts of organic pigments desorbed from their surface and exhibit excellent light resistance due to their ultraviolet absorbing property.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: July 22, 2003
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Mineko Ohsugi, Yusuke Shimohata, Hiroko Morii
  • Publication number: 20030131764
    Abstract: A mechanically activated pozzolan prepared from granitic quarry fines. Quarry fines are milled by a high-energy milling process to convert the essentially inert raw granitic fines into a chemically reactive state. When added to a portland cement mortar mixture, mechanically activated fines combined with calcium hydroxide to improve the strength of the cured mortar compared to a similar mixture prepared with raw fines. Mortars prepared with mechanically activated granitic fines typically show strength values comparable to or exceeding similar mortars made using fly ash as a pozzolan. In some instances, the strength of a mortar prepared with mechanically activated granitic quarry fines exceeded a mortar prepared using 100% portland cement as the cementitious component.
    Type: Application
    Filed: May 12, 1999
    Publication date: July 17, 2003
    Inventors: PAUL C. LESSARD, MICHAEL HAVENS-COOK
  • Patent number: 6579355
    Abstract: The present invention relates to an interference pigment based on multiply-coated platelet-shaped substrates, comprising at least one layer sequence of (A) a high refractive index coating comprising a mixture of TiO2 and Fe2O3 in a ratio of about 10:1 to about 3:1 and optionally one or more metal oxides in amounts of ≲ about 20% by weight based on the layer (A), (B) a colorless coating having a refractive index n ≲ about 1.8, and optionally (C) an outer protective layer.
    Type: Grant
    Filed: February 15, 2000
    Date of Patent: June 17, 2003
    Assignee: Merck Patent Gesellschaft mit Beschraenkter Haftung
    Inventors: Christoph Schmidt, Klaus Bernhardt, Dieter Heinz
  • Publication number: 20030101908
    Abstract: Organic and inorganic composite pigments have an average particle diameter of 0.01 to 10.
    Type: Application
    Filed: June 11, 2002
    Publication date: June 5, 2003
    Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Mineko Ohsugi, Yusuke Shimohata, Hiroko Morii
  • Patent number: 6572784
    Abstract: Interference pigment flakes and foils are provided which have luminescent and color-shifting properties. The pigment flakes can have a symmetrical coating structure on opposing sides of a core layer, can have an asymmetrical coating structure with all of the layers on one side of the core layer, or can be formed with encapsulating coatings around the core layer. The coating structure of the flakes and foils includes a core layer, a dielectric layer overlying the core layer, and an absorber layer overlying the dielectric layer. A luminescent material is incorporated into the flakes or foils as a separate layer or as at least part of one or more of the other layers. The pigment flakes and foils exhibit a discrete color shift so as to have a first color at a first angle of incident light or viewing and a second color different from the first color at a second angle of incident light or viewing.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: June 3, 2003
    Assignee: Flex Products, Inc.
    Inventors: Paul G. Coombs, Jaroslaw Zieba, Richard A. Bradley, Jr., Christopher W. Lantman, Thomas Mayer, Roger W. Phillips, Stacey A. Yamanaka