Zinc Oxide Containing Patents (Class 106/425)
  • Patent number: 5344488
    Abstract: The application relates to pigments based on plate-like substrates which, if desired, are covered with one or more layers comprising metal oxides or metal oxide mixtures, zinc oxide being deposited on the surface of the substrates with the formation of a not entirely continuous layer.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: September 6, 1994
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Peter Reynders, Hans D. Bruckner
  • Patent number: 5340395
    Abstract: The technical field of the invention is concerned with smoke-generating devices and with powdered materials scattered by dispersion means in order to produce a camouflaging cloud which is effective in the infrared region. The material in accordance with the invention essentially consists of at least one powder having grains provided with a coating which is chemically inert with respect to the grain, which affords resistance to temperatures lower than or equal to the dispersion temperature, and which does not oxidize in free air.
    Type: Grant
    Filed: July 1, 1992
    Date of Patent: August 23, 1994
    Assignee: Giat Industries
    Inventors: Daniel Larmignat, Phillippe C. Morand, Christian H. Prieur, Gilles F. Lacreuse
  • Patent number: 5322563
    Abstract: A method for coloring building materials is disclosed, wherein a pigment suspension is added to the building materials. The pigment suspension based on pigment granules contains at least one pigment such as iron oxide, and a soluble phosphate salt. The soluble phosphate salt has a number ratio of monofunctional metal ions to phosphorus of 2:1 to 1:1, and is exemplified by sodium pyrophosphate, sodium polyphosphate, and sodium hexametaphosphate.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: June 21, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Heinz van Bonn, Bernd Krockert, Gunter Linde
  • Patent number: 5318837
    Abstract: Soundproofing materials consisting essentially of zinc oxide whisker particles having a nucleus body and needle crystal portions extending radially from the central body in different plural directions. The materials may comprise a support material for supporting the zinc oxide whisker particles. Such support materials include inorganic materials such as metals, ceramics, glasses, cements, mortars and various fillers in the form of powder, flakes, fibers and the like, and organic materials such as resins, rubbers, waxes and the like. These materials are particularly suitable for sound insulation, sound proofing, vibration damping and vibration insulation.
    Type: Grant
    Filed: December 17, 1991
    Date of Patent: June 7, 1994
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Minoru Yoshinaka, Eizo Asakura, Mitsumasa Oku, Takeshi Hamabe, Motoi Kitano
  • Patent number: 5312614
    Abstract: A method is provided for the high yield production of white, electrically conductive zinc oxide which comprises the simultaneous addition to a reactor of (1) an aqueous solution containing a water-soluble zinc compound and at least one water-soluble compound of a metal selected from the group consisting of tin, aluminum, gallium and indium, and (2) an aqueous alkaline solution, while maintaining the resulting neutralization reaction solution at a pH from 6 to 12.5 to obtain coprecipitates, and then calcining the coprecipitates in a reducing atmosphere to obtain said conductive zinc oxide.
    Type: Grant
    Filed: June 14, 1990
    Date of Patent: May 17, 1994
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Takao Hayashi, Norihiro Sato, Chikara Omotani, Manabu Hosoi, Nobuyoshi Kasahara, Gunther Rudolph, Wolf-Dieter Griebler, Jorg Hocken
  • Patent number: 5298065
    Abstract: Disclosed herein are an ultraviolet-screening scale pigment comprising scale-like inorganic particles and a zinc oxide coating layer of 50 to 250 wt% (calculated as ZnO) based on the scale-like inorganic particles, a water content of said zinc oxide coating layer being not more than 7 wt%; a process for producing the scale pigment; and cosmetics containing the scale pigment.
    Type: Grant
    Filed: January 4, 1993
    Date of Patent: March 29, 1994
    Assignee: Tayca Corporation
    Inventors: Nobumoto Hiraoka, Norihiro Tanimoto, Mayumi Mandai
  • Patent number: 5296285
    Abstract: An aluminum or aluminum alloy substrate having a low absorptance high emittance two-layer coating produced by first anodizing the substrate to form an anodic coating, followed by applying a topcoat of an inorganic white paint on the anodic coating, such dual layer coated substrate having spacecraft application, particularly for radiators.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: March 22, 1994
    Assignee: McDonnell Douglas Corporation
    Inventors: Henry W. Babel, Huong G. Le
  • Patent number: 5254162
    Abstract: Brown spinel pigments based on zinc chromite which are iron-free and exhibit an atomic ratio of chromium to zinc in a range of 1 to greater than 0.5 up to 2 are disclosed. Preferred pigments additionally contain manganese, in which instance the atomic ratio of Mn to Cr is a maximum of 0.2. The production of the pigments involves a firing process of a powder mixture consisting of the oxides the metals, or precursors thereof, contained in the pigment. Instead of previously known grayish-brown unattractive products, attractive brown pigments are obtained by means of the selected molar ratio and a baking temperature above 1200.degree. C. The novel pigments can be used in the presence of glass frits even at firing temperatures above 1200.degree. C. to 1500.degree. C. and are suitable for a common firing of ceramic carrier and decoration.
    Type: Grant
    Filed: September 18, 1992
    Date of Patent: October 19, 1993
    Assignee: Degussa Aktiengesellschaft
    Inventors: Dietrich Speer, Akos Kiss, Jenny Horst
  • Patent number: 5198026
    Abstract: Zinc powder, which contains a coloring element, e.g., Ti, Mn, or V, is heated to a temperature of from 350.degree. to 700.degree. C. so as to oxidize the surface of the powder and hence to develop such colors as brown, navy blue, blue, greenish-brown, green, and coffee brown. The colored zinc powder is sprayed onto a steel, aluminum, or ceramic article to produce a colored article. The colored zinc powder is also used as a pigment.
    Type: Grant
    Filed: September 25, 1991
    Date of Patent: March 30, 1993
    Assignee: Nippon Mining Co., Ltd.
    Inventors: Eiji Nishimura, Chikara Tominaga, Yusaku Masuda, Hiroshi Tasaki
  • Patent number: 5198025
    Abstract: Metal oxide-doped zinc oxide pigments are produced by processing an oxide, carbonate, hydroxide of hydroxycarbonate of zinc in the presence of water and an oxide, carbonate, hydroxide, hydroxy-carbonate, oxalate or formate of the doping metal into a paste using formic acid or oxalic acid in an amount which is at least sufficient for converting the oxides, carbonates, hydroxides or hydroxycarbonates mentioned into formates or oxalates, drying, grinding and calcining at from 700.degree. to 1100.degree. C. in an inert gas atmosphere.
    Type: Grant
    Filed: September 19, 1991
    Date of Patent: March 30, 1993
    Assignee: BASF Aktiengesellschaft
    Inventor: Wilma M. Dausch
  • Patent number: 5190586
    Abstract: Disclosed are pigment composite particles which are superior in water resistance, weather resistance, thermal stability and hardness. The pigment composite particles are prepared by suspension-polymerizing an aqueous suspension comprising(a) a pigment paste comprising pigment and a pigment grinding resin having a hydrophilic group of at least 0.2 mmol/g,(b) a polymerizable monomer and(c) a polymerization initiator.
    Type: Grant
    Filed: November 28, 1990
    Date of Patent: March 2, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Katsumi Mizuguchi, Masanori Ohiwa, Keizou Ishii, Shinichi Ishikura
  • Patent number: 5186748
    Abstract: An improved process for the preparation of bismuth vanadate pigments and solid solutions based on bismuth vanadate by a) mixing a solution of a bismuth (III) salt containing, if required, one or more further metal salts or a mixture thereof with the aqueous solution of a vanadate salt containing, if required, a molybdate, tungstate or sulfate salt or a mixture thereof and b) subjecting the suspension thus obtained to a subsequent aftertreatment to convert the particles first precipitated in amorphous form into crystalline compounds, wherein during the mixing and/or during the subsequent aftertreatment step fluoride ions are used.
    Type: Grant
    Filed: February 27, 1992
    Date of Patent: February 16, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Leonardus J. H. Erkens, Gregor Schmitt, Herman J. J. M Geurts, Werner F. C. G. Corvers
  • Patent number: 5174817
    Abstract: A process for calcining a filter cake in a directly heated rotary kiln wherein part of the filter cake is separated from the entire mass of filter cake, the separated portion is predried and recombined with the remainder portion and the combined predried and remainder portion is calcined. The filter cake can be inorganic solids such as oxides of titanium, chromium (III), zinc and iron.
    Type: Grant
    Filed: June 18, 1990
    Date of Patent: December 29, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Bernd-Michael Holle, Peter Beumer, Rolf M. Braun, Hilmar Rieck, Jurgen Kischkewitz, Gerhard Wiederhoft
  • Patent number: 5171364
    Abstract: A process for preparing a conductive, acicular zinc oxide, comprising the steps of: preparing a zinc oxide slurry comprising an acicular zinc oxide, a salt of at least one metal selected from the group consisting of aluminum, gallium, indium and tin and an aqueous solution of an alkali metal hydroxide and having a pH value maintained at 10 to 13, adjusting the pH value of said zinc oxide slurry to 5 to 9 while stirring, aging the slurry, separating the zinc oxide present in the slurry by filtration, washing and drying the separated zinc oxide, and then firing the dried zinc oxide at 500.degree. to 700.degree. C. in a reducing atmosphere.
    Type: Grant
    Filed: November 13, 1991
    Date of Patent: December 15, 1992
    Assignees: Mitsui Mining & Smelting Co. Ltd., Metallgesellschaft Aktiengesellschaft
    Inventors: Norihiro Sato, Takao Hayashi, Nobuyoshi Kasahara, Wolf-Dieter Griebler, Jorg Hocken, Gunther Rudolph
  • Patent number: 5156678
    Abstract: Effect pigments based on interference pigments coated with phthalocyanine or metal phthalocyanine dyes, characterized in that the dyes are applied to the pigments as a strongly adhering film without the aid of binders or other auxiliary materials, are outstandingly suitable for use in formulations such as paints, dyes, plastics and cosmetics.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: October 20, 1992
    Assignee: Merck Patent Gesellschaft mit beschraenkter Haftung
    Inventor: Ralf Glausch
  • Patent number: 5137567
    Abstract: The pigment is constituted by zinc phosphate dihydrate or tetrahydrate with an excess of from 0.5 to 6% of zinc oxide over the stoichiometric amount and has the form of rough surfaced spheroids having a maximum dimension lying between 0.5 and 6 microns and a mean size lying between 1.5 and 2.5 microns.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: August 11, 1992
    Assignee: Colores Hispania S.A.
    Inventors: Juan Aubareda Vallvey, Oscar Leblanc Francia, Martorell Sole
  • Patent number: 5132104
    Abstract: A needle-like monoammine complex of zinc carbonate containing or not containing aluminum useful as a filler or a precursor of needle-like electroconductive zinc oxide, and a process for producing it which comprises steps of dissolving a zinc compound in a solution containing ammonium ion and carbonate ion in the presence or absence of aluminum compound and then lowering pH of the solution to precipitate zinc carbonate.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: July 21, 1992
    Assignee: Lion Corporation
    Inventors: Nobuyuki Yamamoto, Masahiro Nemoto, Fumitomo Noritake, Junko Tomita, Noriyuki Ban
  • Patent number: 5102650
    Abstract: Needle-like electrically conductive zinc oxide filler having low specific volume resistance and excellent electrical conductivity-imparting effect per unit weight thereof is provided, including a method for its preparation.
    Type: Grant
    Filed: June 26, 1990
    Date of Patent: April 7, 1992
    Assignees: Metallgesellschaft Aktiengesellschaft, Mitsui Mining & Smelting Co., Ltd.
    Inventors: Takao Hayashi, Norihiro Sato, Chikara Omotani, Manabu Hosoi, Nobuyoshi Kasahara, Gunther Rudolph, Wolf-Dieter Griebler, Jorg Hocken
  • Patent number: 5094693
    Abstract: There is disclosed a doped zinc oxide pigment composition and method of preparing said composition, wherein the dopant is uniformly dispersed in the zinc oxide matrix in the form of a solid solution such that the mechanism by which undoped zinc oxide absorbs blue or near ultraviolet light is suppressed, thereby yielding a whiter composition. Preferred dopants are Al and Li.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: March 10, 1992
    Assignee: International Lead Zinc Research Organization, Inc.
    Inventors: James F. Cordaro, Howard C. Rafla-Yuan
  • Patent number: 5006174
    Abstract: A smoke suppressant additive for halogenated polymer compositions which consists of a mixture of from 30 to 70% by weight of zinc oxide and from 70 to 30% by weight of caustic calcined magnesium oxide with the addition thereto of up to 20% by weight of finely divided silica based upon the total weight of the zinc oxide and magnesium oxide, the mixture having being subjected to calcination at a temperature in the range of from 700.degree. to 1100.degree. C. for a period of time of from 1 to 6 hours.The additive is incorporated into halogenated polymers in an amount of from 0.5 to 10% by weight, preferably about 2.5% by weight.
    Type: Grant
    Filed: July 10, 1989
    Date of Patent: April 9, 1991
    Assignee: Cookson Group PLC
    Inventors: Ernest W. J. Michell, Shona M. Page
  • Patent number: 4966630
    Abstract: An anticorrosive pigment composition comprising (A) a slightly water-soluble condensed phosphoric acid salt and (B) at least one compound selected from the group consisting of zinc compounds, boric acid compounds and lead compounds, at least one of (A) and (B) having been chemically modified.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: October 30, 1990
    Assignee: Tayca Corporation
    Inventor: Masaaki Okuda
  • Patent number: 4956019
    Abstract: Flaky colored pigment comprising fine flaky powder as base material, and zinc oxide and an inorganic color pigment attached to the surface thereof.
    Type: Grant
    Filed: August 13, 1987
    Date of Patent: September 11, 1990
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Tamio Noguchi, Takaji Watanabe
  • Patent number: 4952617
    Abstract: A pigment dispersion of enhanced viscosity and heat stability characteristics for use in coating systems is provided. The pigment dispersions generally comprise a pigment carrier, a pigment of the type having a hydrophilic surface, and a surfactant functional as a dispersant in a relatively non polar matrix and which is present on the surface of the pigment in an effective amount. Pigment carriers include water-based carriers and organic solvent-based carriers. Finished coatings having improved viscosity and heat stability are also provided. The finished coatings comprise a coating base and the surfactant treated pigments. Such pigments include iron oxide pigments yellow iron oxide pigment, black iron oxide pigment, divalent ferrite pigments, zinc ferrite pigment, and magnesium ferrite pigment. Such surfactants include trimethylol propane, and trimethylol ethane.
    Type: Grant
    Filed: January 17, 1989
    Date of Patent: August 28, 1990
    Assignee: Columbian Chemicals Company
    Inventors: Jorge A. Ayala, George A. Joyce
  • Patent number: 4944802
    Abstract: Magnetic inks useful for the production of magnetic recording products are disclosed. The present magnetic inks contain ferromagnetic barium ferrite particles dispersed in a flexible polymer medium.
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: July 31, 1990
    Assignee: Omni Quest Corporation
    Inventors: Mark S. Chagnon, John R. Ferris
  • Patent number: 4921540
    Abstract: Corrosion inhibiting pigments on the basis of zinc silicate are produced from 35-65% by weight of ZnO, 15-35% by weight of SiO.sub.2, 5-20% by weight of B.sub.2 O.sub.3, and 1-20% by weight of WO.sub.3 which can be entirely or partly substituted by, MoO.sub.3 and/or SnO.sub.2 wherein the amount of zinc silicate, boron oxide and, if necessary, the other metal oxides or their hydrates singly or in a combination thereof is such that the entire combination with the zinc silicate and the boron oxide contains at least one of the oxides WO.sub.3, MoO.sub.3 and/or SnO.sub.2 in amounts bringing the balance to 100%. The pigments can be manufactured by dry mixing of the components, melting for 1-3 hours at 1100.degree. C.-1400.degree. C. and subsequent grinding to desired fineness.
    Type: Grant
    Filed: March 13, 1987
    Date of Patent: May 1, 1990
    Assignee: Dr. Hans Heubach GmbH & Co. KG
    Inventors: Manfred Gawol, Gerhard Adrian
  • Patent number: 4892591
    Abstract: Disclosed is a filler for ink jet recording paper, said filler being composed of amorphous silica particles having a median diameter, measured by the coulter counter method, of 2 to 15 .mu.m, an oil absorption of at least 180 ml/100 g, a refractive index, measured by the solvent method, of at least 1.450, and a moisture absorption, measured when it is caused to absorb moisture for 200 hours at a relative humidity of 90% and a temperature of 25.degree. C., of at least 35%, and a coating of a compound of a metal of Group II of the periodic table on the surface of the silica particles in an amount of 0.5 to 20% by weight.
    Type: Grant
    Filed: June 3, 1988
    Date of Patent: January 9, 1990
    Assignee: Mizusawa Industrial Chemicals Ltd.
    Inventors: Masahide Ogawa, Teiji Sato, Masao Takahashi, Kazumitsu Enomoto
  • Patent number: 4867793
    Abstract: Platelet-shaped colored pigments in which a platelet-shaped substrate is provided with a compact coating containing iron(II) oxide, which coating has a high gloss and, depending on the layer thickness, shows the interference color of thin platelets, are described.
    Type: Grant
    Filed: May 22, 1987
    Date of Patent: September 19, 1989
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Klaus D. Franz, Kalus Ambrosius, August Kanpp, Hans D. Brucker
  • Patent number: 4840668
    Abstract: The invention relates to corrosion-inhibiting pigments containing metallic oxides, phosphates and/or molybdates, wherein the metals are zinc, aluminum, iron, barium, strontium, calcium, magnesium and titanium, singly or in combination, wherein the pigments also contain 0.03-2% by weight of soluble sodium dichromate or equivalent amounts of potassium dichromate, ammonium dichromate or equivalent amounts of respective chromates or chromic acid, singly or in their mixture. The invention also relates to a process for the manufacture of the pigments by thorough homogenization of the chromate components with the pigments, and to the use of the pigments in primers for ferrous and non-ferrous metallic substrates.
    Type: Grant
    Filed: September 30, 1987
    Date of Patent: June 20, 1989
    Assignee: Dr. Hans Heubach GmbH & Co. KG
    Inventors: Manfred Gawol, Gerhard Adrian