Iron, Tungsten, Molybdenum, Or Cerium Compound Containing (fe, W, Mo, Ce) Patents (Class 106/439)
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Patent number: 11891525Abstract: The invention provides a method for enhancing the durability of a titanium dioxide material, the method including mixing citric acid and an alumina source with an aqueous slurry of titanium dioxide particles and water to form a mixture, the mixture having an acidic pH; and raising the pH of the mixture to a pH of no more than about 7.5 to form alumina-coated titanium dioxide particles. The invention also provides a pigmented plastic article including alumina-coated titanium dioxide particles prepared according to the invention dispersed in a polymer material.Type: GrantFiled: October 15, 2020Date of Patent: February 6, 2024Assignee: Ineos Pigments USA Inc.Inventors: Modasser El-Shoubary, Lee Chris Mundle, Mark B. Watson
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Patent number: 9373863Abstract: A process for forming alkaline earth metal cerate nanoparticles comprises combining a stable cerium oxide aqueous colloidal dispersion with soluble alkaline earth metal salts while maintaining colloidal stability. The resulting alkaline earth metal salts may be calcined to form alkaline earth metal cerate particles having a perovskite structure.Type: GrantFiled: August 2, 2013Date of Patent: June 21, 2016Assignee: CERION LLCInventor: Lyn Marie Irving
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Patent number: 9045643Abstract: A bright pigment of the present invention includes a scaly inorganic base 10, a silver-containing coating 11 that covers the inorganic base 10 and contains silver or a silver alloy, and a yellowing-suppressing coating 2 that covers the inorganic base 10 from outside of the silver-containing coating 11 and contains a metal compound functioning as an oxidizing agent. The metal compound is preferably at least one selected from the group consisting of a hydroxide of metal, an oxide hydrate of metal, and a salt of an oxide hydrate of metal, and the metal is at least one selected from the group consisting of tungsten, molybdenum, bismuth, vanadium, or cerium.Type: GrantFiled: April 23, 2007Date of Patent: June 2, 2015Assignee: Nippon Sheet Glass Company LimitedInventors: Takeaki Kitamura, Yusuke Kimura
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Patent number: 8876964Abstract: The invention relates to a method of making a particulate material comprising; providing mineral wool base material in a form having size at least 80% not more than 40 mm, subjecting the mineral wool base material to sintering by use of a pulse combustor and thereby forming a particulate material in the form of particles having size at least 80% not more than 20 mm. An apparatus for carrying out the method comprises means for size reduction of coherent mineral wool substrate and a reaction chamber in communication with a pulse combustor.Type: GrantFiled: June 22, 2010Date of Patent: November 4, 2014Assignee: Rockwool International A/SInventors: Jean Marie Wilhelmus Cuypers, Andreas Leismann, Stuart Lambie
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Publication number: 20140261085Abstract: A compound or a pigment comprising a compound where there is simultaneous substitution of more or more elements onto both the A and B sites of a pyrochlore lattice or a lattice related to a pyrochlore. The pigment comprises a compound with the formula of AyA?y?BxB?x?Zp. Elements A and A? have a valence of 1, 2, or 3; and are selected from the elements of groups 1, 2, 12, 13, 14, 15, and the first row of transition metals, excluding H, Pb, Cd, Hg, N, As, and Tl. Elements B and B? have a valence of 3, 4, 5, or 6; and are selected from the elements of the first, second, or third row of transition metals, groups 13, 14, and 15, excluding V, C, Pb, and Tl. Element Z is selected from O, F, N, a chalcogen, S, Se, hydroxide ion, and mixtures thereof.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: The Shepherd Color CompanyInventors: Simon K. Boocock, Andrew E. Smith, Miroslav Trojan
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Publication number: 20140256866Abstract: This invention relates to megakalsilite platelets, methods of hydrothermally forming said platelets and the megakalsilite platelets obtainable via the disclosed hydrothermal method. More specifically the disclosure describes an improved hydrothermal synthesis of megakalsilite platelets, which are suitable as platelet for interference pigments, and in barrier and flame retardant applications.Type: ApplicationFiled: March 11, 2014Publication date: September 11, 2014Inventors: Meaghan Clark McGuire, Ivor Bull, Geoffrey Mark Johnson
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Publication number: 20140245927Abstract: A highly loaded concentrate pellet composition includes an active ingredient in a concentration of at least about 60% by weight, and a low molecular weight binder in a concentration of up to about 35% by weight. The active ingredient is evenly dispersed in the binder. The binder has a melting point that permits the composition to melt under shear in an extruder. The binder is non-metallocene and non-stearic.Type: ApplicationFiled: May 13, 2014Publication date: September 4, 2014Inventors: Glen Alan Hirschfeld, Craig A. Dunaway, Jeffrey R. Nonekowski
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Patent number: 8808447Abstract: The present invention relates to a pigment paint for an exterior material and to a method for manufacturing the same. The pigment paint comprises: a flake matrix, a first metal oxide layer coated on the upper portion of the transparent matrix, an oxide layer containing MgO—SiO2 coated on the upper portion of the first metal oxide layer, and a second metal oxide layer coated on the upper portion of the oxide layer. In order to ensure humidity resistance and weather resistance required for a lustrous pigment paint for exterior materials, a cerium layer and an aluminum oxide layer are further coated. Properties such as high luminance, high chromaticity, and high gloss, which could not be achieved using conventional techniques, can be achieved and a pigment paint having a multi-colored pearl luster can be provided.Type: GrantFiled: March 8, 2012Date of Patent: August 19, 2014Assignee: CQV Co., Ltd.Inventors: Jae-Il Jeong, Nam-Il Lee, Sang-Keun Park, Jin-Hyung Lee, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang
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Patent number: 8771717Abstract: The present invention relates to pigments, comprising a plate-like substrate of perlite which does not contain 3D twin structure particles contained in milled expanded perlite in an amount of greater than 5% by weight., and (a) a dielectric material, especially a metal oxide, having a high index of refraction; and/or (a) a metal layer, especially a thin semi-transparent metal layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.Type: GrantFiled: December 1, 2009Date of Patent: July 8, 2014Assignee: BASF SEInventors: Patrice Bujard, Marc Baysang, Philippe Bugnon
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Patent number: 8663820Abstract: The invention relates to a printed document of value having at least one authenticity feature in the form of a luminescent substance based on doped host lattices. The host lattice has a strong crystal field and is doped with at least one chromophore with the electron configuration (3d)2.Type: GrantFiled: March 5, 2002Date of Patent: March 4, 2014Assignee: Giesecke & Devrient GmbHInventors: Thomas Giering, Rainer Hoppe, Fritz Stahr
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Publication number: 20140010772Abstract: A silver-colored pigment is provided having a nonmetallic platelet-shaped substrate and at least one ilmenite-containing coating, wherein the nonmetallic platelet-shaped substrate is a nonmetallic platelet-shaped synthetic substrate and the amount of iron compounds, calculated as elemental iron, in the pigment is less than 5.0% by weight, based on the total weight of the pigment. Processes for preparing the pigment also are provided.Type: ApplicationFiled: March 23, 2012Publication date: January 9, 2014Applicant: ECKART GMBHInventors: Michael Gruner, Thomas Schneider, Gunter Kaupp, Christian Rummer, Dirk Schumacher
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Patent number: 8585818Abstract: The present disclosure relates to a method of making coated perlite flakes comprises: (i) providing perlite flakes; (ii) applying a layer of tin oxide on the perlite flakes to obtain tin oxide coated perlite flakes; (iii) applying a layer titanium dioxide on the tin oxide coated perlite flakes obtained in step (ii) to obtain titanium dioxide and tin oxide coated perlite flakes; and (iv) applying a layer of iron oxide to the titanium dioxide and tin oxide coated perlite flakes to obtain the coated perlite flakes. The present disclosure also relates to coated perlite flakes comprising: perlite flakes with layer of tin oxide, then a layer of titanium dioxide, and then a layer of iron oxide.Type: GrantFiled: March 14, 2013Date of Patent: November 19, 2013Assignee: BASF SEInventor: Steven Alan Jones
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Patent number: 8518174Abstract: Under the presence of at least one out of copper, manganese, nickel, cobalt, iron, zinc, and compounds thereof, a tetravalent titanium salt solution and a basic solution are reacted together to form a hydroxide of titanium and the above metal, and then the titanium hydroxide is peroxidated with an oxidizing agent to manufacture an aqueous liquid or dispersion having titania-metal composite having peroxy groups, and not having a photocatalytic activity fine particles dispersed therein, wherein the titania-metal composite includes particles of at least one of elemental copper, manganese, nickel, cobalt, iron, zinc and compounds thereof; using this to form a coating film, a drop in decorativeness of color due to fading or discoloration of a coating material, a printed article, a building material, a fiber, an organic polymer resin product or the like can be prevented, and moreover surface anti-soiling and hydrophilic properties can be realized.Type: GrantFiled: August 24, 2011Date of Patent: August 27, 2013Assignee: Sustainable Titania Technology IncorporatedInventors: Shiro Ogata, Yoshimitsu Matsui
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Patent number: 8500901Abstract: The present invention relates to interference pigments based on coated flake-form substrates which are distinguished by the fact in that they comprise (A) a layer of SiO2 having a layer thickness of 5-350 nm, (B) a high-refractive-index coating having a refractive index n of >1.8 and/or (C) an interference system consisting of alternating high- and low-refractive-index layers and optionally (D) an outer protective layer, and to the use thereof in paints, coatings, automotive paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tent awnings, as absorbers in the laser marking of paper and plastics, in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, and for the preparation of pigment preparations and dry preparations.Type: GrantFiled: March 22, 2010Date of Patent: August 6, 2013Assignee: Merck Patent GmbHInventors: Reinhold Rueger, Klaus Ambrosius, Marcus Mathias, Helge Bettina Kniess
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Patent number: 8404204Abstract: The present invention is directed to a granulate having photocatalytic activity, comprising particles of an inorganic particulate material coated with a photocatalytically active compound for introducing photocatalytic activity into or on building materials. The invention is further related to the manufacture of such a granulate and its use into or on building materials such as cement, concrete, gypsum and/or limestone and water-based coatings or paints for reducing an accumulation and growth of microorganisms and environmental polluting substances on these materials and thus reducing the tendency of fouling, while the brilliance of the color is maintained and the quality of the air is improved.Type: GrantFiled: March 31, 2008Date of Patent: March 26, 2013Assignee: Rockwood Italia SpAInventors: Marino Sergi, Christian Egger
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Patent number: 8377194Abstract: A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF.B. M comprises at least one metal or metalloid cation S is a sulfur-based species. F optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5. B is a hygroscopic solid at a water to solid molar ratio of 0.1-6 and preferably comprises at least one alkaline earth oxide or lanthanide oxide.Type: GrantFiled: September 23, 2011Date of Patent: February 19, 2013Assignee: Nalco CompanyInventors: Nicholas S. Ergang, Ian Saratovsky, Hung-Ting Chen
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Publication number: 20130008346Abstract: Complex inorganic titanate pigments with low dopant levels (i.e., less than about 5%) exhibit coloristic and enhanced infrared (IR) reflectance characteristics that make them useful in formulating colors exhibiting high IR reflectivity. This characteristic is becoming increasingly useful as a way to keep exterior surfaces and articles cooler during exposure to direct sunlight. Achieving this can decrease energy (e.g., cooling/air conditioning) consumption and costs. Low-loaded titanates can boost IR reflectivity by 1 to 10% in selected visual color spaces. Paint compositions containing those low loaded titanate pigments and a method for providing a surface with high infrared reflectance utilizing those pigments are also disclosed.Type: ApplicationFiled: July 3, 2012Publication date: January 10, 2013Applicant: The Shepherd Color CompanyInventors: James White, Doris Montgomery
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Patent number: 8349067Abstract: A pearlescent pigment, wherein the pigment is an inorganic material and the color of a homogeneous coating of the pigment, measured over a white background, is selected from the group consisting of: a CIELAB L* value of about 30 or less and a chroma value of about 3 or less; a CIELAB hue angle, hab, from about 50 to about 80 degrees, wherein L* is not more than about 85, and the chroma value is greater than 22; a CIELAB hue angle, hab, from about 80 to about 275 degrees, wherein L* is not more than about 80, and the chroma value is greater than about 10; and a CIELAB hue angle, hab, from not less than about 275 to not more than about 50 degrees, wherein L* is not more than about 85, and the chroma value is greater than about 9. The pigments may be used in a variety of applications including cosmetics, plastics, automotive, or architectural coatings.Type: GrantFiled: October 31, 2007Date of Patent: January 8, 2013Assignee: Sun Chemical Corp.Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
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Patent number: 8333835Abstract: A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF. M comprises at least one metal or metalloid cation S is a sulfur-based species optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5.Type: GrantFiled: September 23, 2011Date of Patent: December 18, 2012Assignee: Nalco CompanyInventors: Nicholas S. Ergang, Bruce A. Keiser, Richard Mimna
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Publication number: 20120301554Abstract: The present invention relates to effect pigments having a substrate which has a coating comprising a complex metal oxide containing copper, iron and manganese, and to a process for the preparation of the effect pigments, to the use of the effect pigments in paints, coatings, powder coatings, printing inks, plastics, ceramic materials, glasses, in cosmetic formulations, for laser marking and for the preparation of pigment preparations and dry preparations.Type: ApplicationFiled: December 17, 2010Publication date: November 29, 2012Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNGInventor: Helge Bettina Kniess
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Patent number: 8273171Abstract: A pearlescent pigment (100) includes: a flaky substrate (10); a titanium dioxide layer (20) that is formed on the flaky substrate (10); and an oxazoline compound layer (40) that is formed on the titanium dioxide layer (20) with the titanium dioxide layer (20) being interposed between the flaky substrate (10) and the oxazoline compound layer (40), and serves as a top surface of the pearlescent pigment (100).Type: GrantFiled: August 29, 2007Date of Patent: September 25, 2012Assignee: Nippon Sheet Glass Company, LimitedInventors: Takeaki Kitamura, Juichi Ino
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Publication number: 20120227628Abstract: Enriched titanium hydrochloric acid extract residue is provided, for use as the feed stock in the preparation of titanium pigment by sulfuric acid process. The present invention belongs to the field of the preparation of titanium pigment and particularly, relates to the enriched titanium hydrochloric acid extract residue prepared from ilmenite by hydrochloric acid leaching, its use and the method of preparing titanium pigment. The method for preparing titanium pigment using the enriched titanium hydrochloric acid extract residue can effectively utilize the fine ilmenite in Panxi area (the utilization rate is almost 100%), obtain the titanium sulfate solution with an ultralow ratio of iron to titanium dioxide (Fe/TiO2) and double the throughput of digesting equipment.Type: ApplicationFiled: September 2, 2010Publication date: September 13, 2012Inventors: Lilin Sha, Shuzhong Chen
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Publication number: 20120216717Abstract: This disclosure relates to inorganic particles, typically inorganic metal oxide or mixed metal oxide particles, and more typically titanium dioxide (TiO2) particles, comprising at least about 0.002% of tungsten, based on the total weight of the inorganic particles, wherein inorganic particles have a photostability ratio (PSR) of at least about 2, as measured by the Ag+ photoreduction rate, and color as depicted by an L* of at least about 97.0, and b* of less than about 4. These titanium dioxide particles comprising tungsten may further comprise alumina.Type: ApplicationFiled: November 9, 2010Publication date: August 30, 2012Applicant: E. I. DUPONT DE NEMOURS AND COMPANYInventors: John Davis Bolt, Eugene Michael McCarron, III, Charles David Musick
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Publication number: 20120186491Abstract: The invention relates to a method of making a particulate material comprising; providing mineral wool base material in a form having size at least 80% not more than 40 mm, subjecting the mineral wool base material to sintering by use of a pulse combustor and thereby forming a particulate material in the form of particles having size at least 80% not more than 20 mm. An apparatus for carrying out the method comprises means for size reduction of coherent mineral wool substrate and a reaction chamber in communication with a pulse combustor.Type: ApplicationFiled: June 22, 2010Publication date: July 26, 2012Inventors: Jean Marie Wilhelmus Cuypers, Andreas Leismann, Stuart Lambie
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Patent number: 8221536Abstract: A cosmetic containing a pearlescent pigment comprising a substrate and a first layer, wherein the first layer comprises iron oxide, wherein the iron has from about 1% to about 30% Fe(II) and from about 70% to about 99% Fe(III).Type: GrantFiled: October 31, 2007Date of Patent: July 17, 2012Assignee: Sun Chemical Corp.Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
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Patent number: 8221834Abstract: A titania composite and a preparing method thereof are provided. The titania composite comprises an inner core and a coating film layer, wherein the inner core is a barium sulfate crystal and/or a strontitum sulfate crystal with subsphaeroidal shape, having a particle size of less than 1 ?m and whiteness of more than 98%, and the coating film layer is nano rutile titania. The preparing method thereof comprises the following steps: (a) preparing barium sulfate or strontium sulfate; (b) coating treatment; (c) subjecting the titania composite to a high-temperature heat treatment; and (d) subjecting the titania composite to a post treatment. The subsphaeroidal titania composite is obtained by chemically synthesizing a subsphaeroidal submicron barium sulfide or strontium sulfide, and then hydrolyzing and coating thereon to form a coating film layer of titania to make titania grow evenly.Type: GrantFiled: December 30, 2009Date of Patent: July 17, 2012Assignee: Chongqing Kechang Technology Co., Ltd.Inventors: Dong Hua, Zhengtao Liu
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Patent number: 8211225Abstract: A pearlescent pigment and a process for enhancing the magnetic properties of a pearlescent pigment. The pearlescent pigment has a layer with regions of ?-Fe2O3 and regions of ?-Fe2O3. The magnetic properties of a pearlescent pigment may be enhanced by the steps of: providing a platelet pigment with a layer of Fe2O3, with a magnetic susceptibility less than 0.1×10?5 m3/kg; reducing some or all of the Fe2O3 to Fe3O4; and oxidizing some or all of the Fe3O4 to ?-Fe2O3. The color difference (?E*) between the provided pigment and the resultant pigment is not more than about 5.Type: GrantFiled: April 9, 2008Date of Patent: July 3, 2012Assignee: Sun Chemical Corp.Inventors: Aaron M. Hollman, Philippe Schottland
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Patent number: 8197591Abstract: The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.Type: GrantFiled: February 23, 2007Date of Patent: June 12, 2012Assignee: Eckart GmbHInventors: Günter Kaupp, Ulrich Schmidt
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Patent number: 8158270Abstract: Under the presence of at least one out of copper, manganese, nickel, cobalt, iron, zinc, and compounds thereof, a tetravalent titanium salt solution and a basic solution are reacted together to form a hydroxide of titanium and the above metal, and then the titanium hydroxide is peroxidated with an oxidizing agent to manufacture an aqueous liquid or dispersion having therein titanium oxide fine particles having peroxy groups; by using this alone to form a coating film adjacent to a coating film of an organic dye or pigment, or using this to form a coating film together with an organic dye or pigment, a drop in decorativeness of color due to fading or discoloration of a coating material, a printed article, a building material, a fiber, an organic polymer resin product or the like can be prevented, and moreover surface anti-soiling and hydrophilic properties can be realized.Type: GrantFiled: August 24, 2011Date of Patent: April 17, 2012Assignee: Sustainable Titania Technology IncorporatedInventors: Shiro Ogata, Yoshimitsu Matsui
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Patent number: 8153163Abstract: The present invention relates to a pearl pigment obtained by coating the surface of a flaky powder with a colored metal or a colored metal oxide and further coating the surface of the above colored metal- or colored metal oxide-coated flaky powder with a colorless metal or a colorless metal oxide, wherein when the pearl pigment is applied onto the surface of black artificial leather in an average amount of 0.05 mg/cm2 and the intensity of light reflected from the pearl pigment is measured using illuminant C at a 2° viewing angle with a spectrophotometric colorimeter which is provided with a sheet polarizer S on the light incident side and a sheet polarizer P on the light receiving side, the powder reflection light which is incident to the pearl pigment as a measurement sample at an angle of 45° to the direction normal to the surface of the sample and is received in the direction normal to the surface of the sample has absolute values a* and b* of 10 or less, and make-up cosmetics containing the pearl pigment.Type: GrantFiled: June 28, 2011Date of Patent: April 10, 2012Assignees: Kao Corporation, Nihon Koken Kogyo KKInventors: Eiichiro Misaki, Hiroyuki Shiomi, Maoya Adachi, Takahiro Kaida
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Patent number: 8114211Abstract: The present invention relates to pearlescent pigments based on flake-form substrates which have at least one FeOOH layer and at least one TiO2 layer or at least one TiO2/SiO2/TiO2 layer package, and to the use thereof, inter alia, in paints, coatings, printing inks, powder coatings, plastics and in particular in care and decorative cosmetics.Type: GrantFiled: December 12, 2007Date of Patent: February 14, 2012Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Carsten Handrosch, Marcus Mathias, Nicole Schupp, Meike Willius
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Publication number: 20120034178Abstract: The present invention relates to novel pigment mixtures comprising at least two different particulate components A and B. The first component A comprises titanium suboxide(s), a titanium oxynitride or a titanium nitride species. Component B particle comprises inorganic, or organic pigments. The titanium suboxide particles display a bluish metallic luster, are new and form a further aspect of the present invention. When combined with particles from component B such as variously coated micas, for example, the bluish or bluish/black metallic color effect from component A leads to special color effects in the various mixtures.Type: ApplicationFiled: October 21, 2011Publication date: February 9, 2012Inventors: Patrice Bujard, Philippe Bugnon, Marc Mamak, Urs Leo Stadler
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Publication number: 20110319498Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack. The present effect pigments may be used in cosmetic and industrial applications.Type: ApplicationFiled: July 26, 2011Publication date: December 29, 2011Inventors: Daniel S. Fuller, Curtis J. Zimmermann
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Publication number: 20110269845Abstract: The present invention relates to pigments, comprising a plate-like substrate of perlite which does not contain 3D twin structure particles contained in milled expanded perlite in an amount of greater than 5% by weight, and (a) a dielectric material, especially a metal oxide, having a high index of refraction; and/or (a) a metal layer, especially a thin semi-transparent metal layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.Type: ApplicationFiled: December 1, 2009Publication date: November 3, 2011Applicant: BASF SEInventors: Patrice Bujard, Marc Baysang, Philippe Bugnon
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Patent number: 8029615Abstract: A pearlescent pigment includes a ceramic flake coated with a metal oxide. The metal oxide is, preferably, an oxide of titanium, iron, tin, chromium1, zirconium or a combination thereof, and the refractive index of the metal oxide coating is preferably at least 0.5 higher than that of the ceramic flake. The pearlescent pigment may be included in a coating applied to a metallic or plastic surface to give the surface a lustrous or pearlescent optical effect.Type: GrantFiled: October 30, 2007Date of Patent: October 4, 2011Inventor: Charles Watkinson
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Patent number: 8025976Abstract: Under the presence of at least one out of copper, manganese, nickel, cobalt, iron, zinc, and compounds thereof, a tetravalent titanium salt solution and a basic solution are reacted together to form a hydroxide of titanium and the above metal, and then the titanium hydroxide is peroxidated with an oxidizing agent to manufacture an aqueous liquid or dispersion having therein titanium oxide fine particles having peroxy groups; by using this alone to form a coating film adjacent to a coating film of an organic dye or pigment, or using this to form a coating film together with an organic dye or pigment, a drop in decorativeness of color due to fading or discoloration of a coating material, a printed article, a building material, a fiber, an organic polymer resin product or the like can be prevented, and moreover surface anti-soiling and hydrophilic properties can be realized.Type: GrantFiled: November 4, 2003Date of Patent: September 27, 2011Assignee: Sustainable Titania Technology IncorporatedInventors: Shiro Ogata, Yoshimitsu Matsui
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Patent number: 8016934Abstract: The present invention relates to a pearl pigment obtained by coating the surface of a flaky powder with a colored metal or a colored metal oxide and further coating the surface of the above colored metal- or colored metal oxide-coated flaky powder with a colorless metal or a colorless metal oxide, wherein when the pearl pigment is applied onto the surface of black artificial leather in an average amount of 0.05 mg/cm2 and the intensity of light reflected from the pearl pigment is measured using illuminant C at a 2° viewing angle with a spectrophotometric colorimeter which is provided with a sheet polarizer S on the light incident side and a sheet polarizer P on the light receiving side, the powder reflection light which is incident to the pearl pigment as a measurement sample at an angle of 45° to the direction normal to the surface of the sample and is received in the direction normal to the surface of the sample has absolute values a* and b* of 10 or less, and make-up cosmetics containing the pearl pigment.Type: GrantFiled: December 15, 2005Date of Patent: September 13, 2011Assignees: Kao Corporation, Nihon Koken Kogyo KKInventors: Eiichiro Misaki, Hiroyuki Shiomi, Maoya Adachi, Takahiro Kaida
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Publication number: 20110212832Abstract: In one embodiment, an aqueous dispersion liquid contains at least one particles selected from tungsten oxide particles and tungsten oxide composite particles. A mean primary particle diameter (D50) of the particles is in the range of 1 nm to 400 nm. In the aqueous dispersion liquid, concentration of the particles is in the range of 0.1 mass % to 40 mass %, and pH is in the range of 1.5 to 6.5. The aqueous dispersion liquid excels in dispersibility of particles and capable of maintaining good liquidity for a long period.Type: ApplicationFiled: September 2, 2010Publication date: September 1, 2011Inventors: Kayo Nakano, Akira Sato, Yasuhiro Shirakawa, Keiichi Fuse, Shinya Kasamatsu, Akito Sasaki
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Patent number: 7968503Abstract: Nanoparticles comprising molybdenum, methods of manufacturing nanoparticles comprising molybdenum, and nanotechnology applications of nanoparticles comprising molybdenum, such as electronics, optical devices, photonics, reagents for fine chemical synthesis, pigments and catalysts, are provided.Type: GrantFiled: June 7, 2005Date of Patent: June 28, 2011Assignee: PPG Industries Ohio, Inc.Inventor: Tapesh Yadav
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Patent number: 7951420Abstract: A method of preparing a pigment exhibiting a color-shifting effect, including at least heating mica powder suspension in water, adjusting the pH value of the mixture to between 2 and 9, adding a first inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 6 and 14, adding a second inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 2 and 9, adding a third inorganic salt solution, maintaining the pH value of the mixture constant, and stirring the mixture at constant temperature.Type: GrantFiled: September 26, 2009Date of Patent: May 31, 2011Inventors: Jiansheng Fu, Yiting Peng, Xiaohui Tian
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Publication number: 20100322981Abstract: The present invention relates to (interference) pigments comprising a plate-like substrate, a layer of SnO2, and/or a layer of a metaloxide, which is selected from Fe2O3, TiO2, ZrO2 and/or HfO2, said layer(s) being doped with Mo and/or W, or pigments comprising a plate-like substrate, a layer of a metal oxide, which is selected from Fe2O3, TiO2, ZrO2 and/or HfO2, said layer(s) being doped with Nb and/or Ta, a method of producing the (interference) pigments and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings, printing inks, plastics, cosmetics, glazes for ceramics and glass. The pigments of the present invention have very bright color and show color flop.Type: ApplicationFiled: November 7, 2008Publication date: December 23, 2010Applicant: BASF SEInventors: Patrice Bujard, Marc Baysang, Philippe Bugnon
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Patent number: 7837785Abstract: The present invention relates to pigment granules and to a process for the preparation thereof and their use.Type: GrantFiled: April 23, 2007Date of Patent: November 23, 2010Assignee: LANXESS Deutschland GmbHInventors: Holger Friedrich, Kai Bütje, Udo Holtmann
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Publication number: 20100282128Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.Type: ApplicationFiled: July 26, 2010Publication date: November 11, 2010Applicant: Kronos International Inc.Inventors: Siegfried Blümel, Lydia Drews-Nicolai
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Publication number: 20100255047Abstract: The present invention relates to effect pigments based on thin glass flakes and to a method for the production of such pigments. The resulting pigment can be used in any application for which pearlescent pigments have been heretofore used such as, for example, in plastics, paints, inks, cosmetic formulations, coatings including solvent or waterborne automotive paint systems, powder coatings, inks and agriculture foils.Type: ApplicationFiled: June 16, 2010Publication date: October 7, 2010Inventors: Ralf ANSELMANN, Klaus Ambrosius, Marcus Mathias
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Publication number: 20100189666Abstract: The present invention provides products comprising rutile-type titanium dioxide of a specific shape, i.e., cosmetics which have high UV blocking ability, provide a good feel upon use without leaving squeakiness or graininess on the skin, and also give a natural bare skin appearance without causing white masking, due to adequate tinting strength and covering power, as well as external additives for toner which are excellent in prevention of filming on a photosensitive member and inhibition of aggregation between toner particles.Type: ApplicationFiled: January 26, 2010Publication date: July 29, 2010Applicant: TITAN KOGYO KABUSHIKI KAISHAInventors: Akira NAKAMURA, Masayasu MORISHITA, Hiromasa KONDOH
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Publication number: 20100154680Abstract: The present invention relates to pigment granules which contain inorganic filter aids and a process for the production thereof and their use for colouring lime- and/or cement-bound building materials, asphalt, paints, finishes, paper or plastics.Type: ApplicationFiled: August 20, 2009Publication date: June 24, 2010Applicant: LANXESS DEUTSCHLAND GMBHInventors: Holger Friedrich, Herbert Kunstmann, Krzysztof Chlopek, Jüergen Kischkewitz
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Publication number: 20100064941Abstract: A pearlescent pigment includes a ceramic flake coated with a metal oxide. The metal oxide is, preferably, an oxide of titanium, iron, tin, chromium1, zirconium or a combination thereof, and the refractive index of the metal oxide coating is preferably at least 0.5 higher than that of the ceramic flake. The pearlescent pigment may be included in a coating applied to a metallic or plastic surface to give the surface a lustrous or pearlescent optical effect.Type: ApplicationFiled: October 30, 2007Publication date: March 18, 2010Inventor: Charles Watkinson
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Publication number: 20100021565Abstract: The present invention relates to pearlescent pigments based on flake-form substrates which have at least one FeOOH layer and at least one TiO2 layer or at least one TiO2/SiO2/TiO2 layer package, and to the use thereof, inter alia, in paints, coatings, printing inks, powder coatings, plastics and in particular in care and decorative cosmetics.Type: ApplicationFiled: December 12, 2007Publication date: January 28, 2010Applicant: MERCK PATENT GMBHInventors: Carsten Handrosch, Marcus Mathias, Nicole Schupp, Meike Willius
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Publication number: 20100015436Abstract: To provide composite particles of which discoloration, decomposition and photocatalytic reaction of titanium oxide by ultraviolet rays are suppressed and which are excellent in resistance against hydrogen fluoride; a printing ink containing the composite particles; a resin film with a coating layer having a coating layer made of the printing ink, of which discoloration, a change in the visible light transmittance and a decrease in the mechanical strength are suppressed for a long period of time; and a coating composition containing the composite particles.Type: ApplicationFiled: June 22, 2009Publication date: January 21, 2010Applicant: ASAHI GLASS COMPANY LIMITEDInventor: Hiroshi Aruga
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Patent number: RE41858Abstract: A pearlescent pigment based on a metal oxide-coated, platelet-shaped substrate and a top layer on the metal oxide layer, where the top layer comprises silicon dioxide, at least one further metal hydroxide or metal oxide hydrate and at least one organic coupling reagent. The further metal hydroxides or metal oxide hydrates are hydroxides or oxide hydrates of cerium, aluminum or zirconium, or mixtures thereof. The coupling reagents employed are organofunctional silanes, zirconium aluminates or metal acid esters.Type: GrantFiled: October 7, 2009Date of Patent: October 26, 2010Assignee: Merck Patent Gesellschaft MIT Beschrankter HaftungInventors: Joachim Duschek, Ralf Glausch