Iron, Tungsten, Molybdenum, Or Cerium Compound Containing (fe, W, Mo, Ce) Patents (Class 106/439)
  • Publication number: 20100011992
    Abstract: The present invention relates to novel pigment mixtures comprising at least two different particulate components A and B. The first component A comprises titanium suboxide(s), a titanium oxynitride or a titanium nitride species. Component B particle comprises inorganic, or organic pigments. The titanium suboxide particles display a bluish metallic luster, are new and form a further aspect of the present invention. When combined with particles from component B such as variously coated micas, for example, the bluish or bluish/black metallic color effect from component A leads to special color effects in the various mixtures.
    Type: Application
    Filed: December 17, 2007
    Publication date: January 21, 2010
    Inventors: Patrice Bujard, Philippe Bugnon, Marc Mamak, Urs Leo Stadler
  • Patent number: 7611574
    Abstract: The invention relates to an interference pigment with a high covering power, comprising at least one FeTiO3-containing layer, which is applied to a lamellar inorganic substrate and whose thickness and absorbing power can be precisely set. The invention also relates to a method for producing this interference pigment and to the use thereof.
    Type: Grant
    Filed: May 5, 2004
    Date of Patent: November 3, 2009
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Helge Kniess, Gerhard Pfaff, Klaus Bernhardt
  • Publication number: 20090266269
    Abstract: A household wall non-toxic paint additive comprised of mixture of solvent-soluble compounds, which fine granulated from available mineral composition, with dipole properties, in which aromatic oils can be added to the paint additive is enclosed in this current application. This nontoxic paint additive makes for a type of special painting material, in the current application, is non-harmful for man.
    Type: Application
    Filed: April 23, 2008
    Publication date: October 29, 2009
    Inventors: Kwang Kook Lee, Shin Jong Chang
  • Publication number: 20090260541
    Abstract: An ultra-fine powder formed from a naturally occurring mineral or rock material and having a controlled or “engineered” particle size distribution (PSD) to match the infrared spectra with a maximum particle size in the range of 14-17 microns measured as either D99, or preferably D95, and a minimum particle size D5 in the range of 4-7 microns. Preferably the maximum particle size is about 15 microns, the minimum particle size is about 5 microns and the D50 particle size is about 8-10 microns with the moisture content of the particle size “engineered” powder being less than about 0.20 percent by weight and preferably about 0.05 to 0.08 percent by weight of the powder. This specially “engineered” ultra-fine powder is used to reduce the thermicity of thermal film to a value less than about 20%.
    Type: Application
    Filed: September 25, 2008
    Publication date: October 22, 2009
    Inventors: David D. Kragten, Christy Karr, JR., Scott VanRemortel, Robert Ratcliff, Ibezim Anazia, Louis M. Schlesinger
  • Publication number: 20090255442
    Abstract: A pearlescent pigment and a process for enhancing the magnetic properties of a pearlescent pigment. The pearlescent pigment has a layer with regions of ?-Fe2O3 and regions of ?-Fe2O3. The magnetic properties of a pearlescent pigment may be enhanced by the steps of: providing a platelet pigment with a layer of Fe2O3, with a magnetic susceptibility less than 0.1×10?5 m3/kg; reducing some or all of the Fe2O3 to Fe3O4; and oxidizing some or all of the Fe3O4 to ?-Fe2O3. The color difference (?E*) between the provided pigment and the resultant pigment is not more than about 5.
    Type: Application
    Filed: April 9, 2008
    Publication date: October 15, 2009
    Inventors: Aaron M. Hollman, Philippe Schottland
  • Publication number: 20090249979
    Abstract: The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.
    Type: Application
    Filed: February 23, 2007
    Publication date: October 8, 2009
    Inventors: Günter Kaupp, Ulrich Schmidt
  • Publication number: 20090246294
    Abstract: The invention relates to pigment mixtures comprising at least two components A and B. The inventive pigment mixtures are characterized in that component A is embodied as effect pigments while component B is embodied as coloring agents and fillers. Also disclosed is the use of said pigment mixtures in cosmetic formulations and for coloring food products and pharmaceutical products.
    Type: Application
    Filed: May 9, 2007
    Publication date: October 1, 2009
    Inventors: Veronika Hochstein, Christoph Schmidt, Sabine Schoen
  • Publication number: 20090185992
    Abstract: A pearlescent pigment, wherein the pigment is an inorganic material and the color of a homogeneous coating of the pigment, measured over a black background has a CIELAB hue angle, hab, from about 40 to about 320 degrees, wherein L* is from about 35 to about 80, and the chroma value is less than 5. A substrate is coated with iron oxide by oxidizing an iron salt to form a pigment. The pigment may be made by a process of coating iron oxide on a substrate by oxidizing an iron salt. During the coating of the iron oxide, the pH of the mixture is increased. The coating formed has a Fe(III)/Fe(II) ratio of greater than 2. The pigments may be used in a variety of applications including coating, ink, plastic, and cosmetic compositions.
    Type: Application
    Filed: January 18, 2008
    Publication date: July 23, 2009
    Inventors: Christelle Conan, Aaron M. Hollman, Philippe Schottland, Stephane Nicolas, Marguerite Debacker, Aurelie Antonowicz, Kenneth A. Fields, II
  • Publication number: 20090013905
    Abstract: An ultra-fine nepheline syenite powder produced from a pre-processed nepheline syenite powder feedstock. The powder having a “controlled” maximum grain size D95 or D99 of less than about 20 microns and a “controlled” minimum grain size D5 in the range of 2-8 microns with a particle size spread D5-D95 of less than about 12 microns.
    Type: Application
    Filed: June 27, 2008
    Publication date: January 15, 2009
    Inventors: Scott VanRemortel, Robert Ratcliff, Ibezim Anazia, Louis M. Schlesinger
  • Publication number: 20090004390
    Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).
    Type: Application
    Filed: June 28, 2007
    Publication date: January 1, 2009
    Inventors: Jerome David Smith, Pedro A. Jimenez, Tony Jackson
  • Publication number: 20080295736
    Abstract: The invention relates to a pearl pigment, and the preparing method of the same comprises: coating metal oxides on a sheet-like substrate, and coating metal phosphites (aluminum phosphite or zinc phosphite) on it, and then treating by hydrolysable silane coupling agent. The pearl pigment obtained highly improves its stability and its aging resistance when used for external outsides.
    Type: Application
    Filed: September 21, 2005
    Publication date: December 4, 2008
    Inventors: Yizhong Lin, Wensong Jin
  • Publication number: 20080279796
    Abstract: The present invention relates to effect pigments comprising transition-metal oxides or transition-metal hydroxyoxides or transition-metal hydroxides based on flake-form substrates which are uncoated or coated with one or more metal oxides, and to the use thereof, inter alia in paints, coatings, printing inks, plastics and in particular in cosmetic formulations.
    Type: Application
    Filed: March 5, 2008
    Publication date: November 13, 2008
    Inventors: Carsten HANDROSCH, Frank Pflucker
  • Publication number: 20080207772
    Abstract: The present invention relates to a mixture of interference pigments, where the mixture comprises at least one interference pigment A comprising a substrate and a coating comprising metallic iron, and an interference pigment B comprising a substrate and a coating comprising metallic tin and in addition at least one metal oxide, to the use thereof in cosmetics, surface coatings, inks, plastics, films, in security printing, in security features in documents and identity papers, for colouring seed, for colouring foods, for laser marking or in medicament coatings and for the preparation of pigment compositions and dry preparations, and to cosmetics, surface coatings, inks, plastics, films, documents and identity papers, seed, foods or medicament coatings, pigment compositions and dry preparations comprising the mixture according to the invention.
    Type: Application
    Filed: June 9, 2006
    Publication date: August 28, 2008
    Inventors: Helge Bettina Kniess, Gerhard Pfaff
  • Patent number: 7387672
    Abstract: The present invention relates to oxidation-stable iron oxide pigments which have a coating of at least one organic substance, to their preparation and to their use.
    Type: Grant
    Filed: May 1, 2007
    Date of Patent: June 17, 2008
    Assignee: LANXESS Deutschland GmbH
    Inventor: Holger Friedrich
  • Publication number: 20080134941
    Abstract: The present invention relates to an infrared reflecting black pigment which comprises a composite oxide containing Fe, Co and at least one metal selected from the group consisting of Al, Mg, Ca, Sr, Ba, Ti, Zn, Sn, Zr, Si and Cu; has an average plate surface diameter of 0.02 to 5.0 ?m, a blackness (L* value) of not more than 30, an average reflectance of not more than 10% in a visible light wavelength range of 250 to 780 nm and an average reflectance of not less than 35% in an infrared wavelength range of 780 to 2500 nm. There is provided an infrared reflecting black pigment which is capable of producing a heat-shielding paint containing no harmful elements and exhibiting an excellent infrared reflecting property.
    Type: Application
    Filed: February 8, 2006
    Publication date: June 12, 2008
    Inventor: Kazutoshi Sanada
  • Publication number: 20080115694
    Abstract: A pearlescent pigment, wherein the pigment is an inorganic material and the color of a homogeneous coating of the pigment, measured over a white background, is selected from the group consisting of: a CIELAB L* value of about 30 or less and a chroma value of about 3 or less; a CIELAB hue angle, hab, from about 50 to about 80 degrees, wherein L* is not more than about 85, and the chroma value is greater than 22; a CIELAB hue angle, hab, from about 80 to about 275 degrees, wherein L* is not more than about 80, and the chroma value is greater than about 10; and a CIELAB hue angle, hab, from not less than about 275 to not more than about 50 degrees, wherein L* is not more than about 85, and the chroma value is greater than about 9. The pigments may be used in a variety of applications including cosmetics, plastics, automotive, or architectural coatings.
    Type: Application
    Filed: October 31, 2007
    Publication date: May 22, 2008
    Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
  • Publication number: 20080110372
    Abstract: A pearlescent pigment comprising a substrate and a first layer, wherein the first layer comprises iron oxide, wherein the iron has from about 1% to about 30% Fe(II) and from about 70% to about 99% Fe(III). A process for making these pearlescent pigment, comprise reducing a metal oxide substrate with a hydrogen source in the presence of a noble metal catalyst in a liquid medium. The pigments may be used in a variety of applications including cosmetics, plastics, automotive, or architectural coatings.
    Type: Application
    Filed: October 31, 2007
    Publication date: May 15, 2008
    Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
  • Patent number: 7341626
    Abstract: A pigment composition containing one or more, organic yellow pigments selected from the group C.I. Pigment Yellow (213), Pigment Yellow (214) and disazo pigment of the formula (I) and containing one or more inorganic pigments.
    Type: Grant
    Filed: August 18, 2004
    Date of Patent: March 11, 2008
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Joachim Weber, Gerhard Wilker
  • Patent number: 7291217
    Abstract: A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.
    Type: Grant
    Filed: July 23, 2003
    Date of Patent: November 6, 2007
    Assignee: University of Dayton
    Inventors: Andrew Wells Phelps, Jeffrey Allen Sturgill, Joseph Thomas Swartzbaugh
  • Patent number: 7255736
    Abstract: Effect pigments having improved optical properties based on SiO2 flakes coated with one or more layers, where the SiO2 flakes have a thickness of from 50 nm to 150 nm; processes for the preparation thereof; and use of these pigments in cosmetics, paints, coatings, plastics, films, in security printing, in security features in documents and identity cards, for coloring seed, for coloring foods or in medicament coatings and for the preparation of pigment compositions and dry preparations; are disclosed.
    Type: Grant
    Filed: October 11, 2005
    Date of Patent: August 14, 2007
    Assignee: Merck Patent GmbH
    Inventors: Gerhard Pfaff, Doreen Warthe, Johann Dietz, Cornelia Foerderer
  • Patent number: 7250080
    Abstract: An improved process for making an organosilicon compound surface-treated titanium dioxide material, comprising (a) forming a mixture of the titanium dioxide material in water, (b) wet milling the mixture, (c) adjusting the pH of the slurry resulting from step (b) to between about 5.0 and about 8.5, (d) after step (c), removing the titanium dioxide material from the mixture by vacuum or pressure filtration, (e) after step (d), washing the titanium dioxide material so removed, (f) after step (e), converting the washed titanium dioxide material to a fluid dispersion having a pH of from about 3.5 to less than about 7 via addition of a fluidizing agent comprising a water-soluble monoprotic acid, (g) after, or concurrently with, step (f), adding to the resulting dispersion of titanium dioxide material an organosilicon compound, with mixing, and (h) spray drying the dispersion of the washed titanium dioxide material resulting from step (g) to yield a dry titanium dioxide pigment powder.
    Type: Grant
    Filed: September 6, 2006
    Date of Patent: July 31, 2007
    Assignee: Tronox LLC
    Inventors: Daniel H. Craig, Mark D. Westmeyer
  • Patent number: 7169222
    Abstract: Multilayer interference pigment consisting of a transparent carrier material coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by alternate coating of the transparent carrier material with a metal oxide of high refractive index and with a metal oxide of low refractive index in a wet process by hydrolysis of the corresponding water-soluble metal compounds, separation, drying and, if desired, calcination of the resulting pigment.
    Type: Grant
    Filed: July 11, 2005
    Date of Patent: January 30, 2007
    Assignee: Merck Patent GmbH
    Inventors: Hans-Dieter Brückner, Andrea Heyland, Christoph Schmidt, Christina Schank, Claudia Seibel
  • Patent number: 7160374
    Abstract: A flaky pigment excellent in leafing properties and in adhesion between pigment particles and a coating (resin) was obtained by coating the surface of a flaky pigment with a coupling agent and a phosphate having a perfluoroalkly group or a silane compound. Accordingly, the flaky pigment is excellent as a pigment for coating or printing ink of which brightness and durability are required.
    Type: Grant
    Filed: February 15, 2001
    Date of Patent: January 9, 2007
    Assignee: Merck Patent GmbH
    Inventors: Eiji Umehara, Koushiro Kunii
  • Patent number: 7135206
    Abstract: A method for producing nanoscale titanium dioxide particles which are coated with an oxide, a hydroxide or an oxide hydroxide of Al, Ce, Zr and/or Si wherein the enzymatic precipitant system urease/urea is used. Said coated titanium dioxide particles can have an average size of less than 50 nm, the coating providing effective protection against photocatalytic reactions. The coated particles are suitable, in particular, as UV absorbers in a transparent organic matrix.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: November 14, 2006
    Assignee: Leibniz-Institut Fuer Neue Materialien Gemeinnuetzige GmbH
    Inventor: Martin Schichtel
  • Patent number: 7105467
    Abstract: The present invention provides nickel catalysts and solvents which are useful in a cross-coupling reaction between an organomagnesium compound and an aromatic ether compound, such as an anisole derivative.
    Type: Grant
    Filed: July 8, 2003
    Date of Patent: September 12, 2006
    Assignee: Pharmacore, Inc.
    Inventor: John W. Dankwardt
  • Patent number: 7018465
    Abstract: A spray glaze or opaque composition for coating dental restorations and other surfaces and objects such as hobby ceramics that comprises about 4 to about 50 weight % glaze material, about 5 to about 60 weight % restoration wetting agent, and about 10 to about 90% non CFC propellant. An opaque composition further comprises about 5 to about 30% opaque material.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: March 28, 2006
    Assignee: Enamelite, LLC
    Inventors: Phillip G. Pitts, James R. Vinson
  • Patent number: 6997982
    Abstract: The invention relates to a pigment with a metallic luster, comprising a plate-like non-metallic substrate having a thickness lower an 200 nm, which is entirely coated with a metallic layer.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: February 14, 2006
    Assignee: Merck Patent GmbH
    Inventors: Gerhard Pfaff, Stephanie Andes, Michael Uhlig
  • Patent number: 6984682
    Abstract: A metallic effect pigment including a metallic, corrosion resistant reflective core of reflectivity from 40% to 80%; having deposited thereupon at least one dielectric coating layer formed of at least one metal oxide, the metal oxide layer having been formed by deposition on the core by hydrolysis of a hydrolyzable metal salt in an strongly acidic aqueous medium, and thereafter full transformation into the oxide by calcination.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: January 10, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jack Polonka, Patrice Bujard, Natacha Bonnard Pillonel, Fritz Herren
  • Patent number: 6953504
    Abstract: A black pigment powder having a low value of magnetization according to the present invention is characterized in that it consists of a composite oxide containing Fe2TiO4 as a main component, wherein the total amount of Fe (II) and Fe (III) to Ti is from 150 to 300 atomic %, in such an amount that the amount of Fe (II) to the total amount of Fe (II) and Fe (III) is 0.50 or more, and that the L value of a coating according to the Hoover-type muller method is 9.0 or less. It is employed to produce a toner composition, a coating composition, a resin composition, a cosmetic material and the like.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: October 11, 2005
    Assignee: Titan Kogyo Kabushiki Kaisha
    Inventors: Koji Nakata, Koji Kurosaki, Nobuyuki Hashimoto
  • Patent number: 6929690
    Abstract: A pigment with a metallic luster, comprising a wafer-like substrate made of aluminium dioxide having a thickness of more than 250 nm and less than 1 ?m, which is fully enveloped by a metal layer.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: August 16, 2005
    Assignee: Merck Patent GmbH
    Inventors: Reiner Vogt, Gerhard Pfaff, Stephanie Andes, Michael Uhlig, Martin Friz, Katsuhisa Nitta
  • Patent number: 6887566
    Abstract: The present invention provides a cerium oxide particulate composition and a process for preparing a cerium oxide particulate composition comprising aggregates of approximately spherical primary particles of cerium oxide. The method involves preparing a solution of a cerium oxide precursor, aerosolizing the cerium oxide precursor solution, and heating the aerosol to provide the cerium oxide particle composition.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: May 3, 2005
    Assignee: Cabot Corporation
    Inventors: Cheng-Hung Hung, Joseph D. Smith, George P. Fotou, Kenneth C. Koehlert
  • Patent number: 6884289
    Abstract: The present invention relates to colored pigments based on multicoated platelet-shaped substrates which are distinguished by the fact that they comprise (A) a coating having a refractive index of n>1.8 and a layer thickness of 20-500 nm, (B) a colorless coating having a refractive index of n?1.8 and a layer thickness of 10-100 nm, (C) a colorless coating having a refractive index of n>1.8 and a layer thickness of 20-500 nm, (D) a covering of absorbent pigment particles having a particle size of 1-500 nm, and optionally (E) an outer protective layer, and to their use in paints, coatings, printing inks, plastics, ceramic materials, glasses, for laser marking, in cosmetic formulations and for the production of pigment preparations and dry preparations.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: April 26, 2005
    Assignee: Merck Patent Gmbh
    Inventors: Sabine Schoen, Christoph Schmidt
  • Patent number: 6875264
    Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: April 5, 2005
    Assignee: Engelhard Corporation
    Inventors: Curtis J. Zimmermann, Daniel Stevenson Fuller
  • Patent number: 6858294
    Abstract: A coating liquid for forming on a substrate surface a hard coat film which exhibits a high refractive index, being excellent in resistance to hot water, weather resistance, scuffing resistance, attrition resistance and dye affinity, and which does not exhibit photochromism, is provided. A coating liquid for forming a hard coat film, comprises a matrix-forming component and composite metal oxide particles of 1 to 100 nm average particle size, composed either of an iron oxide component and a titanium oxide component used at a specified ratio or an iron oxide component, a titanium oxide component and a silica component used at a specified ratio. A substrate coated with a hard coat film is formed by applying the above coating liquid to the substrate surface and effecting drying.
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: February 22, 2005
    Assignee: Catalyst & Chemicals Industries Co., Ltd.
    Inventors: Hirokazu Tanaka, Masafumi Hirai, Chiemi Murakami
  • Patent number: 6783584
    Abstract: To provide a high-chromatic flaky pigment with good colorability, and to provide a method for producing the flaky pigment in a simple and inexpensive plant. A high-chromatic flaky pigment of which the entire surface of the flaky substrate coated with a metal oxide having an interference color is further coated with a semi-transparent thin metal film to enhance the interference color of the pigment.
    Type: Grant
    Filed: September 18, 2002
    Date of Patent: August 31, 2004
    Assignee: Merck Patent GmbH
    Inventor: Norio Takahashi
  • Patent number: 6767633
    Abstract: The invention relates to a transparent medium comprising multilayer pigments having angle-selective reflection or transmission properties and/or absorption properties, and to their use, in particular in transparent thermal insulation systems (TTIs).
    Type: Grant
    Filed: October 10, 2002
    Date of Patent: July 27, 2004
    Assignee: Merck Patent GmbH
    Inventors: Elke Steudel, Hans-Dieter Brückner, Gerhard Pfaff, Peter Reynders, Christoph Schmidt, Carsten Brabänder, Wolfgang Hechler
  • Patent number: 6758893
    Abstract: A method for the preparation of pigment granules includes mixing at least one pigment selected from the group consisting of iron oxide and chromium oxides with 1-25 wt. % water to form a damp powder. The damp powder is then pressure extruded through at least one die to form granules. The granules are then dried so that the final water content of the granules is less than about 1%, crumble and sieved to form the final product.
    Type: Grant
    Filed: June 20, 2002
    Date of Patent: July 6, 2004
    Assignee: Elementis Pigments, Inc.
    Inventors: Hugh Joseph McAulay, George Podolsky, Andrew Morris, Roy Laundon
  • Publication number: 20040094068
    Abstract: The invention relates to a titanium dioxide pigment mixture comprising a pigment having high greying stability (pigment type A) and a pigment having increased SiO2 and Al2O3 content in flaky precipitation (pigment type B). Said mixture provides, for example in paper, a high level of opacity for sufficient greying stability. If necessary, the light-fastness of the paper can be further increased by means of known production-conditioned measures on pigment type B.
    Type: Application
    Filed: August 13, 2003
    Publication date: May 20, 2004
    Inventors: J?uuml;rgen Bender, Siegfried Blmel, Volker Schmitt, Brigitte Vielhaber-Kirsch
  • Patent number: 6719838
    Abstract: The present invention relates to colored interference pigments based on multicoated, platelet-shaped substrates, which are distinguished in that they comprise (A) a colored coating having a refractive index of n>1.8, (B) a colorless coating having a refractive index of n>1.8, (C) a colorless coating having a refractive index of n≦1.8, (D) a colorless coating having a refractive index of n>1.8, and optionally (E) an outer protective layer, and to their use in paints, surface coatings, printing inks, plastics, ceramic materials, glasses, for laser marking, in cosmetic formulations and for the production of pigment preparations and dry preparations.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: April 13, 2004
    Assignee: Merck Patent GmbH
    Inventors: Lilia Heider, Manuela Loch, Nicole Schupp, Helge Kniess
  • Patent number: 6706109
    Abstract: Optically variable interference pigments are composed of platelets of at least partly core-free titanium dioxide-coated substrate of about 1-25 mm particle size and an interference thickness of about 5-600 nm which have an oxide coating thereon.
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: March 16, 2004
    Assignee: Engelhard Corporation
    Inventor: Carmine V. DeLuca, Jr.
  • Patent number: 6692561
    Abstract: The invention relates to intensely colored interference pigments based on multi-layered plate-like substrates with at least two sequences of layers consisting of (A) a colorless layer with a refraction index n≦1,8; (B) a high-index layer consisting of a mixture of TiO2 and Fe2O3 in a ratio of 1:0.1 to 1:5 and optionally, one or more metal oxides in quantities of to layer (B); and optionally (C) an outer protective layer.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: February 17, 2004
    Assignee: Merck Patent Gesellschaft mit beschränkter Haftung
    Inventors: Sabine Schoen, Klaus Bernhardt, Christoph Schmidt
  • Patent number: 6689205
    Abstract: Multilayer interference pigment consisting of a transparent carrier material coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by alternate coating of the transparent carrier material with a metal oxide of high refractive index and with a metal oxide of low refractive index in a wet process by hydrolysis of the corresponding water-soluble metal compounds, separation, drying and, if desired, calcination of the resulting pigment.
    Type: Grant
    Filed: October 24, 2000
    Date of Patent: February 10, 2004
    Assignee: Merck Patent Gesellschaft
    Inventors: Hans-Dieter Brückner, Andrea Heyland, Christoph Schmidt, Christina Schank, Claudia Seibel
  • Patent number: 6686042
    Abstract: Pigment flakes are provided which can be used to produce colorant compositions having color shifting properties. The pigment flakes can have a symmetrical coating structure on opposing sides of a reflector layer, can have an asymmetrical coating structure with all of the layers on one side of the reflector layer, or can be formed with encapsulating coatings around a reflector layer. The coating structure includes a selective absorbing layer on one or more sides of the reflector layer, a dielectric layer on the selective absorbing layer, and an absorber layer on the dielectric layer. The pigment flakes exhibit a discrete color shift such that the pigment flakes have a first color at a first angle of incident light or viewing and a second color different from the first color at a second angle of incident light or viewing. The pigment flakes can be interspersed into liquid media such as paints or inks for subsequent application to objects or papers.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: February 3, 2004
    Assignee: Flex Products, Inc.
    Inventor: Charlotte R. LeGallee
  • Patent number: 6656261
    Abstract: The present invention provides titanium dioxide pigments with improved gloss and/or durability. The titanium dioxide pigments are made by treating titanium dioxide with a plurality of metal salts under conditions suitable to form the titanium dioxide pigment having improved gloss and/or durability, wherein at least one metal salt is capable of providing a monovalent anion. Preferred pigments of the present invention are substantially-sulfate free.
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: December 2, 2003
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Brian Tear, John Stratton, Robert Burniston
  • Publication number: 20030213409
    Abstract: Optically variable interference pigments are composed of platelets of at least partly core-free titanium dioxide-coated substrate of about 1-25 mm particle size and an interference thickness of about 5-600 nm which have an oxide coating thereon.
    Type: Application
    Filed: May 14, 2002
    Publication date: November 20, 2003
    Inventor: Carmine V. DeLuca
  • Patent number: 6648956
    Abstract: The invention relates to a nondusting, solvent-containing homogeneous pigment preparation that includes ≧70% by weight of one or more effect pigments 0.1-30% by weight of an organic solvent or solvent mixture having an evaporation number (EN) of 10 to 100 and a surface tension (ST) of ≦35 mN/m and optionally 0-5% by weight of a surface-active substance.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: November 18, 2003
    Assignee: Merck Patent Gesellschaft mit beschraenkter Haftung
    Inventors: Wolfgang Hechler, Gerhard Herget, Brigitte Husseini, Sabine Schoen
  • Patent number: 6648957
    Abstract: Multilayer pearl lustre pigment on the basis of a platelet-shaped substrate comprising a material of low refractive index in the range from 1.35 to 1.8, which comprises at least (i) one first layer comprising a material having a refractive index of more than 1.8, (ii) optionally, a second layer comprising a material of low refractive index in the range from 1.35 to 1.8, (iii) a semitransparent metal layer which is applied to the substrate or to the layers (i) or (ii), and (iv) if desired, an aftercoating, the substrate being platelet-shaped silicon dioxide, aluminium oxide, boron oxide or magnesium fluoride.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: November 18, 2003
    Assignee: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerald Fuchs-Pohl, Gerhard Pfaff
  • Patent number: 6645286
    Abstract: The present invention is concerned with soft-magnetic iron effect pigments with metallic luster, which are produced by grinding reductively treated carbonyl iron powder, and which are passivated either during grinding or subsequent to the grinding. The products find application in the decorative and functional fields in paint and lacquer coatings, coloring of plastics, in printing, cosmetics, and glass and ceramics.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: November 11, 2003
    Assignee: Eckart GmbH & Co. KG
    Inventors: Werner Ostertag, Stefan Trummer, Frank Henglein, Klaus Greiwe
  • Publication number: 20030181329
    Abstract: A method of producing composite particles of titanium dioxide and a compound inactive as a photocatalyst, comprising the steps of preparing a water based slurry of pH 3 to 5 comprising titanium dioxide, preparing a water based solution comprising a compound inactive as a photocatalyst, and reacting the slurry and the water based solution together at a pH within a range from 4 to 10 is provided, together with highly active photocatalyst particles produced using such a method, and potential uses of such photocatalyst particles.
    Type: Application
    Filed: December 19, 2002
    Publication date: September 25, 2003
    Applicant: SHOWA DENKO K.K.
    Inventors: Jun Tanaka, Masayuki Sanbayashi, Yoshinori Ueyoshi
  • Patent number: 6620233
    Abstract: Goniochromatic luster pigments are based on titanium dioxide-coated silicatic platelets which have been heated in a reducing atmosphere and which comprise at least one layer packet comprising A) a colorless coating having a refractive index n≦1.8 and B) a coating which has a refractive index n≧2.0, which includes iron(III) oxide and which selectively absorbs visible light.
    Type: Grant
    Filed: April 23, 2002
    Date of Patent: September 16, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Oliver Seeger, Raimund Schmid, Norbert Mronga, Jörg Adel