Iron, Tungsten, Molybdenum, Or Cerium Compound Containing (fe, W, Mo, Ce) Patents (Class 106/439)
  • Patent number: 6616745
    Abstract: A metal oxide-coated mica pearlescent pigment having a coating of copper chromite thereon is provided.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: September 9, 2003
    Assignee: Engelhard Corporation
    Inventors: Samuel F. Narvarti, Mark E. Gall, Thomas V. Edwards, Frank A. Mazzella, William L. Howell, Jr.
  • Patent number: 6610136
    Abstract: Aggregated mineral pigments (such as kaolin clay pigments) having a high surface area and useful in coating and filling compositions for ink jet printing media are manufactured by dry grinding an unground mineral composition starting material and then optionally acid treating the ground material.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: August 26, 2003
    Assignee: Thiele Kaolin Company
    Inventors: Prakash B. Malla, Siva Devisetti
  • Patent number: 6602934
    Abstract: This invention provides a multicolor coating composition comprising a vehicle and a metal oxide-coated silica flake pigment wherein a coating film resulting from baking of said coating composition and a coating film resulting from reheating of the former coating film under the same conditions as in said baking, followed by 10 minutes of standing at room temperature show a color difference of less than 0.5.
    Type: Grant
    Filed: July 21, 2000
    Date of Patent: August 5, 2003
    Assignee: Nippon Paint Co., Ltd.
    Inventor: Yoshikatsu Saito
  • Patent number: 6599351
    Abstract: Anticorrosive white pigments useful for inhibiting corrosion include surface-coated TiO2 base bodies, preferably in the rutile modification, having Mn3(PO4)2 and one or more of the substances chosen from aluminum oxides, aluminum hydroxides, aluminum phosphates, aluminum hydrogen phosphates, aluminum dihydrogen phosphates and aluminum polyphosphates are precipitated on to the TiO2 base bodies. Mn3(PO4)2 may be replaced completely or partially by Zn3(PO4)2. Phosphates and/or oxides of cerium may be additionally deposited singly, or several of them may be deposited, on to the TiO2 base bodies.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: July 29, 2003
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Thomas Rentschler, Fritz Muller, Jochen Winkler, Wolf-Rudiger Karl, Kirsten Fohr
  • Patent number: 6596070
    Abstract: The present invention relates to interference pigments on the basis of multiply coated, platelet-shaped substrates which comprise at least one layer sequence comprising (A) a coating having a refractive index n≧2.0, (B) a colorless coating having a refractive index n≦1.8, and (C) a nonabsorbing coating of high refractive index, and, if desired, (D) an external protective layer.
    Type: Grant
    Filed: April 17, 2000
    Date of Patent: July 22, 2003
    Assignee: Merck Patent Gesellschaft
    Inventors: Christoph Schmidt, Gerhard Pfaff, Christina Schank, Sabine Schoen
  • Publication number: 20030124076
    Abstract: Iron oxide-silicon dioxide-titanium dioxide mixed oxide is produced by burning vapourable compounds of iron, silicon and titanium together in a hydrogen/oxygen flame.
    Type: Application
    Filed: December 9, 2002
    Publication date: July 3, 2003
    Applicant: Degussa AG
    Inventors: Ina Hemme, Herbert Habermann, Steffen Hasenzahl
  • Patent number: 6582506
    Abstract: Pigment flakes having cores preferably composed of resins, polymers, thermoplastics, and/or thermosets with colorant (pigment and/or dyes) deposited thereon, coating applications thereof, and a method for making pigment flakes which includes providing a core material, compounding the core material, processing the core material into uniform forms such as films, wires, thread with rectangular cross sections and bead strings, providing colorant material, vaporizing the colorant material, exposing a surface of core material to the vaporized colorant material to form a layer of colorant on thereon, and fracturing the resultant colorant layered core material into flakes.
    Type: Grant
    Filed: May 25, 2001
    Date of Patent: June 24, 2003
    Assignee: Hampden Papers, Inc.
    Inventor: Michael E. Archambeault
  • Publication number: 20030097965
    Abstract: The present invention relates to coloured interference pigments based on multicoated, platelet-shaped substrates, which are distinguished in that they comprise
    Type: Application
    Filed: October 24, 2002
    Publication date: May 29, 2003
    Applicant: Merck Patent GmbH
    Inventors: Lilia Heider, Manuela Loch, Nicole Schupp, Helge Kniess
  • Patent number: 6547870
    Abstract: The invention relates to a non-dusting, homogeneous pigment preparation, comprising ≧40% by weight of one or more effect pigments, 0.5-60% by weight of a polyalkylene glycol and/or one or more polyalkylene glycol derivatives, 0-10% by weight of a redispersing auxiliary, 0-40% by weight of water or an organic solvent or solvent mixture, 0-40% by weight of at least one further hydroxyl-rich resin, and to its use as a precursor for printing inks.
    Type: Grant
    Filed: December 13, 2000
    Date of Patent: April 15, 2003
    Assignee: Merck Patent Gesellschaft mit beschränkter Haftung
    Inventors: Carsten Griessmann, Gerhard Herget
  • Patent number: 6544327
    Abstract: The invention relates to a non-dusting homogeneous pigment preparation which is notable in that it comprises at least 40% by weight of one or more effect pigments, from 0.5 to 60% by weight of an aldehyde resin and/or ketonic resin and from 0.1 to 10% by weight of a redispersant.
    Type: Grant
    Filed: September 14, 2000
    Date of Patent: April 8, 2003
    Assignee: Merck Patent GmbH
    Inventors: Carsten Griessmann, Wolfgang Hechler, Gerhard Herget
  • Patent number: 6540824
    Abstract: The present invention provides a yellow pigment which contains a titanium-iron complex oxide of the pseudo-brookite type and produces a stabilized color more yellowish than conventionally and which is universally usable for coloring plastics, ceramics and coating compositions. The pigment of the invention is a titanium-iron complex oxide pigment which contains a pseudo-brookite complex oxide represented by the composition formula (M1-x•Fex)O•2TiO2 or the composition formula (Fe1-y•Aly)2O3•TiO2 wherein M is one of the bivalent metals Mg, Sr and Zn, the ratios of Fe, Al and M to Ti are in the respective ranges of 0.3≦Fe/Ti≦4.5, 0≦Al/Ti≦6.5 and 0≦M/Ti≦2.6, and x and y are in the respective ranges of 0≦x<1 and 0≦y<1.
    Type: Grant
    Filed: February 7, 2002
    Date of Patent: April 1, 2003
    Assignee: Ferro Enamels (Japan) Limited
    Inventors: Takayuki Suzuki, Koji Kataoka
  • Patent number: 6533857
    Abstract: Luster pigments based on multiply coated reflecting platelet-shaped substrates and comprising at least one layer packet comprising A) a low refractive coating which selectively absorbs visible light and B) a reflective coating which is at least partially transparent to visible light and also, if desired, C) an outer protective layer.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: March 18, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Arno Böhm, Oliver Seeger, Norbert Mronga, Thorsten Clemens
  • Publication number: 20030037705
    Abstract: A titanium dioxide powder/iron oxide mixed oxide which is prepared from FeCl3 and TiCl4 using a pyrogenic, especially a flame hydrolytic method. A further possibility is to coat pyrogenically, especially flame hydrolytically prepared titanium dioxide with iron oxide in aqueous dispersion. Both of these titanium dioxide powders which contain iron oxide may be used as a UV absorber in sunscreens.
    Type: Application
    Filed: March 26, 2002
    Publication date: February 27, 2003
    Applicant: Dehussa Aktiengesellschaft
    Inventors: Werner Hartmann, Dieter Kerner
  • Patent number: 6508877
    Abstract: The present invention relates to a process for the production of an aluminum-containing iron oxide crystallization nucleus with a &agr;-FeOOH crystal structure from FeCl2. This nucleus is suitable as starting material for the production of iron oxide red (&agr;-Fe2O3) via &agr;-FeOOH as an intermediate product.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: January 21, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventor: Ulrich Meisen
  • Patent number: 6508290
    Abstract: The invention relates to a method of preparing an aluminium-containing iron oxide nucleus with an &agr;-FeOOH crystal structure from FeCl2. This nucleus is a suitable starting material for the preparation of iron oxide yellow and for use as a yellow coloring pigment.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: January 21, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventor: Ulrich Meisen
  • Patent number: 6500251
    Abstract: Multilayer interference pigment consisting of plateletlike titanium dioxide as carrier material, coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by solidification and hydrolysis of an aqueous solution of a thermally hydrolyzable titanium compound on a continuous belt, detachment of the resulting coat, coating of the resulting titanium dioxide platelets, with or without drying in between, by a wet method with, alternately, a metal oxide hydrate of high refractive index and a metal oxide hydrate of low refractive index by hydrolysis of the corresponding, water-soluble metal compounds, separation, drying and, if desired, calcining of the material obtained.
    Type: Grant
    Filed: March 9, 1999
    Date of Patent: December 31, 2002
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Stephanie Andes, Gerd Bauer, Günter Brenner, Dieter Brückner, Michael Schmelz, Andrea Heyland, Matthias Kuntz, Karl Osterried, Gerhard Pfaff
  • Patent number: 6488757
    Abstract: The present invention relates to a pearl luster pigment on the basis of a platelet-shaped substrate coated with metal oxides and a top layer which is located on the metal oxide layer and can possess a multilayer structure, comprising a first layer, containing a hydroxide or oxide hydrate of the elements aluminum or silicon, a second layer, containing at least one hydroxide or oxide hydrate of the elements aluminum, silicon, cerium or zirconium, with the exception of the hydroxide or oxide hydrate which forms the first layer, and a third layer, containing at least one organic hydrophobic coupling agent. The present invention also relates to a preparation process and the use of pigments in paints, inks, plastics, coatings and cosmetics.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: December 3, 2002
    Assignee: Merck Patent Gesellschaft mit beschraenker Haftung
    Inventor: Ralf Glausch
  • Patent number: 6488758
    Abstract: The invention relates to a pearl luster pigment which may possess a first, inner layer, consisting of a platelet-shaped substrate, a second layer, comprising one or more metal oxides, the first and second layers forming a calcined base pigment, a third layer, comprising the corresponding uncalcined oxide, hydroxide or oxide hydrate of the oxide of the second layer, a fourth layer, comprising oxides, hydroxides and/or oxide hydrates of silicon or aluminum, a fifth layer, comprising oxides, hydroxides and/or oxide hydrates of silicon, aluminum, zirconium and/or cerium, this layer differing from the fourth layer, and a sixth layer, comprising one or more organofunctional coupling reagents. The present invention relates to also a preparation process, and the use of the pigments in paints, inks, plastics, coatings and cosmetics.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: December 3, 2002
    Assignee: Merck Patent Gesellschaft mit beschraenkter Haftung
    Inventors: Ralf Glausch, Marita Jekel
  • Patent number: 6485556
    Abstract: Pearlescent pigment having a chromium coating thereon and an iron oxide coating on the chromium coating are intensely colored, almost phosphorescently colored, and are highly reflective.
    Type: Grant
    Filed: October 10, 2001
    Date of Patent: November 26, 2002
    Assignee: Engelhard Corporation
    Inventor: Carmine V. DeLuca, Jr.
  • Patent number: 6454848
    Abstract: The present invention provides new solid solutions having a corundum-hematite crystalline structure which are useful as inorganic color pigments. Solid solutions according to the present invention include a host component having a corundum-hematite crystalline structure which contains as guest components one or more elements from the group consisting of aluminum, antimony, bismuth, boron, chrome, cobalt, gallium, indium, iron, lanthanum, lithium, magnesium, manganese, molybdenum, neodymium, nickel, niobium, silicon, tin, titanium, vanadium, and zinc. Solid solutions according to the present invention are formed by thoroughly mixing compounds, usually metal oxides or precursors thereof, which contain the host and guest components and then calcining the compounds to form the solid solutions having the corundum-hematite crystalline structure. Some of the new solid solutions according to the present invention exhibit relatively low Y CIE tri-stimulus values and relatively high near infrared reflectance.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: September 24, 2002
    Assignee: Ferro Corporation
    Inventors: Terrence R. Sliwinski, Richard A. Pipoly, Robert P. Blonski
  • Patent number: 6451102
    Abstract: The present invention is directed to a process for producing a master batch of pigment, comprising mixing a pigment having a high aspect ratio, embedded in a material increasing bulk density of the pigment, with a plastic so as to produce a dispersion of pigment and plastic.
    Type: Grant
    Filed: May 4, 2000
    Date of Patent: September 17, 2002
    Assignee: Merck Patent GmbH
    Inventors: Robin Hilder, Manfred Kieser
  • Publication number: 20020121227
    Abstract: A titanium dioxide powder/iron oxide mixed oxide which is prepared from FeCl3 and TiCl4 using a pyrogenic, especially a flame hydrolytic method. A further possibility is to coat pyrogenically, especially flame hydrolytically prepared titanium dioxide with iron oxide in aqueous dispersion. Both of these titanium dioxide powders which contain iron oxide may be used as a UV absorber in sunscreens.
    Type: Application
    Filed: December 14, 2001
    Publication date: September 5, 2002
    Applicant: Degussa AG
    Inventors: Werner Hartmann, Dieter Kerner
  • Patent number: 6432195
    Abstract: The invention relates to a non-dusting, homogeneous pigment preparation which is distinguished by the fact that it comprises at least 40% by weight of one or more effect pigments and 0.5-59.5% by weight of a modified colophony resin, based on the pigment preparation, and the use thereof, in particular for the production of dry preparations. The pigment preparation according to the invention and the dry preparations produced therefrom are particularly suitable for the pigmenting of paints, coatings, powder coatings, printing inks and plastics.
    Type: Grant
    Filed: May 14, 2001
    Date of Patent: August 13, 2002
    Assignees: Merck Patent Gesellschaft mit beschraenkter Haftung, Lackharzwerke Robert Kraemer GmbH & Co.
    Inventors: Thomas Rathschlag, Carsten Griessmann, Sabine Schoen, Werner Sarfert
  • Patent number: 6406532
    Abstract: A titanium dioxide powder/iron oxide mixed oxide which is prepared from FeCl3 and TiCl4 using a pyrogenic, especially a flame hydrolytic method. A further possibility is to coat pyrogenically, especially flame hydrolytically prepared titanium dioxide with iron oxide in aqueous dispersion. Both of these titanium dioxide powders which contain iron oxide may be used as a UV absorber in sunscreens.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: June 18, 2002
    Assignee: Degussa Aktiengesellschaft
    Inventors: Werner Hartmann, Dieter Kerner
  • Publication number: 20020061285
    Abstract: Iron oxide-silicon dioxide-titanium dioxide mixed oxide is produced by burning vapourable compounds of iron, silicon and titanium together in a hydrogen/oxygen flame. They are used as UV absorbers in cosmetics.
    Type: Application
    Filed: September 21, 2001
    Publication date: May 23, 2002
    Inventors: Ina Hemme, Herbert Habermann, Steffen Hasenzahl
  • Patent number: 6387498
    Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: May 14, 2002
    Assignee: Flex Products, Inc.
    Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
  • Patent number: 6383638
    Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: May 7, 2002
    Assignee: Flex Products, Inc.
    Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
  • Patent number: 6361593
    Abstract: A lustrous interference pigment with a black absorption color is obtained by forming a mica coated with hydrous titanium, iron and cobalt or chromium oxides, calcining the coated mica and then coating the resulting product with hydrous titanium and/or iron oxides and calcining the resulting product.
    Type: Grant
    Filed: May 9, 2001
    Date of Patent: March 26, 2002
    Assignee: Engelhard Corporation
    Inventors: Carmine Vincent DeLuca, Jr., William P. Kurtenbach, Christine Mans
  • Patent number: 6334893
    Abstract: The present invention relates to pigment mixtures containing at least two components component A being Al2O3 flakes coated with one or more metals, metal oxides and/or metal sulfides and component B being acicular or spherical colorants, and to their use in particular in varnishes, paints, printing inks, powder coating materials, plastics and cosmetic formulations.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: January 1, 2002
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Gerhard Pfaff, Sabine Schoen, Kaiman Shimizu
  • Patent number: 6334892
    Abstract: Tungsten nickel-antimony-rutile mixed-phase pigments in which the nickel/tungsten molar ratio is ≧4 are used to color plastics, coating materials, printing inks and ceramic glazes.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: January 1, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Hansulrich Reisacher, Uwe Mauthe
  • Patent number: 6294011
    Abstract: The present invention is concerned with a titanium-, -and alkaline- or alkaline-earth-based compound, processes for the preparation thereof, and use thereof as a coloring pigment. The product of the invention is characterized in that it corresponds to formula (1) MxCeyTizOt wherein M represents an alkaline or an alkaline-earth, and x, y and z satisfy the following equations: 0.1≦y/z≦1.5, 1≦(x+z)/y≦15, x+y+z=1, (x+3y=4z)/2≦t≦(x+4y+4z)/2.
    Type: Grant
    Filed: February 23, 2000
    Date of Patent: September 25, 2001
    Inventors: Catherine Hedouin, Thierry Seguelong
  • Patent number: 6290766
    Abstract: A lustrous interference pigment with a black absorption color is obtained by forming a mica coated with hydrous titanium, iron and cobalt or chromium oxides, calcining the coated mica and then coating the resulting product with hydrous titanium and/or iron oxides and calcining the resulting product.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: September 18, 2001
    Assignee: Engelhard Corporation
    Inventors: Carmine Vincent DeLuca, Jr., William P. Kurtenbach, Christine Mans
  • Patent number: 6284032
    Abstract: Multilayer interference pigment consisting of plateletlike titanium dioxide as carrier material, coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by solidification and hydrolysis of an aqueous solution of a thermally hydrolysable titanium compound on a continuous belt, detachment of the resulting coat, coating of the resulting titanium dioxide platelets, with or without drying in between, by a wet method with, alternately, a metal oxide hydrate of high refractive index and a metal oxide hydrate of low refractive index by hydrolysis of the corresponding, water-soluble metal compounds, separation, drying and, if desired, calcining of the material obtained.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: September 4, 2001
    Assignee: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerd Bauer, Günter Brenner, Dieter Brückner, Michael Schmelz, Andrea Heyland, Matthias Kuntz, Karl Osterried, Gerhard Pfaff
  • Patent number: 6271157
    Abstract: Composition whereby ceramic manufactured articles, obtained by moulding a conventional ceramic mixture without added TiO2., are colored from yellow to orange, said composition consisting of an aqueous solution of inorganic compounds or organic complexes of titanium and chromium combined with antimony or tungsten or mixtures thereof, in quantities corresponding to 2 to 6% by wt. Ti, 3 to 12% Sb (or 4 to 14% tungsten) and 0.2 to 2.5% chromium.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: August 7, 2001
    Inventors: Graziano Vignali, Fabrizio Guizzardi
  • Patent number: 6238471
    Abstract: Multilayer interference pigment having a blue mass tone, comprised of a platelet-shaped carrier material and a coating which is formed from (i) a first layer of a colorless, transparent metal oxide of high refractive index, (ii) a second layer of colorless, transparent metal oxide of low refractive index and (iii) a third, outer layer of cobalt aluminate, cobalt-containing glass, tungsten bronzes or cobalt oxide, it also being possible for the first and third layer to be swapped around.
    Type: Grant
    Filed: February 1, 1999
    Date of Patent: May 29, 2001
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Reiner Vogt, Hans-Dieter Brückner
  • Patent number: 6238472
    Abstract: Colored pearl luster pigment consisting of a core of platelet shaped titanium dioxide and one or more layers of other metal oxides or metal oxide hydrates obtainable by solidifying an aqueous solution of a thermally hydrolyzable titanium compound on a continuous belt, detaching the resulting layer, coating the resulting titanium dioxide platelets, with or without drying in between, with one or more other metal oxides or metal oxide hydrates, for example Fe2O3, Fe3O4, FeOOH or Cr2O3, by a wet method, separating, drying and, if desired, calcining the material obtained.
    Type: Grant
    Filed: March 9, 1999
    Date of Patent: May 29, 2001
    Assignee: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerd Bauer, Günter Brenner, Dieter Brückner, Michael Schmelz, Andrea Heyland, Matthias Kuntz, Karl Osterried, Gerhard Pfaff
  • Publication number: 20010001174
    Abstract: Multilayer interference pigment consisting of plateletlike titanium dioxide as carrier material, coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by solidification and hydrolysis of an aqueous solution of a thermally hydrolysable titanium compound on a continuous belt, detachment of the resulting coat, coating of the resulting titanium dioxide platelets, with or without drying in between, by a wet method with, alternately, a metal oxide hydrate of high refractive index and a metal oxide hydrate of low refractive index by hydrolysis of the corresponding, water-soluble metal compounds, separation, drying and, if desired, calcining of the material obtained.
    Type: Application
    Filed: January 11, 2001
    Publication date: May 17, 2001
    Applicant: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Stephanie Andes, Gerd Bauer, Gunter Brenner, Dieter Bruckner, Michael Schmelz, Andrea Heyland, Matthias Kuntz, Karl Osterried, Gerhard Pfaff
  • Patent number: 6200376
    Abstract: Heat-resistant yellow pigment particles of the present invention comprise a composite metal oxide containing Fe, Ti and Li, and comprising a crystal phase having a pseudobrookite-type structure. Such the heat-resistant yellow pigment particles are free from contamination of harmful metals such as Pb, Cr, Cd, etc., show a clear yellow color, are excellent in heat resistance, chemical resistance and light resistance, and have a low specific gravity.
    Type: Grant
    Filed: April 7, 1999
    Date of Patent: March 13, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Tsutomu Katamoto, Mamoru Fujimoto
  • Patent number: 6193795
    Abstract: A method of producing a low structure pyrogenic metal oxide filler is disclosed. The method involves subjecting pyrogenically produced metal oxide agglomerates and aggregates selected from silicon oxide, aluminum oxide, zirconium oxide, or titanium oxide to a dry milling process whereby the pyrogenically produced metal oxide is contacted in an agitating zone with an energy specific force.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: February 27, 2001
    Assignee: Degussa Corporation
    Inventors: Maria R. Nargiello, Gary J. Bush, Sturgis G. Allen
  • Patent number: 6193794
    Abstract: The iron oxide platelets comprise at least one layer packet comprising A) a colorless coating having a refractive index n≦1.8, and B) a colorless coating having a refractive index n≧2.0.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: February 27, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Oliver Seeger, Norbert Mronga
  • Patent number: 6176918
    Abstract: Modified pearl luster pigments for waterborn coating systems, based on a platelet-form substrate coated with metal oxides and, located on the topmost metal oxide layer, a top layer consisting of at least two oxides and/or mixed oxides from the group consisting of silicon dioxide, aluminium oxide, cerium oxide, titanium oxide and zirconium oxide, and on a water-based oligomeric silane system. The oligomeric silane system can be described, for example, by the following approximate structure: [HO[Si(A)(OH)z(CH3)1−zO]a[Si(B)(OH)y(CH3)1−yO]b[Si(E)(OH)w(CH3)1−wO]c[Si(D)(OH)v(CH3)1−vO]dH].
    Type: Grant
    Filed: May 22, 1998
    Date of Patent: January 23, 2001
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung and Huels AG
    Inventors: Ralf Glausch, Nicole Fornoff, Joachim Duschek, Burkhard Standke, Roland Edelmann
  • Patent number: 6165260
    Abstract: A metal substrate having a pearlescent pigment coating thereon in which the pearlescent pigment is an iron oxide-coated interference thickness titanium dioxide platelet and in which the iron content of the combined oxide coatings is at least 1% exhibits color travel.
    Type: Grant
    Filed: March 30, 1999
    Date of Patent: December 26, 2000
    Assignee: Engelhard Corporation
    Inventor: Jeannine M. Gale
  • Patent number: 6129784
    Abstract: A color titanium dioxide coated mica pigment and a coated body applied the pigment which comprise a flaky mica substrate and a composite oxide that is coated onto said mica substrate, and titanium, iron, and nickel are comprised as a metal that is composed of said composite oxide, can improve the color tone of the titanium dioxide coated mica pigment without using an organic substance and a color titanium dioxide coated mica pigment and a coated body applied the pigment which coats a titanium dioxide layer onto said composite oxide can provide a pigment which has color tone flip-flop property that the color tone changes according to the observed direction.
    Type: Grant
    Filed: September 28, 1998
    Date of Patent: October 10, 2000
    Assignee: Shiseido Co., Ltd.
    Inventors: Yukie Ikuta, Asa Kimura
  • Patent number: 6080232
    Abstract: The invention relates to spherical colored pigments having an average particle diameter of less than 10 .mu.m on the basis of an oxide, a mixed oxide or a silicate. The pigments are obtainable by means of spray-pyrolysis technology: a solution containing oxide-forming or silicate-forming metal compounds is converted into an aerosol and the latter is fed, preferably after predrying, to a pyrolysis reactor; the pigment is separated from the pyrolysis gas. The colored pigments according to the invention are suitable for the production of ceramic decorations and for the coloring of plastics, synthetic foils, fibers and also lacquers. By reason of the spherical shape, unusual technical application properties are achieved.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: June 27, 2000
    Assignee: Degussa Aktiengesellschaft
    Inventors: Jorg Sperlich, Ralph Brandes, Hauke Jacobsen, Stipan Katusic, Andreas Schulz
  • Patent number: 6036763
    Abstract: In one embodiment, the present invention relates to a KOH neutralized metatitanic acid mixture containing from about 30% to about 99% by weight metatitanic acid, from about 1% to about 20% by weight of a titanyl compound, and optionally from about 0% to about 55% by weight titanium dioxide, wherein the KOH neutralized metatitanic acid mixture has a pH from about 4 to about 6.5. In another embodiment, the present invention relates to a pigment composition made by combining a KOH neutralized metatitanic acid mixture and at least one guest element precursor, wherein the KOH neutralized metatitanic acid mixture contains metatitanic acid, a titanyl compound, and optionally titanium dioxide, the KOH neutralized metatitanic acid mixture having a pH from about 4 to about 6.5.
    Type: Grant
    Filed: October 16, 1998
    Date of Patent: March 14, 2000
    Assignee: Engelhard Corporation
    Inventors: Thomas V. Edwards, William L. Howell, Jr., Frank A. Mazzella
  • Patent number: 6022404
    Abstract: Surface-modified, pyrogenically produced mixed oxides which contain two or more components of the series SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2, ZrO.sub.2, Fe.sub.2 O.sub.3, Nb.sub.2 O.sub.5, V.sub.2 O.sub.5, WO.sub.3, SnO.sub.2, GeO.sub.2 and have been surface-modified with one to several compounds of the following groups:(a) organosilanes of the type (RO).sub.3 Si(C.sub.n H.sub.2n+1),(b) R'.sub.x (RO).sub.y Si(C.sub.n H.sub.2n+1),(c) X.sub.3 Si(C.sub.n H.sub.2n+1),(d) X.sub.2 (R')Si(C.sub.n H.sub.2n+1),(e) X(R').sub.2 Si(C.sub.n H.sub.2n+1),(f) (RO).sub.3 Si(CH.sub.2).sub.m --R',(g) (R").sub.x (RO).sub.y Si(CH.sub.2).sub.m --R',(h) X.sub.3 Si(CH.sub.2).sub.m --R',(i) (R)X.sub.2 Si(CH.sub.2).sub.m --R',(j) (R).sub.2 X Si(CH.sub.2).sub.m --R',(k) Silazanes of the type ##STR1## (l) Cyclic polysiloxanes, (m) Polysiloxanes or silicone oils.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: February 8, 2000
    Assignee: Degussa Aktiengesellschaft
    Inventors: Manfred Ettlinger, Werner Hartmann, Dieter Kerner, Jurgen Meyer
  • Patent number: 6007616
    Abstract: Disclosed is a system of natural colours consisting of thousands of coloured powders of mineral origin and of materials in or on which pigments have been applied and, afterwards, submitted to at least one thermal treatment and/or irradiation. These natural colours cover the totality of the visible spectrum and offer a great variety of tones, tints and reflections from white to black, including all the rainbow colours. The powders of this system are obtained by mechanical, chemical, thermal and/or physical processes and are used alone or in combination. They are particularly useful to colour materials and, more especially those used in the construction and architectural fields.
    Type: Grant
    Filed: October 8, 1996
    Date of Patent: December 28, 1999
    Inventor: Paulette Tourangeau
  • Patent number: 6004391
    Abstract: Purple pigments according to the invention based on a stovable support material, in particular a glass frit, having a coat applied by coprecipitation of an oxide hydrate of one or more elements from the range comprising Al, Si, Sn, Pb, Ti, Nb, Ta, Sc, Y, La, Ce and Zn and a water-insoluble gold compound or colloidal gold are distinguished from prior art pigments of a similar composition by improved color stability in high temperature firing. The pigments are obtainable in the aqueous phase by coprecipitation of an oxide hydrate and a gold compound or colloidal gold in the presence of a support material and in the absence of a reducing agent. Pigments containing gold compounds assume a purple color on heat treatment or by chemical reduction. Preferred pigments containing gold compounds, which may directly be used as decorative colorants, conveniently develop their color during firing of the decoration.
    Type: Grant
    Filed: November 28, 1997
    Date of Patent: December 21, 1999
    Assignee: Cerdec Aktiengesellschaft Keramische Farben
    Inventors: Hans-Peter Letschert, Jenny Wilfert
  • Patent number: 5993536
    Abstract: A method of decoloring a colored concrete, comprises adding to the colored concrete, a decoloring pigment comprising a titanium oxide pigment, or a titanium oxide pigment and a pigment having a complementary color relative to color of the colored concrete. Such method can decolore the color of the colored concrete residue which attaches to or remains in production facilities in order to return a color thereof to that of an ordinary plain concrete, without works or treatments for washing-out or removing the colored concrete residue which attaches to or remains in the production facilities, in which the works or treatments are required in the case where the production facilities are used for the production of an ordinary plain concrete after the colored concrete has been produced therein, and without works or treatments for purifying a waste water generated upon washing-out or removing the residue and for making the waste water harmless; and a pigment used therefor.
    Type: Grant
    Filed: February 4, 1998
    Date of Patent: November 30, 1999
    Assignee: Toda Kogyo Corporation
    Inventors: Toshiki Matsui, Masaru Isoai, Yasuhiko Fujii, Tomoyuki Imai
  • Patent number: 5985020
    Abstract: Plateletlike titanium dioxide reduction pigment consisting of titanium dioxide, titanium suboxides and, if desired, a further metal oxide or titanium oxynitride, obtainable by solidifying an aqueous solution of a thermally hydrolysable titanium compound on a continuous belt, detaching the resulting coat, coating the resulting titanium dioxide platelets, with or without drying in between, with further titanium dioxide by a wet method, drying and, if desired, calcining the material, and treating the material obtained with a reducing agent in a nonoxidizing gas atmosphere.
    Type: Grant
    Filed: January 9, 1998
    Date of Patent: November 16, 1999
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Stefanie Andes, Sabine Hock, Gunter Brenner, Dieter Bruckner, Andrea Heyland, Matthias Kuntz, Karl Osterried, Gerhard Pfaff, Michael Schmelz