Phosphorus Containing Patents (Class 106/443)
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Patent number: 12110634Abstract: Process for the surface treatment of a titanium dioxide pigment, characterized in that it comprises the following steps: an aqueous suspension of titanium dioxide pigments is formed, in a first step, a layer of alumina phosphate is precipitated on the surface of the pigment, in a second step, a layer of alumina is precipitated over the first layer of alumina phosphate, and in an optional third step, a layer of magnesium oxide is precipitated on the layer of alumina. Titanium dioxide pigments made by the disclosed process and method using said pigments in paper manufacturing are also disclosed.Type: GrantFiled: June 19, 2019Date of Patent: October 8, 2024Assignee: Tronox LLCInventors: Robert McIntyre, Julie Elizabeth Kerrod, Ben Webber, Neil Burniston
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Patent number: 12031754Abstract: A smart sub-ambient radiative cooling composition including TiO2 particles; inorganic particles selected from the group consisting of SiO2, CaCO3, SiC, ZnO, Al2O3, ZnO, and mixtures thereof; fluorescent pigment particles; and a polymer useful for sub-ambient radiative cooling, methods of preparation, and use thereof.Type: GrantFiled: October 29, 2020Date of Patent: July 9, 2024Assignee: THE HONG KONG POLYTECHNIC UNIVERSITYInventors: Jianguo Dai, Xiao Xue, Dangyuan Lei, Meng Qiu, Wei Jin
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Patent number: 11371190Abstract: Process for the surface treatment of a titanium dioxide pigment, characterized in that it comprises the following steps: an aqueous suspension of titanium dioxide pigments is formed, in a first step, a layer of alumina phosphate is precipitated on the surface of the pigment, in a second step, a layer of alumina is precipitated over the first layer of alumina phosphate, and in a third step, a layer of magnesium oxide and alumina is precipitated on the layer of alumina. Also included are titanium dioxide pigments made by the disclosed process and method using said pigments in paper manufacturing.Type: GrantFiled: June 19, 2019Date of Patent: June 28, 2022Assignee: TRONOX LLCInventors: Robert McIntyre, Julie Elizabeth Kerrod, Ben Webber, Neil Burniston
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Patent number: 11022276Abstract: A wavelength conversion device, a manufacturing method thereof, and a related illumination device. The wavelength conversion device comprises a fluorescent powder layer (110) that is successively stacked, a diffuse reflection layer (120), and a high-thermal-conductivity substrate (130). The diffuse reflection layer (120) comprises white scattered particles for scattering the incident light; the high-thermal-conductivity substrate (130) is one of an aluminum nitride substrate, a silicon nitride substrate, a silicon carbide substrate, a boron nitride substrate, and a beryllium oxide substrate. The wavelength conversion device has good reflectivity and thermal stability.Type: GrantFiled: June 7, 2014Date of Patent: June 1, 2021Assignee: Appotronics Corporation LimitedInventors: Yanzheng Xu, Zifeng Tian, Qian Li, Hu Xu
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Patent number: 10636330Abstract: The present invention includes a label, a label sheet and a method for manufacturing the label. The label includes a paper facestock having first and second surfaces and a layer of pressure sensitive adhesive proximal to the second surface. The label can be adhered to a substrate having pre-applied indicia to cover the indicia and the label is opaque enough to prevent the viewing of the covered indicia while matching the color of the substrate.Type: GrantFiled: May 1, 2018Date of Patent: April 28, 2020Assignee: CCL LABEL, INC.Inventors: Alan W. Maule, Brian R. McCarthy, Martin Utz, Andrew J. Conti, Linwood G. Koger, Kenneth J. Wolfe
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Patent number: 10589490Abstract: A laminated polyester film includes a pigment-containing polyester layer A and wax-containing polyester layers B1 and B2 on both sides of the polyester layer A, wherein the film satisfies formulae (I) and (II), and the coefficient of variation of water contact angle for each layer B1 and layer B2 is not less than 0% and not more than 10%, when the contact angle with water is measured 10 times at arbitrary defined positions within the range of 200 mm×200 mm: Wb1>Wa??(I) Wb2>Wa??(II) wherein Wb1 and Wb2 represent the wax content per unit area of the layer B1 and layer B2 respectively, and Wa represents the wax content per unit area of the layer A, and wherein the coefficient of variation represents a value obtained by dividing the standard deviation in values measured 10 times by the average value.Type: GrantFiled: February 19, 2016Date of Patent: March 17, 2020Assignee: Toray Industries, Inc.Inventors: Mitsutaka Sakamoto, Mayumi Nakamura, Isao Manabe, Yasushi Takada, Satoshi Nakamura
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Patent number: 10131792Abstract: A method for producing surface-treated particles includes surface treatment of titanium dioxide, barium sulfate, zinc sulfide or lithopone particles, and to mixtures of the particles with alkoxylated siloxanes and phthalate-free plasticizers for improving dispersion in plastics.Type: GrantFiled: March 13, 2015Date of Patent: November 20, 2018Assignee: Huntsman P&A Germany GmbHInventors: Petra Fritzen, Bernd Rohe, Jörg Hocken
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Patent number: 9505022Abstract: A method is provided for the wet surface treatment of titanium dioxide, in order to produce durable universal grade titanium dioxide rutile pigment with superior optical properties. The method is characterized in that, a hydrous zirconia and silica composite layer is co-precipitated at acidic pH. Then, a layer of alumina is precipitated under a range of pH required for complete precipitation above the initial composite layer. The upper pH limit of the slurry during the alumina precipitation can be well controlled to avoid any chance for dissolution or damage of the composite zirconia-silica layer formed. Zirconia-silica composite layers and alumina thus precipitated advantageously improve the competence of the layers formed over a TiO2 base and provide improved durability with superior optical performance. The total surface treatment cycle time and chemicals used are minimal compared to conventional methods. Improvements in throughput and washing efficiency are also realized.Type: GrantFiled: December 4, 2012Date of Patent: November 29, 2016Assignee: The National Titanium Dioxide Co. Ltd. (Cristal)Inventors: Ahmed Yasir Vakayil, Ahmad I. Jomha
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Patent number: 9056791Abstract: A composition comprising cement and nano-sized crystalline particles of boehmite alumina or nano-sized crystalline particles of boehmite alumina which have been modified by the inclusion of silicon oxide, calcium oxide, or magnesium oxide. The boehmite alumina has an average crystallite size from about 2 nm to about 80 nm and a content of non-crystalline alumina of less than about 25 mol percent based on total aluminum.Type: GrantFiled: February 12, 2014Date of Patent: June 16, 2015Assignee: Sasol North America, Inc.Inventors: Steven Baxter, Jeff Fenton, Reiner Glockler
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Patent number: 8845803Abstract: The invention relates to a method for the surface treatment of inorganic pigment particles with agglomerates of fine primary particles or single crystals of inorganic compounds, particularly of oxides or sulphates. The method is characterized in that the inorganic compounds are first precipitated from an aqueous solution under suitable pH conditions in a separate vessel in the form of fluffily structured agglomerates and/or single crystals. The precipitation product is subsequently added to an aqueous suspension of inorganic pigment particles. The method is particularly suitable for the surface treatment of titanium dioxide particles, in order to achieve high hiding power or high opacity when used in emulsion paints or laminates.Type: GrantFiled: June 28, 2013Date of Patent: September 30, 2014Assignee: Kronos International, Inc.Inventors: Volker Juergens, Alexander Breyder, Frank Mersch, Siegfried Bluemel, Volker Schmitt
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Publication number: 20140163151Abstract: AlP composite materials comprise an AlP aggregate core, and a shell disposed partially or entirely over the core and formed from a pigment material, e.g., TiO2, having an index of refraction greater than the core, providing an overall index or refraction greater than the core and suited for use as a pigment replacement or extender. The AlP core comprises amorphous AlP, crystalline AlP, or a combination thereof, and can have an average particle size of less than about 30 microns. The TiO2 can have an average grain size less than about 10 microns. The shell can have a layer thickness that is at least about 0.0001 microns. The shell is bonded to the core by a reaction between functional groups of the shell and core. The AlP composite material can be engineered to provide properties in addition to brightness for use as a pigment such as anticorrosion and/or antimicrobial protection.Type: ApplicationFiled: December 7, 2012Publication date: June 12, 2014Applicant: Bunge Amorphic Solutions LLCInventors: Ronald James Lewarchik, Raymond E. Foscante
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Patent number: 8475582Abstract: The present invention relates to a process for making a titanium dioxide pigment consisting of titanium dioxide and single layer of inorganic surface treatment consisting of aluminum phosphate wherein the pigment is characterized by and isoelectric point which is greater than pH 6 and a negative zeta potential of at a pH of 7.5 or more.Type: GrantFiled: March 6, 2008Date of Patent: July 2, 2013Assignee: E I du Pont de Nemours and CompanyInventors: Erik Shepard Thiele, John Davis Bolt, Scott Richard Mehr
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Publication number: 20130133552Abstract: The present invention relates to a process for making a titanium dioxide pigment having consisting of titanium dioxide and single layer of inorganic surface treatment consisting of aluminum phosphate wherein the pigment is characterized by and isoelectric point which is greater than pH 6 and a negative zeta potential of at a pH of 7.5 or more.Type: ApplicationFiled: January 24, 2013Publication date: May 30, 2013Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: E I DU PONT DE NEMOURS AND COMPANY
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Publication number: 20130040130Abstract: A pigment mixture comprising (a) pigment particles, (b) colloidal spacer particles dispersed on surfaces of the pigment particles, and (c) carrier particles, wherein the pigment particles with colloidal spacer particles are dispersed on surfaces of the carrier particles. A pigment mixture of titanium dioxide pigment particles having colloidal silica spacer particles on surfaces of the titanium dioxide, the titanium dioxide and colloidal silica attached to surfaces of diatomaceous earth carrier particles, provides improved optical efficiency of the pigment and improved retention in a paper fiber matrix.Type: ApplicationFiled: August 9, 2011Publication date: February 14, 2013Inventors: Neil Burniston, Robert Burniston
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Patent number: 8158270Abstract: Under the presence of at least one out of copper, manganese, nickel, cobalt, iron, zinc, and compounds thereof, a tetravalent titanium salt solution and a basic solution are reacted together to form a hydroxide of titanium and the above metal, and then the titanium hydroxide is peroxidated with an oxidizing agent to manufacture an aqueous liquid or dispersion having therein titanium oxide fine particles having peroxy groups; by using this alone to form a coating film adjacent to a coating film of an organic dye or pigment, or using this to form a coating film together with an organic dye or pigment, a drop in decorativeness of color due to fading or discoloration of a coating material, a printed article, a building material, a fiber, an organic polymer resin product or the like can be prevented, and moreover surface anti-soiling and hydrophilic properties can be realized.Type: GrantFiled: August 24, 2011Date of Patent: April 17, 2012Assignee: Sustainable Titania Technology IncorporatedInventors: Shiro Ogata, Yoshimitsu Matsui
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Patent number: 8025976Abstract: Under the presence of at least one out of copper, manganese, nickel, cobalt, iron, zinc, and compounds thereof, a tetravalent titanium salt solution and a basic solution are reacted together to form a hydroxide of titanium and the above metal, and then the titanium hydroxide is peroxidated with an oxidizing agent to manufacture an aqueous liquid or dispersion having therein titanium oxide fine particles having peroxy groups; by using this alone to form a coating film adjacent to a coating film of an organic dye or pigment, or using this to form a coating film together with an organic dye or pigment, a drop in decorativeness of color due to fading or discoloration of a coating material, a printed article, a building material, a fiber, an organic polymer resin product or the like can be prevented, and moreover surface anti-soiling and hydrophilic properties can be realized.Type: GrantFiled: November 4, 2003Date of Patent: September 27, 2011Assignee: Sustainable Titania Technology IncorporatedInventors: Shiro Ogata, Yoshimitsu Matsui
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Patent number: 7988780Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.Type: GrantFiled: July 26, 2010Date of Patent: August 2, 2011Assignee: Kronos International IncInventors: Siegfried Bluemel, Lydia Drews-Nicolai
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Patent number: 7951855Abstract: What is disclosed is a plurality of prepaints which are used in any combination to produce base paints and/or colored paints of varying end-use application characteristics. Additionally, a mobile paint factory for producing a plurality of lines of architectural coatings from a plurality of prepaints en route to and/or at various locations is disclosed. The mobile paint factory may include a vehicle having a paint production system and a paint mixer located thereon. Furthermore, a method of producing a plurality of lines of user-selected architectural coatings from a plurality of prepaints en route to and/or at various locations is disclosed. The method may include: providing a mobile paint factory; prompting a user to select through the paint production system an interior or exterior application environment, a paint sheen, and a paint quality; automatically dispensing predetermined amounts of appropriate prepaints; and agitating the dispensed prepaints.Type: GrantFiled: December 18, 2008Date of Patent: May 31, 2011Assignee: Microblend Technologies, Inc.Inventors: Daniel K. Trevino, III, Mel Sauder, Randall L. Hughes, David C. Philbrook, C. Daniel McClain
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Patent number: 7919546Abstract: What is disclosed is a plurality of prepaints which are used in any combination to produce base paints and/or colored paints of varying end-use application characteristics. Additionally, a mobile-paint factory for producing a plurality of lines of architectural coatings from a plurality of prepaints en route to and/or at various locations is disclosed. The mobile paint factory may include a vehicle having a paint production system and a paint mixer located thereon. Furthermore, a method of producing a plurality of lines of user-selected architectural coatings from a plurality of prepaints en route to and/or at various locations is disclosed. The method may include: providing a mobile paint factory; prompting a user to select through the paint production system an interior or exterior application environment, a paint sheen, and a paint quality; automatically dispensing predetermined amounts of appropriate prepaints; and agitating the dispensed prepaints.Type: GrantFiled: August 15, 2008Date of Patent: April 5, 2011Assignee: Microblend Technologies, Inc.Inventors: Daniel K. Trevino, III, Mel Sauder, Randall L. Hughes, David C. Philbrook, C. Daniel McClain, Mel Sauder, legal representative
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Patent number: 7905953Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.Type: GrantFiled: January 30, 2007Date of Patent: March 15, 2011Assignee: Kronos International IncInventors: Siegfried Bluemel, Lydia Drews-Nicolai
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Patent number: 7842131Abstract: The invention relates to a rutile titanium dioxide pigment for use in decorative laminating papers that yields higher opacity of the papers compared to the prior art, as well as a method for its manufacture. The pigment displays a surface coating that contains aluminum phosphate, aluminum oxide, silicon oxide and titanium oxide. The silicon oxide is precipitated in fluffy form. The coated particles display a BET value of at least 15 m2/g. The manufacturing method is characterized in that an aluminum and a phosphorus component are first added to a TiO2 suspension. Thereafter, an alkaline silicon component, an acid-reacting titanium component and, optionally, a further pH-regulating component are added, the pH value being set in the range from 4 to 9 in this context.Type: GrantFiled: January 30, 2007Date of Patent: November 30, 2010Assignee: Kronos International IncInventors: Siegfried Blümel, Lydia Drews-Nicolai, Volker Jürgens, Volker Schmitt
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Patent number: 7815727Abstract: A thermoplastic resin composition which comprises (A) 40 to 98 mass % thermoplastic resin and (B) 60 to 2 mass % titanium oxide particles whose surface has been coated with a hydrous oxide and/or oxide of at least one metal selected from the group consisting of aluminum, silicon, zirconium, tin, cerium, titanium, and zinc, wherein the titanium oxide particles contain 80 to 97 mass %, excluding 97 mass %, titanium oxide ingredient and have total content of alkali metal cations and alkaline earth metal cations extractable with pure water of 120 mass ppm or lower. The resin composition is excellent in reflectance and thermal stability in residence during molding into large products.Type: GrantFiled: November 5, 2003Date of Patent: October 19, 2010Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hiroshi Kawato, Yoshihiko Horio
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Patent number: 7763110Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.Type: GrantFiled: January 30, 2007Date of Patent: July 27, 2010Assignee: Kronos International IncInventors: Siegfried Bluemel, Lydia Drews-Nicolai
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Publication number: 20100180801Abstract: The present invention provides white pigments of crystalline aluminium orthophosphate dihydrate, their use as white pigment in paints and also processes for their production.Type: ApplicationFiled: June 28, 2008Publication date: July 22, 2010Applicant: BK Giulini GmbHInventors: Henrike Thauern, Michael Schmitt, Thomas Staffel
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Patent number: 7686882Abstract: In various embodiments, methods and compositions are provided comprising titanium dioxide and silica spacers having improved light stability for use in paper, plastic and paints.Type: GrantFiled: September 7, 2007Date of Patent: March 30, 2010Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Duen-Wh Hua, Fu-Chu Wen
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Publication number: 20090158963Abstract: A method for coloring powders is provided that includes mixing a base powder and non-incorporated pigments. A colored powder composition having a base powder particle and at least a partial shell of non-incorporated pigments about the base powder particle is also provided. Articles having a coating of the colored powder composition are also provided.Type: ApplicationFiled: October 18, 2006Publication date: June 25, 2009Applicant: Valspar Sourcing, Inc.Inventors: William G. O'Dell, Larry B. Brandenburger, Steven D. Johnson, Judith L. Bourdeau
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Patent number: 7503970Abstract: A particulate metal oxide having the mean length of the primary particles in the range from 50 to 90 nm, the mean width of the primary particles in the range from 5 to 20 nm, and the median volume particle diameter of the secondary particles is less than 45 nm. The metal oxide can be used in a sunscreen product that exhibits both effective UV protection and improved transparency.Type: GrantFiled: April 13, 2007Date of Patent: March 17, 2009Assignee: Croda International PLCInventors: Graham Paul Dransfield, Susan Cutter, Phillip Laurence Lyth
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Publication number: 20090004390Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).Type: ApplicationFiled: June 28, 2007Publication date: January 1, 2009Inventors: Jerome David Smith, Pedro A. Jimenez, Tony Jackson
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Publication number: 20080308009Abstract: The present disclosure relates to a process for making a titanium dioxide pigment comprising a thermally treated titanium dioxide having an inorganic surface treatment of comprising a source of phosphorus, typically phosphoric acid, and a source of aluminum, typically sodium aluminate, wherein the pigment is characterized by an isoelectric point which is greater than pH 6 and a negative zeta potential of at least 20 mV at a pH of 7.5 or more and wherein the pigment has improved light fastness.Type: ApplicationFiled: August 15, 2008Publication date: December 18, 2008Inventor: Erik Shepard Thiele
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Publication number: 20080160267Abstract: The present invention relates to a process for making a titanium dioxide pigment having consisting of titanium dioxide and single layer of inorganic surface treatment consisting of aluminum phosphate wherein the pigment is characterized by and isoelectric point which is greater than pH 6 and a negative zeta potential of at a pH of 7.5 or more.Type: ApplicationFiled: March 6, 2008Publication date: July 3, 2008Inventors: Erik Shepard Thiele, John Davis Bolt, Scott Richard Mehr
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Patent number: 7390355Abstract: A dispersion containing zinc oxide particles having a dispersion particle size of (i) median volume particle diameter in the range from 70 to 130 nm, (ii) less than 16% by volume of particles having a volume diameter of less than 35 nm below the median volume particle diameter, and (iii) more than 84% by volume of particles having a volume diameter of less than 57 nm above the median volume particle diameter. The zinc oxide dispersion can be used in a sunscreen product that exhibits both effective UV protection and improved transparency. The zinc oxide is particularly suitable for use in combination with transparent titanium dioxide.Type: GrantFiled: June 10, 2004Date of Patent: June 24, 2008Assignee: Croda International PlcInventor: Philip Laurence Lyth
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Patent number: 7371276Abstract: The titanium dioxide pigment of the present invention contains an anatase type crystal in an amount of 98-100% and has an average particle diameter of 0.2-0.4 ?m and a whiteness of 95-97 in terms of L value of linseed oil. The titanium dioxide pigment of the present invention has characteristics peculiar to anatase type, for example, optical characteristics such as bluish color tone and physical characteristics such as low hardness, and furthermore has high opacity which is not possessed by conventional anatase type titanium oxide pigments.Type: GrantFiled: August 6, 2003Date of Patent: May 13, 2008Assignee: Ishihara Sangyo Kaisha, Ltd.Inventors: Hideo Takahashi, Toshihiko Akamatsu, Kazuhiro Tominaga, Taku Katou, Yoshio Nagai, Yoshitaka Muraki, Yukako Ota
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Patent number: 7288146Abstract: A coated titanium dioxide pigment with good opacity and simultaneously good retention for use in decorative laminating paper characterized by a surface coating containing aluminum oxide phosphate and attached hollow bodies, e.g., hollow microbodies. A manufacturing method is characterized in that an aluminum containing component and a phosphorus containing component are first added to a TiO2 suspension, during which time the pH value does not drop below 10. The hollow bodies are subsequently added, followed by addition of at least one acidic component, as a result of which the pH value of the suspension is lowered to the range from about 4 to 9. In an alternative embodiment of the method, the suspension has a pH value of under 4 at the time of addition of the aluminum containing component and a phosphorus containing component.Type: GrantFiled: February 23, 2007Date of Patent: October 30, 2007Assignee: Kronos International, Inc.Inventors: Lydia Drews Nicolai, Siegfried Blümel
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Patent number: 7285162Abstract: In various embodiments, methods and compositions are provided comprising titanium dioxide and silica spacers having improved light stability for use in paper, plastic and paints.Type: GrantFiled: November 30, 2004Date of Patent: October 23, 2007Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Duen-Wh Hua, Fu-Chu Wen
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Publication number: 20070215005Abstract: A coated titanium dioxide pigment with good opacity and simultaneously good retention for use in decorative laminating paper characterized by a surface coating containing aluminium oxide phosphate and attached hollow bodies, e.g., hollow microbodies. A manufacturing method is characterized in that an aluminium containing component and a phosphorus containing component are first added to a TiO2 suspension, during which time the pH value does not drop below 10. The hollow bodies are subsequently added, followed by addition of at least one acidic component, as a result of which the pH value of the suspension is lowered to the range from about 4 to 9. In an alternative embodiment of the method, the suspension has a pH value of under 4 at the time of addition of the aluminium containing component and a phosphorus containing component.Type: ApplicationFiled: February 23, 2007Publication date: September 20, 2007Inventors: Lydia Drews Nicolai, Siegfried Blumel
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Patent number: 7264672Abstract: A process for producing an improved titanium dioxide pigment composite is provided, as are particles produced thereby. The process comprises producing a slurry comprising titanium dioxide particles, leaching alumina from the surface of the titanium dioxide particles in the presence of a soluble phosphate and precipitating aluminum phosphate from the slurry onto the surface of the titanium dioxide particles thereby forming a uniform coating of aluminum phosphate on the surfaces of the titanium dioxide particles. An anionic poly-electrolyte can be added to the resulting slurry. The slurry can then be treated such that the anionic poly-electrolyte forms an additional coating on the aluminum phosphate-coated titanium dioxide particles.Type: GrantFiled: October 31, 2006Date of Patent: September 4, 2007Assignee: National Titanium Dioxide Co. Ltd. (Cristal)Inventors: Fadi Mohammed Saeed Trabzuni, Chathangat Cheroolil Gopalkrishnan
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Publication number: 20070175363Abstract: The invention relates to a rutile titanium dioxide pigment for use in decorative laminating papers that yields higher opacity of the papers compared to the prior art, as well as a method for its manufacture. The pigment displays a surface coating that contains aluminium phosphate, aluminium oxide, silicon oxide and titanium oxide. The silicon oxide is precipitated in fluffy form. The coated particles display a BET value of at least 15 m2/g. The manufacturing method is characterized in that an aluminium and a phosphorus component are first added to a TiO2 suspension. Thereafter, an alkaline silicon component, an acid-reacting titanium component and, optionally, a further pH-regulating component are added, the pH value being set in the range from 4 to 9 in this context.Type: ApplicationFiled: January 30, 2007Publication date: August 2, 2007Applicant: Kronos International Inc.Inventors: Siegfried Blumel, Lydia Drews-Nicolai, Volker Jurgens, Volker Schmitt
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Patent number: 7250080Abstract: An improved process for making an organosilicon compound surface-treated titanium dioxide material, comprising (a) forming a mixture of the titanium dioxide material in water, (b) wet milling the mixture, (c) adjusting the pH of the slurry resulting from step (b) to between about 5.0 and about 8.5, (d) after step (c), removing the titanium dioxide material from the mixture by vacuum or pressure filtration, (e) after step (d), washing the titanium dioxide material so removed, (f) after step (e), converting the washed titanium dioxide material to a fluid dispersion having a pH of from about 3.5 to less than about 7 via addition of a fluidizing agent comprising a water-soluble monoprotic acid, (g) after, or concurrently with, step (f), adding to the resulting dispersion of titanium dioxide material an organosilicon compound, with mixing, and (h) spray drying the dispersion of the washed titanium dioxide material resulting from step (g) to yield a dry titanium dioxide pigment powder.Type: GrantFiled: September 6, 2006Date of Patent: July 31, 2007Assignee: Tronox LLCInventors: Daniel H. Craig, Mark D. Westmeyer
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Patent number: 7220305Abstract: A particulate metal oxide having the mean length of the primary particles in the range from 50 to 90 nm, the mean width of the primary particles in the range from 5 to 20 nm, and the median volume particle diameter of the secondary particles is less than 45 nm. The metal oxide can be used in a sunscreen product that exhibits both effective UV protection and improved transparency.Type: GrantFiled: November 4, 2005Date of Patent: May 22, 2007Assignee: Croda International PLCInventors: Graham Paul Dransfield, Susan Cutter, Phillip Lawrence Lyth
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Patent number: 7160374Abstract: A flaky pigment excellent in leafing properties and in adhesion between pigment particles and a coating (resin) was obtained by coating the surface of a flaky pigment with a coupling agent and a phosphate having a perfluoroalkly group or a silane compound. Accordingly, the flaky pigment is excellent as a pigment for coating or printing ink of which brightness and durability are required.Type: GrantFiled: February 15, 2001Date of Patent: January 9, 2007Assignee: Merck Patent GmbHInventors: Eiji Umehara, Koushiro Kunii
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Patent number: 7147702Abstract: The invention relates to a method for the surface treatment of a titanium dioxide that leads to pigments with improved retention and improved opacity, where consistently high opacity can be obtained using less pigment. The method is characterised in that an aluminium component and a phosphorus component are first added to a TiO2 suspension, during which process its pH value does not drop below 10. The pH value of the suspension is subsequently lowered to below 9 by adding an acid component. The pigment produced by the method according to the invention is eminently suited to use in decorative laminating paper.Type: GrantFiled: July 12, 2004Date of Patent: December 12, 2006Assignee: Kronos InternationalInventors: Lydia Drews-Nicolai, Siegfried Bluemel, Volker Jürgens, Volker Schmitt
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Patent number: 7138010Abstract: The invention is a pigment comprising titanium dioxide and an amino phosphoryl compound. The pigment of the invention imparts improved physical qualities, such as improved lacing resistance and dispersion, when incorporated into polymers.Type: GrantFiled: December 12, 2005Date of Patent: November 21, 2006Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Modasser El-Shoubary, M. Kamal Akhtar
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Patent number: 7132470Abstract: The present invention is directed to the provision of premixed aqueous compositions which are used to provide a paint composition of varying finish characteristics at the point of sale. Thus, the merchant distributing the paint composition made from the subject premixed compositions need only maintain inventory of four compositions. The particular compositions which are the subject of the invention exhibit stable characteristics during storage in their respective reservoirs. The compositions include a pigment composition, a dispersant thickening agent, a high resin content binder, and a low resin content binder. The compositions are combined in differing amounts to produce paint compositions being suitable for either interior or exterior use and having differing sheens, quality levels, and color bases.Type: GrantFiled: September 15, 2003Date of Patent: November 7, 2006Assignee: Coatings Management Systems, Inc.Inventors: C. Daniel McClain, Randall L. Hughes
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Patent number: 7065429Abstract: The present invention is directed to the provision of premixed aqueous compositions which are used to provide a paint composition of varying finish characteristics at the point of sale. Thus, the merchant distributing the paint composition made from the subject premixed compositions need only maintain inventory of four compositions. The particular compositions which are the subject of the invention exhibit stable characteristics during storage in their respective reservoirs. The compositions include a pigment composition, a dispersant thickening agent, a high resin content binder, and a low resin content binder. The compositions are combined in differing amounts to produce paint compositions being suitable for either interior or exterior use and having differing sheens, quality levels, and color bases.Type: GrantFiled: November 1, 2002Date of Patent: June 20, 2006Assignee: MicroBlend Technologies, Inc.Inventors: C. Daniel McClain, Randall L. Hughes
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Patent number: 6962622Abstract: The invention relates to a titanium dioxide pigment mixture comprising a pigment having high greying stability (pigment type A) and a pigment having increased SiO2 and Al2O3 content in flaky precipitation (pigment type B). Said mixture provides, for example in paper, a high level of opacity for sufficient greying stability. If necessary, the light-fastness of the paper can be further increased by means of known production-conditioned measures on pigment type B.Type: GrantFiled: March 12, 2002Date of Patent: November 8, 2005Assignee: Kronos Titan GmbHInventors: Jürgen Bender, Siegfried Blümel, Volker Schmitt, Brigitte Vielhaber-Kirsch
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Publication number: 20040025749Abstract: A method and material for improved TiO2 pigment for paper and laminates is described. Phosphorous, titanium, and aluminum compounds are successively added to a TiO2 pigment suspension. Resulting pigments show improved greying resistance and hiding power over prior art pigments, and show improved results as pigments in tests of paper and laminates.Type: ApplicationFiled: August 8, 2003Publication date: February 12, 2004Applicant: Kronos International Inc.Inventors: Lydia Drews-Nicolai, Siegfried Bluemel, Lothar Elfenthal, Volker Schmitt
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Publication number: 20030181329Abstract: A method of producing composite particles of titanium dioxide and a compound inactive as a photocatalyst, comprising the steps of preparing a water based slurry of pH 3 to 5 comprising titanium dioxide, preparing a water based solution comprising a compound inactive as a photocatalyst, and reacting the slurry and the water based solution together at a pH within a range from 4 to 10 is provided, together with highly active photocatalyst particles produced using such a method, and potential uses of such photocatalyst particles.Type: ApplicationFiled: December 19, 2002Publication date: September 25, 2003Applicant: SHOWA DENKO K.K.Inventors: Jun Tanaka, Masayuki Sanbayashi, Yoshinori Ueyoshi
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Patent number: 6620508Abstract: Firstly, a powder matrix is kept in a fluent state, said powder matrix consisting of a first oxide having an absorbed water amount of 0.1 to 50%, an averaged particle diameter of 0.005 to 0.5 &mgr;m and a surface hydroxyl group number of 0.1 to 25 &mgr;mol/m2. Then, one or both of a halide and an alkoxide including metal or semi-metal identical with or different from the metal or semi-metal constituting said first oxide is allowed to contact with said powder matrix kept in the fluent state, by means of an inert carrier gas, and then they are heated at a temperature of from 25 to 800° C., to thereby coat said powder matrix by a coating layer consisting of a second oxide. Further, a reaction by-product consisting of one or both of a hydrogen halide or an alcohol generated by said contacting is heated at a temperature of from 200 to 1000° C. within the inert carrier gas to thereby eliminate the reaction by-product.Type: GrantFiled: September 25, 2001Date of Patent: September 16, 2003Assignee: Nippon Aerosil Co., Ltd.Inventors: Akira Inoue, Eiji Komai, Takeyoshi Shibasaki, Hirokuni Shirono
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Patent number: 6616746Abstract: The titanium dioxide pigment of this invention has on the titanium dioxide particle surface a coating layer comprising a polyhydric alcohol and a hydrolysis product of an aminosilane compound, has a dispersibility of not more than 20 kg/cm2 as judged in terms of resin pressure increase, and is excellent in hydrophobicity and dispersibility. The pigment is useful as a coloring agent for plastics which requires good lacing resistance and dispersibility.Type: GrantFiled: June 13, 2002Date of Patent: September 9, 2003Assignee: Ishihara Sangyo Kaisha, Ltd.Inventors: Hideo Takahashi, Eiji Yamada, Toshihiko Akamatsu, Takeshi Fujimura
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Patent number: 6613832Abstract: Sets of fluid premixes useful for adhesives and caulks are provided. Also provided are methods of providing adhesive lines and a caulk lines using the sets of premixes. Further provided are ranges of adhesives and caulks based on the adhesive and caulk lines. Utilizing these methods the manufacturer, seller, or user can to adjust the adhesive or caulk at the point of manufacture, sale, or use to suit the processing and end-use conditions, in addition to the other benefits offered by delayed product differentiation.Type: GrantFiled: February 16, 2001Date of Patent: September 2, 2003Assignee: Rohm and Haas CompanyInventors: John Michael Friel, John William Hook, III, Jerry William Washel, Dennis Paul Lorah, James Alexander Costanzo