Aluminum Compound Or Silicon Containing Patents (Class 106/442)
  • Patent number: 10662335
    Abstract: The invention relates to the manufacture of composite pigments containing aluminum hydroxide, and their use for improving the pigment light-scattering efficiency in coatings, plastics, paper and laminates. The composite pigment particles contain pigment particles such as titanium dioxide and precipitated aluminum hydroxide and are manufactured by in-situ precipitation of aluminum hydroxide in an aqueous pigment particle suspension. Use of the composite pigment particles according to the invention, based on titanium dioxide, permits savings on pigment with little or no loss of optical properties. Alternatively, if the pigment content remains unchanged, it is also possible to achieve better optical properties.
    Type: Grant
    Filed: March 10, 2016
    Date of Patent: May 26, 2020
    Inventors: Frank Mersch, Uwe Wilkenhoener
  • Patent number: 10457812
    Abstract: Alpha-Alumina flakes having a particle thickness of 550-1000 nm, a D50-value of 15-30 ?m, a D90-value of 30-45 ?m and a D10-value of ?9.0 ?m. Use of the alumina flakes in varnishes, paints, automotive coatings printing inks, masterbatches, plastics and cosmetic formulations. Also, use of the alumina flakes as a substrate for effect pigments and in organic dyes.
    Type: Grant
    Filed: April 25, 2014
    Date of Patent: October 29, 2019
    Assignee: Merck Patent GmbH
    Inventors: Ryuta Suzuki, Gerhard Pfaff, Sabine Schoen, Fumiko Sasaki, Satoru Kobayashi, Koshiro Kunii, Yuji Takenaka, Katsuhisa Nitta
  • Patent number: 10259943
    Abstract: Disclosed is a method for manufacturing plate ?-alumina pearlescent pigments and nano-metal coating pearlescent pigments with a large aspect ratio, having excellent reflectivity and capable of expressing various colors.
    Type: Grant
    Filed: February 14, 2014
    Date of Patent: April 16, 2019
    Assignee: CQV CO., LTD.
    Inventors: Myung-Ho Jung, Kyung-Jun Han, Jae-Il Jeong, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang, Jae-Soo Choi, Beom-Jae Lee, Jung-Min Lee
  • Patent number: 9551817
    Abstract: The present invention relates to composite polymeric particles for use as infrared reflectors in optical bandpass applications.
    Type: Grant
    Filed: December 16, 2010
    Date of Patent: January 24, 2017
    Assignee: ROHM AND HAAS COMPANY
    Inventors: Edward Greer, Brian Einsla, Susan Fitzwater
  • Patent number: 9512303
    Abstract: PLA-containing materials, and building components containing such materials, include: polylactic acid (PLA); one or more inorganic pigments; and one or more stabilizers that includes one or more carbodiimide groups.
    Type: Grant
    Filed: August 5, 2014
    Date of Patent: December 6, 2016
    Assignee: Andersen Corporation
    Inventors: Michael Deaner, Patrick Gronlund, Larry Morelli, Stacha Reed
  • Patent number: 9464200
    Abstract: A pigment for ink-jet recording contains a porous particle, a sealing agent, and an inorganic pigment layer containing an inorganic pigment. The sealing agent is arranged in a pore opening of the porous particle. The inorganic pigment layer is formed on the surface of the porous particle.
    Type: Grant
    Filed: February 26, 2015
    Date of Patent: October 11, 2016
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Jun Sakai, Masayoshi Fuji, Chika Takai
  • Patent number: 9096762
    Abstract: The invention relates to a method for the surface treatment of inorganic pigment particles with agglomerates of fine primary particles or single crystals of inorganic compounds, particularly of oxides or sulphates. The method is characterized in that the inorganic compounds are first precipitated from an aqueous solution under suitable pH conditions in a separate vessel in the form of fluffily structured agglomerates and/or single crystals. The precipitation product is subsequently added to an aqueous suspension of inorganic pigment particles. The method is particularly suitable for the surface treatment of titanium dioxide particles, in order to achieve high hiding power or high opacity when used in emulsion paints or laminates.
    Type: Grant
    Filed: August 1, 2014
    Date of Patent: August 4, 2015
    Assignee: Kronos International, Inc.
    Inventors: Volker Juergens, Alexander Breyder, Frank Mersch, Siegfried Bluemel, Volker Schmitt
  • Patent number: 8932512
    Abstract: The present invention relates to polymers comprising absorption pigments, which are distinguished by the fact that they have high absorption in the near IR region, and to the use thereof, in particular in thermoforming and in IR light welding.
    Type: Grant
    Filed: July 26, 2006
    Date of Patent: January 13, 2015
    Assignee: Merck Patent GmbH
    Inventors: Gerhard Edler, Rainer Linzmeier
  • Publication number: 20140373753
    Abstract: The present invention relates to polyoxometalate-coated alumina trihydrate dispersants prepared by combining a polyaluminum chloride having certain characteristics with alumina trihydrate particles. Such dispersants are useful for forming cationic alumina trihydrate slurries, which can be mixed with titanium dioxide to produce stable cationic slurry blends useful in paper, paper-board, and paint (coatings) applications. The dispersants are also useful for preparing cationic titanium dioxide slurries.
    Type: Application
    Filed: May 15, 2012
    Publication date: December 25, 2014
    Applicants: ALCLEAR LLC, ALCLEAR LLC
    Inventors: Kenneth Cornick, Caryn Seidman-Becker
  • Publication number: 20140338566
    Abstract: The invention relates to a method for the surface treatment of inorganic pigment particles with agglomerates of fine primary particles or single crystals of inorganic compounds, particularly of oxides or sulphates. The method is characterized in that the inorganic compounds are first precipitated from an aqueous solution under suitable pH conditions in a separate vessel in the form of fluffily structured agglomerates and/or single crystals. The precipitation product is subsequently added to an aqueous suspension of inorganic pigment particles. The method is particularly suitable for the surface treatment of titanium dioxide particles, in order to achieve high hiding power or high opacity when used in emulsion paints or laminates.
    Type: Application
    Filed: August 1, 2014
    Publication date: November 20, 2014
    Applicant: Kronos International, Inc.
    Inventors: Volker Juergens, Alexander Breyder, Frank Mersch, Siegfried Bluemel, Volker Schmitt
  • Patent number: 8876965
    Abstract: A composite comprising a silicate material, such as, a sodium aluminosilicate, and titanium dioxide disposed on the surface thereof is disclosed, together with formulations comprising the composite and methods for preparing the same.
    Type: Grant
    Filed: March 11, 2013
    Date of Patent: November 4, 2014
    Assignee: J.M. Huber Corporation
    Inventors: Hilary Ellen Matthews, Ronald Louis Romer
  • Patent number: 8858701
    Abstract: The invention relates to the manufacture of pigment-containing composite pigment particles containing titanium dioxide pigment particles and at least one inorganic and/or organic filler as extender, as well as calcium carbonate that is precipitated in the process, and their use for improving the pigment light-scattering efficiency in coatings, plastics and laminates. The extender is preferably selected from Ca-, Ca—Mg- and Mg-carbonates, natural and synthetic silicon dioxide and oxides and are manufactured in a combined process of precipitation and dispersion. Depending on the combination selected, the use of composite pigment particles according to the invention permits pigment savings with little or no loss of optical properties. Alternatively, if the pigment content remains unchanged, it is possible to achieve better values, e.g. for tinting strength. Particularly, a part or the whole TiO2 quantity in the user system can be replaced by the composite pigment particles according to the invention.
    Type: Grant
    Filed: June 28, 2013
    Date of Patent: October 14, 2014
    Assignee: Kronos International, Inc.
    Inventors: Uwe Wilkenhoener, Frank Mersch
  • Patent number: 8845803
    Abstract: The invention relates to a method for the surface treatment of inorganic pigment particles with agglomerates of fine primary particles or single crystals of inorganic compounds, particularly of oxides or sulphates. The method is characterized in that the inorganic compounds are first precipitated from an aqueous solution under suitable pH conditions in a separate vessel in the form of fluffily structured agglomerates and/or single crystals. The precipitation product is subsequently added to an aqueous suspension of inorganic pigment particles. The method is particularly suitable for the surface treatment of titanium dioxide particles, in order to achieve high hiding power or high opacity when used in emulsion paints or laminates.
    Type: Grant
    Filed: June 28, 2013
    Date of Patent: September 30, 2014
    Assignee: Kronos International, Inc.
    Inventors: Volker Juergens, Alexander Breyder, Frank Mersch, Siegfried Bluemel, Volker Schmitt
  • Patent number: 8840719
    Abstract: The invention provides a coated inorganic oxide pigment. The inventive coated inorganic oxide pigment comprises an inorganic oxide base pigment, a porous inorganic coating formed on the base pigment, and a dense inorganic coating formed on the base pigment. The porous inorganic coating and dense inorganic coating each consist essentially of a material selected from the group consisting of silica and alumina. In another aspect, the invention provides a method of manufacturing a coated inorganic oxide pigment. In yet another aspect, the invention provides a polymer composition comprising a base polymer, and a coated inorganic oxide pigment admixed with the base polymer.
    Type: Grant
    Filed: March 9, 2011
    Date of Patent: September 23, 2014
    Assignee: Tronox LLC
    Inventors: Venkata Rama Rao Goparaju, Michael L. Ashley
  • Publication number: 20140261086
    Abstract: A process for manufacturing titanium dioxide pigment is provided. The process comprises preparing an aqueous slurry of titanium dioxide particles. The process further includes deagglomerating the aqueous slurry of titanium dioxide particles using ultrasonication.
    Type: Application
    Filed: March 12, 2014
    Publication date: September 18, 2014
    Applicant: Tronox LLC
    Inventors: Venkata Rama Rao Goparaju, David F. Marshall, Vahid Kazerooni
  • Patent number: 8808447
    Abstract: The present invention relates to a pigment paint for an exterior material and to a method for manufacturing the same. The pigment paint comprises: a flake matrix, a first metal oxide layer coated on the upper portion of the transparent matrix, an oxide layer containing MgO—SiO2 coated on the upper portion of the first metal oxide layer, and a second metal oxide layer coated on the upper portion of the oxide layer. In order to ensure humidity resistance and weather resistance required for a lustrous pigment paint for exterior materials, a cerium layer and an aluminum oxide layer are further coated. Properties such as high luminance, high chromaticity, and high gloss, which could not be achieved using conventional techniques, can be achieved and a pigment paint having a multi-colored pearl luster can be provided.
    Type: Grant
    Filed: March 8, 2012
    Date of Patent: August 19, 2014
    Assignee: CQV Co., Ltd.
    Inventors: Jae-Il Jeong, Nam-Il Lee, Sang-Keun Park, Jin-Hyung Lee, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang
  • Publication number: 20140109796
    Abstract: The present invention relates to polyoxometalate-coated alumina trihydrate dispersants prepared by combining a polyaluminum chloride having certain characteristics with alumina trihydrate particles. Such dispersants are useful for forming cationic alumina trihydrate slurries, which can be mixed with titanium dioxide to produce stable cationic slurry blends useful in paper, paper-board, and paint (coatings) applications. The dispersants are also useful for preparing cationic titanium dioxide slurries.
    Type: Application
    Filed: October 22, 2013
    Publication date: April 24, 2014
    Inventor: Glenn R. Evers
  • Patent number: 8663380
    Abstract: A flame spray pyrolysis process for the preparation of ultrafine titania particles coated with a smooth, homogeneous coating of one or more metal oxides is provided. The metal oxide coating is achieved by contacting the titania particles with a metal oxide precursor downstream of the titania formation zone, after the titania particles have formed. The process provides titania particles with a high rutile content and a smooth and homogeneous coating of a metal oxide.
    Type: Grant
    Filed: November 16, 2007
    Date of Patent: March 4, 2014
    Assignee: Cristal USA Inc.
    Inventors: M. Kamal Akhtar, Sotiris Emmanuel Pratsinis, Martin Christian Heine, Alexandra Teleki Harsanyi, Reto Strobel
  • Patent number: 8647429
    Abstract: The present invention relates to effect pigments based on uncoated or coated flake-form substrates having an outer coating comprising a) TiO2 and b) Al2O3, MgO and/or CaO and c) SiO2 and d) ZnO and/or e) at least one mixed oxide of the elements mentioned under a) to d), and to the use thereof, inter alia in paints, coatings, printing inks, plastics and cosmetic formulations.
    Type: Grant
    Filed: February 2, 2011
    Date of Patent: February 11, 2014
    Assignee: Merck Patent GmbH
    Inventors: Sabine Melson, Volker Wilhelm, Ulrich Schoenefeld
  • Patent number: 8641870
    Abstract: The invention relates to a method for the surface treatment of a titanium dioxide with aluminum phosphate and hydrous aluminum oxide that leads to pigments with improved greying resistance, while simultaneously maintaining good brightness and opacity. The method is characterized in that phosphoric acid is initially added to a TiO2 suspension with a pH value of at least 8, in which context the pH value drops to 3 or below. An alkaline aluminum compound is subsequently added, in which context the pH rises to at least 5, after which an acid aluminum compound is added, as a result of which a pH value of 4.5 to 7 is obtained. The pigment manufactured by the method according to the invention is eminently suitable for use in decorative laminating paper.
    Type: Grant
    Filed: March 26, 2012
    Date of Patent: February 4, 2014
    Assignee: Kronos International, Inc.
    Inventors: Volker Jurgens, Janine Siekman, Siegfried Blumel, Alexander Breyder, Volker Schmitt
  • Publication number: 20140000483
    Abstract: The invention relates to a method for the surface treatment of inorganic pigment particles with agglomerates of fine primary particles or single crystals of inorganic compounds, particularly of oxides or sulphates. The method is characterized in that the inorganic compounds are first precipitated from an aqueous solution under suitable pH conditions in a separate vessel in the form of fluffily structured agglomerates and/or single crystals. The precipitation product is subsequently added to an aqueous suspension of inorganic pigment particles. The method is particularly suitable for the surface treatment of titanium dioxide particles, in order to achieve high hiding power or high opacity when used in emulsion paints or laminates.
    Type: Application
    Filed: June 28, 2013
    Publication date: January 2, 2014
    Applicant: Kronos International, Inc.
    Inventors: Volker Juergens, Alexander Breyder, Frank Mersch, Siegfried Bluemel, Volker Schmitt
  • Patent number: 8475582
    Abstract: The present invention relates to a process for making a titanium dioxide pigment consisting of titanium dioxide and single layer of inorganic surface treatment consisting of aluminum phosphate wherein the pigment is characterized by and isoelectric point which is greater than pH 6 and a negative zeta potential of at a pH of 7.5 or more.
    Type: Grant
    Filed: March 6, 2008
    Date of Patent: July 2, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Erik Shepard Thiele, John Davis Bolt, Scott Richard Mehr
  • Publication number: 20130118380
    Abstract: A system of N?3 interference pigments, which is distinguished in that it exhibits a maximum color gamut through specification of the optimum pigment hue angle hu?v?i (i=1 to N) in the CIELUV system.
    Type: Application
    Filed: August 9, 2012
    Publication date: May 16, 2013
    Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNG
    Inventors: Michael ROESLER, Adalbert HUBER
  • Publication number: 20130074734
    Abstract: The invention relates to a method for the surface modification of titanium dioxide pigment and to its use, particularly in coatings, for interior and exterior walls (emulsion paints) and in water-borne paint systems. The method for surface modification is based on a titanium dioxide pigment that has been provided with a fluffily structured surface coating and where the fluffily structure of the surface coating is at least partially compacted, preferably by exposing the pigment particles to high shear and impact forces. The pigment particles are preferably coated with silicon oxide and/or aluminium oxide. The method according to the invention preferably reduces the specific surface area (BET) by roughly 30%. The pigment according to the invention can be used to optimise the rheological properties and the open time of the paint.
    Type: Application
    Filed: September 20, 2012
    Publication date: March 28, 2013
    Inventors: Uwe Wilkenhoner, Jurgen Bender
  • Patent number: 8377194
    Abstract: A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF.B. M comprises at least one metal or metalloid cation S is a sulfur-based species. F optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5. B is a hygroscopic solid at a water to solid molar ratio of 0.1-6 and preferably comprises at least one alkaline earth oxide or lanthanide oxide.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: February 19, 2013
    Assignee: Nalco Company
    Inventors: Nicholas S. Ergang, Ian Saratovsky, Hung-Ting Chen
  • Publication number: 20130035399
    Abstract: The subject matter of the present invention is marked inorganic additives, a method for their production and also their use.
    Type: Application
    Filed: September 21, 2012
    Publication date: February 7, 2013
    Applicant: SACHTLEBEN CHEMIE GMBH
    Inventor: SACHTLEBEN CHEMIE GMBH
  • Patent number: 8333835
    Abstract: A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF. M comprises at least one metal or metalloid cation S is a sulfur-based species optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: December 18, 2012
    Assignee: Nalco Company
    Inventors: Nicholas S. Ergang, Bruce A. Keiser, Richard Mimna
  • Publication number: 20120288715
    Abstract: TiO2 pigments in the anatase modification with increased light and weather resistance have the advantages of blue tint, low hardness and abrasiveness.
    Type: Application
    Filed: January 11, 2011
    Publication date: November 15, 2012
    Applicant: SACHTLEBEN CHEMIE GMBH
    Inventors: Wolf-Dieter Griebler, Ulrich Gesenhues
  • Publication number: 20120247702
    Abstract: The invention relates to a method for the surface treatment of a titanium dioxide with aluminium phosphate and hydrous aluminium oxide that leads to pigments with improved greying resistance, while simultaneously maintaining good brightness and opacity. The method is characterised in that phosphoric acid is initially added to a TiO2 suspension with a pH value of at least 8, in which context the pH value drops to 3 or below. An alkaline aluminium compound is subsequently added, in which context the pH rises to at least 5, after which an acid aluminium compound is added, as a result of which a pH value of 4.5 to 7 is obtained. The pigment manufactured by the method according to the invention is eminently suitable for use in decorative laminating paper.
    Type: Application
    Filed: March 26, 2012
    Publication date: October 4, 2012
    Inventors: Volker Jurgens, Janine Siekman, Siegfried Blumel, Alexander Breyder, Volker Schmitt
  • Patent number: 8273171
    Abstract: A pearlescent pigment (100) includes: a flaky substrate (10); a titanium dioxide layer (20) that is formed on the flaky substrate (10); and an oxazoline compound layer (40) that is formed on the titanium dioxide layer (20) with the titanium dioxide layer (20) being interposed between the flaky substrate (10) and the oxazoline compound layer (40), and serves as a top surface of the pearlescent pigment (100).
    Type: Grant
    Filed: August 29, 2007
    Date of Patent: September 25, 2012
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Takeaki Kitamura, Juichi Ino
  • Patent number: 8268069
    Abstract: The present invention relates to pearlescent pigments based on glass flakes which are distinguished by the fact that they have the following layer structure: A) optionally a layer of SiO2, B) a high-refractive-index coating have a refractive-index n>1.8 which essentially consists of TiO2, C) a low-refractive-index layer comprising SiO2 and/or Al2O3 and optionally D) an outer protective layer, and to the use thereof in paints, coatings, automobile paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tarpaulins, as absorbers in the laser marking of paper and plastics, as absorbers for the laser welding of plastics, in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, for the preparation of pigment compositions and dry preparations.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: September 18, 2012
    Assignee: Merck Patent GmbH
    Inventors: Sabine Melson, Marc Entenmann, Marita Jekel, Marcus Mathias
  • Patent number: 8197591
    Abstract: The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.
    Type: Grant
    Filed: February 23, 2007
    Date of Patent: June 12, 2012
    Assignee: Eckart GmbH
    Inventors: Günter Kaupp, Ulrich Schmidt
  • Publication number: 20120110921
    Abstract: The present invention relates to sintered abrasive grit agglomerates based on aluminum oxide, having homogeneously distributed nanoscale pores in the range of 100-300 nm, with a pore volume of at least 15%. The average diameter of primary particles of the aluminum oxide primary particles is less than 5 ?m, wherein said primary particles are connected to each other without additional adhesive agent.
    Type: Application
    Filed: July 21, 2009
    Publication date: May 10, 2012
    Applicant: Center for Abrasives and Refractories Research & Development C.A.R.R.D. GmbH
    Inventors: Maria Christina DiDavide, Reiner Kunz
  • Publication number: 20120034178
    Abstract: The present invention relates to novel pigment mixtures comprising at least two different particulate components A and B. The first component A comprises titanium suboxide(s), a titanium oxynitride or a titanium nitride species. Component B particle comprises inorganic, or organic pigments. The titanium suboxide particles display a bluish metallic luster, are new and form a further aspect of the present invention. When combined with particles from component B such as variously coated micas, for example, the bluish or bluish/black metallic color effect from component A leads to special color effects in the various mixtures.
    Type: Application
    Filed: October 21, 2011
    Publication date: February 9, 2012
    Inventors: Patrice Bujard, Philippe Bugnon, Marc Mamak, Urs Leo Stadler
  • Patent number: 8105432
    Abstract: The present invention relates to a TiO2 pigment coated sequentially in a wet treatment process with hydrous silica and hydrous alumina both in the presence of citric acid wherein the resulting pigment is coated with from 1 to 4% amorphous alumina based on the weight of the untreated TiO2; from 3 to 6% silica glass based on the weight of the untreated TiO2.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: January 31, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Charles Robert Bettler, Michael Patrick Diebold
  • Patent number: 8092586
    Abstract: Described herein is a photocatalytic composite comprising a titanium dioxide supported on metakaolin. In comparison to known embodiments of the sector, the composite of the present invention makes it possible to obtain binders and derived products with high photocatalytic efficiency, even when using photocatalyst quantities which are lesser than those present in products of prior technical art.
    Type: Grant
    Filed: December 17, 2008
    Date of Patent: January 10, 2012
    Assignee: Italcementi S.p.A.
    Inventors: Renato Ancora, Massimo Borsa, Luigi Cassar
  • Patent number: 8025726
    Abstract: A silica containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF: wherein M is at least one of the following metal or metalloid cations: boron, magnesium, aluminum, calcium, titanium, vanadium, manganese, iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, palladium, silver, cadmium, tin, platinum, gold, and bismuth; wherein S is a sulfur-based species selected from at least one of the following: sulfide salts, dithiocarbamates, polymer-based dithiocarbamates, and polysulfide salts; wherein F optionally exists and said F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of 0.01-100%; and wherein the molar ratio of y/x is equal to 0.01-0.5, the molar ratio of x/z is equal to 3-300, and the molar ratio of a/z is 1-5.
    Type: Grant
    Filed: April 8, 2010
    Date of Patent: September 27, 2011
    Assignee: Nalco Company
    Inventors: Bruce A. Keiser, Nicholas S. Ergang, Richard Mimna
  • Patent number: 7988780
    Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.
    Type: Grant
    Filed: July 26, 2010
    Date of Patent: August 2, 2011
    Assignee: Kronos International Inc
    Inventors: Siegfried Bluemel, Lydia Drews-Nicolai
  • Patent number: 7959727
    Abstract: The present invention relates to pigments, the particles of which generally have a length of from 2 ?m to 5 mm, a width of from 2 ?m to 2 mm, and a thickness of from 20 nm to 2 ?m, and a ratio of length to thickness of at least 2:1, wherein the particles contain a core of SiO2 or a silicon/silicon oxide obtained by heating SiOy flakes with 1.1?y?1.8 in an oxygen-free atmosphere at a temperature of at least 400° C., which core has a narrow distribution of particle sizes and two substantially parallel faces, the distance between which is the shortest axis of the core, and a material layer having a high index of refraction a metal oxide; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: June 14, 2011
    Assignee: BASF SE
    Inventors: Patrice Bujard, Holger Leybach
  • Patent number: 7951420
    Abstract: A method of preparing a pigment exhibiting a color-shifting effect, including at least heating mica powder suspension in water, adjusting the pH value of the mixture to between 2 and 9, adding a first inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 6 and 14, adding a second inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 2 and 9, adding a third inorganic salt solution, maintaining the pH value of the mixture constant, and stirring the mixture at constant temperature.
    Type: Grant
    Filed: September 26, 2009
    Date of Patent: May 31, 2011
    Inventors: Jiansheng Fu, Yiting Peng, Xiaohui Tian
  • Patent number: 7905953
    Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: March 15, 2011
    Assignee: Kronos International Inc
    Inventors: Siegfried Bluemel, Lydia Drews-Nicolai
  • Patent number: 7842131
    Abstract: The invention relates to a rutile titanium dioxide pigment for use in decorative laminating papers that yields higher opacity of the papers compared to the prior art, as well as a method for its manufacture. The pigment displays a surface coating that contains aluminum phosphate, aluminum oxide, silicon oxide and titanium oxide. The silicon oxide is precipitated in fluffy form. The coated particles display a BET value of at least 15 m2/g. The manufacturing method is characterized in that an aluminum and a phosphorus component are first added to a TiO2 suspension. Thereafter, an alkaline silicon component, an acid-reacting titanium component and, optionally, a further pH-regulating component are added, the pH value being set in the range from 4 to 9 in this context.
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: November 30, 2010
    Assignee: Kronos International Inc
    Inventors: Siegfried Blümel, Lydia Drews-Nicolai, Volker Jürgens, Volker Schmitt
  • Patent number: 7824486
    Abstract: The present disclosure relates to a process for making a decorative base paper for a paper laminate comprising impregnating a base paper with a pigment mixture of titanium dioxide and water wherein the titanium dioxide pigment is made by treating a mixture of titanium dioxide pigment and water with a source of phosphorus and a source of aluminum; drying the treated mixture to form a treated pigment, the treated pigment having surface hydroxyl groups; and removing a major proportion of the surface hydroxyl groups of the treated pigment. Preferably the surface hydroxyl groups are removed by thermal treatment, for example at temperatures ranging from 300° C. to 800° C. The source of phosphorus is typically phosphoric acid and the source of aluminum is typically sodium aluminate. The pigment can be characterized by an isoelectric point which is greater than pH 6 and a negative zeta potential of at least 20 mV at a pH of 7.5 or more and wherein the pigment has improved light fastness.
    Type: Grant
    Filed: September 27, 2005
    Date of Patent: November 2, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Erik Shepard Thiele
  • Publication number: 20100227181
    Abstract: A bright pigment 100 includes: a flaky substrate 10; a first layer 20 that is formed on the flaky substrate 10 and that contains one selected from the group consisting of titanium dioxide, silver and a silver alloy as its main component; and a second layer 30 that is formed so that the first layer 20 is interposed between the flaky substrate 10 and the second layer 30 and that contains the hydroxide or hydrated oxide of neodymium.
    Type: Application
    Filed: October 17, 2008
    Publication date: September 9, 2010
    Applicant: NIPPON SHEET GLASS COMPANY, LIMITED
    Inventor: Takeaki Kitamura
  • Publication number: 20100218703
    Abstract: The present invention relates to pigments comprising (A) a platelet-shaped substrate (S), (B) a coating comprising two different metal oxides having a difference in refractive index of at least 0.1, wherein the metal oxide having a higher refractive indexis the metal oxide MOH and the metal oxide having a lower refractive index is the metal oxide MOL, wherein the amount of MOH and the amount of MOL changes (continuously), (C) a coating comprising metal oxides MOH and MOL, wherein the amount of MOH and the amount of MOL changes (continuously), and (D) optionally an outer protecting layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass. The pigments can show enhanced colour chroma while maintaining the lightness of coventional interference pigments, or vice versa.
    Type: Application
    Filed: July 21, 2008
    Publication date: September 2, 2010
    Inventors: Patrice Bujard, Philippe Bugnon
  • Publication number: 20100189666
    Abstract: The present invention provides products comprising rutile-type titanium dioxide of a specific shape, i.e., cosmetics which have high UV blocking ability, provide a good feel upon use without leaving squeakiness or graininess on the skin, and also give a natural bare skin appearance without causing white masking, due to adequate tinting strength and covering power, as well as external additives for toner which are excellent in prevention of filming on a photosensitive member and inhibition of aggregation between toner particles.
    Type: Application
    Filed: January 26, 2010
    Publication date: July 29, 2010
    Applicant: TITAN KOGYO KABUSHIKI KAISHA
    Inventors: Akira NAKAMURA, Masayasu MORISHITA, Hiromasa KONDOH
  • Patent number: 7763110
    Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: July 27, 2010
    Assignee: Kronos International Inc
    Inventors: Siegfried Bluemel, Lydia Drews-Nicolai
  • Publication number: 20100119769
    Abstract: A bonding material for a honeycomb structure comprises inorganic particles in which D90/D10 is from 10 to 500, D10 is 100 ?m or less and D90 is 4 ?m or more, and the D10 and D90 are the values of 10% diameter and 90% diameter from a smaller particle diameter side, respectively, in volume-based integrated fractions of a particle diameter distribution measurement by a laser diffraction/scattering method.
    Type: Application
    Filed: January 15, 2010
    Publication date: May 13, 2010
    Applicant: NGK Insulators, Ltd.
    Inventors: Atsushi Watanabe, Suguru Kodama, Shuichi Ichikawa, Fumiharu Sato
  • Publication number: 20100112280
    Abstract: There is provided a coating material for a honeycomb structure, the coating material including inorganic particles or organic particles having D90/D10 of 5 to 50 with D10 of 50 ?m or less and D90 of 4 ?m or more (wherein D10 and D90 are values of 10% diameter and 90% diameter, respectively, in volume-based integrated fraction of a particle diameter distribution measured by a laser diffraction/scattering method from the smaller particle diameter side).
    Type: Application
    Filed: January 15, 2010
    Publication date: May 6, 2010
    Applicant: NGK Insulators, Ltd.
    Inventors: Masaki Iwamoto, Atsushi Watanabe, Shuichi Ichikawa
  • Patent number: 7686882
    Abstract: In various embodiments, methods and compositions are provided comprising titanium dioxide and silica spacers having improved light stability for use in paper, plastic and paints.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: March 30, 2010
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Duen-Wh Hua, Fu-Chu Wen