Aluminum Compound Or Silicon Containing Patents (Class 106/442)
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Patent number: 10662335Abstract: The invention relates to the manufacture of composite pigments containing aluminum hydroxide, and their use for improving the pigment light-scattering efficiency in coatings, plastics, paper and laminates. The composite pigment particles contain pigment particles such as titanium dioxide and precipitated aluminum hydroxide and are manufactured by in-situ precipitation of aluminum hydroxide in an aqueous pigment particle suspension. Use of the composite pigment particles according to the invention, based on titanium dioxide, permits savings on pigment with little or no loss of optical properties. Alternatively, if the pigment content remains unchanged, it is also possible to achieve better optical properties.Type: GrantFiled: March 10, 2016Date of Patent: May 26, 2020Inventors: Frank Mersch, Uwe Wilkenhoener
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Patent number: 10457812Abstract: Alpha-Alumina flakes having a particle thickness of 550-1000 nm, a D50-value of 15-30 ?m, a D90-value of 30-45 ?m and a D10-value of ?9.0 ?m. Use of the alumina flakes in varnishes, paints, automotive coatings printing inks, masterbatches, plastics and cosmetic formulations. Also, use of the alumina flakes as a substrate for effect pigments and in organic dyes.Type: GrantFiled: April 25, 2014Date of Patent: October 29, 2019Assignee: Merck Patent GmbHInventors: Ryuta Suzuki, Gerhard Pfaff, Sabine Schoen, Fumiko Sasaki, Satoru Kobayashi, Koshiro Kunii, Yuji Takenaka, Katsuhisa Nitta
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Patent number: 10259943Abstract: Disclosed is a method for manufacturing plate ?-alumina pearlescent pigments and nano-metal coating pearlescent pigments with a large aspect ratio, having excellent reflectivity and capable of expressing various colors.Type: GrantFiled: February 14, 2014Date of Patent: April 16, 2019Assignee: CQV CO., LTD.Inventors: Myung-Ho Jung, Kyung-Jun Han, Jae-Il Jeong, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang, Jae-Soo Choi, Beom-Jae Lee, Jung-Min Lee
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Patent number: 9551817Abstract: The present invention relates to composite polymeric particles for use as infrared reflectors in optical bandpass applications.Type: GrantFiled: December 16, 2010Date of Patent: January 24, 2017Assignee: ROHM AND HAAS COMPANYInventors: Edward Greer, Brian Einsla, Susan Fitzwater
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Patent number: 9512303Abstract: PLA-containing materials, and building components containing such materials, include: polylactic acid (PLA); one or more inorganic pigments; and one or more stabilizers that includes one or more carbodiimide groups.Type: GrantFiled: August 5, 2014Date of Patent: December 6, 2016Assignee: Andersen CorporationInventors: Michael Deaner, Patrick Gronlund, Larry Morelli, Stacha Reed
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Patent number: 9464200Abstract: A pigment for ink-jet recording contains a porous particle, a sealing agent, and an inorganic pigment layer containing an inorganic pigment. The sealing agent is arranged in a pore opening of the porous particle. The inorganic pigment layer is formed on the surface of the porous particle.Type: GrantFiled: February 26, 2015Date of Patent: October 11, 2016Assignee: Brother Kogyo Kabushiki KaishaInventors: Jun Sakai, Masayoshi Fuji, Chika Takai
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Patent number: 9096762Abstract: The invention relates to a method for the surface treatment of inorganic pigment particles with agglomerates of fine primary particles or single crystals of inorganic compounds, particularly of oxides or sulphates. The method is characterized in that the inorganic compounds are first precipitated from an aqueous solution under suitable pH conditions in a separate vessel in the form of fluffily structured agglomerates and/or single crystals. The precipitation product is subsequently added to an aqueous suspension of inorganic pigment particles. The method is particularly suitable for the surface treatment of titanium dioxide particles, in order to achieve high hiding power or high opacity when used in emulsion paints or laminates.Type: GrantFiled: August 1, 2014Date of Patent: August 4, 2015Assignee: Kronos International, Inc.Inventors: Volker Juergens, Alexander Breyder, Frank Mersch, Siegfried Bluemel, Volker Schmitt
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Patent number: 8932512Abstract: The present invention relates to polymers comprising absorption pigments, which are distinguished by the fact that they have high absorption in the near IR region, and to the use thereof, in particular in thermoforming and in IR light welding.Type: GrantFiled: July 26, 2006Date of Patent: January 13, 2015Assignee: Merck Patent GmbHInventors: Gerhard Edler, Rainer Linzmeier
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Publication number: 20140373753Abstract: The present invention relates to polyoxometalate-coated alumina trihydrate dispersants prepared by combining a polyaluminum chloride having certain characteristics with alumina trihydrate particles. Such dispersants are useful for forming cationic alumina trihydrate slurries, which can be mixed with titanium dioxide to produce stable cationic slurry blends useful in paper, paper-board, and paint (coatings) applications. The dispersants are also useful for preparing cationic titanium dioxide slurries.Type: ApplicationFiled: May 15, 2012Publication date: December 25, 2014Applicants: ALCLEAR LLC, ALCLEAR LLCInventors: Kenneth Cornick, Caryn Seidman-Becker
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Publication number: 20140338566Abstract: The invention relates to a method for the surface treatment of inorganic pigment particles with agglomerates of fine primary particles or single crystals of inorganic compounds, particularly of oxides or sulphates. The method is characterized in that the inorganic compounds are first precipitated from an aqueous solution under suitable pH conditions in a separate vessel in the form of fluffily structured agglomerates and/or single crystals. The precipitation product is subsequently added to an aqueous suspension of inorganic pigment particles. The method is particularly suitable for the surface treatment of titanium dioxide particles, in order to achieve high hiding power or high opacity when used in emulsion paints or laminates.Type: ApplicationFiled: August 1, 2014Publication date: November 20, 2014Applicant: Kronos International, Inc.Inventors: Volker Juergens, Alexander Breyder, Frank Mersch, Siegfried Bluemel, Volker Schmitt
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Patent number: 8876965Abstract: A composite comprising a silicate material, such as, a sodium aluminosilicate, and titanium dioxide disposed on the surface thereof is disclosed, together with formulations comprising the composite and methods for preparing the same.Type: GrantFiled: March 11, 2013Date of Patent: November 4, 2014Assignee: J.M. Huber CorporationInventors: Hilary Ellen Matthews, Ronald Louis Romer
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Patent number: 8858701Abstract: The invention relates to the manufacture of pigment-containing composite pigment particles containing titanium dioxide pigment particles and at least one inorganic and/or organic filler as extender, as well as calcium carbonate that is precipitated in the process, and their use for improving the pigment light-scattering efficiency in coatings, plastics and laminates. The extender is preferably selected from Ca-, Ca—Mg- and Mg-carbonates, natural and synthetic silicon dioxide and oxides and are manufactured in a combined process of precipitation and dispersion. Depending on the combination selected, the use of composite pigment particles according to the invention permits pigment savings with little or no loss of optical properties. Alternatively, if the pigment content remains unchanged, it is possible to achieve better values, e.g. for tinting strength. Particularly, a part or the whole TiO2 quantity in the user system can be replaced by the composite pigment particles according to the invention.Type: GrantFiled: June 28, 2013Date of Patent: October 14, 2014Assignee: Kronos International, Inc.Inventors: Uwe Wilkenhoener, Frank Mersch
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Patent number: 8845803Abstract: The invention relates to a method for the surface treatment of inorganic pigment particles with agglomerates of fine primary particles or single crystals of inorganic compounds, particularly of oxides or sulphates. The method is characterized in that the inorganic compounds are first precipitated from an aqueous solution under suitable pH conditions in a separate vessel in the form of fluffily structured agglomerates and/or single crystals. The precipitation product is subsequently added to an aqueous suspension of inorganic pigment particles. The method is particularly suitable for the surface treatment of titanium dioxide particles, in order to achieve high hiding power or high opacity when used in emulsion paints or laminates.Type: GrantFiled: June 28, 2013Date of Patent: September 30, 2014Assignee: Kronos International, Inc.Inventors: Volker Juergens, Alexander Breyder, Frank Mersch, Siegfried Bluemel, Volker Schmitt
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Patent number: 8840719Abstract: The invention provides a coated inorganic oxide pigment. The inventive coated inorganic oxide pigment comprises an inorganic oxide base pigment, a porous inorganic coating formed on the base pigment, and a dense inorganic coating formed on the base pigment. The porous inorganic coating and dense inorganic coating each consist essentially of a material selected from the group consisting of silica and alumina. In another aspect, the invention provides a method of manufacturing a coated inorganic oxide pigment. In yet another aspect, the invention provides a polymer composition comprising a base polymer, and a coated inorganic oxide pigment admixed with the base polymer.Type: GrantFiled: March 9, 2011Date of Patent: September 23, 2014Assignee: Tronox LLCInventors: Venkata Rama Rao Goparaju, Michael L. Ashley
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Publication number: 20140261086Abstract: A process for manufacturing titanium dioxide pigment is provided. The process comprises preparing an aqueous slurry of titanium dioxide particles. The process further includes deagglomerating the aqueous slurry of titanium dioxide particles using ultrasonication.Type: ApplicationFiled: March 12, 2014Publication date: September 18, 2014Applicant: Tronox LLCInventors: Venkata Rama Rao Goparaju, David F. Marshall, Vahid Kazerooni
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Patent number: 8808447Abstract: The present invention relates to a pigment paint for an exterior material and to a method for manufacturing the same. The pigment paint comprises: a flake matrix, a first metal oxide layer coated on the upper portion of the transparent matrix, an oxide layer containing MgO—SiO2 coated on the upper portion of the first metal oxide layer, and a second metal oxide layer coated on the upper portion of the oxide layer. In order to ensure humidity resistance and weather resistance required for a lustrous pigment paint for exterior materials, a cerium layer and an aluminum oxide layer are further coated. Properties such as high luminance, high chromaticity, and high gloss, which could not be achieved using conventional techniques, can be achieved and a pigment paint having a multi-colored pearl luster can be provided.Type: GrantFiled: March 8, 2012Date of Patent: August 19, 2014Assignee: CQV Co., Ltd.Inventors: Jae-Il Jeong, Nam-Il Lee, Sang-Keun Park, Jin-Hyung Lee, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang
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Publication number: 20140109796Abstract: The present invention relates to polyoxometalate-coated alumina trihydrate dispersants prepared by combining a polyaluminum chloride having certain characteristics with alumina trihydrate particles. Such dispersants are useful for forming cationic alumina trihydrate slurries, which can be mixed with titanium dioxide to produce stable cationic slurry blends useful in paper, paper-board, and paint (coatings) applications. The dispersants are also useful for preparing cationic titanium dioxide slurries.Type: ApplicationFiled: October 22, 2013Publication date: April 24, 2014Inventor: Glenn R. Evers
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Patent number: 8663380Abstract: A flame spray pyrolysis process for the preparation of ultrafine titania particles coated with a smooth, homogeneous coating of one or more metal oxides is provided. The metal oxide coating is achieved by contacting the titania particles with a metal oxide precursor downstream of the titania formation zone, after the titania particles have formed. The process provides titania particles with a high rutile content and a smooth and homogeneous coating of a metal oxide.Type: GrantFiled: November 16, 2007Date of Patent: March 4, 2014Assignee: Cristal USA Inc.Inventors: M. Kamal Akhtar, Sotiris Emmanuel Pratsinis, Martin Christian Heine, Alexandra Teleki Harsanyi, Reto Strobel
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Patent number: 8647429Abstract: The present invention relates to effect pigments based on uncoated or coated flake-form substrates having an outer coating comprising a) TiO2 and b) Al2O3, MgO and/or CaO and c) SiO2 and d) ZnO and/or e) at least one mixed oxide of the elements mentioned under a) to d), and to the use thereof, inter alia in paints, coatings, printing inks, plastics and cosmetic formulations.Type: GrantFiled: February 2, 2011Date of Patent: February 11, 2014Assignee: Merck Patent GmbHInventors: Sabine Melson, Volker Wilhelm, Ulrich Schoenefeld
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Patent number: 8641870Abstract: The invention relates to a method for the surface treatment of a titanium dioxide with aluminum phosphate and hydrous aluminum oxide that leads to pigments with improved greying resistance, while simultaneously maintaining good brightness and opacity. The method is characterized in that phosphoric acid is initially added to a TiO2 suspension with a pH value of at least 8, in which context the pH value drops to 3 or below. An alkaline aluminum compound is subsequently added, in which context the pH rises to at least 5, after which an acid aluminum compound is added, as a result of which a pH value of 4.5 to 7 is obtained. The pigment manufactured by the method according to the invention is eminently suitable for use in decorative laminating paper.Type: GrantFiled: March 26, 2012Date of Patent: February 4, 2014Assignee: Kronos International, Inc.Inventors: Volker Jurgens, Janine Siekman, Siegfried Blumel, Alexander Breyder, Volker Schmitt
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Publication number: 20140000483Abstract: The invention relates to a method for the surface treatment of inorganic pigment particles with agglomerates of fine primary particles or single crystals of inorganic compounds, particularly of oxides or sulphates. The method is characterized in that the inorganic compounds are first precipitated from an aqueous solution under suitable pH conditions in a separate vessel in the form of fluffily structured agglomerates and/or single crystals. The precipitation product is subsequently added to an aqueous suspension of inorganic pigment particles. The method is particularly suitable for the surface treatment of titanium dioxide particles, in order to achieve high hiding power or high opacity when used in emulsion paints or laminates.Type: ApplicationFiled: June 28, 2013Publication date: January 2, 2014Applicant: Kronos International, Inc.Inventors: Volker Juergens, Alexander Breyder, Frank Mersch, Siegfried Bluemel, Volker Schmitt
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Patent number: 8475582Abstract: The present invention relates to a process for making a titanium dioxide pigment consisting of titanium dioxide and single layer of inorganic surface treatment consisting of aluminum phosphate wherein the pigment is characterized by and isoelectric point which is greater than pH 6 and a negative zeta potential of at a pH of 7.5 or more.Type: GrantFiled: March 6, 2008Date of Patent: July 2, 2013Assignee: E I du Pont de Nemours and CompanyInventors: Erik Shepard Thiele, John Davis Bolt, Scott Richard Mehr
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Publication number: 20130118380Abstract: A system of N?3 interference pigments, which is distinguished in that it exhibits a maximum color gamut through specification of the optimum pigment hue angle hu?v?i (i=1 to N) in the CIELUV system.Type: ApplicationFiled: August 9, 2012Publication date: May 16, 2013Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNGInventors: Michael ROESLER, Adalbert HUBER
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Publication number: 20130074734Abstract: The invention relates to a method for the surface modification of titanium dioxide pigment and to its use, particularly in coatings, for interior and exterior walls (emulsion paints) and in water-borne paint systems. The method for surface modification is based on a titanium dioxide pigment that has been provided with a fluffily structured surface coating and where the fluffily structure of the surface coating is at least partially compacted, preferably by exposing the pigment particles to high shear and impact forces. The pigment particles are preferably coated with silicon oxide and/or aluminium oxide. The method according to the invention preferably reduces the specific surface area (BET) by roughly 30%. The pigment according to the invention can be used to optimise the rheological properties and the open time of the paint.Type: ApplicationFiled: September 20, 2012Publication date: March 28, 2013Inventors: Uwe Wilkenhoner, Jurgen Bender
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Patent number: 8377194Abstract: A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF.B. M comprises at least one metal or metalloid cation S is a sulfur-based species. F optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5. B is a hygroscopic solid at a water to solid molar ratio of 0.1-6 and preferably comprises at least one alkaline earth oxide or lanthanide oxide.Type: GrantFiled: September 23, 2011Date of Patent: February 19, 2013Assignee: Nalco CompanyInventors: Nicholas S. Ergang, Ian Saratovsky, Hung-Ting Chen
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Publication number: 20130035399Abstract: The subject matter of the present invention is marked inorganic additives, a method for their production and also their use.Type: ApplicationFiled: September 21, 2012Publication date: February 7, 2013Applicant: SACHTLEBEN CHEMIE GMBHInventor: SACHTLEBEN CHEMIE GMBH
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Patent number: 8333835Abstract: A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF. M comprises at least one metal or metalloid cation S is a sulfur-based species optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5.Type: GrantFiled: September 23, 2011Date of Patent: December 18, 2012Assignee: Nalco CompanyInventors: Nicholas S. Ergang, Bruce A. Keiser, Richard Mimna
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Publication number: 20120288715Abstract: TiO2 pigments in the anatase modification with increased light and weather resistance have the advantages of blue tint, low hardness and abrasiveness.Type: ApplicationFiled: January 11, 2011Publication date: November 15, 2012Applicant: SACHTLEBEN CHEMIE GMBHInventors: Wolf-Dieter Griebler, Ulrich Gesenhues
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Publication number: 20120247702Abstract: The invention relates to a method for the surface treatment of a titanium dioxide with aluminium phosphate and hydrous aluminium oxide that leads to pigments with improved greying resistance, while simultaneously maintaining good brightness and opacity. The method is characterised in that phosphoric acid is initially added to a TiO2 suspension with a pH value of at least 8, in which context the pH value drops to 3 or below. An alkaline aluminium compound is subsequently added, in which context the pH rises to at least 5, after which an acid aluminium compound is added, as a result of which a pH value of 4.5 to 7 is obtained. The pigment manufactured by the method according to the invention is eminently suitable for use in decorative laminating paper.Type: ApplicationFiled: March 26, 2012Publication date: October 4, 2012Inventors: Volker Jurgens, Janine Siekman, Siegfried Blumel, Alexander Breyder, Volker Schmitt
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Patent number: 8273171Abstract: A pearlescent pigment (100) includes: a flaky substrate (10); a titanium dioxide layer (20) that is formed on the flaky substrate (10); and an oxazoline compound layer (40) that is formed on the titanium dioxide layer (20) with the titanium dioxide layer (20) being interposed between the flaky substrate (10) and the oxazoline compound layer (40), and serves as a top surface of the pearlescent pigment (100).Type: GrantFiled: August 29, 2007Date of Patent: September 25, 2012Assignee: Nippon Sheet Glass Company, LimitedInventors: Takeaki Kitamura, Juichi Ino
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Patent number: 8268069Abstract: The present invention relates to pearlescent pigments based on glass flakes which are distinguished by the fact that they have the following layer structure: A) optionally a layer of SiO2, B) a high-refractive-index coating have a refractive-index n>1.8 which essentially consists of TiO2, C) a low-refractive-index layer comprising SiO2 and/or Al2O3 and optionally D) an outer protective layer, and to the use thereof in paints, coatings, automobile paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tarpaulins, as absorbers in the laser marking of paper and plastics, as absorbers for the laser welding of plastics, in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, for the preparation of pigment compositions and dry preparations.Type: GrantFiled: August 10, 2005Date of Patent: September 18, 2012Assignee: Merck Patent GmbHInventors: Sabine Melson, Marc Entenmann, Marita Jekel, Marcus Mathias
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Patent number: 8197591Abstract: The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.Type: GrantFiled: February 23, 2007Date of Patent: June 12, 2012Assignee: Eckart GmbHInventors: Günter Kaupp, Ulrich Schmidt
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Publication number: 20120110921Abstract: The present invention relates to sintered abrasive grit agglomerates based on aluminum oxide, having homogeneously distributed nanoscale pores in the range of 100-300 nm, with a pore volume of at least 15%. The average diameter of primary particles of the aluminum oxide primary particles is less than 5 ?m, wherein said primary particles are connected to each other without additional adhesive agent.Type: ApplicationFiled: July 21, 2009Publication date: May 10, 2012Applicant: Center for Abrasives and Refractories Research & Development C.A.R.R.D. GmbHInventors: Maria Christina DiDavide, Reiner Kunz
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Publication number: 20120034178Abstract: The present invention relates to novel pigment mixtures comprising at least two different particulate components A and B. The first component A comprises titanium suboxide(s), a titanium oxynitride or a titanium nitride species. Component B particle comprises inorganic, or organic pigments. The titanium suboxide particles display a bluish metallic luster, are new and form a further aspect of the present invention. When combined with particles from component B such as variously coated micas, for example, the bluish or bluish/black metallic color effect from component A leads to special color effects in the various mixtures.Type: ApplicationFiled: October 21, 2011Publication date: February 9, 2012Inventors: Patrice Bujard, Philippe Bugnon, Marc Mamak, Urs Leo Stadler
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Patent number: 8105432Abstract: The present invention relates to a TiO2 pigment coated sequentially in a wet treatment process with hydrous silica and hydrous alumina both in the presence of citric acid wherein the resulting pigment is coated with from 1 to 4% amorphous alumina based on the weight of the untreated TiO2; from 3 to 6% silica glass based on the weight of the untreated TiO2.Type: GrantFiled: September 28, 2007Date of Patent: January 31, 2012Assignee: E.I. du Pont de Nemours and CompanyInventors: Charles Robert Bettler, Michael Patrick Diebold
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Patent number: 8092586Abstract: Described herein is a photocatalytic composite comprising a titanium dioxide supported on metakaolin. In comparison to known embodiments of the sector, the composite of the present invention makes it possible to obtain binders and derived products with high photocatalytic efficiency, even when using photocatalyst quantities which are lesser than those present in products of prior technical art.Type: GrantFiled: December 17, 2008Date of Patent: January 10, 2012Assignee: Italcementi S.p.A.Inventors: Renato Ancora, Massimo Borsa, Luigi Cassar
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Patent number: 8025726Abstract: A silica containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF: wherein M is at least one of the following metal or metalloid cations: boron, magnesium, aluminum, calcium, titanium, vanadium, manganese, iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, palladium, silver, cadmium, tin, platinum, gold, and bismuth; wherein S is a sulfur-based species selected from at least one of the following: sulfide salts, dithiocarbamates, polymer-based dithiocarbamates, and polysulfide salts; wherein F optionally exists and said F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of 0.01-100%; and wherein the molar ratio of y/x is equal to 0.01-0.5, the molar ratio of x/z is equal to 3-300, and the molar ratio of a/z is 1-5.Type: GrantFiled: April 8, 2010Date of Patent: September 27, 2011Assignee: Nalco CompanyInventors: Bruce A. Keiser, Nicholas S. Ergang, Richard Mimna
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Patent number: 7988780Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.Type: GrantFiled: July 26, 2010Date of Patent: August 2, 2011Assignee: Kronos International IncInventors: Siegfried Bluemel, Lydia Drews-Nicolai
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Patent number: 7959727Abstract: The present invention relates to pigments, the particles of which generally have a length of from 2 ?m to 5 mm, a width of from 2 ?m to 2 mm, and a thickness of from 20 nm to 2 ?m, and a ratio of length to thickness of at least 2:1, wherein the particles contain a core of SiO2 or a silicon/silicon oxide obtained by heating SiOy flakes with 1.1?y?1.8 in an oxygen-free atmosphere at a temperature of at least 400° C., which core has a narrow distribution of particle sizes and two substantially parallel faces, the distance between which is the shortest axis of the core, and a material layer having a high index of refraction a metal oxide; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.Type: GrantFiled: February 26, 2009Date of Patent: June 14, 2011Assignee: BASF SEInventors: Patrice Bujard, Holger Leybach
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Patent number: 7951420Abstract: A method of preparing a pigment exhibiting a color-shifting effect, including at least heating mica powder suspension in water, adjusting the pH value of the mixture to between 2 and 9, adding a first inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 6 and 14, adding a second inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 2 and 9, adding a third inorganic salt solution, maintaining the pH value of the mixture constant, and stirring the mixture at constant temperature.Type: GrantFiled: September 26, 2009Date of Patent: May 31, 2011Inventors: Jiansheng Fu, Yiting Peng, Xiaohui Tian
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Patent number: 7905953Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.Type: GrantFiled: January 30, 2007Date of Patent: March 15, 2011Assignee: Kronos International IncInventors: Siegfried Bluemel, Lydia Drews-Nicolai
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Patent number: 7842131Abstract: The invention relates to a rutile titanium dioxide pigment for use in decorative laminating papers that yields higher opacity of the papers compared to the prior art, as well as a method for its manufacture. The pigment displays a surface coating that contains aluminum phosphate, aluminum oxide, silicon oxide and titanium oxide. The silicon oxide is precipitated in fluffy form. The coated particles display a BET value of at least 15 m2/g. The manufacturing method is characterized in that an aluminum and a phosphorus component are first added to a TiO2 suspension. Thereafter, an alkaline silicon component, an acid-reacting titanium component and, optionally, a further pH-regulating component are added, the pH value being set in the range from 4 to 9 in this context.Type: GrantFiled: January 30, 2007Date of Patent: November 30, 2010Assignee: Kronos International IncInventors: Siegfried Blümel, Lydia Drews-Nicolai, Volker Jürgens, Volker Schmitt
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Patent number: 7824486Abstract: The present disclosure relates to a process for making a decorative base paper for a paper laminate comprising impregnating a base paper with a pigment mixture of titanium dioxide and water wherein the titanium dioxide pigment is made by treating a mixture of titanium dioxide pigment and water with a source of phosphorus and a source of aluminum; drying the treated mixture to form a treated pigment, the treated pigment having surface hydroxyl groups; and removing a major proportion of the surface hydroxyl groups of the treated pigment. Preferably the surface hydroxyl groups are removed by thermal treatment, for example at temperatures ranging from 300° C. to 800° C. The source of phosphorus is typically phosphoric acid and the source of aluminum is typically sodium aluminate. The pigment can be characterized by an isoelectric point which is greater than pH 6 and a negative zeta potential of at least 20 mV at a pH of 7.5 or more and wherein the pigment has improved light fastness.Type: GrantFiled: September 27, 2005Date of Patent: November 2, 2010Assignee: E. I. du Pont de Nemours and CompanyInventor: Erik Shepard Thiele
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Publication number: 20100227181Abstract: A bright pigment 100 includes: a flaky substrate 10; a first layer 20 that is formed on the flaky substrate 10 and that contains one selected from the group consisting of titanium dioxide, silver and a silver alloy as its main component; and a second layer 30 that is formed so that the first layer 20 is interposed between the flaky substrate 10 and the second layer 30 and that contains the hydroxide or hydrated oxide of neodymium.Type: ApplicationFiled: October 17, 2008Publication date: September 9, 2010Applicant: NIPPON SHEET GLASS COMPANY, LIMITEDInventor: Takeaki Kitamura
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Publication number: 20100218703Abstract: The present invention relates to pigments comprising (A) a platelet-shaped substrate (S), (B) a coating comprising two different metal oxides having a difference in refractive index of at least 0.1, wherein the metal oxide having a higher refractive indexis the metal oxide MOH and the metal oxide having a lower refractive index is the metal oxide MOL, wherein the amount of MOH and the amount of MOL changes (continuously), (C) a coating comprising metal oxides MOH and MOL, wherein the amount of MOH and the amount of MOL changes (continuously), and (D) optionally an outer protecting layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass. The pigments can show enhanced colour chroma while maintaining the lightness of coventional interference pigments, or vice versa.Type: ApplicationFiled: July 21, 2008Publication date: September 2, 2010Inventors: Patrice Bujard, Philippe Bugnon
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Publication number: 20100189666Abstract: The present invention provides products comprising rutile-type titanium dioxide of a specific shape, i.e., cosmetics which have high UV blocking ability, provide a good feel upon use without leaving squeakiness or graininess on the skin, and also give a natural bare skin appearance without causing white masking, due to adequate tinting strength and covering power, as well as external additives for toner which are excellent in prevention of filming on a photosensitive member and inhibition of aggregation between toner particles.Type: ApplicationFiled: January 26, 2010Publication date: July 29, 2010Applicant: TITAN KOGYO KABUSHIKI KAISHAInventors: Akira NAKAMURA, Masayasu MORISHITA, Hiromasa KONDOH
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Patent number: 7763110Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.Type: GrantFiled: January 30, 2007Date of Patent: July 27, 2010Assignee: Kronos International IncInventors: Siegfried Bluemel, Lydia Drews-Nicolai
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Publication number: 20100119769Abstract: A bonding material for a honeycomb structure comprises inorganic particles in which D90/D10 is from 10 to 500, D10 is 100 ?m or less and D90 is 4 ?m or more, and the D10 and D90 are the values of 10% diameter and 90% diameter from a smaller particle diameter side, respectively, in volume-based integrated fractions of a particle diameter distribution measurement by a laser diffraction/scattering method.Type: ApplicationFiled: January 15, 2010Publication date: May 13, 2010Applicant: NGK Insulators, Ltd.Inventors: Atsushi Watanabe, Suguru Kodama, Shuichi Ichikawa, Fumiharu Sato
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Publication number: 20100112280Abstract: There is provided a coating material for a honeycomb structure, the coating material including inorganic particles or organic particles having D90/D10 of 5 to 50 with D10 of 50 ?m or less and D90 of 4 ?m or more (wherein D10 and D90 are values of 10% diameter and 90% diameter, respectively, in volume-based integrated fraction of a particle diameter distribution measured by a laser diffraction/scattering method from the smaller particle diameter side).Type: ApplicationFiled: January 15, 2010Publication date: May 6, 2010Applicant: NGK Insulators, Ltd.Inventors: Masaki Iwamoto, Atsushi Watanabe, Shuichi Ichikawa
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Patent number: 7686882Abstract: In various embodiments, methods and compositions are provided comprising titanium dioxide and silica spacers having improved light stability for use in paper, plastic and paints.Type: GrantFiled: September 7, 2007Date of Patent: March 30, 2010Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Duen-Wh Hua, Fu-Chu Wen