Phosphorus Containing Patents (Class 106/443)
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Patent number: 6576051Abstract: Composite particles and a method of preparing the composite particles are provided. The composite particles contain titanium dioxide particles with adsorbed two-phase polymer particles. The two-phase polymer particles have a soft polymer phase and a hard polymer phase in which the weight ratio of the hard polymer phase to the soft polymer phase is in the range of 10:1 to 1:5. The composite particles containing the two-phase polymer particles have improved aqueous stability and provide coatings with improved scrub resistance.Type: GrantFiled: November 14, 2001Date of Patent: June 10, 2003Assignee: Rohm and Haas CompanyInventors: James Keith Bardman, Ward Thomas Brown, Kenneth Michael Donnelly, Wei Zhang, Bernhard Helmut Lieser
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Patent number: 6576052Abstract: The titanium dioxide pigment of the present invention comprises titanium dioxide particles, the coating layer containing the aluminum phosphate compound and the coating layer containing the hydrolyzate of the organosilane compound, on the surface of the particles, in which a difference in water content between 100° C. and 300° C., determined by the Karl Fischer method, is not greater than 1500 ppm, and is thus excellent in light fastness, hydrophobicity and dispersibility. In particular, the titanium dioxide pigment of the invention is extremely advantageous as a colorant for plastics, which requires light fastness (resistance to discoloration) lacing resistance and dispersibility, to a high degree.Type: GrantFiled: March 12, 2002Date of Patent: June 10, 2003Assignee: Ishihara Sangyo Kaisha, Ltd.Inventors: Hideo Takahashi, Masaki Shimojo, Toshihiko Akamatsu
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Publication number: 20030031785Abstract: The use of surface-coated rutile modification TiO2 pigments having a primary particle grain size d50 of 0.1 to 1.0 &mgr;m as an anticorrosive white pigment, with firstly magnesium phosphate and secondly aluminum oxides and/or aluminum hydroxides being precipitated onto the TiO2 pigments, is described.Type: ApplicationFiled: June 14, 2002Publication date: February 13, 2003Inventors: Thomas Rentschler, Jochen Winkler
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Publication number: 20030024437Abstract: The present invention provides methods and compositions comprising inorganic solids for use as pigments in paints, papers and plastics.Type: ApplicationFiled: August 1, 2001Publication date: February 6, 2003Inventors: Fu-Chu Wen, Duen-Wu Hua, Deborah E. Busch
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Patent number: 6428615Abstract: Pigment preparations including as essential blending components A) an inorganic pigment from the group of the bismuth vanadate pigments and rutile pigments and B) a phosphate, are produced and used for coloring polymeric materials.Type: GrantFiled: June 19, 2000Date of Patent: August 6, 2002Assignee: BASF AktiengesellschaftInventors: Hansulrich Reisacher, Oliver Seeger
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Patent number: 6372036Abstract: The present invention relates to a pigment preparation containing a mixture of coated or uncoated Al2O3 flakes, and one or more special-effect pigments, and a phosphate derivative, and to the use thereof, especially in printing inks.Type: GrantFiled: December 23, 1999Date of Patent: April 16, 2002Assignee: Merck Patent Gesellschaft Beschraenkter HaftungInventors: Gerhard Pfaff, Sabine Schoen, Norio Takahashi
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Patent number: 6342099Abstract: The present invention provides a coated titanium dioxide pigment which includes a base titanium dioxide pigment; a first deposit of a phosphate compound contiguous with the base titanium dioxide pigment; a deposit of a silica or zirconia compound contiguous with the phosphate deposit; a second deposit of a phosphate compound contiguous with the silica or zirconia compound; and a deposit of an alumina compound contiguous with the second phosphate deposit. Titanium dioxide pigments of the present invention are easily dispersible, and display excellent durability and gloss.Type: GrantFiled: September 15, 2000Date of Patent: January 29, 2002Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Michael Hiew, Philip Chegwidden
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Patent number: 6254992Abstract: A support for recording sheet in which there is no film cracking, the occurrence of die-lip stripes is inhibited, and which has excellent image sharpness and has excellent light fading resistance. The support for recording sheet is provided with a substrate having an image printing side and another side opposite the image printing side, a water resistant resin coating layer provided on each side of the substrate, at least the resin coating layer provided on the image printing side containing a titanium dioxide pigment, the titanium dioxide pigment including a titanium dioxide having a particulate surface treated by a silane coupling agent and aluminum phosphate in an aqueous slurry state, with a treatment amount of the aluminum phosphate with respect to the titanium dioxide being from 0.05 wt % to 1.2 wt %.Type: GrantFiled: September 11, 2000Date of Patent: July 3, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Shinji Kato
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Patent number: 6221145Abstract: A process for producing water-based paint from a plurality of premixed compositions includes mixing at least two of a pigment composition, a dispersant thickening agent, a high resin content binder, and a low resin content binder. The pigment composition includes a pigment, water, a mixture of clay and silica, a viscosity controlling agent, and a dispersant thickener. The dispersant thickening agent includes a phosphate-based dispersant, water, a cellulosic thickener, and a coalescent.Type: GrantFiled: December 23, 1998Date of Patent: April 24, 2001Assignee: Coating Management Systems, Inc.Inventor: C. Daniel McClain
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Patent number: 6200375Abstract: The invention concerns a novel titania pigment useful for external painting. This pigment has a titania nucleus coated successively with a layer of zirconium hydroxide or oxyhydroxide, then a layer of titanium hydroxide or oxyhydroxide, then of a layer of co-precipitated phosphate and silica, and finally a layer of aluinium oxyhydroxide. The invention also concerns a method for preparing said pigment and its use in paints, plastics and laminated paper.Type: GrantFiled: July 26, 1999Date of Patent: March 13, 2001Assignee: Millennium Inorganic Chemicals, S.A.Inventors: Anny Guez, Caroline Steiner
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Patent number: 5980980Abstract: A ceramic composition for the repair of porous ceramic bodies comprises a ceramic material having cations which are reactive with phosphate ions, a source of reactive phosphate ions, and filler. An aqueous slurry of the ceramic composition is prepared and applied to the damaged region of a porous ceramic body. The slurry mixture is dried within the damaged region of the porous ceramic body and heated to bind the mixture together and to bond the mixture to the porous ceramic body within the damaged region. The method of the invention allows for the in situ repair of ceramic materials without removing them from their supporting structure and can be used in the repair of ceramic tiles for spacecraft and aircraft.Type: GrantFiled: October 29, 1997Date of Patent: November 9, 1999Assignee: McDonnell Douglas CorporationInventors: Robert A. DiChiara, Jr., Robert A. Jurf
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Patent number: 5976237Abstract: Improved coated inorganic pigments having a first coating of Al.sub.2 O.sub.3, SiO.sub.2, or optionally other oxide such as a source of P.sub.2 O.sub.5, or mixtures thereof, an optional coating of ZrO.sub.2, SnO.sub.2, TiO.sub.2, SiO.sub.2, CeO.sub.2 or mixtures thereof, and a final coating of Al.sub.2 O.sub.3 which exhibit good durability, dispersibility, and optical properties in plastic or paint compositions are disclosed. Also disclosed is a process whereby an aqueous slurry of an inorganic pigment is milled to achieve a particular particle size distribution, a first coating of Al.sub.2 O.sub.3, SiO.sub.2, or optionally other oxide such as a source of P.sub.2 O.sub.5, or mixtures thereof is precipitated onto the pigment material within a first pH range, an optional amount of ZrO.sub.2, SnO.sub.2, SiO.sub.2, TiO.sub.2, CeO.sub.2 or mixtures thereof is added to the aqueous slurry within a second pH range to obtain an optional coating over the first coating, and a final coating of Al.sub.2 O.sub.Type: GrantFiled: February 27, 1997Date of Patent: November 2, 1999Assignee: Kerr-McGee Chemical CorporationInventors: John E. Halko, Fran Tyler
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Patent number: 5958125Abstract: Goniochromatic luster pigments based on multiply coated, high refractive, nonmetallic, platelet-shaped substrates which are at least partially transparent to visible light, comprising at least one layer packet ofA) a colorless coating having a refractive index n.ltoreq.1.8 andB) a reflecting, selectively or nonselectively absorbing coating which is at least partially transparent to visible light,and also, if desired, additionallyC) an outer protective layer,and their use for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.Type: GrantFiled: July 5, 1996Date of Patent: September 28, 1999Inventors: Raimund Schmid, Norbert Mronga
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Patent number: 5942281Abstract: Process for the surface treatment of a titanium dioxide pigment, characterized in that it comprises the following steps:an aqueous suspension of titanium dioxide pigments is formed,in a first step, a layer of alumina phosphate is precipitated on the surface of the pigment,in a second step, a layer of alumina is precipitated over the first layer of alumina phosphate,the pigment is recovered from the suspension;and titanium dioxide pigment, characterized in that it comprises a titanium dioxide core coated successively with a layer of alumina phosphate, then with a layer of alumina and then with a layer of magnesium oxide.Type: GrantFiled: April 26, 1997Date of Patent: August 24, 1999Inventors: Anny Guez, Remy Lorang
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Patent number: 5922120Abstract: The present invention provides a process for producing titanium dioxide (TiO.sub.2) pigment having a coating comprising silica and a second oxide selected from the group consisting of oxides of boron, phosphorus, magnesium, niobium, germanium, and mixtures thereof, comprising the steps of (a) reacting titanium tetrachloride (TiCl.sub.4) in the vapor phase with an aluminum compound and an oxygen-containing gas in a reactor at a temperature in the range of about 900.degree. C. to about 1600.degree. C. to provide a gaseous suspension comprising TiO.sub.2 particles, (b) contacting the gaseous suspension comprising the TiO.sub.2 particles with a silicon halide and an oxide precursor of boron, phosphorus, magnesium, niobium, germanium, and mixtures thereof, and (c) cooling the gaseous suspension to produce TiO.sub.2 pigment having a coating comprising silica and a second oxide.Type: GrantFiled: December 23, 1997Date of Patent: July 13, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Narayanan Sankara Subramanian, Pratibha Laxman Gai, Russell Bertrum Diemer, Jr., Alvin Allen, John Steven Gergely
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Patent number: 5910213Abstract: A pigmentary material comprises particulate titanium dioxide the particles of which have been treated with a polymeric hindered amine stabiliser. The stabiliser is a polymer having a main chain substantially free of acidic groups and having hindered amine stabilising groups. The stabilising groups comprise at least 35 per cent by weight of the polymer. Preferably, the titanium dioxide particles are also treated with an organic compound such as a polyhydric alcohol, an alkanolamine, a polysiloxane or a fatty acid.Type: GrantFiled: July 31, 1997Date of Patent: June 8, 1999Assignee: Tioxide Group Services LimitedInventors: Steven Hugh Ashdown, Robert McIntyre, Neil Martin Richmond
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Patent number: 5851652Abstract: Rutile TiO.sub.2 pigment particles bearing coatings comprising:(a) an inner layer comprising about 0.05-1 percent by weight, based on the weight of the TiO.sub.2, of cerium radicals and about a stoichiometric amount of phosphate radicals, based on the amount of cesium radicals,(b) a second layer of about 0.1-4 percent by weight, based on the weight of the TiO.sub.2, of amorphous silica, and optionally(c) an outer layer of (1) about 0.5 to 8 percent by weight, based on the weight of the TiO.sub.2, of hydrous alumina or (2) hydrous alumina in the amount of about 0.5-8 percent, based on the weight of the TiO.sub.2, and associated therewith up to about a stoichiometric amount of phosphate radicals needed to form aluminum phosphate,the combined total weight of said coatings being about 2 to 12 percent by weight, based on the weight of the TiO.sub.2.Type: GrantFiled: August 22, 1996Date of Patent: December 22, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Howard W. Jacobson, Andrew A. Feng
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Patent number: 5840111Abstract: The present invention relates to nanodisperse titanium dioxide, to a process for the production thereof and to the use thereof.Type: GrantFiled: November 8, 1996Date of Patent: November 24, 1998Assignee: Bayer AGInventors: Gerhard Wiederhoft, Kai Butje, Peter-Joachim Barenthien, Michael Bodiger, Heinrich Alberts
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Patent number: 5824146Abstract: This invention relates to a new method for making a photodurable, aqueous titanium dioxide (TiO.sub.2) pigment slurry. This method involves reacting titanium tetrachloride, aluminum chloride and an oxygen-containing gas in the presence of a nucleant in the vapor phase to produce TiO.sub.2 pigment. A sufficient amount of aluminum chloride is added to provide at least 2 wt. % alumina in the TiO.sub.2 pigment. The TiO.sub.2 pigment is separated from the reaction gases; and mixed with sufficient water to produce a TiO.sub.2 slurry comprising at least 78 wt. % TiO.sub.2 solids. The slurry may be used in coating formulations such as paints.Type: GrantFiled: July 3, 1997Date of Patent: October 20, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Michael Warren Ott
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Patent number: 5824145Abstract: This invention relates to a new method for making a photodurable, aqueous titanium dioxide (TiO.sub.2) pigment slurry. The method involves mixing amorphous alumina, TiO.sub.2 pigment particles, water, and at least one dispersant to form the slurry. The initial slurry comprises at least about 78 wt. % TiO.sub.2 solids and at least about 3 wt. % alumina. The resulting slurry may be diluted to a lower TiO.sub.2 solids content and subsequently screened and media-milled. The titanium dioxide pigment slurry is suitable for use in coatings formulations such as paints.Type: GrantFiled: May 14, 1997Date of Patent: October 20, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Robert Elroy Marganski, Michael Warren Ott
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Patent number: 5792250Abstract: This invention relates to a process for the production of inorganically coated pigments and fillers and to the use thereof.Type: GrantFiled: June 3, 1997Date of Patent: August 11, 1998Assignee: Bayer AktiengesellschaftInventors: Rolf-Michael Braun, Jurgen Kischkewitz, Hilmar Rieck, Udo Holtmann
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Patent number: 5785748Abstract: A method for the manufacture of a titanium dioxide pigment comprises mixing a suspension of titanium dioxide with a reagent formed by reacting concentrated phosphoric acid with aluminium or an aluminium compound at elevated temperature and adding an alkaline compound to the suspension until a pH value of at least 3.5 is achieved. A novel pigment which can be prepared by the method of the invention comprises titanium dioxide, the particles of which have a surface coating of aluminium phosphate in which the molar ratio of aluminium to phosphorus lies in the range 1.8:1 to 1:1.4 Al:P. The pigments prepared according to the invention are useful in the preparation of paper laminates.Type: GrantFiled: June 27, 1996Date of Patent: July 28, 1998Assignee: Tioxide Group Services LimitedInventors: Jonathan Banford, Geoffrey Elliott Maud, Maria Leonida Demosthenous
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Patent number: 5776373Abstract: A product and process are disclosed that relate to electroconductive powders based on tantalum, niobium, or phosphorus or any combination thereof doped tin oxide and coatings containing such powders. These powders can be used for making transparent coated films that are conductive and have desirable properties for a number of end uses. Some important end uses are in static dissipative fiber and films, coatings for recyclable containers, materials involved in packaging, where the presence of certain heavy metals is undesirable, transparent conductive coatings, among other uses.Type: GrantFiled: March 6, 1996Date of Patent: July 7, 1998Assignee: E. I. Du Pont de Nemours and CompanyInventors: Oswald Robert Bergmann, Thomas Paul Feist, Jacob Hormadaly, Howard Wayne Jacobson
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Patent number: 5688314Abstract: A pearl pigment which is excellent in discoloration resistance and in affinity (dispersibility) with resins, a production method for the same, and a resin composition, paint and ink into which the above pearl pigment is incorporated. The pearl pigment comprises a flake substrate, titanium oxide coated on the surface thereof, and a phosphoric acid metal compound, or a phosphoric acid metal compound and a metal oxide coated on the surface of particles coated with titanium oxide.Type: GrantFiled: August 2, 1996Date of Patent: November 18, 1997Assignee: Merck Patent Gesellschaft Mit Beschrankter HaftungInventors: Atuko Nishimagi, Masahiko Yazawai, Katuhisa Nitta
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Patent number: 5665466Abstract: Process for the surface treatment of a titanium dioxide pigment, characterized in that it comprises the following steps:an aqueous suspension of titanium dioxide pigments is formed,in a first step, a layer of alumina phosphate is precipitated on the surface of the pigment,in a second step, a layer of alumina is precipitated over the first layer of alumina phosphate,the pigment is recovered from the suspension;and titanium dioxide pigment, characterized in that it comprises a titanium dioxide core coated successively with a layer of alumina phosphate, then with a layer of alumina and then with a layer of magnesium oxide.Type: GrantFiled: November 8, 1995Date of Patent: September 9, 1997Assignee: Rhone-Poulenc ChimieInventors: Anny Guez, Remy Lorang
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Patent number: 5650002Abstract: A TiO.sub.2 pigment particle having a surface coating of inorganic particles or mineral particles exhibiting improved light scattering efficiency of TiO.sub.2 at a moderate to high pigment volume concentration (PVC) and a low oil absorption when incorporated in coatings applications is disclosed, and methods of accomplishing the same.Type: GrantFiled: November 13, 1995Date of Patent: July 22, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: John Davis Bolt
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Patent number: 5571456Abstract: A product and process are disclosed that relate to electroconductive powders based on tantalum, niobium, or phosphorus or any combination thereof doped tin oxide and coatings containing such powders. These powders can be used for making transparent coated films that are conductive and have desirable properties for a number of end uses. Some important end uses are in static dissipative fiber and films, coatings for recyclable containers, materials involved in packaging, where the presence of certain heavy metals is undesirable, transparent conductive coatings, among other uses.Type: GrantFiled: April 24, 1995Date of Patent: November 5, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Oswald R. Bergmann, Thomas P. Feist, Jacob Hormadaly, Howard W. Jacobson
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Patent number: 5569412Abstract: A product and process are disclosed that relate to electroconductive powders based on tantalum, niobium, or phosphorus or any combination thereof doped tin oxide and coatings containing such powders. These powders can be used for making transparent coated films that are conductive and have desirable properties for a number of end uses. Some important end uses are in static dissipative fiber and films, coatings for recyclable containers, materials involved in packaging, where the presence of certain heavy metals is undesirable, transparent conductive coatings, among other uses.Type: GrantFiled: August 18, 1994Date of Patent: October 29, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Thomas P. Feist, Howard W. Jacobson
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Patent number: 5565144Abstract: A product and process are disclosed that relate to electroconductive powders based on tantalum niobium, or phosphorus or any combination thereof doped tin oxide and coatings containing such powders. These powders can be used for making transparent coated films that are conductive and have desirable properties for a number of end uses. Some important end uses are in static dissipative fiber and films, coatings for recyclable containers, materials involved in packaging, where the presence of certain heavy metals is undesirable, transparent conductive coatings, among other uses.Type: GrantFiled: April 24, 1995Date of Patent: October 15, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Thomas P. Feist, Jacob Hormadaly, Howard W. Jacobson
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Patent number: 5562990Abstract: Organosilicon treatment of TiO.sub.2 particles coated with alumina or alumina-silica having a fluoride compound or fluoride ions associated with them is disclosed to improve properties such as photostability and humidity resistance when incorporated in powder coatings and/or plastics.Type: GrantFiled: February 23, 1995Date of Patent: October 8, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Patricia A. Tooley, Philipp M. Niedenzu, Austin H. Reid, Jr.
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Patent number: 5330953Abstract: a process for the preparation of anatase titanium dioxide having a high surface area and suitable as a catalyst support is described.The process involves forming an aqueous dispersion of titanium dioxide at a pH less than 3 and preferably less than 1 and depositing a first coating of a hydrous oxide of an element which acts as a rutilisation inhibitor and a second coating of a phosphate on the particles of titanium dioxide.The product of the process has a high surface area which is retained on heating for long periods at high temperature.A novel product is particulate anatase titanium dioxide which has been coated with a rutile inhibitor and a phosphate, has a specific surface area of at least 50 m.sup.2 /g and retains at least 80% of its surface area after heating at 800.degree. C. for 7 days.Type: GrantFiled: April 26, 1993Date of Patent: July 19, 1994Assignee: Tioxide Specialties LimitedInventor: Dominic G. Meina
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Patent number: 5165995Abstract: The object of the invention is a process for coating a titanium dioxide pigment according to which a dispersion of titanium dioxide in water is formed, optionally in the presence of a dispersing agent, such as a water soluble silicate and/or an aminoalcohol, whereafter to the titanium dioxide pigment dispersion (1) an acidic hydrolysable titanium compound in an amount of 0.1 to 1.5% by weight calculated as TiO.sub.2, (2) a water soluble phosphate in an amount of 0.1 to 1.0% by weight calculated as P.sub.2 O.sub.5, (3) an acidic hydrolysable zirconium salt in an amount of 0.1 to 1.4% by weight calculated as ZrO.sub.2, is added, the slurry is made alkaline with a base, and (4) a water soluble hydrolysable alkaline aluminium compound is added in an amount of 0.5 to 5.5% by weight calculated as Al.sub.2 O.sub.3, whereby all the percentages by weight are calculated from the weight of the TiO.sub.Type: GrantFiled: June 26, 1990Date of Patent: November 24, 1992Assignee: Kemira OyInventor: Tuomo Losoi
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Patent number: 5114486Abstract: A new process for the production of pigments suitable for use in paper laminates has been developed in which a metal oxide is treated with a water-soluble salt of zinc and a phosphate or phosphoric acid and subsequently with an alkali metal aluminate in such a manner that there is deposited on the metal oxide a coating containing zinc and phosphate ions together with aluminium ions. The pH of the dispersion following the metal oxide is maintained at a value not exceeding 8.0 during precipitation. A particularly useful pigment is produced which has a coating containing zinc ions in an amount of 0.5 to 5% by weight as ZnO, phosphate ions in an amount of 0.2 to 3% as P.sub.2 O.sub.5 and aluminium ions in an amount of 0.5 to 5% expressed as Al.sub.2 O.sub.3 on the weight of TiO.sub.2.Type: GrantFiled: March 26, 1991Date of Patent: May 19, 1992Assignee: Tioxide Group PLCInventors: Maria Demosthenous, Francis Van Meyel
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Patent number: 5037478Abstract: Disclosed is a corrosion preventive pigment consisting essentially of(a) a phosphorus compound which generates phosphate ions in the presence of water and oxygen, selected from the group consisting of a phosphorous pentoxide, an orthophosphoric acid, a condensed phosphoric acid, and alkaline earth metal or transition metal phosphate, or an alkaline earth metal or transition metal condensed phosphate, and(b) a vanadium compound which generates a vanadate ion in the presence of water and oxygen, selected from the group consisting of vanadium (V) oxide, a vanadyl compound, an alkaline earth metal or transition metal vanadate, a baked condensate of alkaline earth metal or transition metal vanadates, or a heterocondensate of alkaline earth metal or transition metal vanadates;and which has a pH value of from 5 to 9.Type: GrantFiled: July 6, 1989Date of Patent: August 6, 1991Assignee: Nippon Paint Co., Ltd.Inventors: Toshihiro Okai, Yoshiaki Okumura, Mitsuyuki Oda, Takashi Yamamoto, Masahiro Jinnouti
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Patent number: 4929381Abstract: A novel anion exchange material comprising substantially crystalline inorganic mixed metal hydroxides and mixed metal hydrated oxides exhibiting anion exchange properties at temperatures up to about 150.degree. C. and a method of preparing the same is disclosed. The anion exchanger composition is prepared by coprecipitating hydroxides or hydrated oxides of metal elements such as aluminum and titanium and then drying the mixed metal hydroxides or hydrated oxides.Type: GrantFiled: March 1, 1988Date of Patent: May 29, 1990Assignee: The Dow Chemical CompanyInventor: Howard W. Clark