Organic Material Containing Patents (Class 106/447)
-
Patent number: 6110266Abstract: The present invention relates to pigment preparations containing(a) at least one pigment having an average primary particle size of 0.1 to 50 nm selected from the group consisting of carbides, nitrides, borides, and silicides of the elements Ti, Zr, Hf, Si, Ge, and Sn,(b) at least one dispersant having a weight average molecular weight (M.sub.w) greater than 1000, and(c) water.The invention further relates to the use of such pigment preparations in inks for ink-jet printing.Type: GrantFiled: October 28, 1998Date of Patent: August 29, 2000Assignee: Bayer AktiengesellschaftInventors: Juan Gonzalez-Blanco, Werner Hoheisel, Peter Roger Nyssen, Dirk Pfutzenreuter
-
Patent number: 6107350Abstract: New gel conpositions which comprise a carbonaceous component attached to a gel component. Preferably, the corbonaceous component is selected from the group consisting of: carbon blacks, carbon fibers, activated carbons and graphitic carbons; and the gel component is selected from the group consisting of: metal oxide gels and polymeric gels. Also disclosed are new gel composition comprising: a gel component and a carbon black product having attached at least one organic group, the organic group comprising: a) at least one aromatic group, and b) at least one ionic group, at least one ionizable group, or a mixture of an ionic group and an ionizable group, wherein at least one aromatic group of the organic group is directly attached to the carbon black. Further disclosed are new gel compositon comprising: a gel component and a carbon black product having attached at least one organic group, the organic group comprising: a) at least one C.sub.1 -C.sub.Type: GrantFiled: August 8, 1997Date of Patent: August 22, 2000Assignee: Cabot CorporationInventors: Ralph Ulrich Boes, James A. Belmont, David J. Kaul, Douglas M. Smith, William C. Ackerman
-
Patent number: 6103360Abstract: A ceiling board coating composition includes water, a binder and a filler, said filler having large particles with an average particle size of a minimum of about 50 microns, medium particles with an average particle size in the range of from about 1.2 to about 30 microns, and small particles which have an average particle size in the range of from about 0.1 to about 1.0 microns.Type: GrantFiled: January 9, 1998Date of Patent: August 15, 2000Assignee: Armstrong World Industries, Inc.Inventors: Kenneth G. Caldwell, Raymond H. Fernando
-
Patent number: 6083308Abstract: Effective anti-corrosive pigments are obtained using basic or neutral to basic polyvalent metal organophosphonates. The anti-corrosive organophosphonate pigments may optionally contain a co-acidic substance such as silica. The organophosphonate pigments provide ant-corrosive protection comparable to traditional pigments while enabling the avoidance of heavy metals.Type: GrantFiled: February 24, 1998Date of Patent: July 4, 2000Inventor: Tim Fletcher
-
Patent number: 6068688Abstract: A modified particle is disclosed wherein a particle has an attached group having the formula: ##STR1## wherein Ar represents an aromatic group; R.sup.1 represents a bond, an arylene group, an alkylene ##STR2## wherein R.sup.4 is an alkyl or alkylene group or an aryl or arylene group; R.sup.2 and R.sup.3, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.5, --NHR.sup.5, --NR.sup.5 R.sup.5, or --SR.sup.5, wherein R.sup.5, which is the same or different, represents an alkyl group or an aryl group; and SFR represents a stable free radical. Also disclosed is a modified particle or aggregate having attached a group having the formula: ##STR3## wherein CoupA represents a Si-containing group, a Ti-containing group, or a Zr-containing group; R.sup.8 and R.sup.9, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.10, --NHR.sup.10, --NR.sup.10 R.sup.10, or --SR.sup.10, wherein R.sup.Type: GrantFiled: November 12, 1997Date of Patent: May 30, 2000Assignee: Cabot CorporationInventors: Robert S. Whitehouse, Russell L. Warley, Thimma R. Rawalpally, Hairuo Tu
-
Patent number: 6051060Abstract: A method for making coated pigment particles by forming a suspension of the desired pigment particles in a medium that also comprises a polymer characterized by having hydrophobic moieties on the polymer backbone and ionic moieties that are present on, or can be formed on a polymer side chain or at the polymer terminals; allowing the suspension of pigment particles to contact said polymer at a temperature above the softening point of the polymer, allowing the resultant suspension to cool to a temperature below the solidification temperature for the polymer while maintaining the pigment particles in suspension, and, if required, forming the ionic moieties.Type: GrantFiled: December 4, 1997Date of Patent: April 18, 2000Assignee: Marconi Data Systems, Inc.Inventor: Yoshikazu Mizobuchi
-
Patent number: 6022404Abstract: Surface-modified, pyrogenically produced mixed oxides which contain two or more components of the series SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2, ZrO.sub.2, Fe.sub.2 O.sub.3, Nb.sub.2 O.sub.5, V.sub.2 O.sub.5, WO.sub.3, SnO.sub.2, GeO.sub.2 and have been surface-modified with one to several compounds of the following groups:(a) organosilanes of the type (RO).sub.3 Si(C.sub.n H.sub.2n+1),(b) R'.sub.x (RO).sub.y Si(C.sub.n H.sub.2n+1),(c) X.sub.3 Si(C.sub.n H.sub.2n+1),(d) X.sub.2 (R')Si(C.sub.n H.sub.2n+1),(e) X(R').sub.2 Si(C.sub.n H.sub.2n+1),(f) (RO).sub.3 Si(CH.sub.2).sub.m --R',(g) (R").sub.x (RO).sub.y Si(CH.sub.2).sub.m --R',(h) X.sub.3 Si(CH.sub.2).sub.m --R',(i) (R)X.sub.2 Si(CH.sub.2).sub.m --R',(j) (R).sub.2 X Si(CH.sub.2).sub.m --R',(k) Silazanes of the type ##STR1## (l) Cyclic polysiloxanes, (m) Polysiloxanes or silicone oils.Type: GrantFiled: January 11, 1996Date of Patent: February 8, 2000Assignee: Degussa AktiengesellschaftInventors: Manfred Ettlinger, Werner Hartmann, Dieter Kerner, Jurgen Meyer
-
Patent number: 6019834Abstract: A pigment of the present invention comprises:pigment particle as core particle;a lower coat formed on at least a part of surface of the pigment particle, comprising squaric acid, polyol having an anthraquinone skeleton represented by the general formula (I): ##STR1## wherein m is an integer of 0 to 4, n is an integer of 0 to 4 and m+n is an integer of 2 to 4,or a mixture of the squaric acid and the polyol having an anthraquinone skeleton represented by the general formula (I); andan upper coat formed on at least a part of surface of the obtained particle, comprising at least one alkylene glycol represented by the general formula (II):C.sub.q H.sub.2q (OH).sub.2 (II)wherein q is an integer of 2 to 10.Such pigment has excellent dispersion facility, dispersion homogeneity and dispersion stability, and is suitably used for not only organic solvent-type paints but also water-based paints.Type: GrantFiled: March 5, 1998Date of Patent: February 1, 2000Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Mineko Ohsugi, Hiroko Morii, Mamoru Kamigaki
-
Patent number: 5964935Abstract: Initiator-treated pigment particles for use in making polymer coated pigment particles, are made up of a plurality of pigment particles. Each of the pigment particles has an outer surface that is covered with a coating of initiator material. The initiator material operates as a nucleus for initiating polymerization on the surface of the particle. The initiator-treated pigment particles are made by providing a plurality of pigment particles and applying a coating of initiator material to the outer surface of each pigment particle.Type: GrantFiled: August 22, 1997Date of Patent: October 12, 1999Assignee: Copytele, Inc.Inventors: Jing Hong Chen, Frederic E. Schubert
-
Patent number: 5961710Abstract: The invention relates to granules of inorganic pigments, a process for their production using several auxiliary substances by compacting and their use in many technical fields.Type: GrantFiled: February 12, 1998Date of Patent: October 5, 1999Assignee: Bayer AktiengesellschaftInventors: Gunter Linde, Manfred Eitel, Olaf Schmidt-Park, Kai Butje
-
Patent number: 5910213Abstract: A pigmentary material comprises particulate titanium dioxide the particles of which have been treated with a polymeric hindered amine stabiliser. The stabiliser is a polymer having a main chain substantially free of acidic groups and having hindered amine stabilising groups. The stabilising groups comprise at least 35 per cent by weight of the polymer. Preferably, the titanium dioxide particles are also treated with an organic compound such as a polyhydric alcohol, an alkanolamine, a polysiloxane or a fatty acid.Type: GrantFiled: July 31, 1997Date of Patent: June 8, 1999Assignee: Tioxide Group Services LimitedInventors: Steven Hugh Ashdown, Robert McIntyre, Neil Martin Richmond
-
Patent number: 5908498Abstract: A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.Type: GrantFiled: March 31, 1998Date of Patent: June 1, 1999Assignee: Kerr-McGee Chemical LLCInventors: James W. Kauffman, Phillip M. Story, John E. Halko
-
Patent number: 5882395Abstract: The present invention relates to a process for producing inorganic granules and to their use for the coloring of building materials, particularly concrete, asphalt, plaster, mortar and cement mortar, and for the production of paints for the protection of buildings.Type: GrantFiled: August 8, 1997Date of Patent: March 16, 1999Assignee: Bayer AktiengesellschaftInventors: Gunter Linde, Lothar Steiling
-
Patent number: 5873934Abstract: A surface-treating agent for use in an inorganic pigment in which a metallic oxide layer and/or a hydrated metallic oxide layer is formed on the surface of said pigment, characterized in that said surface-treating agent contains one or more compounds selected from the group consisting of (1) a polyglycidyl ether compound, (2) a polyglycidyl ester compound, and (3) a diglycidyl polysiloxane compound.Type: GrantFiled: December 9, 1996Date of Patent: February 23, 1999Assignee: Merck Patent Gesellschaft MIT Beschrankter HaftungInventors: Koshiro Kunii, Yoshifumi Horie
-
Patent number: 5855662Abstract: Aqueous pigment preparations comprisinga) 10 to 80% by weight, in particular 20 to 60% by weight, of a pigment,b) 0.1 to 20% by weight, in particular 0.1 to 15% by weight, of an oxyalkylation product which is obtained by addition of optionally substituted styrenes onto optionally substituted phenols and reaction with ethylene oxide and/or propylene oxide,c) 2 to 30% by weight of a polyether-polyol having a boiling point under normal pressure of greater than 150.degree. C. andd) if appropriate further additives, and water as the remainder,which are particularly suitable for pigmenting naturally occurring and synthetic materials, such as emulsion paints, emulsion coatings and emulsion printing inks, have been found.Type: GrantFiled: March 26, 1996Date of Patent: January 5, 1999Assignee: Bayer AktiengesellschaftInventors: Achim Brand, Josef Leitermann, Roger Nyssen, Klaus Schubert, Erhard Schuffenhauer, Karlheinz Wieser, Herbert Wigger
-
Patent number: 5853476Abstract: A method for coloring cementitious systems using compacted inorganic granules, wherein said compacted inorganic granules comprise an inorganic pigment and a dispersing agent. Particularly, a method for coloring cementitious systems using compacted inorganic granules; wherein said compacted inorganic granules are produced by a process consisting of: (a) mixing an inorganic pigment and a dispersing agent, (b) compacting the mixture, (c) milling the compacted mixture, and (d) classifying the compacted mixture into at least one oversize material stream, at least one undersize material stream and at least one product stream of compacted inorganic granules; and wherein the coloring effect of the compacted inorganic granules in the cementitious system equals or exceeds the powder standard.Type: GrantFiled: August 11, 1997Date of Patent: December 29, 1998Assignee: Elementis Pigments, Inc.Inventor: James T. Will
-
Patent number: 5849219Abstract: The invention relates to a stable aqueous dispersion of particles which can be flocculated by increasing the temperature to a value above the transition temperature. The invention is characterized in that the dispersion comprises a polymer selected from the group consisting of polyvinyl methyl ether and a block copolymer of polyvinyl methyl ether and a polyvinyl ether, the ether group bonded to the main chain via the oxygen atom being adsorbed onto the surface of the particles. The invention also relates to a block polymer of the above-mentioned type and to a method of manufacturing such a block copolymer. The invention enables very fine powders of ceramic particles having a very high homogeneity to be obtained.Type: GrantFiled: January 24, 1997Date of Patent: December 15, 1998Assignee: U.S. Philips CorporationInventors: Antonius W. M. De Laat, Hermannus F. M. Schoo
-
Patent number: 5840111Abstract: The present invention relates to nanodisperse titanium dioxide, to a process for the production thereof and to the use thereof.Type: GrantFiled: November 8, 1996Date of Patent: November 24, 1998Assignee: Bayer AGInventors: Gerhard Wiederhoft, Kai Butje, Peter-Joachim Barenthien, Michael Bodiger, Heinrich Alberts
-
Patent number: 5837049Abstract: A treated inorganic solid comprises particulate inorganic material the particles of which are coated with an alkylphosphonic acid or ester thereof, the alkylphosphonic acid containing 6 to 22 carbon atoms. The particulate material is usually a pigment, extender or filler which is treated by mixing with the alkylphosphonic acid or ester for example in an aqueous dispersion or during a process step such as milling. The treated inorganic solid is particularly useful for preparing polymer compositions such as masterbatches.Type: GrantFiled: October 23, 1997Date of Patent: November 17, 1998Assignee: Tioxide Group Services LimitedInventors: Colin Lloyd Watson, Peter James Allen
-
Patent number: 5837045Abstract: A surface-modified colored pigment is disclosed which includes a colored pigment having no primary amines and at least one attached hydrophilic organic group, wherein said organic group comprises a) at least one aromatic group, and b) at least one ionic group or ionizable group, or a mixture of an ionic group or an ionizable group. The colored pigment may be blue, brown, cyan, green, violet, magenta, red, orange, yellow, mixtures thereof and the like. The surface-modified colored pigment, due to the hydrophilic groups on its surface, is readily dispersed in a liquid vehicle without the addition of a surfactant or other dispersing aid or additive. The surface-modified color pigment may be used in a variety of aqueous systems including, but not limited to, coatings, paints, papers, adhesives, latexes, inks, toners, textiles and fibers. In addition, an aqueous composition is disclosed including water-based liquid vehicle and the surface-modified colored pigment described above.Type: GrantFiled: June 17, 1996Date of Patent: November 17, 1998Assignee: Cabot CorporationInventors: Joseph E. Johnson, James A. Belmont
-
Patent number: 5759256Abstract: A rutile mixed metal oxide pigment can be prepared by calcining a rutile ore with a transition metal oxide. The rutile mixed oxide pigment can be dispersed in an emulsion to produce a paint or coating or the pigment can be combined with a network former and network modifier to produce a ceramic glaze.Type: GrantFiled: May 24, 1996Date of Patent: June 2, 1998Assignee: Kerr-McGee Chemical Corp.Inventor: Rodney D. Stramel
-
Patent number: 5753024Abstract: Tin-containing grey pigments of high opacity, processes for their preparation and use thereof.Type: GrantFiled: June 19, 1996Date of Patent: May 19, 1998Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Reiner Vogt, Klaus Bernhard, Gerhard Pfaff, Matthias Kuntz, Susanne Rudolph, Sylvia Schmidt
-
Patent number: 5746819Abstract: The present invention discloses high solids slurries of sulfate process, anatase titanium dioxide pigment. The improvements of these slurries over those of the prior art are improved slurry stability, tolerance to calcium and magnesium ions, foaming tendencies and reduced tendency to flocculate. The slurries of the present invention are comprised of at least 65% by weight of anatase TiO.sub.Type: GrantFiled: November 14, 1995Date of Patent: May 5, 1998Assignee: SCM Chemicals, Inc.Inventors: Robert J. Kostelnik, Fu-Chu Wen
-
Patent number: 5733365Abstract: A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.Type: GrantFiled: February 18, 1997Date of Patent: March 31, 1998Assignee: Kerr-McGee CorporationInventors: John E. Halko, Phillip M. Story, James W. Kauffman, Kelly A. Green
-
Patent number: 5718907Abstract: Organophilic particles of a metal oxide chosen from alumina Al.sub.2 O.sub.3, silica SiO.sub.2, transition metal oxides, especially titanium oxide TiO.sub.2, and rare-earth metal oxides, especially cerium oxide CeO.sub.2, are prepared by reacting an aqueous-alcoholic suspension (a) of metal Oxide particles which have no pores less than 5 nm in di-meter at their surface with an anhydrous alcoholic solution (b) comprising at least one alkoxysilane of formula (1)Si(OR).sub.x R'.sub.4-x (1)in which R represents an alkyl group containing from 1 to 6 carbon atoms, R' represents a hydrocarbon group chosen from alkyl, cycloalkyl, aryl, alkylaryl, arylalkyl, alkenyl and alkynyl groups containing at least one carbon atom and x is an integer from 1 to 3, the said alcohols, which may be identical or different, containing from 1 to 5 carbon atoms.Type: GrantFiled: June 26, 1995Date of Patent: February 17, 1998Assignee: Rhone-Poulenc ChimieInventor: Dominique Labarre
-
Patent number: 5705033Abstract: Unique titanium dioxide (TiO.sub.2) particulates have an especially high physicochemical affinity for cellulosic fibers and, thus, are well suited as opacifying pigments for paper and paper laminates, and include a zeta potential-adjusting amount of at least one cationic polymer, e.g., a polymer of a quaternary ammonium, sulfonium or phosphonium salt or a copolymer of acrylamide with a cationic comonomer, fixed to the face surfaces thereof.Type: GrantFiled: December 30, 1992Date of Patent: January 6, 1998Assignee: Rhone-Poulenc ChimieInventors: Bernard Gerard, Remy Lorang, Anny Mazzacavallo
-
Patent number: 5683501Abstract: Compound fine particles include inorganic fine particles and an organic polymer bound to surfaces of the inorganic fine particles, and have an average particle diameter of 5 to 200 nm and a particle diameter variation coefficient of 50% or less. The compound fine particles are obtainable by hydrolyzing and condensing an organic polymer, wherein the organic polymer has, per molecule, at least one polysiloxane group containing at least one Si--OR.sup.1 group, wherein R.sup.1 denotes a hydrogen atom, an unsubstituted or substituted alkyl group, or an unsubstituted or substituted acyl group. A compound fine particle dispersion includes the compound fine particles and a dispersion medium. A composition for forming a film includes this dispersion.Type: GrantFiled: November 4, 1994Date of Patent: November 4, 1997Assignee: Nippon Shokubai Co., Ltd.Inventors: Daijo Tomihisa, Shigefumi Kuramoto, Satoshi Ishida, Tadahiro Yoneda, Masaya Yoshida, Ichiro Namura
-
Patent number: 5676748Abstract: A method for producing bulking and opacifying kaolin fillers for filling cellulosic products is disclosed. An aqueous slurry of anionically dispersed kaolin particles is formed at 1 to 30% solids. A low-molecular-weight cationic aggregating agent is then added to the dispersed slurry to selectively aggregate fine and ultra-fine particles. The resultant aggregates are of larger mean particle size than the feed material and contain little or no fine and ultra-fine or colloidal particles. The net charge present on the aggregated particles is lower than that of the feed material. The aggregated structure contains within it a labyrinth of internal voids or pores. These mineral aggregates are then of a suitable size and surface charge to be retained well in a fiber web, and provide added bulk and opacity to the cellulosic products.Type: GrantFiled: December 29, 1995Date of Patent: October 14, 1997Assignee: Columbia River CarbonatesInventor: Alan J. Brown
-
Patent number: 5676746Abstract: A process is provided for the selective aggregation of the fine and ultrafine particles present in an anionically or cationically dispersed mineral pigment slurry, such that an aggregated structure is formed which contains within it a labyrinth of internal voids or pores, which collectively function as light scattering centers. The aggregates are formed from an assemblage of fine mineral particles, interconnected or bonded together with small quantities of a cationic or anionic polymer or agent of low molecular weight. The resultant aggregates are of larger mean particle size than the feed material and contain little or no fine and colloidal particles. The net charge present on the aggregated particles is lower than that of the feed material. These mineral aggregates are then of a suitable size and surface charge to be retained well in a fiber web by a combination of filtration retention and adsorption retention, and provide added bulk and opacity to the finished sheet of paper.Type: GrantFiled: April 11, 1995Date of Patent: October 14, 1997Assignee: Columbia River CarbonatesInventor: Alan J. Brown
-
Patent number: 5676747Abstract: A method for producing structured calcium carbonate pigments for coating paper is disclosed. An aqueous slurry of anionically dispersed calcium carbonate particles is formed at 1 to 30 percent solids. A low-molecular-weight cationically charged aggregating agent is then added to the slurry to selectively aggregate fine and ultra-fine particles. The resultant aggregates are of larger mean particle size than the mixture of particles in the original slurry and contain little or no fine and colloidal particles. The net charge present on the aggregated particles is lower than that of the original mineral particles. The low solids suspension of the aggregated mineral particles is then dewatered, or increased in solids to form a slurry with a solids content greater than 60 percent by weight.Type: GrantFiled: December 29, 1995Date of Patent: October 14, 1997Assignee: Columbia River CarbonatesInventor: Alan J. Brown
-
Patent number: 5672201Abstract: A process for preparing a structured composite pigmentary material comprises forming a dispersion of uncoated particles of titanium dioxide at a pH value at which the particles have a surface charge and subjecting the dispersion to cross-flow filtration until the dispersion contains more than 50% by weight titanium dioxide. The concentrated dispersion is mixed with a dispersion of chemically distinct particles having a surface charge of opposite sign under conditions which ensure that the sign of the surface charge on either of the particulate materials is not reversed. In the resultant composite pigmentary material the titanium dioxide particles are held in association with the chemically distinct particles as a result of said surface charges.Type: GrantFiled: March 5, 1996Date of Patent: September 30, 1997Assignee: Tioxide Group Services LimitedInventors: Leslie Ainsley Simpson, Keith Robson, David Trevor Knight, Ronald Brown
-
Patent number: 5653795Abstract: A method is disclosed for producing bulking and opacifying pigments for filling paper by the selective aggregation of fine particles in an anionically or cationically dispersed slurry, such that an aggregated structure is formed which contains within it a labyrinth of internal voids or pores. The aqueous slurry is formed at one to thirty percent solids. A low molecular weight agent of opposite ionic charge is then added to the slurry to selectively aggregate the fine particles present. The resultant aggregates are of larger mean particle size than the feed material and contain little or no fine and colloidal particles. The net charge present on the aggregated particles is lower than that of the feed material.Type: GrantFiled: November 16, 1995Date of Patent: August 5, 1997Assignee: Columbia River CarbonatesInventor: Alan J. Brown
-
Patent number: 5646212Abstract: This invention relates to novel polymeric compounds, more particularly to novel block or graft copolymers which are useful in dispersing inorganic pigments, lakes and/or toners in organic medium, to methods for preparing such copolymers, and to surfactant compositions containing such polymers. The block or graft copolymers of the invention belong to the class in which one type of polymeric component is derived from an oil-soluble complex monocarboxylic acid and another component which is the residue of an alkyl glycol and/or a polyoxyalkylene compounds.Type: GrantFiled: September 2, 1994Date of Patent: July 8, 1997Assignee: ICI Americas Inc.Inventor: Peter Glynn Hibbert
-
Patent number: 5643974Abstract: A process for the production of a structured composite pigmentary material in the form of a dispersion comprises mixing an aqueous dispersion of inorganic pigmentary particles and an aqueous dispersion of polyvinyl chloride (PVC) particles. The inorganic pigment particles carry a positive surface charge and the PVC particles carry a negative surface charge and the particles in the composite are held in association as a result of these charges. The inorganic pigment particles and PVC particles are mixed in the presence of a surfactant system which provides both anionic and steric stabilisation.Type: GrantFiled: February 6, 1996Date of Patent: July 1, 1997Assignee: Tioxide Group Services LimitedInventors: Leslie Ainsley Simpson, Keith Robson, David Trevor Knight, Martin Alec Williamson
-
Patent number: 5630873Abstract: A delustering composition for acetyl cellulose fibers is described which contains 15 to 85% by weight TiO.sub.2, 15 to 85% by weight paraffin oil and 0.5 to 10% by weight dispersing agent. Furthermore, a method for producing the delustering composition and also the use thereof for delustering acetyl cellulose fibers is described. Finally, the use of the delustered acetyl cellulose fibers in the production of cigarette filters and textile products is described.Type: GrantFiled: March 1, 1996Date of Patent: May 20, 1997Assignee: Metallgesellschaft AktiengesellschaftInventors: Peter Weiser, Franz Meyers, Jorg Hocken, Heinrich Dumke
-
Patent number: 5599530Abstract: An organic pigment particle having chemically bonded to its surface an organometallic zirconium compound, cosmetic compositions containing the pigment particles, and a method for reducing the staining potential of organic pigments.Type: GrantFiled: December 16, 1994Date of Patent: February 4, 1997Assignee: Revlon Consumer Products CorporationInventors: Anjali A. Patil, Joseph F. Calello, Robert W. Sandewicz
-
Patent number: 5587011Abstract: This invention involves a method of optically whitening clay minerals to transform their natural yellow tint to increased whiteness. Generally, it has been found that clay materials having low cation exchange capability can be directly reacted with very small amounts of cationic dyes, the apparent whiteness of said clay minerals being substantially increased thereby.Type: GrantFiled: April 6, 1995Date of Patent: December 24, 1996Assignee: J. M. Huber CorporationInventors: Carl J. Marshall, Jr., Gary M. Freeman
-
Patent number: 5562990Abstract: Organosilicon treatment of TiO.sub.2 particles coated with alumina or alumina-silica having a fluoride compound or fluoride ions associated with them is disclosed to improve properties such as photostability and humidity resistance when incorporated in powder coatings and/or plastics.Type: GrantFiled: February 23, 1995Date of Patent: October 8, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Patricia A. Tooley, Philipp M. Niedenzu, Austin H. Reid, Jr.
-
Patent number: 5556641Abstract: A composition comprising colorant-containing particles having a coating comprising propylene glycol and a carrier component selected from the group consisting of carriers suitable for food, drug and cosmetic preparations and mixtures thereof.Type: GrantFiled: June 17, 1994Date of Patent: September 17, 1996Assignee: Whittaker, Clark & Daniels, Inc.Inventors: George C. Lambridis, Nathanial Goodwin
-
Patent number: 5505965Abstract: A composition comprising colorant-containing particles having a coating comprising propylene glycol and a carrier component selected from the group consisting of carriers suitable for food, drug and cosmetic preparations and mixtures thereof.Type: GrantFiled: December 6, 1994Date of Patent: April 9, 1996Assignee: Whittaker, Clark & Daniels, Inc.Inventors: George C. Lambridis, Nathanial Goodwin
-
Patent number: 5501732Abstract: Disclosed is an improved process for preparing a silanized TiO.sub.2 pigment by media milling.Type: GrantFiled: February 23, 1995Date of Patent: March 26, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Philipp M. Niedenzu, Scott M. Herkimer, Ronald L. Chaney
-
Patent number: 5486233Abstract: A pigment composition includes a pigment extender which optionally contains a pigment, and further includes a non-hydrogenated phospholipid material, such as non-hydrogenated lecithin, and a surface modifying agent. Suitable modifying agents are selected from fatty acids, fatty acid esters or fatty acid triglycerides, silicones and mixtures thereof.Type: GrantFiled: October 28, 1993Date of Patent: January 23, 1996Assignee: Western Mining Corporation LimitedInventors: Lance S. Mitchell, Mary Ann Nordhauser, Justin M. Willis
-
Patent number: 5484481Abstract: The present invention relates to a process for the coloration of building materials such as concrete or asphalt by granulated inorganic pigments.Type: GrantFiled: October 17, 1994Date of Patent: January 16, 1996Assignee: Bayer AGInventors: Gunter Linde, Manfred Eitel
-
Patent number: 5482640Abstract: Aqueous dispersions of PTFE and TiO.sub.2 stabilized from the effects of freeze/thaw cycles are disclosed, wherein the stabilizing agents are monohydric alcohols and monoamines having less than five carbon atoms.Type: GrantFiled: October 28, 1994Date of Patent: January 9, 1996Assignee: Consep, Inc.Inventor: Thomas H. Eberlein
-
Patent number: 5447561Abstract: Herein is disclosed a pigment-dispersed resin composition comprising (a) a surface modified pigment in respect of which a surface modifying mixture consisting of a titanium oligomer and an organic acid ester is coated uniformly on the surface of the pigment particles and (b) a resin, usable, e.g., as an ingredient of a paint or a printing ink.Type: GrantFiled: May 4, 1992Date of Patent: September 5, 1995Assignee: Kenrich Petrochemicals, Inc.Inventors: Naoki Chiba, Koichiro Sagawa, Takashi Zama
-
Patent number: 5439514Abstract: An ink is provided which contains a pigment and a dispersing agent in an aqueous medium, and further contains at least one fine particulate white inorganic material selected from fine particulate titanium dioxide, and fine particulate alumina. An ink-jet recording method and an ink-jet recording apparatus are also provided.Type: GrantFiled: March 30, 1994Date of Patent: August 8, 1995Assignee: Canon Kabushiki KaishaInventors: Akio Kashiwazaki, Yuko Suga, Aya Takaide
-
Patent number: 5401313Abstract: This invention relates to modifying the surface of particles for improved dispersion characteristics in aqueous, solvent, resinous, polymeric, cementitious or the like application systems. In particular, this invention relates to a pigment or filler particle whose surface is coated with at least one electric charge modifying agent and at least one dispersion promoting agent, which has improved dispersibility, coloring, handling, and other processing properties in application systems. The electric charge modifying agent may be selected from the group of Mg, Ca, Ba, Sr, Ti, V, Zr, Cr, Mn, Fe, Co, Ni, Cu, Zn, and Al. The dispersion promoting agent may be selected from the group of stearates, acetates, alkylphenols, cellulosics, waxes, lignins, polyacrylics, polyepoxies, polyurethanes, polyethylenes, polystyrenes and polypropylenes, and polymers having functional groups of alcohols, glycols, aldehydes, amides and carboxylic acids. Iron oxide is the preferred pigment particle.Type: GrantFiled: February 10, 1993Date of Patent: March 28, 1995Assignee: Harcros Pigments, Inc.Inventors: William W. Supplee, James T. Will, Jr.
-
Patent number: 5397391Abstract: A pigment composition of improved dispersibility in thermoplastic resins and concentrates of the pigment composition in thermoplastic resin are provided. The pigment composition is comprised of an inorganic pigment such as titanium dioxide having an organophosphate ester treating agent deposited thereon.Type: GrantFiled: April 4, 1994Date of Patent: March 14, 1995Assignee: Kerr-McGee Chemical CorporationInventor: Rodney D. Stramel
-
Patent number: 5380359Abstract: A melanin-coated pigment obtained by coating a carrier with a readily alkali-soluble natural melanin, and a cosmetic containing the pigment are provided. The melanin-coated pigment is highly safe and has high coloring and high saturation tone, and a cosmetic which contains it is also expected to have ultraviolet-ray-absorbing and anti-oxidizing effects.Type: GrantFiled: November 24, 1993Date of Patent: January 10, 1995Assignee: Kyowa Hakko Kogyo Co., Ltd.Inventors: Shinkichi Honda, Yoichiro Takekoshi, Yoichiro Arai
-
Patent number: 5380361Abstract: A hydrophobic filler material for alkaline paper is disclosed. The filler material comprises finely divided particles of an inorganic material, a majority of particles having a surface all of which is substantially modified with a water soluble C.sub.12 -C.sub.22 fatty acid salt and a metal ion in an amount at least effective to complex all of the fatty acid salt present. An alkaline paper is disclosed. The alkaline paper comprises a hydrophobic filler material comprising finely divided inorganic material, a majority of particles having substantially all of their surface being modified with a water soluble C.sub.12 -C.sub.22 fatty acid salt. A method for improving sizing of alkaline paper is disclosed, comprising preparing a filler material and adding the same to cellulose fiber. The filler material is prepared by selecting finely divided particles of an inorganic material and substantially modifying all of the surface of a majority of the particles with a C.sub.12 -C.sub.Type: GrantFiled: March 12, 1993Date of Patent: January 10, 1995Assignee: Minerals Technologies, Inc.Inventor: Robert A. Gill