Organic Material Containing Patents (Class 106/447)
  • Patent number: 5348666
    Abstract: A method is disclosed for stabilizing glutaraldehyde in aqueous systems is disclosed. The method of the invention comprises the addition of an oxidizer to the aqueous system so as to prevent the undesired conversion of glutaraldehyde to non-biocidal products.
    Type: Grant
    Filed: March 31, 1993
    Date of Patent: September 20, 1994
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Lawrence A. Grab
  • Patent number: 5344489
    Abstract: A method of making synthetic color pigments comprises synthesizing monodispersed colloidal core particles by precipitation from a solution and applying dye material to the core particles either by adsorption directly into the core particles or by adsorption or incorporation into alumina fixation shells at the surfaces of the core particles. Additional functional shells may be applied to the dyed core particles for various reasons. The pigments are useful for the coloration of various media such as printing inks and paint compositions.
    Type: Grant
    Filed: November 15, 1991
    Date of Patent: September 6, 1994
    Assignee: Manfred R. Kuehnle
    Inventors: Egon Matijevic, Wan P. Hsu, Manfred R. Kuehnle
  • Patent number: 5338353
    Abstract: A method for the production of powder of fine inorganic particles excellent in dispersibility in various solvents from a slurry of said fine inorganic particles containing water, which method comprises preparing a slurry as a raw material by incorporating in said slurry at least one orgaic compound selected from the group consisting of (A) methanol and (B) organic compound capable of dissolving of dissolving water in an amount of not less than 1.0% by weight at 20.degree. C. and forming a two-component azeotropic mixture of water and organic compounds having a water content of not less than 4.0% by weight and converting said prepared slurry into powder by the use of a powderization apparatus comprising an externally heatable pipe one end of which serves as a slurry inlet and the other end of which serves as a device for separating the produced powder and a vapor held in a vacuum state and a powder and a powder collecting chamber connected to said separating device.
    Type: Grant
    Filed: October 20, 1992
    Date of Patent: August 16, 1994
    Assignee: Nippon Shokubai Kagaku Kogyo
    Inventors: Hiroyoshi Uchino, Tadahiro Yoneda
  • Patent number: 5326381
    Abstract: A trace amount of a polytetrafluoroethylene resin is incorporated with an abrasive pigment prior to or during the preparation of an aqueous pigment slurry or is applied to dry pigment to reduce the abrasivity of the pigment. The treated pigment can be employed in the manufacture of filled and coated paper.
    Type: Grant
    Filed: May 10, 1993
    Date of Patent: July 5, 1994
    Assignee: Engelhard Corporation
    Inventor: Joseph H. Z. Wu
  • Patent number: 5318625
    Abstract: A pigment composition of improved dispersibility in thermoplastic resins and concentrates of the pigment composition in thermoplastic resin are provided. The pigment composition is comprised of an inorganic pigment such as titanium dioxide having an organophosphate ester treating agent deposited thereon.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: June 7, 1994
    Assignee: Kerr-McGee Chemical Corporation
    Inventor: Rodney D. Stramel
  • Patent number: 5318624
    Abstract: A process for preparing a uniform aqueous dispersion of titanium dioxide, gelatin, polymer beads and other components of a reflective binder layer for a photographic paper is disclosed. The process comprises combining all the components without regard to the creation of aggregates and then passing the entire mixture through a media mill to form a uniform dispersion.
    Type: Grant
    Filed: September 4, 1992
    Date of Patent: June 7, 1994
    Assignee: Eastman Kodak Company
    Inventor: Douglas D. Corbin
  • Patent number: 5288320
    Abstract: Titanium dioxide carries an ester or a partial ester of an hydroxy compound containing 1 to 6 OH groups and an aliphatic saturated C.sub.10 to C.sub.22 monocarboxylic acid. The product is easily dispersible in plastics compositions, particularly masterbatches. The titanium dioxide can also be coated with one or more hydrous oxides.The product is prepared by milling the titanium dioxide in a fluid energy mill in the presence of the ester or partial ester.
    Type: Grant
    Filed: December 30, 1991
    Date of Patent: February 22, 1994
    Assignee: Tioxide Group Services Limited
    Inventor: Guy Decelles
  • Patent number: 5282898
    Abstract: The present invention provides a simple inexpensive means to decrease the abrasivity of abrasive pigments such as calcined kaolin and titania. In accordance with this invention, a trace of a nonionic and/or anionic surfactant is incorporated with abrasion pigment prior to or during the preparation of an aqueous pigment slurry or to dry pigment.
    Type: Grant
    Filed: June 12, 1992
    Date of Patent: February 1, 1994
    Assignee: Engelhard Corporation
    Inventor: Joseph H. Z. Wu
  • Patent number: 5282893
    Abstract: An ethanol type marking ink composition comprises ethanol as a main solvent, titanium oxide and a condensation product of urea and aliphatic aldehydes. The composition is less toxic and gives good fixability, weather resistance and fastness of drawing lines. The redispersing property of titanium oxide is good even after a long time storage.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: February 1, 1994
    Assignee: Mitsubishi Pencil Kabushiki Kaisha
    Inventor: Motohiro Komiya
  • Patent number: 5279662
    Abstract: Alkyl polyglycoside surfactants are effective dispersing agents for TiO.sub.2 in aqueous dispersions.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: January 18, 1994
    Assignee: Henkel Corporation
    Inventor: George A. Smith
  • Patent number: 5279664
    Abstract: A method for dispersing a comminuted solid in an aqueous medium is described. An aqueous dispersing agent is added to an aqueous medium in an amount sufficient to disperse the comminuted solid in the aqueous medium. The aqueous dispersing agent includes from about 10 wt. % to about 55 wt. % of an amine compound selected from the group consisting of alkanolamines, triethylamine and morpholine, from about 15 wt. % to about 35 wt. % of a base selected from the group consisting of sodium hydroxide and potassium hydroxide, and from about 0.1 wt. % to about 15 wt. % chelating agent.
    Type: Grant
    Filed: December 17, 1991
    Date of Patent: January 18, 1994
    Assignee: Angus Chemical Company
    Inventors: Glenn N. Robinson, Gregory E. McWright
  • Patent number: 5270076
    Abstract: A process for coating at least one cationically charged ketene dimer on titanium dioxide comprising grinding the titanium dioxide in acidic aqueous media in the presence of a cationically charged ketene dimer.
    Type: Grant
    Filed: April 11, 1991
    Date of Patent: December 14, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Glenn R. Evers
  • Patent number: 5264030
    Abstract: In order to provide a filler for degradable plastics which can simplify the stages for producing a degradable plastic, give effective plastic-degradability, and stabilize the quality of the plastic article, the filler is used as a carrier substance and effective biodegradable and/or photodegradable components are adsorbed on the surfaces of the filler particles via a surface treating agent.
    Type: Grant
    Filed: April 6, 1992
    Date of Patent: November 23, 1993
    Assignee: Nittetsu Mining Co., Ltd.
    Inventors: Katsuyuki Tanabe, Masaharu Umebayashi, Atsushi Ugomori, Seiji Asaba
  • Patent number: 5264033
    Abstract: Disclosed is a process for producing a titanium dioxide pigment used for a resin-coated paper type photographic support, comprising the following steps:(a) a step of adding at least one alkaline earth metal compound in an amount of 0.01-2.0% by weight in terms of a metal oxide based on the titanium dioxide before calcination step and(b) an acid-washing step of washing the titanium dioxide at acidic state after the calcination step and before a step of surface treatment with a hydrated metal oxide,and wherein particle size of the titanium dioxide pigment is 0.110-0.150 .mu.m shown by number-average diameter obtained by measuring the diameter in a certain direction using an electron microscope.A photographic support which comprises the above titanium dioxide pigment is also disclosed.Occurrence of die lip stain and microgrit are substantially restrained in this photographic support and a photographic material made of it shows improved image sharpness.
    Type: Grant
    Filed: June 13, 1991
    Date of Patent: November 23, 1993
    Assignees: Mitsubishi Paper Mills Ltd, Tohkem Products Corp.
    Inventors: Touru Noda, Akira Uno, Kazuyoshi Muraoka
  • Patent number: 5258071
    Abstract: Vitreous filler material for incorporation into a polymerizable matrix, including a filler material which is vitreous; a polymerization catalyst; and a fixing agent which is applied to at least a part of the surface of the filler material and which affixes the polymerization catalyst to the surface of the filler material. Fixing catalyst to the surface of the filler material prior to its being contacted with the polymerizable matrix material facilitates good distribution of the catalyst within the polymerizable matrix material, and advantageously allows rapid catalytic action and a reduction in the amount of catalyst required.
    Type: Grant
    Filed: June 16, 1992
    Date of Patent: November 2, 1993
    Assignee: Glaverbel
    Inventor: Pierre LaRoche
  • Patent number: 5232881
    Abstract: The present invention provides a simple inexpensive means to decrease the abrasivity of abrasive pigments such as calcined kaolin and titania. In accordance with this invention, a trace of a nonionic surfactant of the general formula ##STR1## is incorporated with abrasive pigment prior to or during the preparation of an aqueous pigment slurry or to dry pigment.
    Type: Grant
    Filed: November 3, 1992
    Date of Patent: August 3, 1993
    Assignee: Engelhard Corporation
    Inventor: Joseph H. Z. Wu
  • Patent number: 5190583
    Abstract: An aqueous coating composition is provided which reflects light, especially UV radiation, and can be colored as desired. It is prepared from a synthetic resin dispersion and inorganic pigments having a particle size ranging between 7 and 10 nm, with the exception of carbon black.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: March 2, 1993
    Assignee: Transfer-Electric Gesellschaft Fur
    Inventors: Tankred Menzel, Hermann Nickel
  • Patent number: 5152835
    Abstract: Novel titania-calcined kaolin composite pigments wherein structuring and adhesion of titania and calcined kaolin particles is achieved by use of a cationic polyelectrolyte. Methods for compositing titania and calcined kaolin pigments which feature the presence of at least one polyanionic dispersant (such as sodium polyacrylate, sodium silicate, sodium condensed phosphate or mixtures thereof) in the pigment slurry into which cationic polyelectrolyte is introduced and the use of strongly alkaline pH (e.g., above 9).
    Type: Grant
    Filed: May 8, 1991
    Date of Patent: October 6, 1992
    Assignee: Engelhard Corporation
    Inventor: Saad Nemeh
  • Patent number: 5116411
    Abstract: The addition of an organophosphato-titanate and an organophosphato-zirconate to printing ink improves the adhesivity of the ink to a variety of substrates. A concentrate of the two organo-metallic components may be added to a conventional ink or added to the ink formulation during the ink's initial preparation. In addition to improving adhesivity, the additives reduce drying time, permit more rapid processing, and minimize the need for solvent diluents.
    Type: Grant
    Filed: December 22, 1989
    Date of Patent: May 26, 1992
    Assignee: Topez Company
    Inventors: Michael W. O'Neill, Gerald Sugerman
  • Patent number: 5108508
    Abstract: Novel rutile mixed phase pigment microgranulates are disclosed which comprise hemispherical particles indented to form toroid-shaped beads. The microgranulates are free-flowing, non-dust forming, and are stable in handling.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: April 28, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jakob Rademachers, Hans-Ulrich Hofs, Dieter Rade
  • Patent number: 5082498
    Abstract: Solid pigment formulations containing from 70 to 97% by weight, based on the total weight of the formulation, of one or more pigments and also from 3 to 30% by weight, based on the total weight of the formulation, of at least one surfactant which is an adduct of ethylene oxide and optionally propylene oxide with ethylenediamine, the proportion of ethylene oxide being from 46 to 100% by weight, based on the total weight of ethylene oxide and propylene oxide in the adduct, and the adduct having an average molecular weight of from 5000 to 40,000, are useful for pigmenting printing ink and gloss paint compositions.
    Type: Grant
    Filed: May 29, 1990
    Date of Patent: January 21, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Kurtz, Karl Muench, Joachim Kranz, Horst Belde
  • Patent number: 5076846
    Abstract: An aqueous suspension of minerals and/or fillers and/or pigments having a solid content .gtoreq.60% by weight, the mineral or the filler or the pigment being dispersed with one or more dispersing agents, is characterized in that the dispersing agent contains one or more amphoteric polyelectrolytes and/or cationic polyelectrolytes and/or amphoteric cationoic polyelectrolytes and/or amphoteric anionic polyelectrolytes and/or partially neutralized anionic polyelectrolytes and/or partially neutralized amphoteric anionic polyelectrolytes, the filler and/or pigment and/or mineral particles carrying a charge neutral or positive to the outside.Furthermore is disclosed a process characterized in that a part of the polyelectrolytes according to the invention is added before the grinding, a part thereof may be added during the grinding and a part thereof may be added after the grinding. According to the invention grinding and dispersing is achieved in only one process step.
    Type: Grant
    Filed: June 6, 1990
    Date of Patent: December 31, 1991
    Assignee: Pluss-Staufer AG
    Inventors: Matthias Buri, Daniel Frey
  • Patent number: 5074917
    Abstract: Novel Pigmentary colorants, well adapted for the production of electrostatic developer powders and dentifrices, are comprised of coprecipitated/crystallized mineral oxide particulates and at least one dye. The at least one dye is at least partly physically confined within a matrix of the mineral oxide.
    Type: Grant
    Filed: March 29, 1989
    Date of Patent: December 24, 1991
    Assignee: Rhone-Poulenc Chimie
    Inventor: Jacques Persello
  • Patent number: 5021091
    Abstract: A hard coating composition comprising an organic silicon compound and inorganic submicron particles such as silica sol and antimony oxide sol is improved in curing properties and shelf stability by blending aluminum perchlorate as the curing catalyst.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: June 4, 1991
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mitsuhiko Takarada, Kazuharu Sato, Kenji Yamamoto, Shigeru Mori
  • Patent number: 5017231
    Abstract: A heat-resistant pigment can be produced by forming a dense and uniform coating on the surface of the pigment by contacting a hydrophilic pigment with a metal oxide in at least partly water-miscible solvent.
    Type: Grant
    Filed: January 3, 1990
    Date of Patent: May 21, 1991
    Assignee: Mitsubishi Kinzoku Kabushiki Kaisha
    Inventors: Akira Nishihara, Makoto Tsunashima
  • Patent number: 4999055
    Abstract: An improved inorganic pigment (e.g., TiO.sub.2), process for treating such pigment and polymer (e.g., polyethylene, polypropylene or polystyrene) incorporating such pigment wherein the inorganic pigment is coated with maleic, malonic, benzoic, fumaric, or phthalic acid or mixtures thereof. The coated pigments exhibit excellent resistance to polymer yellowing or discoloration and do not appear to degrade polymer properties.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: March 12, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Dwight A. Holtzen, Austin H. Reid, Jr.
  • Patent number: 4935502
    Abstract: When a diamine of the formula ##STR1## in which n is 1 to 4, is bis-diazotized and the resulting bis-diazo compound is coupled with 2 moles of one or more coupling components of the formula ##STR2## in which R.sup.1 is hydrogen, chlorine, bromine, methyl or methoxy and R.sup.2 is hydrogen or, if R.sup.1 is hydrogen, also methyl or ethyl, disazo compounds are obtained which are colorants. Due to their high fastness to light and to migration and their heat stability and dispersibility, these compounds are useful for pigmenting high molecular weight materials, especially polyolefins.
    Type: Grant
    Filed: August 22, 1989
    Date of Patent: June 19, 1990
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudolf Kuhne, Heinrich Hamal
  • Patent number: 4894092
    Abstract: A heat-resistant pigment can be produced by forming a dense and uniform coating on the surface of the pigment by contacting said pigment with a metal alkoxide diluted with a water-miscible or semi-water-miscible solvent.
    Type: Grant
    Filed: April 14, 1987
    Date of Patent: January 16, 1990
    Assignee: Mitsubishi Kinzoku Kabushiki Kaisha
    Inventors: Akira Nishihara, Makoto Tsunashima
  • Patent number: 4885034
    Abstract: In a process for producing a composite TiO.sub.2 pigment which contains a white inert extender, the neutralization is simplified and the need for washing processes is eliminated in that a metatitanic acid suspension, which contains free and combined sulfuric acid and has been purified for the removal of chromophoric elements, is neutralized by an addition of calcium oxide and/or barium oxide in quantities which are stoichiometric with respect to total sulfate, the calcium sulfate and/or barium sulfate is precipitated in an intimate mixture with the metatitanic acid, and the coprecipitate is separated and dried. The precipitated calcium sulfate and/or barium sulfate is contained in the coprecipitate in an amount from 1 to 25% by weight.
    Type: Grant
    Filed: August 24, 1987
    Date of Patent: December 5, 1989
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Wolfgang Kreth, Wolf-Dieter Griebler
  • Patent number: 4870164
    Abstract: Symmetrical and asymmetrical disazo compounds of the formula: ##STR1## wherein: the R.sup.1 's are identical or different and are hydrogen, chlorine, bromine, methyl or methoxy;the R.sup.2 's are hydrogen, or, if the R.sup.1 's are hydrogen, the R.sup.2 's are hydrogen, methyl or ethyl, the two R.sup.2 radicals being identical or different; andn is 1 to 4and mixtures of such compounds as colorants, especially for pigmenting high molecular weight organic material.
    Type: Grant
    Filed: January 28, 1985
    Date of Patent: September 26, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudolf Kuhne, Heinrich Hamal
  • Patent number: 4832944
    Abstract: Pigmented nail enamels in which the pigment is coated with an organo-polysiloxane exhibit greatly reduced settling and migration of the pigment.
    Type: Grant
    Filed: December 3, 1986
    Date of Patent: May 23, 1989
    Assignee: Revlon Inc.
    Inventors: Robert L. Socci, Anatoly A. Ismailer, Anthony Castrogiovanni
  • Patent number: 4775420
    Abstract: Complex pigment compositions for the coating of paper, comprising an aqueous phase, at least one pigment of mineral origin, a binding agent, optionally various customary additives, and a dispersing agent comprised of carboxyl-containing polymers which are water soluble and are converted to form salts. The polymers are obtained by known polymerization processes. The dispersing agent(a) has a specific viscosity (measured on the sodium salt) of between 0.25 and 2; and(b) is converted to the salt form to the extent of at least 60% by at least one salt-forming agent which has a polyvalent function.These complex pigment compositions have very low viscosities. They may also simultaneously contain diverse pigments, such as kaolin, titanium dioxode, and calcium carbonate, without suffering the usual increase in viscosity and the risk of setting.
    Type: Grant
    Filed: March 30, 1987
    Date of Patent: October 4, 1988
    Assignee: Coatex, S.A.
    Inventors: Olivier Gonnet, Jean Vallas
  • Patent number: 4769079
    Abstract: A water-insoluble pigment comprising a complex of an inorganic water-insoluble anion exchange material and a water-soluble dye is disclosed. The anion exchange material may be represented by the general formula:[M.sub.1-x.sup.a Q.sub.x.sup.a+1 O.sub.y (OH).sub.z ](A.sup.-1).sub.d (A.sup.-2).sub.e (A.sup.-3).sub.f (A.sup.-4).sub.g.nH.sub.2 Owherein M is a metal element or elements each with a positive valence of a; Q is a metal element or elements each with a positive valence of a+1; a is 2, 3, 4 or 5; A.sup.-1, A.sup.-2, A.sup.-3, and A.sup.-4 are each one or more exchangeable anions each having a negative valence of 1, 2, 3 and 4, respectively; x is 0<x.ltoreq.0.5; and n, y, z, d, e, f, and g are real numbers greater than or equal to zero and satisfy the following:2y+z=a0<d+2e+3f+4g.ltoreq.x0.ltoreq.n.ltoreq.10provided that when y=0, a is not equal to 2.
    Type: Grant
    Filed: June 20, 1986
    Date of Patent: September 6, 1988
    Assignee: The Dow Chemical Company
    Inventors: Howard W. Clark, Tracy E. Chapman, Ronald L. Yates
  • Patent number: 4762568
    Abstract: A pigment composition contains a pigment and a dispersant. The dispersant is a phosphoric ester compound represented by the following general formula: ##STR1## wherein at least one of the three Rs is a residuum of a polyester chain containing as principal bonds thereof ester bonds of a polycarboxylic acid and a polyalcohol.
    Type: Grant
    Filed: August 12, 1987
    Date of Patent: August 9, 1988
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Michiei Nakamura, Hitoshi Takeuchi, Tetsujiro Takahashi, Yoshitake Kori, Minoru Takizawa, Takamitsu Shinoda, Shojiro Horiguchi